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41. 发明申请

US20050101708A1 Flame-retardant thermoset compositions 审中-公开
标题翻译：阻燃热固性组合物
公开(公告)号：US20050101708A1
公开(公告)日：2005-05-12
申请号：US10669921
申请日：2003-09-24
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： C09K21/02 , C08K3/00 , C08K5/5313 , C08L101/00 , C09K21/04 , C09K21/12 , C09K21/14 , C08K5/49
CPC分类号： C08K5/5313 , C08K3/016 , C08L63/00 , C08L67/06
摘要： The invention relates to flame-retardant thermoset compositions which comprise, as flame retardant, at least one phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or polymers of these (component A) where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, and also comprise as component B at least one synthetic inorganic compound and/or a mineral product. The invention further relates to a process for preparing these flame-retardant thermoset compositions.
摘要翻译：本发明涉及阻燃热固性组合物，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些（组分A）的聚合物，其中 R 1，R 2，R 2相同或不同，为C 1 -C 6 -C 6 - 烷基，直链或支链，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; 并且x为1至4，并且还包含作为组分B的至少一种合成无机化合物和/或矿物产品。本发明还涉及制备这些阻燃热固性组合物的方法。

42. 发明申请

US20050101706A1 Granular flame-retardant compositon 有权
标题翻译：颗粒阻燃组合物
公开(公告)号：US20050101706A1
公开(公告)日：2005-05-12
申请号：US10656398
申请日：2003-09-05
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/12 , C08K5/3467 , C08K5/5313 , C08K5/5317 , C08L101/00 , C09K21/02 , C09K21/04 , C09K21/10 , C09K21/14 , C08K5/49
CPC分类号： C08K5/5313
摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.
摘要翻译：本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐，黑夜和/或混战。

43. 发明申请

US20050049339A1 Flame-retardant thermoset compositions 审中-公开
标题翻译：阻燃热固性组合物
公开(公告)号：US20050049339A1
公开(公告)日：2005-03-03
申请号：US10669973
申请日：2003-09-24
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： B29C43/02 , B29K101/10 , C08K5/3492 , C08K5/5313 , C08L101/00 , C08K5/49
CPC分类号： C08K5/34922 , C08K5/5313 , C08L67/06 , C08L63/00
摘要： The invention relates to flame-retardant thermoset compositions which comprise, as flame retardant, at least one phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or polymers of these where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, and also at least one synergistic component from the substance class of the organic or inorganic phosphorus compounds, and at least one synergistic component from the substance class of the nitrogen compounds. The invention further relates to a process for preparing these flame-retardant thermoset compositions.
摘要翻译：本发明涉及阻燃热固性组合物，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1， R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; 和x为1至4，以及来自有机或无机磷化合物的物质类别的至少一种协同组分，以及来自氮化合物的物质类别的至少一种协同组分。本发明还涉及制备这些阻燃热固性组合物的方法。

44. 发明申请

US20050014875A1 Flame retardant formulation 有权
标题翻译：阻燃配方
公开(公告)号：US20050014875A1
公开(公告)日：2005-01-20
申请号：US10890427
申请日：2004-07-13
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： C08K5/523 , C08K5/5313 , C08L101/00 , C09D5/18 , C09D7/12 , C09K21/12 , C09K21/14 , C08K5/53 , C08K3/32 , C09K21/00
CPC分类号： C08K5/523 , C08K5/5313 , C09K21/12
摘要： The invention relates to a novel flame retardant formulation for thermoplastic and thermoset polymers, containing, as flame retardant component A, from 90 to 99.9% by weight of phosphinate salt of the formula (I) and/or a diphosphinate salt of the formula (II) and/or polymers thereof where R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and, as component B, from 0 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 10% by weight of a liquid component.
摘要翻译：本发明涉及用于热塑性和热固性聚合物的新型阻燃剂配方，其包含作为阻燃组分A的90至99.9重量％的式（I）的次膦酸盐和/或式（II）的二亚膦酸盐）和/或其中R 1，R 2相同或不同且为C 1 -C 6 - 烷基，直链或支链和/或芳基的聚合物; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K; m为1〜4; n为1至4; x为1〜4，作为B成分，为0〜50重量％的含氮增效剂或磷/氮阻燃剂，作为C成分，为0.1〜10重量％的液态成分。

45. 发明申请

US20050004277A1 Halogen-containing flame retardant combination 审中-公开
标题翻译：含卤素阻燃剂组合
公开(公告)号：US20050004277A1
公开(公告)日：2005-01-06
申请号：US10840861
申请日：2004-05-07
申请人： Sebastian Hoerold , Susanne Knop , Martin Sicken
发明人： Sebastian Hoerold , Susanne Knop , Martin Sicken
IPC分类号： C09K21/14 , C08K5/02 , C08K5/03 , C08K5/5313 , C08L101/00 , C09K21/02 , C09K21/08 , C09K21/12 , C08K5/34 , C08K5/49 , C09K21/00
CPC分类号： C08K5/03 , C08K5/02 , C08K5/5313
摘要： The invention relates to a flame retardant combination which comprises, as component A, at least one phosphinic salt of the formula (I), and/or one diphosphinic salt of the formula (II), and/or polymers of these, where R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na; K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and also comprises at least one synergistic halogen-containing component as component B.
摘要翻译：本发明涉及阻燃剂组合，其包含作为组分A的至少一种式（I）的次膦酸盐和/或一种式（II）的二膦酸盐，和/或这些的聚合物，其中R 1， R 1，R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na; K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，并且还包含至少一种协同卤素组分作为组分B.

46. 发明授权

US09481831B2 Mixtures of flame protection means containing flame protection means and aluminium phosphites, method for production and use thereof 有权
标题翻译：包含火焰保护装置和亚磷酸铝的火焰保护装置的混合物，其生产和使用方法
公开(公告)号：US09481831B2
公开(公告)日：2016-11-01
申请号：US14362886
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C09K21/04 , C08K3/32 , C08K5/5313 , C09K21/12 , C09K21/10
CPC分类号： C09K21/04 , C08K3/32 , C08K5/5313 , C09K21/10 , C09K21/12
摘要： The invention relates to flame retardant mixtures comprising flame retardant and aluminum phosphites, to processes for preparation thereof and to the use thereof.
摘要翻译：本发明涉及包含阻燃剂和亚磷酸铝的阻燃剂混合物，其制备方法及其用途。

47. 发明申请

US20150018464A1 Mixed Alkali-Aluminum Phosphites, Method For Producing Same, And The Use Thereof 有权
标题翻译：混合碱 - 铝亚磷酸盐，生产方法及其用途
公开(公告)号：US20150018464A1
公开(公告)日：2015-01-15
申请号：US14362871
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C09K21/04 , C08K5/56 , C08K7/14 , C08K3/32
摘要： The invention relates to mixed alkali-aluminum phosphites of the formula (I) Al2.00Mz(HPO3)y(OH)vx(H2O)w (I) in which M represents alkali metal ions, z is 0.01 to 1.5, y is 2.63 to 3.5, v is 0 to 2, w is 0 to 4; to a process for preparation thereof and to the use thereof.
摘要翻译：本发明涉及式（I）Al2.00Mz（HPO3）y（OH）vx（H2O）w（I）的混合碱金属铝亚磷酸盐，其中M表示碱金属离子，z为0.01至1.5，y为2.63 至3.5，v为0至2，w为0至4; 涉及其制备方法及其用途。

48. 发明申请

US20140336325A1 Mixtures of Flame Protection Means Containing Flame Protection Means and Aluminium Phosphites, Method for Production and Use Thereof 有权
标题翻译：含有火焰保护装置和亚磷酸铝的火焰保护装置的混合物，其生产和使用方法
公开(公告)号：US20140336325A1
公开(公告)日：2014-11-13
申请号：US14362886
申请日：2012-11-28
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C09K21/04 , C08K5/5313 , C09K21/12 , C08K3/32
CPC分类号： C09K21/04 , C08K3/32 , C08K5/5313 , C09K21/10 , C09K21/12
摘要： The invention relates to flame retardant mixtures comprising flame retardant and aluminum phosphites, to processes for preparation thereof and to the use thereof.
摘要翻译：本发明涉及包含阻燃剂和亚磷酸铝的阻燃剂混合物，其制备方法及其用途。

49. 发明申请

US20130172457A1 Phosphorus-Containing Mixtures, Processes for Preparing Them and Use Thereof 审中-公开
标题翻译：含磷的混合物，其制备方法和用途
公开(公告)号：US20130172457A1
公开(公告)日：2013-07-04
申请号：US13822536
申请日：2011-09-13
申请人： Harald Bauer , Sebastian Hoerold , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Martin Sicken
IPC分类号： C07F9/30
CPC分类号： C07F9/303 , C07F9/383 , C07F9/48 , C08K5/5313 , C08L25/06 , C08L77/00
摘要： The invention provides phosphorus-containing mixtures comprising a) from 50 to 100 mol % of compounds of the formula (1) in which R1 and R2 are identical or different and are C6-C9-alkyl, b) 0 to 50 mol % of compounds of the formula (1) in which R1 is H and R2 is C6-C9-alkyl, c) 0 to 50 mol % of compounds of the formula (1) in which R1 is OH and R2 is C6-C9-alkyl, d) from 0 to 50 mol % of compounds of the formula (1) in which R1 is OH and R2 is H, and e) from 0 to 50 mol % of compounds of the formula (1) in which R1 is H and R2 is H, with the sum of a), b), c), d), and e) always being 100 mol %.
摘要翻译：本发明提供含磷混合物，其包含a）50-100摩尔％的式（1）化合物，其中R 1和R 2相同或不同，为C 6 -C 9 - 烷基，b）0至50摩尔％的化合物式（1）中R 1为H且R 2为C 6 -C 9 - 烷基，c）0至50摩尔％的式（1）化合物，其中R 1为OH且R 2为C 6 -C 9 - 烷基，d ）0至50mol％的式（1）化合物，其中R 1为OH且R 2为H，e）0至50mol％的式（1）化合物，其中R 1为H且R 2为 H，与a），b），c），d）和e）总和为100mol％。

50. 发明申请

US20130131239A1 Method for Producing Mixtures of Alkylphosphonous Acid Salts And Dialkylphosphinic Acid Salts 有权
标题翻译：制备烷基膦酸盐和二烷基次膦酸盐的混合物的方法
公开(公告)号：US20130131239A1
公开(公告)日：2013-05-23
申请号：US13643899
申请日：2011-04-20
申请人： Michael Hill , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Michael Hill , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/12
CPC分类号： C09K21/12 , C07F9/3808 , C07F9/4816
摘要： The invention relates to a method for producing mixtures of alkylphosphonous acid and dialkylphosphinic acid salts, characterised in that a) a phosphinic acid source (I) is reacted with olefins (II) in the presence of a catalyst A to obtain a mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or salts or esters thereof, and b) the thus obtained mixture of alkylphosphonous acid (III) and dialkylphosphinic acid (IV) or the salts or esters thereof is reacted with metal compounds of Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base to obtain the corresponding mixtures of alkylphosphonous acid salt (V) and dialkylphosphinic acid salt (VI) of said metals and/or a nitrogen compound, (V) (VI), wherein Y represents Mg, Ca, AI, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na; K and/or a nitrogen compound and n represents ¼, ⅓, ½, 1.
摘要翻译：本发明涉及烷基磷酸和二烷基次膦酸盐的混合物的制备方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（II）反应，得到烷基亚磷酸（III）和二烷基次膦酸（IV）或其盐或酯，和b）由此得到的烷基亚磷酸（III）和二烷基次膦酸（IV）或其盐或酯的混合物与Mg，Ca， Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化的氮碱，得到烷基亚磷酸盐（V）和二烷基次膦酸所述金属的酸性盐（VI）和/或氮化合物（V）（VI），其中Y表示Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr ，Mn，Li，Na; K和/或氮化合物，n表示¼，1/3，½，1。

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