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1. 发明授权

US07332534B2 Flame retardant formulation 有权
标题翻译：阻燃配方
公开(公告)号：US07332534B2
公开(公告)日：2008-02-19
申请号：US10890427
申请日：2004-07-13
申请人： Susanne Knop , Martin Sicken , Sebastien Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastien Hoerold
IPC分类号： C08K5/5313
CPC分类号： C08K5/523 , C08K5/5313 , C09K21/12
摘要： The invention relates to a novel flame retardant formulation for thermoplastic and thermoset polymers, containing, as flame retardant component A, from 90 to 99.9% by weight of phosphinate salt of the formula (I) and/or a diphosphinate salt of the formula (II) and/or polymers thereof where R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and, as component B, from 0 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 10% by weight of a liquid component.
摘要翻译：本发明涉及用于热塑性和热固性聚合物的新型阻燃剂配方，其包含作为阻燃组分A的90至99.9重量％的式（I）的次膦酸盐和/或式（II）的二亚膦酸盐）和/或其中R 1，R 2和R 2相同或不同且各自为C 1 -C 6的聚合物，直链或支链的烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K; m为1〜4; n为1至4; x为1〜4，作为B成分，为0〜50重量％的含氮增效剂或磷/氮阻燃剂，作为C成分，为0.1〜10重量％的液态成分。

2. 发明申请

US20050004278A1 Flame-retardant thermoset compositions, their use and process for their preparation 审中-公开
标题翻译：阻燃热固性组合物，其用途及其制备方法
公开(公告)号：US20050004278A1
公开(公告)日：2005-01-06
申请号：US10840972
申请日：2004-05-07
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： C09K21/14 , C08K5/02 , C08K5/03 , C08K5/5313 , C08L63/00 , C08L67/06 , C08L101/00 , C09K21/08 , C09K21/10 , C09K21/12 , C08K5/34 , C08K5/49 , C09K21/00
CPC分类号： C08K5/5313 , C08K5/02 , C08K5/03
摘要： The invention relates to flame-retardant thermoset composition which comprises, as flame retardant combination, at least one phosphinic salt of the formula (I), and/or one diphosphinic salt of the formula (II), and/or polymers of these (component A), where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and also comprises at least one synergistic halogen-containing component (component B). The invention also relates to a process for preparing these flame-retardant thermoset compositions, and also to their use.
摘要翻译：本发明涉及阻燃热固性组合物，其包含作为阻燃剂组合的至少一种式（I）的次膦酸盐和/或一种式（II）的二膦酸盐，和/或这些（组分 A），其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，并且还包含至少一种协同含卤素组分（组分B）。本发明还涉及制备这些阻燃热固性组合物的方法，也涉及它们的用途。

3. 发明授权

US07273901B2 Flame retardant dispersion 有权
标题翻译：阻燃分散体
公开(公告)号：US07273901B2
公开(公告)日：2007-09-25
申请号：US10794019
申请日：2004-03-05
申请人： Martin Sicken , Susanne Knop , Sebastian Hoerold , Harald Bauer
发明人： Martin Sicken , Susanne Knop , Sebastian Hoerold , Harald Bauer
IPC分类号： C08K5/5313
CPC分类号： C08K5/17 , C08K5/51 , H05K1/0373
摘要： The invention relates to a novel flame retardant dispersion for thermoplastic and thermoset polymers, comprising, as component A, a phosphinic salt of the formula (I), and/or a diphosphinic salt of the formula (II), and/or polymers of these, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and, as component B, a nitrogen-containing synergist or a phosphorus/nitrogen flame retardant, and, as component C, a liquid compound.
摘要翻译：本发明涉及用于热塑性和热固性聚合物的新型阻燃分散体，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐，和/或这些其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，线性或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K; m为1〜4; n为1至4; x为1〜4，作为组分B，含氮增效剂或磷/氮阻燃剂，作为组分C，为液态化合物。

4. 发明申请

US20050101708A1 Flame-retardant thermoset compositions 审中-公开
标题翻译：阻燃热固性组合物
公开(公告)号：US20050101708A1
公开(公告)日：2005-05-12
申请号：US10669921
申请日：2003-09-24
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： C09K21/02 , C08K3/00 , C08K5/5313 , C08L101/00 , C09K21/04 , C09K21/12 , C09K21/14 , C08K5/49
CPC分类号： C08K5/5313 , C08K3/016 , C08L63/00 , C08L67/06
摘要： The invention relates to flame-retardant thermoset compositions which comprise, as flame retardant, at least one phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or polymers of these (component A) where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, and also comprise as component B at least one synthetic inorganic compound and/or a mineral product. The invention further relates to a process for preparing these flame-retardant thermoset compositions.
摘要翻译：本发明涉及阻燃热固性组合物，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些（组分A）的聚合物，其中 R 1，R 2，R 2相同或不同，为C 1 -C 6 -C 6 - 烷基，直链或支链，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; 并且x为1至4，并且还包含作为组分B的至少一种合成无机化合物和/或矿物产品。本发明还涉及制备这些阻燃热固性组合物的方法。

5. 发明申请

US20050049339A1 Flame-retardant thermoset compositions 审中-公开
标题翻译：阻燃热固性组合物
公开(公告)号：US20050049339A1
公开(公告)日：2005-03-03
申请号：US10669973
申请日：2003-09-24
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： B29C43/02 , B29K101/10 , C08K5/3492 , C08K5/5313 , C08L101/00 , C08K5/49
CPC分类号： C08K5/34922 , C08K5/5313 , C08L67/06 , C08L63/00
摘要： The invention relates to flame-retardant thermoset compositions which comprise, as flame retardant, at least one phosphinic salt of the formula (I) and/or a diphosphinic salt of the formula (II) and/or polymers of these where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4, and also at least one synergistic component from the substance class of the organic or inorganic phosphorus compounds, and at least one synergistic component from the substance class of the nitrogen compounds. The invention further relates to a process for preparing these flame-retardant thermoset compositions.
摘要翻译：本发明涉及阻燃热固性组合物，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1， R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; 和x为1至4，以及来自有机或无机磷化合物的物质类别的至少一种协同组分，以及来自氮化合物的物质类别的至少一种协同组分。本发明还涉及制备这些阻燃热固性组合物的方法。

6. 发明申请

US20050014875A1 Flame retardant formulation 有权
标题翻译：阻燃配方
公开(公告)号：US20050014875A1
公开(公告)日：2005-01-20
申请号：US10890427
申请日：2004-07-13
申请人： Susanne Knop , Martin Sicken , Sebastian Hoerold
发明人： Susanne Knop , Martin Sicken , Sebastian Hoerold
IPC分类号： C08K5/523 , C08K5/5313 , C08L101/00 , C09D5/18 , C09D7/12 , C09K21/12 , C09K21/14 , C08K5/53 , C08K3/32 , C09K21/00
CPC分类号： C08K5/523 , C08K5/5313 , C09K21/12
摘要： The invention relates to a novel flame retardant formulation for thermoplastic and thermoset polymers, containing, as flame retardant component A, from 90 to 99.9% by weight of phosphinate salt of the formula (I) and/or a diphosphinate salt of the formula (II) and/or polymers thereof where R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and, as component B, from 0 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and, as component C, from 0.1 to 10% by weight of a liquid component.
摘要翻译：本发明涉及用于热塑性和热固性聚合物的新型阻燃剂配方，其包含作为阻燃组分A的90至99.9重量％的式（I）的次膦酸盐和/或式（II）的二亚膦酸盐）和/或其中R 1，R 2相同或不同且为C 1 -C 6 - 烷基，直链或支链和/或芳基的聚合物; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K; m为1〜4; n为1至4; x为1〜4，作为B成分，为0〜50重量％的含氮增效剂或磷/氮阻燃剂，作为C成分，为0.1〜10重量％的液态成分。

7. 发明申请

US20050004277A1 Halogen-containing flame retardant combination 审中-公开
标题翻译：含卤素阻燃剂组合
公开(公告)号：US20050004277A1
公开(公告)日：2005-01-06
申请号：US10840861
申请日：2004-05-07
申请人： Sebastian Hoerold , Susanne Knop , Martin Sicken
发明人： Sebastian Hoerold , Susanne Knop , Martin Sicken
IPC分类号： C09K21/14 , C08K5/02 , C08K5/03 , C08K5/5313 , C08L101/00 , C09K21/02 , C09K21/08 , C09K21/12 , C08K5/34 , C08K5/49 , C09K21/00
CPC分类号： C08K5/03 , C08K5/02 , C08K5/5313
摘要： The invention relates to a flame retardant combination which comprises, as component A, at least one phosphinic salt of the formula (I), and/or one diphosphinic salt of the formula (II), and/or polymers of these, where R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na; K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and also comprises at least one synergistic halogen-containing component as component B.
摘要翻译：本发明涉及阻燃剂组合，其包含作为组分A的至少一种式（I）的次膦酸盐和/或一种式（II）的二膦酸盐，和/或这些的聚合物，其中R 1， R 1，R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na; K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，并且还包含至少一种协同卤素组分作为组分B.

8. 发明申请

US20070203270A1 FLAME RETARDANT DISPERSION 有权
标题翻译：阻燃剂分散剂
公开(公告)号：US20070203270A1
公开(公告)日：2007-08-30
申请号：US10794019
申请日：2004-03-05
申请人： Martin Sicken , Susanne Knop , Sebastian Hoerold , Harald Bauer
发明人： Martin Sicken , Susanne Knop , Sebastian Hoerold , Harald Bauer
IPC分类号： C08K5/53
CPC分类号： C08K5/17 , C08K5/51 , H05K1/0373
摘要： The invention relates to a novel flame retardant dispersion for thermoplastic and thermoset polymers, comprising, as component A, a phosphinic salt of the formula (I), and/or a diphosphinic salt of the formula (II), and/or polymers of these, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4, and, as component B, a nitrogen-containing synergist or a phosphorus/nitrogen flame retardant, and, as component C, a liquid compound.
摘要翻译：本发明涉及用于热塑性和热固性聚合物的新型阻燃分散体，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐，和/或这些其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，线性或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K; m为1〜4; n为1至4; x为1〜4，作为组分B，含氮增效剂或磷/氮阻燃剂，作为组分C，为液态化合物。

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