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41. 发明授权

US5041603A N-phenylsulfonyl-N'-pyrimidinyl-ureas and N-phenyl-sulfonyl-N'-triazinyl ureas 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基脲和N-苯基 - 磺酰基-N'-三嗪基脲
公开(公告)号：US5041603A
公开(公告)日：1991-08-20
申请号：US464578
申请日：1990-01-12
申请人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
发明人： Willy Meyer , Dieter Reinehr , Konrad Oertle , Rolf Schurter
IPC分类号： B01J31/24 , A01N47/36 , A01P13/00 , C07B61/00 , C07C303/22 , C07C309/29 , C07C309/30 , C07C309/44 , C07C309/86 , C07C309/87 , C07C311/15 , C07C311/16 , C07C311/29 , C07C311/53 , C07C311/54 , C07C311/58 , C07C311/65 , C07C317/10 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/69 , C07D251/16 , C07D251/42 , C07D251/46 , C07D251/52 , C07D521/00
CPC分类号： C07C311/65 , A01N47/36 , C07C309/00 , C07D239/47 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 -C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 or 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.

42. 发明授权

US4978383A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4978383A
公开(公告)日：1990-12-18
申请号：US777502
申请日：1985-09-19
申请人： Erfinders K. Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Erfinders K. Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, andQ is cyano or --COB in which B is alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms; phenyl; phenyl substituted with cyano, nitro, halo, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, or haloalkyl of 1 to 3 carbon atoms; amino; alkylamino of 1 to 4 carbon atoms; or dialkylamino of 1 to 4 carbon atoms in each alkyl group.

43. 发明授权

US4940792A Herbicidal sulfonylureas 失效
标题翻译：除草磺酰脲类
公开(公告)号：US4940792A
公开(公告)日：1990-07-10
申请号：US128761
申请日：1987-12-04
申请人： Werner Topfl , Willy Meyer , Hans-Dieter Schneider
发明人： Werner Topfl , Willy Meyer , Hans-Dieter Schneider
IPC分类号： A01N47/36 , C07D239/42 , C07D239/46 , C07D239/48 , C07D239/52 , C07D249/08 , C07D251/52 , C07D403/12 , C07D521/00
CPC分类号： C07D239/42 , A01N47/36 , C07D231/12 , C07D233/56 , C07D239/47 , C07D239/48 , C07D239/52 , C07D249/08 , C07D251/52 , C07D403/12 , C07D521/00
摘要： Novel substituted N-sulfonyl-N'-pyrimidinylureas or N-sulfonyl-N'-triazinylureas of the formula I ##STR1## have good pre- and postemergence selective herbicidal and growth regulating properties.In this formulaE is nitrogen or --CH.dbd.,the group ##STR2## is a phenyl, naphthyl, furyl, thiophenyl, pyrrole or pyridinyl radical which is substituted in accordance with the definitions ofR.sup.1 and R.sup.2,R.sup.3 and R.sup.4 are hydrogen, lower alkyl or lower alkoxy, or one of R.sup.3 and R.sup.4 may also be halogen, lower alkenyl, lower haloalkenyl, lower haloalkoxy, amino, lower alkylamino, --CH(OCH.sub.3).sub.2, a cyclized ketal group or a saturated 5- or 7-membered heterocycle which is bound through the nitrogen atom,R.sup.5 is hydrogen, lower alkyl, lower haloalkyl, or an unsubstituted or substituted phenyl, benzyl or naphthyl radical, andR.sup.6 is an alkyl, acyl or acylamido radical which is bound through sulfur or a sulfinyl or sulfonyl group and is as defined in the description, or is a 5- to 7-membered heterocyclic amino radical which is bound through the nitrogen atom.These compounds are particularly suitable for selectively controlling weeds in crops of cereals.

44. 发明授权

US4881964A N-heterocyclosulfonyl-N'-pyrimidinylureas 失效
标题翻译： N-杂环磺酰基-N'-嘧啶基脲
公开(公告)号：US4881964A
公开(公告)日：1989-11-21
申请号：US198031
申请日：1988-05-24
申请人： Werner Fory , Willy Meyer
发明人： Werner Fory , Willy Meyer
IPC分类号： A01N47/36 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： N-(3,4-Dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-pyrimidinylureas, N-(3,4-dihydro-2,2-dioxo-1,2-benzoxathiin-8-ylsulfonyl)-N'-triazolylureas and N-(3,4-dihydro-2,2-dioxo-1,2-dioxo-1,2-benz-oxathiin-8-ylsulfonyl)-N'-triazinylureas of the formula ##STR1## wherein R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sup.2 and R.sup.3 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.4 is hydrogen, methyl or ethyl,W is oxygen or sulfur, andA is a radical ##STR2## in which formulae the substituents E.sup.1, E.sup.2, X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, X.sup.6, X.sup.7, X.sup.8, Y.sup.1, Y.sup.2, Y.sup.3, Y.sup.4, Y.sup.6 1, Y.sup.8, Y.sup.8 1, Z.sup.3 and Z.sup.5 are customary organic radicals, and the salts thereof with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases have good pre- and postemergence selective herbicidal and growth regulating properties.
摘要翻译： N-（3,4-二氢-2,2-二氧代-1,2-苯并恶嗪-8-基磺酰基）-N'-嘧啶基脲，N-（3,4-二氢-2,2-二氧代-1,2 - 苯并恶嗪-8-基磺酰基）-N'-三唑基脲和N-（3,4-二氢-2,2-二氧代-1,2-二氧代-1,2-苯并恶唑烷-8-基磺酰基）-N'- 式（I）的三嗪基脲其中R 1是氢，卤素，硝基，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷氧基羰基，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基，C 1 C 1-4烷基磺酰基或C 2 -C 5烷氧基烷氧基，R 2和R 3各自独立地为另一个氢或C 1 -C 4烷基，R 4是氢，甲基或乙基，W是氧或硫，A是基团。取代基E1，E2，X1，X2，X3，X4，X5，X6，X7，X8，Y1，Y2，Y3，Y4，Y6 1，Y8，Y8 1，Z3分别表示 + TR Z5是常规的有机基团，其盐与胺，碱金属碱或碱土金属碱基或季铵碱基具有良好的芽前和芽后选择性除草和生长调节剂操作。

45. 发明授权

US4835311A N-phenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲
公开(公告)号：US4835311A
公开(公告)日：1989-05-30
申请号：US141820
申请日：1988-01-11
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms of C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲以及这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R3是卤素，氢，-NR4R5，C1-C3烷基，未取代或被C1-C4烷氧基的1至3个卤素原子取代，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C1-C3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸的基团酸和羧酸，该基团可以进一步被取代并具有官能结构。

46. 发明授权

US4764203A Herbicidal sulfonylureas 失效
标题翻译：除草磺酰脲类
公开(公告)号：US4764203A
公开(公告)日：1988-08-16
申请号：US53912
申请日：1987-05-26
申请人： Werner Topfl , Willy Meyer , Hans-Dieter Schneider
发明人： Werner Topfl , Willy Meyer , Hans-Dieter Schneider
IPC分类号： A01N47/36 , C07D239/42 , C07D239/46 , C07D239/48 , C07D239/52 , C07D249/08 , C07D251/52 , C07D403/12 , C07D521/00 , A01N43/66 , C07D251/18 , C07D251/46 , C07D251/70
CPC分类号： C07D239/42 , A01N47/36 , C07D231/12 , C07D233/56 , C07D239/47 , C07D239/48 , C07D239/52 , C07D249/08 , C07D251/52 , C07D403/12 , C07D521/00
摘要： Novel substituted N-sulfonyl-N'-pyrimidinylureas or N-sulfonyl-N'-triazinylureas of the formula I ##STR1## have good pre- and postemergence selective herbicidal and growth regulating properties.In this formulaE is nitrogen or --CH.dbd.,the group ##STR2## is a phenyl, naphthyl, furyl, thiophenyl, pyrrole or pyridinyl radical which is substituted in accordance with the definitions of R.sup.1 and R.sup.2,R.sup.3 and R.sup.4 are hydrogen, lower alkyl or lower alkoxy, or one of R.sup.3 and R.sup.4 may also be halogen, lower alkenyl, lower haloalkenyl, lower haloalkoxy, amino, lower alkylamino, --CH(OCH.sub.3).sub.2, a cyclized ketal group or a saturated 5- to 7-membered heterocycle which is bound through the nitrogen atom,R.sup.5 is hydrogen, lower alkyl, lower haloalkyl, or an unsubstituted or substituted phenyl, benzyl or naphthyl radical, andR.sup.6 is an alkyl, acyl or acylamido radical which is bound through sulfur or a sulfinyl or sulfonyl group and is as defined in the description, or is a 5- to 7-membered heterocyclic amino radical which is bound through the nitrogen atom.These compounds are particularly suitable for selectively controlling weeds in crops of cereals.
摘要翻译：式I（I）的新型取代的N-磺酰基-N'-嘧啶基或N-磺酰基-N'-三嗪基脲具有良好的芽前和芽后选择性除草和生长调节性质。在该式中，E是氮或-CH =，根据R1和R2的定义被取代的苯基，萘基，呋喃基，噻吩基，吡咯基或吡啶基，R3和R4是氢，低级烷基或低级烷氧基，或者R 3和R 4中的一个也可以是卤素，低级烯基，低级卤代烯基，低级卤代烷氧基，氨基，低级烷基氨基，-CH（OCH 3）2，环状缩酮基或饱和的5-至7-元通过氮原子结合的杂环，R5是氢，低级烷基，低级卤代烷基或未取代或取代的苯基，苄基或萘基，R6是通过硫或亚磺酰基结合的烷基，酰基或酰基酰氨基，磺酰基，如描述中所定义，或是通过氮原子结合的5-至7-元杂环氨基。这些化合物特别适用于选择性地控制谷物作物中的杂草。

47. 发明授权

US4727186A Certain alkynyl-benzene sulfonamide intermediates useful for preparing ureas herbicides 失效
标题翻译：某些用于制备脲类除草剂的炔基 - 苯磺酰胺中间体
公开(公告)号：US4727186A
公开(公告)日：1988-02-23
申请号：US745747
申请日：1985-06-17
申请人： Rolf Schurter , Werner Fury , Willy Meyer
发明人： Rolf Schurter , Werner Fury , Willy Meyer
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/42 , C07D401/12 , C07D409/12 , C07D521/00 , C07C143/78 , C07C149/447
CPC分类号： C07D521/00 , A01N47/36
摘要： Phenylsulfonamides of Formula II ##STR1## wherein A is a radical of the formula --C.tbd.C--R;R is H, or an optionally substituted (i) C.sub.1 -C.sub.9 alkyl, (ii) C.sub.3 -C.sub.9 cycloalkyl, (iii) phenyl, or (iv) 5-or-6 membered heterocyclic ring;m is one or two;R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, or --Y--R.sub.5 ;R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkenyl, --Y--R.sub.5, --COOR.sub.6, --NO.sub.2, or --CO--NR.sub.7 --R.sub.8 ;R.sub.5 and R.sub.6 are each independently C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl, or C.sub.2 -C.sub.6 alkoxyalkyl;R.sub.7 and R.sub.8 are each independently hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, or C.sub.2 -C.sub.6 alkynyl; andY is oxygen, sulfur, sulfinyl or sulfonyl bridge; or a salt thereof.
摘要翻译：式II的苯磺酰胺（II）其中A是式-C3OND C-R的基团; R为H或任选取代的（ⅰ）C 1 -C 9烷基，（ⅱ）C 3 -C 9环烷基，（ⅲ）苯基或（ⅳ）5-或6-元杂环; m是一两个; R1是氢，卤素，C1-C5烷基，C2-C5烯基或-Y-R5; R2是氢，卤素，C1-C5烷基，C2-C5烯基，C1-C4卤代烯基，-Y-R5，-COOR6，-NO2或-CO-NR7-R8; R 5和R 6各自独立地为C 1 -C 5烷基，C 2 -C 5烯基，C 2 -C 6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基; R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基; Y是氧，硫，亚磺酰基或磺酰基桥; 或其盐。

48. 发明授权

US4671819A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4671819A
公开(公告)日：1987-06-09
申请号：US810010
申请日：1985-12-17
申请人： Willy Meyer , Konrad Oertle
发明人： Willy Meyer , Konrad Oertle
IPC分类号： C07D249/16 , A01N43/70 , A01N47/36 , C07C20060101 , C07C67/00 , C07C301/00 , C07C309/86 , C07C311/15 , C07C311/16 , C07C311/17 , C07C311/29 , C07C311/39 , C07C311/53 , C07C311/65 , C07C325/00 , C07C331/16 , C07C331/32 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D239/69 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/46 , C07D251/52 , C07D521/00
CPC分类号： C07C309/86 , A01N47/36 , C07C311/65 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen, andZ is oxygen or sulfur;and also the salts of these compounds.
摘要翻译：式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基，R 1是氢，卤素，硝基，氰基，C 1 C 1-4烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4 - 烷基亚磺酰基，C 1 -C 4烷基磺酰基，-CO-R 6，-NR 7 R 8，-CO-NR 9 R 10或-SO 2 -NR 11 R 12，R 2是氢，卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基，R 3和R 4彼此独立地各自为氢，卤素，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 2 -C 4烷氧基烷基，C 1 -C 4烷氧基或-NR 12 R 13，，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，R 6是C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4烷硫基，C 2 -C 6烷氧基烷氧基，氢，C 1 -C 4烷基或C 1 -C 4 卤代烷基，R7，R8，R9，R10，R11，R12和R13各自独立地为氢或C1-C4烷基，E为氮，Z为氧或硫; 以及这些化合物的盐。

49. 发明授权

US4648899A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4648899A
公开(公告)日：1987-03-10
申请号：US855060
申请日：1986-04-23
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , A01N43/70 , C07D251/42
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO--, or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸和羧酸，该基团可进一步被取代并具有官能结构。

50. 发明授权

US4618363A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4618363A
公开(公告)日：1986-10-21
申请号：US458799
申请日：1983-01-18
申请人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
发明人： Karl Gass , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07D211/22 , C07D213/30 , C07D213/64 , C07D213/643 , C07D239/42 , C07D251/46 , C07D251/52 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D401/12 , C07D405/12 , C07D409/12 , C07D521/00 , A01N43/66 , A01N43/70
CPC分类号： C07D213/30 , C07D213/643 , C07D301/14 , C07D303/22 , C07D307/12 , C07D309/06 , C07D317/22 , C07D333/16 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence.In the formulaR.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl,R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms,R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms,R.sub.4 is hydrogen or methyl,R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy,A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl,m is 0 or 1,E is nitrogen or the methine group,X is oxygen, sulfur, --SO-- or --SO.sub.2 --, andQ is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基脲和-N'-三嗪基脲和这些化合物与胺，碱金属碱和碱土金属碱或季铵碱的盐具有良好的选择性除草和植物应用芽前和芽后的生长调节性质。式中R 1为氢，卤素，硝基，C 1 -C 4卤代烷基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 5烯基或C 1 -C 4烷氧基羰基，R 2为C 1 -C 3烷基或C 1 -C 3烷氧基，各自未被取代或被1至3个卤素原子，R 3是卤素，氢，-NR 4 R 5，未被取代或被1至3个卤素原子或C 1 -C 4烷氧基取代的C 1 -C 3烷基，或是未被取代或被甲氧基，乙氧基或1至3个卤素原子取代的C 1 -C 3烷氧基， R4是氢或甲基，R5是氢，C1-C2烷基或甲氧基，A是C1-C4亚烷基或C2-C4亚烯基，各自未被取代或被C1-C4烷基取代，m是0或1，E是氮或次甲基，X 是氧，硫，-SO-或-SO 2 - ，Q是羟基，氰基或选自5-或6-元杂环和稠合同系物，胺，缩醛，酯，酮，苯基，磺酸的基团酸和羧酸，该基团可以进一步被取代并具有官能结构。

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