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41. 发明授权

US4606901A Deagglomeration of porous siliceous crystalline materials 失效
标题翻译：多孔硅质结晶材料的团聚
公开(公告)号：US4606901A
公开(公告)日：1986-08-19
申请号：US805491
申请日：1985-12-05
申请人： Pochen Chu , Albin Huss, Jr. , James C. Vartuli
发明人： Pochen Chu , Albin Huss, Jr. , James C. Vartuli
IPC分类号： C01B39/02 , C01B33/28
CPC分类号： C01B33/2876 , Y10S423/22 , Y10S423/29
摘要： Agglomerated crystalline zeolites are deagglomerated by treating the zeolite during its formation or shortly thereafter. The particles are contacted with additional basic solution when crystallization is near completion to effect deagglomeration.
摘要翻译：聚集的结晶沸石通过在其形成期间或之后不久处理沸石而被解团聚。当结晶接近完成时，颗粒与附加的碱性溶液接触以实现解聚。

42. 发明授权

US5625113A Isoparaffin/olefin alkylation 失效
标题翻译：异链烷烃/烯烃烷基化
公开(公告)号：US5625113A
公开(公告)日：1997-04-29
申请号：US365334
申请日：1994-12-28
申请人： Mohsen N. Harandi , James H. Beech, Jr. , Albin Huss, Jr. , Robert A. Ware , Altaf Husain
发明人： Mohsen N. Harandi , James H. Beech, Jr. , Albin Huss, Jr. , Robert A. Ware , Altaf Husain
IPC分类号： C07C2/58 , C07C2/62 , C07C9/16
CPC分类号： C07C2/58 , C07C2/62 , C07C9/16 , C07C2527/054 , C07C2529/70
摘要： A process is disclosed for alkylating an isoparaffin with an olefin comprising the steps of:(a) reacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in a first alkylation reaction stage at temperature from about -40.degree. C. to about 500.degree. C. and overall isoparaffin:olefin feed weight ratio of from about 1:1 to about 250:1 with a solid alkylation catalyst comprising a synthetic porous crystalline material characterized by an X-ray diffraction pattern including values substantially as set forth in Table I of the specification and having a composition comprising the molar relationshipX.sub.2 O.sub.3 :(n)YO.sub.2,wherein n is less than about 35, X is a trivalent element and Y is a tetravalent element;(b) mixing the effluent from said first alkylation stage with additional olefin to evolve an intermediate stream having an isoparaffin:olefin weight ratio of from about 2:1 to about 100:1; and(c) reacting said intermediate stream in a second alkylation stage in the absence of intermediate fractionation with a liquid acid catalyst comprising H.sub.2 SO.sub.4 to produce C.sub.5 + alkylate.
摘要翻译：公开了一种用烯烃烷基化异链烷烃的方法，该方法包括以下步骤：（a）使第一烷基化反应阶段中具有4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃反应， 40℃至约500℃，总异构链烷烃：烯烃进料重量比为约1:1至约250:1，其中固体烷基化催化剂包含合成多孔结晶材料，其特征在于X射线衍射图包括值基本上如说明书的表I所述，并且具有包含摩尔关系X 2 O 3：（n）YO 2的组成，其中n小于约35，X是三价元素，Y是四价元素; （b）将来自所述第一烷基化阶段的流出物与另外的烯烃混合以产生具有约2:1至约100:1的异链烷烃：烯烃重量比的中间料流; 和（c）在不与中间分级分离的第二烷基化阶段中使所述中间物流与包含H 2 SO 4的液体酸催化剂反应，以产生C5 +烷基化物。

43. 发明授权

US5516959A Highly selective n-olefin isomerization process using ZSM-35 失效
标题翻译：使用ZSM-35的高选择性正烯烃异构化方法
公开(公告)号：US5516959A
公开(公告)日：1996-05-14
申请号：US357841
申请日：1994-12-09
申请人： Iraj I. Rahmim , Albin Huss, Jr. , Daria N. Lissy , Donald J. Klocke , Werner O. Haag
发明人： Iraj I. Rahmim , Albin Huss, Jr. , Daria N. Lissy , Donald J. Klocke , Werner O. Haag
IPC分类号： B01J29/65 , B01J29/70 , C07C5/27 , C07C5/22
CPC分类号： B01J29/7042 , B01J29/65 , B01J29/7046 , C07C5/2775 , B01J2229/26 , B01J2229/42
摘要： A process is disclosed for the highly selective skeletal isomerization of linear olefin-containing organic feeds to iso-olefins at high levels of feed conversion wherein linear olefins, e.g., n-butenes, are contacted with catalyst comprising ZSM-35 under skeletal isomerization conditions which can include temperatures of 100 to 750.degree. C. The process uses a catalyst composition comprising ZSM-35, e.g., microcrystalline ZSM-35 having a crystal size whose largest dimension is no greater than 0.5 micron and whose ratio of its second largest dimension to said largest dimension ranges from 0.5 to 1. The process exhibits enhanced catalyst cycle life where the ZSM-35 is composited with a silica-containing matrix to provide a catalyst composite having a total pore volume greater than 0.6 cc/g or 300.sup.+ angstroms pore volume of greater than 0.1 cc/g.
摘要翻译：公开了一种用于在高水平进料转化率下将含线性烯烃的有机原料高度选择性骨架异构化为异烯烃的方法，其中线性烯烃例如正丁烯在骨架异构化条件下与包含ZSM-35的催化剂接触，可以包括100至750℃的温度。该方法使用包含ZSM-35的催化剂组合物，例如具有最大尺寸不大于0.5微米的晶体尺寸的微晶ZSM-35，其第二大尺寸与所述最大尺寸范围为0.5至1.该方法表现出增强的催化剂循环寿命，其中ZSM-35与含二氧化硅的基质复合以提供总孔体积大于0.6cc / g或300多埃孔体积的催化剂复合材料大于0.1cc / g。

44. 发明授权

US5347064A Multiple split feed isoparaffin-olefin alkylation 失效
标题翻译：多分散进料异链烷烃烯烃烷基化
公开(公告)号：US5347064A
公开(公告)日：1994-09-13
申请号：US45435
申请日：1993-04-12
申请人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Robert S. Kurtas
发明人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Robert S. Kurtas
IPC分类号： C07C2/62 , C07C9/16
CPC分类号： C10G50/00 , C07C2/62 , C07C9/16 , C07C2527/1213 , C07C2527/173
摘要： An isoparaffin-olefin alkylation process is disclosed which improves alkylate quality by segregating the olefin feed into intermediate feedstreams which are enriched in propene, 1-butene, and/or 2-butenes with respect to the olefin feed, and alkylating these intermediate feedstreams in separate reaction zones at reaction temperatures specific to the olefin feed to increase the ratio of trimethylpentanes to dimethylhexanes in the resulting alkylate product.
摘要翻译：公开了一种异链烷烃烯烃烷基化方法，其通过将烯烃进料分离成相对于烯烃进料富含丙烯，1-丁烯和/或2-丁烯的中间进料流，并将这些中间进料流分离反应区域在烯烃进料特有的反应温度下，以增加所得烷基化产物中三甲基戊烷与二甲基己烷的比例。

45. 发明授权

US5345027A Alkylation process using co-current downflow reactor with a continuous hydrocarbon phase 失效
标题翻译：使用具有连续烃相的并流下流反应器的烷基化方法
公开(公告)号：US5345027A
公开(公告)日：1994-09-06
申请号：US933163
申请日：1992-08-21
申请人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
发明人： Jonathan E. Child , Kenneth J. Del Rossi , Albin Huss, Jr. , Frederick J. Krambeck , Thomas R. Melli , Sergei Yurchak
IPC分类号： B01J27/12 , B01J27/16 , C07C2/62 , C07C2/56 , C07C2/58
CPC分类号： C07C2/62 , B01J27/12 , B01J27/16 , C07C2527/1213 , C07C2527/173
摘要： A continuous alkylation process for the production of high octane gasoline comprising contacting a mixture of an isoparaffin and an olefin with a catalyst complex comprising BF3:H.sub.3 PO.sub.4 in a continuous hydrocarbon downflow reactor.
摘要翻译：包括用于生产高辛烷值汽油的连续烷基化方法，包括使异链烷烃和烯烃的混合物与包含BF 3 :H 3 PO 4的催化剂络合物在连续的烃下流反应器中接触。

46. 发明授权

US5292982A Liquid acid alkylation catalyst and isoparaffin-olefin alkylation process 失效
标题翻译：液体酸烷基化催化剂和异链烷烃烯烃烷基化方法
公开(公告)号：US5292982A
公开(公告)日：1994-03-08
申请号：US974550
申请日：1992-11-12
申请人： Kenneth J. Del Rossi , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , Albin Huss, Jr.
IPC分类号： B01J27/06 , B01J27/12 , B01J31/02 , B01J31/04 , C07C2/62
CPC分类号： B01J31/0235 , B01J27/06 , B01J27/12 , B01J31/0209 , B01J31/0227 , B01J31/0231 , B01J31/04 , C07C2/62 , B01J2231/32 , C07C2527/03 , C07C2527/1206 , C07C2527/16 , C07C2531/02 , C07C2531/025 , C07C2531/04
摘要： This invention provides an isoparaffin-olefin alkylation catalyst composition comprising hydrofluoric acid, an additive, and a superacid promoter. The additive is present in concentration sufficient to effect deactivation of the hydrofluoric acid for isoparaffin-olefin alkylation such that the catalytic properties of said admixture of the hydrofluoric acid and the additive, in the absence of superacid promoter are characterized by the conversion of a mixed isoparaffin-olefin stream to product containing more than about 0.1 weight percent of alkyl halide.
摘要翻译：本发明提供了包含氢氟酸，添加剂和超酸促进剂的异链烷烃烷基化烷基化催化剂组合物。添加剂的存在浓度足以使氢氟酸失活用于异链烷烃 - 烯烃烷基化，使得在不存在超酸催化剂的情况下，所述氢氟酸与添加剂的混合物的催化性质的特征在于混合的异链烷烃 α-烯烃流加入含有大于约0.1重量％烷基卤的产物。

47. 发明授权

US5256277A Paraffin isomerization process utilizing a catalyst comprising a mesoporous crystalline material 失效
标题翻译：使用包含介孔结晶材料的催化剂的石蜡异构化方法
公开(公告)号：US5256277A
公开(公告)日：1993-10-26
申请号：US734991
申请日：1991-07-24
申请人： Kenneth J. Del Rossi , George H. Hatzikos , Albin Huss, Jr.
发明人： Kenneth J. Del Rossi , George H. Hatzikos , Albin Huss, Jr.
IPC分类号： B01J29/04 , C10G35/06 , C10G45/64 , C10G35/085 , C10G35/095
CPC分类号： C10G45/64 , B01J29/042 , B01J29/043 , C10G35/065 , B01J2229/42 , B01J29/045
摘要： Paraffins, especially paraffins in the C.sub.4 -C.sub.8 range, are isomerized to iso-paraffins over an isomerization catalyst comprising a noble metal such as platinum on a support material comprising an inorganic, non-layered, porous, crystalline phase aluminosilicate material with pores of at least 13 .ANG. and which exhibits, after calcination, an X-ray diffraction pattern with at least one peak at a d-spacing greater than 18 .ANG.. These materials have a high surface area and sorption capacity marked by a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred form, the support material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern.
摘要翻译：链烷烃，特别是C4-C8范围内的链烷烃，在包含贵金属如铂的异构化催化剂上异构化成异链烷烃，载体材料包含无机，非层状，多孔，结晶相的硅铝酸盐材料，孔隙为至少13个ANGSTROM，并且其在煅烧后显示具有大于18安培的d间距的至少一个峰的X射线衍射图。这些材料具有高的表面积和吸附能力，其标记为在50托和25℃下每100克苯吸附能力大于约15克苯。在其优选形式中，载体材料具有均匀的六边形排列的孔其直径至少约为13安格姆和六角形电子衍射图案，其可以用对应于X射线衍射图中的至少一个峰的d100值大于约18的折射率进行索引。

48. 发明授权

US5245101A Isoparaffin:olefin alkylation process and catalyst complex 失效
标题翻译：异链烷烃：烯烃烷基化方法和催化剂配合物
公开(公告)号：US5245101A
公开(公告)日：1993-09-14
申请号：US608856
申请日：1990-11-05
申请人： Kenneth J. Del Rossi , Albin Huss, Jr. , Samuel A. Tabak
发明人： Kenneth J. Del Rossi , Albin Huss, Jr. , Samuel A. Tabak
IPC分类号： C07C2/62
CPC分类号： C07C2/62 , C07C2527/1213 , C07C2527/173
摘要： The invention provides a catalyst complex for promoting alkylation of an isoparaffin with an olefin, said catalyst complex comprising the reaction product of BF.sub.3 and at least one selected from the group consisting of H.sub.3 PO.sub.4 and H.sub.2 O; and, additionally, excess BF.sub.3 in concentration of from about 10 ppm (weight) to about 5 percent by weight of the total isoparaffin and olefin feed.The invention further provides a process for the alkylation of an isoparaffin with an olefin by contacting a mixture of isoparaffin and olefin with the catalyst complex of the invention, decanting the hydrocarbon product from the catalyst complex, and deacidifying the hydrocarbon product.
摘要翻译：本发明提供了一种用于促进异链烷烃与烯烃烷基化的催化剂配合物，所述催化剂配合物包含BF 3的反应产物和选自H 3 PO 4和H 2 O的至少一种; 另外还含有过量的BF 3，其浓度为总异链烷烃和烯烃进料的约10ppm（重量）至约5％重量。本发明还提供了一种通过使异链烷烃和烯烃的混合物与本发明的催化剂络合物接触，从催化剂络合物中倾析烃产物，并使烃产物脱酸来使烯烃与烷烃烷基化的方法。

49. 发明授权

US5221777A Isoparaffin:olefin alkylation process employing Lewis-acid promoted pillared layered silicate 失效
标题翻译：异链烷烃：使用路易斯酸促进柱状层状硅酸盐的烯烃烷基化方法
公开(公告)号：US5221777A
公开(公告)日：1993-06-22
申请号：US713240
申请日：1991-06-07
申请人： Albin Huss, Jr. , Ivy D. Johnson
发明人： Albin Huss, Jr. , Ivy D. Johnson
IPC分类号： C07C2/60
CPC分类号： C07C2/60 , C07C2521/08 , C07C2527/1213 , C07C2527/126 , C07C2527/133
摘要： A process is provided for alkylating an isoparaffin with an olefin comprising effecting reaction of isoparaffin and olefin in the presence of an alkylation catalyst complex comprising a Lewis acid and a solid component, said solid component comprising a layered silicate and pillars of an oxide of at least one element selected from Groups IB, IIB, IIIA, IIIB, IVA, IVB, VA, VB, VIA, VIIA and VIIIA of the Periodic Table of the Elements separating the layers of the silicate.
摘要翻译：提供了一种用烯烃烷基化异链烷烃的方法，包括在包含路易斯酸和固体组分的烷基化催化剂络合物的存在下进行异链烷烃和烯烃的反应，所述固体组分包含层状硅酸盐和至少一种氧化物的柱选自分离硅酸盐层的元素周期表的IB，IIB，IIIA，IIIB，IVA，IVB，VA，VB，VIA，VIIA和VIIIA中的一种元素。

50. 发明授权

US5191147A Isoparaffin/olefin alkylation 失效
标题翻译：异链烷烃/烯烃烷基化
公开(公告)号：US5191147A
公开(公告)日：1993-03-02
申请号：US785398
申请日：1991-10-30
申请人： Thomas F. Degnan , Kenneth J. Del Rossi , Altaf Husain , Albin Huss, Jr.
发明人： Thomas F. Degnan , Kenneth J. Del Rossi , Altaf Husain , Albin Huss, Jr.
IPC分类号： B01J29/04 , C07C2/58
CPC分类号： C07C2/58 , B01J29/041 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2521/16
摘要： The present invention provides a process for alkylating an isoparaffin with an olefin comprising contacting an isoparaffin having from 4 to 8 carbon atoms with an olefin having from 2 to 12 carbon atoms in an alkylation reaction zone at temperature from about -20.degree. C. to about 200.degree. C. in the presence of a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a d-spacing greater than about 18 Angstrom Units and having a benzene adsorption capacity of greater than 15 grams benzene per 100 grams of said material at 50 torr and 25.degree. C., wherein the molar ratio of said isoparaffin to said olefin is from about 1:1 to about 250:1 to evolve a product stream containing C.sub.5 + alkylate. In a preferred embodiment, the alkylation catalyst complex comprises a Bronsted acid and an inorganic, porous crystalline phase material having, after calcination, a hexagonal arrangement of uniformly-sized pores having diameters of at least about 13 Angstrom Units and exhibiting a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 Angstrom Units.
摘要翻译：本发明提供了一种用烯烃烷基化异链烷烃的方法，包括在烷基化反应区中将约4至8个碳原子的异链烷烃与具有2至12个碳原子的烯烃在约-20℃至约在布朗斯台德酸和无机多孔结晶相材料存在下，在煅烧后，d-间距大于约18埃单位，苯吸附量大于15克苯/ 100克所述材料在50托和25℃下，其中所述异链烷烃与所述烯烃的摩尔比为约1:1至约250:1，以放出含有C5 +烷基化物的产物流。在优选的实施方案中，烷基化催化剂络合物包括布朗斯台德酸和无机多孔结晶相材料，其在煅烧之后具有直径为至少约13埃单位的均匀尺寸的孔的六边形排列并且显示出六边形电子衍射图可以用大于约18埃单位的d100值进行索引。

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