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    • 42. 发明授权
    • Photopolymerizable composition
    • 可光聚合组合物
    • US5011760A
    • 1991-04-30
    • US522406
    • 1990-05-11
    • Jun YamaguchiMasaki OkazakiYoshio Inagaki
    • Jun YamaguchiMasaki OkazakiYoshio Inagaki
    • C08F2/50G03C5/16G03F7/029
    • G03F7/029Y10S430/115Y10S430/116Y10S430/121
    • A photopolymerizable composition which comprises (a) a polymerizable compound having at least one ethylenic unsaturated bond, and (b) a salt formed by an organic cationic dye compound and an organic boron compound anion, wherein the salt is represented by the following formula (I), in which an organic cationic dye compound is employed as D.sup..sym. to impart high spectral sensitivities to the composition ##STR1## wherein D.sup..sym. represents a cationic dye, and R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which may be the same or different, each represents an alkyl group, an aryl group, an aralkyl group, an alkaryl group, an alkenyl group, an alkynyl group, or a group derived therefrom; and two or more of the substituent groups R.sup.1 and R.sup.4 can be combined to form a cyclic structure. The cationic dye D.sup..sym. is represented by formula (II).phi..sup..sym. -L=.PSI. (II)wherein .phi. and .PSI., which may be the same or different, each represents a heterocyclic ring containing at least one nitrogen atom, and L represents a methine group, or a tri-, penta-, hepta- or nona-methine group formed by linking methine groups one after another by conjugated double bonds, each of which may be substituted, provided that L combines with at least either .phi. or .PSI. to form a ring.
    • 一种可光聚合组合物,其包含(a)具有至少一个烯键式不饱和键的可聚合化合物,和(b)由有机阳离子染料化合物和有机硼化合物阴离子形成的盐,其中所述盐由下式(I ),其中使用有机阳离子染料化合物作为D(+)以赋予其中D(+)表示阳离子染料,R1,R2,R3和R4的组合物(I)具有高光谱灵敏度,其中 可以相同或不同,分别表示烷基,芳基,芳烷基,烷芳基,烯基,炔基或由其衍生的基团。 并且两个或更多个取代基R1和R4可以结合形成环状结构。 阳离子染料D(+)由式(II)表示:phi(+) - L = PSI(II)其中,phi和PSI可以相同或不同,各自表示含有至少一个氮原子的杂环, L表示次甲基,或通过共轭双键将次甲基彼此连接形成的三 - ,五 - ,七 - 或九 - 次甲基,每个可以被取代,条件是L与至少一个 phi或PSI形成戒指。
    • 45. 发明授权
    • Laser light source
    • 激光光源
    • US4981613A
    • 1991-01-01
    • US116923
    • 1987-11-04
    • Masaki OkazakiSeiiti Kubodera
    • Masaki OkazakiSeiiti Kubodera
    • G02F1/361
    • G02F1/3612
    • A light source composed of a semiconductor laser and a nonlinear optical element which converts a laser beam emitted from the semiconductor laser to a laser beam having a shorter wavelength, disposed in the path of a laser beam produced by the laser, the nonlinear optical element containing a compound represented by formula (I): ##STR1## wherein Z.sup.1, Z.sup.2, X and n are as defined in the specification, of formula (II) ##STR2## wherein Z.sup.3 and Z.sup.4 are defined in the specification, or an acid adduct therefore. the nonlinear optical element exhibits high transmittances to blue light and generates a laser beam having a shorter wavelength than that of the laser applied.
    • 由半导体激光器和非线性光学元件组成的光源,其将从半导体激光器发射的激光束转换为具有较短波长的激光束,设置在由激光器产生的激光束的路径中,所述非线性光学元件包含 式(I)表示的化合物:其中Z 1,Z 2,X和n如说明书中定义的式(II)其中Z 3和Z 4在说明书中定义的式(I) ,或酸加合物。 非线性光学元件对蓝色光表现出高的透射率,并且产生具有比所施加激光的波长短的波长的激光束。
    • 47. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US4945038A
    • 1990-07-31
    • US310104
    • 1989-02-14
    • Yasuhito MomokiTakanori HiokiMasaki Okazaki
    • Yasuhito MomokiTakanori HiokiMasaki Okazaki
    • G03C1/28
    • G03C1/28
    • A silver halide color photographic material is described, comprising a support having provided thereon at least one silver halide emulsion layer, wherein said at least one silver halide emulsion layer comprises at least one compound represented by the formula (I) and at least one compound represented by the formula (II): ##STR1## wherein V.sub.1, V.sub.2, V.sub.3 and V.sub.4 each represents a hydrogen atom, a halogen atom, an alkyl group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a carboxy group, a cyano group, a hydroxy group, an amino group, an acylamino group, an alkoxy group or an aryl group, or V.sub.1 and V.sub.2, or V.sub.3 and V.sub.4 may be bound to each other to form a benzene ring;R.sub.1 and R.sub.2, which may be the same or different, each represents an alkyl group and may optionally form a salt with a metal atom or other organic compound;X.sup..crclbar. represents an anion; andl represents 0 or 1 or, when the dye forms an inner salt, l represents 0; ##STR2## wherein D represents a divalent aromatic moiety;R.sub.3, R.sub.4, R.sub.5 and R.sub.6 each represents a hydrogen atom, a hydroxy group, an alkoxy group, an aryloxy group,a heterocyclic group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclylthio group, an amino group, an alkylamino group, a cyclohexylamino group, an arylamino group, a heterocyclylamino group, an aralkylamino group or an aryl group;Y.sub.1 and Y.sub.2 each represents --N.dbd. or --CH.dbd.; andZ.sub.1 and Z.sub.2 each represents --N.dbd. or --CH.dbd.;further at least one of Y.sub.1 and Z.sub.1 is --N.dbd., and at least one of Y.sub.2 and Z.sub.2 is --N.dbd..
    • 描述了一种卤化银彩色照相材料,包括其上提供有至少一个卤化银乳剂层的载体,其中所述至少一种卤化银乳剂层包含至少一种由式(I)表示的化合物和至少一种表示的化合物 式(II):其中V1,V2,V3和V4各自表示氢原子,卤素原子,烷基,酰基,酰氧基,烷氧基羰基,氨基甲酰基 ,氨基磺酰基,羧基,氰基,羟基,氨基,酰氨基,烷氧基或芳基,或V1和V2,或V3和V4可以彼此结合形成 苯环; R1和R2可以相同或不同,各自表示烷基,并且可以任选地与金属原子或其它有机化合物形成盐; X( - )表示阴离子; l代表0或1,或当染料形成内盐时,l代表0; (II)其中D表示二价芳族部分; R3,R4,R5和R6各自表示氢原子,羟基,烷氧基,芳氧基,杂环基,巯基,烷硫基,芳硫基,杂环硫基,氨基, 烷基氨基,环己基氨基,芳基氨基,杂环基氨基,芳烷基氨基或芳基; Y1和Y2各自表示-N =或-CH =; 并且Z 1和Z 2各自表示-N =或-CH =; 进一步,Y1和Z1中的至少一个为-N =,Y2和Z2中的至少一个为-N =。