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    • 37. 发明申请
    • DIFFERENTIAL EXCITATION SPECTROSCOPY
    • 差异激发光谱
    • US20150069258A1
    • 2015-03-12
    • US14473796
    • 2014-08-29
    • Eugene W. ButlerTimothy M. StratmanBoyd V. HunterPaul HarrisonJason M. Cox
    • Eugene W. ButlerTimothy M. StratmanBoyd V. HunterPaul HarrisonJason M. Cox
    • G01N21/62G01N22/00G01N21/27
    • G01N21/35G01N21/031G01N21/27G01N21/3581G01N21/636G01N22/00G01N2021/3125
    • A new technique which uses a pump-probe methodology to place a molecule into one or more excited rotational and/or vibrational states. By evaluating spectral changes due to at least one discrete frequency of pump photons a multi-dimensional characterization of the molecule's excited state energy level results. This multi-dimensional characterization typically involves evaluating the changes between excited and unexcited state measurements. The differential nature of the evaluation makes the technique self-referencing and solves problems common to many spectroscopic techniques. The multi-dimensionality of the technique provides high specificity and immunity to interferents. The preferred embodiments involve excitation by using photons suited to pumping the rotational states and evaluating the effects by probing the energy levels of one of more vibrational states. The technique is capable of detecting bulk and trace concentrations of a molecule in gas, liquid and solid phases, both in pure form and in the presence of other molecules.
    • 一种使用泵浦探针方法将分子置于一个或多个激发的旋转和/或振动状态的新技术。 通过评估由于至少一个离散频率的泵浦光子的光谱变化,可以得到分子激发态能级的多维表征。 这种多维表征通常包括评估激发态和不精确状态测量之间的变化。 评估的差异性使得技术自我参照并且解决了许多光谱技术常见的问题。 该技术的多维度为干扰物提供了高度的特异性和免疫性。 优选实施例涉及通过使用适于泵送旋转状态的光子并通过探测更多振动状态之一的能量水平来评估效果来激发。 该技术能够检测气体,液体和固相中分子的体积和痕量浓度,无论是纯形式还是在其它分子存在下。
    • 39. 发明申请
    • MEASUREMENT OF GASEOUS COMPOUNDS USING SPECTROSCOPY
    • 使用光谱测定气体化合物
    • WO2014041240A1
    • 2014-03-20
    • PCT/FI2013/050870
    • 2013-09-10
    • METSO POWER OY
    • SORVAJÄRVI, TapioTOIVONEN, Juha
    • G01N21/17
    • G01N21/3103G01J3/427G01N21/631G01N2021/3125
    • A method for measuring the profile of the content of a gas compound from a gas mixture. The method comprises generating a light beam (170) and guiding at least part of the light beam (170) to a first optical path (160) such that at least part of the photons of the light beam (170) travel the first optical path (160) in a first direction. The method further comprises generating at least a last light pulse (710, 710a); transforming, using at least the last light pulse (710, 710a), at least part of the gas compound (510) atoms, molecules, ions, or radicals, to at least a first part (520); selecting wavelength of the light beam (170) such that is corresponds to an absorption profile of the first part (520); guiding at least part of the a light pulse (710, 710a, 710, 710a, 710b, 710c) to the first optical path (160), such that the photons (515, 515b) of the guided part of the light pulse travel in a second direction, wherein the second direction is reverse to the first direction; detecting a first profile (I k (t)) indicative of the intensity of the attenuated light beam (175) as function of time; and determining, using the first profile (I k (t)) indicative of the intensity of the attenuated light beam (175) as function of time, the profile (ξG(x)) of content of the gas compound on the first optical path (160). In addition, a device arranged to perform the method.
    • 一种用于测量气体混合物中气体化合物含量分布的方法。 该方法包括产生光束(170)并将光束(170)的至少一部分引导到第一光路(160),使得光束(170)的至少一部分光子行进第一光路 (160)在第一方向上。 该方法还包括产生至少最后一个光脉冲(710,710a); 将至少一部分气体化合物(510)原子,分子,离子或自由基至少使用最后的光脉冲(710,710a)转化至至少第一部分(520); 选择光束(170)的波长,使得其对应于第一部分(520)的吸收分布; 将光脉冲(710,710a,710,710a,710b,710c)的至少一部分引导到第一光路(160),使得光脉冲的被引导部分的光子(515,515b)进入 第二方向,其中所述第二方向与所述第一方向相反; 检测指示衰减光束(175)的强度的第一轮廓(Ik(t))作为时间的函数; 并且使用指示衰减光束(175)的强度的第一轮廓(Ik(t))作为时间的函数,确定第一光学上的气体化合物的含量的轮廓(&xgr; G(x)) 路径(160)。 另外,布置成执行该方法的装置。
    • 40. 发明申请
    • A DIFFUSION-TYPE NDIR GAS ANALYZER WITH FAST RESPONSE TIME DUE TO CONVECTION FLOW
    • 具有对流流量的快速反应时间的扩散型NDIR气体分析仪
    • WO02004926A3
    • 2002-06-20
    • PCT/US2001/041326
    • 2001-07-11
    • G01N21/31G01N21/35G01N21/61
    • G01N21/61G01N21/3504G01N2021/3125G01N2021/317
    • A diffusion-type NDIR gas analyzer with an improved response time due to convetion flow created by a temperature gradient between gas located within a waveguide and gas located within a diffusion pocket of space created between the waveguide and a semi-permeable membrane which surrounds the waveguide. The temperature gradient may be created by a thermally resistive radiation source that is not thermally isolated from the waveguide. The semi-permeable membrane is made of a hydrophobic material and has a thickness sufficient to provide its own structural integrity. The semi-permeable membrane can have a porosity less than approximately 50 mu m and be comprised of ultra high molecular weight polyethylene or TEFLON.
    • 扩散型NDIR气体分析仪,其由于位于波导内的气体之间的温度梯度产生的响应时间而改善的响应时间,以及位于波导与包围波导的半透膜之间的空间扩散槽内的气体 。 温度梯度可以由不与波导热隔离的热阻辐射源产生。 半透膜由疏水材料制成,具有足以提供其自身结构完整性的厚度。 半透膜可以具有小于约50μm的孔隙,并且由超高分子量聚乙烯或TEFLON组成。