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    • 32. 发明授权
    • Stable solid formulations of cyclohexenone oxime ether herbicides
    • 环己烯酮肟醚除草剂稳定的固体制剂
    • US5981440A
    • 1999-11-09
    • US913779
    • 1997-09-23
    • Matthias BratzKarl-Friedrich JagerRainer BerghausHans Ziegler
    • Matthias BratzKarl-Friedrich JagerRainer BerghausHans Ziegler
    • A01N25/12A01N25/22A01N35/10A01N43/16A01N43/18A01N43/76A01N43/56A01N37/00A01N43/02
    • A01N35/10A01N25/12A01N43/16A01N43/18
    • Crop protection active compound formulations, comprising a cyclohexenone oxime ether of the general formula I ##STR1## where the radicals R.sup.1 -R.sup.6 have the following meanings: R.sup.1 is ethyl or propyl;R.sup.2 is hydrogen or an equivalent of an agriculturally utilizable cation;R.sup.3 is 2-thioethylpropyl, tetrahydrothiopyran-3-yl, tetrahydrothiopyran-4-yl, tetrahydropyran-3-yl, tetrahydropyran-4-yl, 1-methylthiocyclopropyl, 5-isopropylisoxazol-3-yl, 2,5-dimethylpyrazol-3-yl, 2,4,6-trimethylphenyl or 2,4,6-trimethyl-3-butyrylphenyl;R.sup.4 and R.sup.5 independently of one another are hydrogen, methyl or methoxycarbonyl;Alk is CH.sub.2 CH.sub.2, CH.sub.2 CH(CH.sub.3), CH.sub.2 CH.dbd.CH, CH.sub.2 CH.dbd.C(Cl) or CH.sub.2 CH.sub.2 CH.dbd.CH;R.sup.6 is hydrogen, phenyl, halophenyl, dihalophenyl, phenoxy, halophenoxy or dihalophenoxy;and a water-soluble basic salt of an acid having a pK.sub.a of greater than 5, alkali metal hydroxides and alkali metal carbonates being excluded, their preparation and use as herbicides are described.
    • PCT No.PCT / EP96 / 01046 Sec。 371日期1997年9月23日 102(e)1997年9月23日PCT 1996年3月12日PCT公布。 公开号WO96 / 29869 日期1996年10月3日保护活性化合物制剂,其包含通式I的环己烯酮肟醚,其中基团R 1 -R 6具有以下含义:R 1是乙基或丙基; R2是氢或相当于农业上可用的阳离子; R 3是2-硫代乙基丙基,四氢噻喃-3-基,四氢噻喃-4-基,四氢吡喃-3-基,四氢吡喃-4-基,1-甲硫基环丙基,5-异丙基异恶唑-3-基,2,5-二甲基吡唑-3-基, 2,4,6-三甲基苯基或2,4,6-三甲基-3-丁酰苯基; R 4和R 5彼此独立地是氢,甲基或甲氧基羰基; Alk是CH 2 CH 2,CH 2 CH(CH 3),CH 2 CH = CH,CH 2 CH = C(Cl)或CH 2 CH 2 CH = CH; R6是氢,苯基,卤代苯基,二卤代苯基,苯氧基,卤代苯氧基或二卤代苯氧基; 和pKa大于5的酸的水溶性碱性盐,不包括碱金属氢氧化物和碱金属碳酸盐,它们作为除草剂的制备和用途被描述。
    • 35. 发明申请
    • NON-AQUEOUS ACTIVE INGREDIENT CONCENTRATES HAVING AN HERBICIDAL EFFECT
    • 具有除草效果的非水性活性成分浓度
    • US20100227763A1
    • 2010-09-09
    • US12376320
    • 2007-08-03
    • Michael KrappRainer BerghausMatthias BratzElmar KiblerHerve R. Vantieghem
    • Michael KrappRainer BerghausMatthias BratzElmar KiblerHerve R. Vantieghem
    • A01N43/56
    • A01N43/56A01N25/02A01N25/30A01N43/10A01N43/80A01N2300/00
    • The present invention relates to active compound concentrates having herbicidal action, comprising a) from 10 to 100 g/l of at least one 4-benzoyl-substituted pyrazole compound of the formula I in which R1, R3 independently of one another are hydrogen, halogen, methyl, halomethyl, methoxy, halomethoxy, methylthio, methylsulfinyl or methylsulfonyl; R2 is a 5-membered heterocyclic radical which is unsubstituted or carries 1, 2, 3 or 4 substituents selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy and C1-C4-alkylthio; R4 is hydrogen, halogen or methyl; R5 is C1-C6-alkyl, C3-C6-cycloalkyl or C3-C6-cycloalkylmethyl; and R6 is hydrogen or C1-C4-alkyl; or one of its agriculturally useful salts, b) from 200 to 700 g/l of 2-chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide, and c) from 10 to 200 g/l of at least one surfactant S selected from a mixture of at least one anionic surfactant and at least one nonionic surfactant, where the components a), b) and c) are present dissolved in a mixture of organic solvents consisting to at least 95% by weight, based on the solvent mixture, of d1) at least one aprotic polar organic solvent having a miscibility with water at 25° C. and 1 bar of at least 50 g/l, and d2) at least one organic solvent having a solubility in water at 25° C. and 1 bar of less than 5 g/l.
    • 本发明涉及具有除草作用的活性化合物浓缩物,其包含a)10-100g / l至少一种式I的4-苯甲酰基取代的吡唑化合物,其中R 1,R 3彼此独立地为氢,卤素 ,甲基,卤代甲基,甲氧基,卤代甲氧基,甲硫基,甲基亚磺酰基或甲基磺酰基; R2是未取代的或携带1,2,3或4个选自卤素,C 1 -C 6烷基,C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷基,C 1 -C 4的取代基的5元杂环基 - 卤代烷氧基和C 1 -C 4 - 烷硫基; R4是氢,卤素或甲基; R5是C1-C6-烷基,C3-C6-环烷基或C3-C6-环烷基甲基; 和R6是氢或C1-C4-烷基; 或其农业上有用的盐之一,b)200-700g / l的2-氯-N-(2,4-二甲基-3-噻吩基)-N-(2-甲氧基-1-甲基乙基)乙酰胺,和 c)10至200g / l的至少一种选自至少一种阴离子表面活性剂和至少一种非离子表面活性剂的混合物的表面活性剂S,其中组分a),b)和c)存在于 基于溶剂混合物,至少95重量%的有机溶剂为d1)至少一种与25℃的水混合的至少一种非质子极性有机溶剂和至少50g / l的1巴,d2 )至少一种在25℃下在水中的溶解度和小于5g / l的1巴的有机溶剂。
    • 38. 发明申请
    • Amphiphilic Polymer Compositions and their Use
    • 两亲聚合物组合物及其用途
    • US20080287593A1
    • 2008-11-20
    • US11628609
    • 2005-06-07
    • Gunter OetterChristian KrugerHarald KohleMaria SchererNorbert WagnerMatthias BratzRainer BerghausRichard van Gelder
    • Gunter OetterChristian KrugerHarald KohleMaria SchererNorbert WagnerMatthias BratzRainer BerghausRichard van Gelder
    • C08L33/00C08L71/00
    • A01N25/04A01N25/30C08G18/283C08G18/3876C08G18/7831C08L33/06C08L75/04A01N47/24A01N43/653A01N43/40A01N53/00C08L2666/04
    • The present invention relates to amphiphilic polymer compositions, to a process for their preparation and to their use for preparing aqueous active compound compositions of water-insoluble active compounds, in particular active compounds for crop protection.The amphiphilic polymer compositions can be obtained by reacting a) at least one hydrophobic polymer P1 which carries functional groups R1 which are reactive toward isocyanate groups and which is constructed of ethylenically unsaturated monomers M1, comprising: a1) at least 10% by weight, based on the total amount of monomers M1, of monomers M1a of the formula I in which X is oxygen or a group N—R4; R1, R2, R3 and R4 are as defined in the claims and the description; a2) up to 90% by weight, based on the total amount of monomers M1, of neutral monoethylenically unsaturated monomers M1b whose solubility in water at 25° C. is less than 50 g/l and which are different from the monomers M1a; and a3) up to 30% by weight, based on the total amount of monomers M1, of ethylenically unsaturated monomers M1c which are different from the monomers M1a and M1b, b) at least one hydrophilic polymer P2 which carries functional groups R2 which are reactive toward isocyanate groups, c) with at least one compound V which contains isocyanate groups and, with respect to the isocyanate groups, has a functionality of at least 1.5.
    • 本发明涉及两亲聚合物组合物,其制备方法及其用于制备水不溶性活性化合物,特别是用于作物保护的活性化合物的水性活性化合物组合物的用途。 两亲性聚合物组合物可以通过使a)至少一种携带官能团R 1的疏水性聚合物P1与异氰酸酯基团反应,并由烯属不饱和单体M1构成,包括:a1) 至少10重量%,基于单体M1的总量,其中X是氧或NR 4的式I的单体M1a; R 1,R 2,R 3和R 4如权利要求和说明书所定义。 a2)高达90重量%,基于单体M1的总量,在25℃下在水中的溶解度小于50g / l且不同于单体M1a的中性单烯属不饱和单体M1b; 和a3)至多30重量%,基于单体M1的总量,不同于单体M1a和M1b的烯键式不饱和单体M1c,b)至少一种携带官能团R a的亲水性聚合物P2, 其对于异氰酸酯基团是反应性的,c)与至少一种含有异氰酸酯基团的化合物V相对于异氰酸酯基团具有至少1.5的官能度。