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31. 发明授权

US09321037B2 Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units 有权
标题翻译：加氢处理助催化剂组合物及其引入加氢处理装置的方法
公开(公告)号：US09321037B2
公开(公告)日：2016-04-26
申请号：US13715918
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： B01J8/20 , B01J23/78 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J35/00 , B01J23/85 , B01J31/02 , B01J35/02 , B01J37/00 , B01J31/04 , B01J31/06 , C10G45/08 , C10G45/16 , B01J37/04 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12
CPC分类号： B01J23/78 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J23/85 , B01J31/0247 , B01J31/04 , B01J31/06 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/04 , C10G45/08 , C10G45/16 , C10G2300/1033 , C10G2300/202
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
摘要翻译：加氢处理助催化剂组合物可以在一个实施方案中包括包含助催化剂颗粒和液体载体的第一组分，和包含分散剂和分散剂稀释剂的第二组分。助催化剂颗粒可以在微米尺寸范围内，并且分散剂可以促进助催化剂颗粒在诸如液体载体，分散剂稀释剂及其组合的材料中的分散。还公开了将加氢助催化剂组合物引入加氢处理系统的方法。

32. 发明授权

US08809223B2 Hydroprocessing catalysts and methods for making thereof 有权
标题翻译：加氢处理催化剂及其制备方法
公开(公告)号：US08809223B2
公开(公告)日：2014-08-19
申请号：US13331660
申请日：2011-12-20
申请人： Joseph V. Nguyen , Julie Chabot , Oleg Mironov
发明人： Joseph V. Nguyen , Julie Chabot , Oleg Mironov
IPC分类号： B01J27/02 , B01J27/043 , B01J27/045 , B01J23/00 , B01J23/40 , B01J23/42 , B01J23/58 , B01J23/70 , B01J23/74 , B01J23/44 , B01J23/02 , B01J23/06 , B01J23/883 , B01J23/85 , B01J27/051 , C10G49/04 , B01J35/00 , B01J37/20 , B01J23/24 , B01J23/887 , B01J35/10
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： A process for preparing an improved slurry catalyst for the upgrade of heavy oil feedstock is provided. The process comprises providing at least a metal precursor in solution comprising at least two different metal cations in its molecular structure, with at least one of the metal cations is a Group VIB metal cation; sulfiding the metal precursor with a sulfiding agent in solution forming a catalyst precursor; and mixing the catalyst precursor with a hydrocarbon diluent to form the slurry catalyst. In one embodiment, the at least a metal precursor comprising at least two different metal cations is prepared by combining and reacting at least one Group VIB metal compound with at least a Promoter metal compound selected from Group VIII, Group IIB, Group IIA, Group IVA metals and combinations thereof.
摘要翻译：提供了一种制备用于提高重油原料的改进的浆料催化剂的方法。该方法包括在其分子结构中提供包含至少两种不同金属阳离子的溶液中的至少一种金属前体，至少一种金属阳离子是VIB族金属阳离子; 在形成催化剂前体的溶液中用硫化剂硫化金属前体; 并将催化剂前体与烃稀释剂混合以形成浆料催化剂。在一个实施方案中，至少包含至少两种不同金属阳离子的金属前体通过将至少一种VIB族金属化合物与至少一种选自第VIII族，IIB族，IIA族，IVA族的促进剂金属化合物金属及其组合。

33. 发明申请

US20140171299A1 HYDROPROCESSING CO-CATALYST COMPOSITIONS AND METHODS OF INTRODUCTION THEREOF INTO HYDROPROCESSING UNITS 有权
标题翻译：氢化催化剂组合物及其引入方法进入水解单位
公开(公告)号：US20140171299A1
公开(公告)日：2014-06-19
申请号：US13715943
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： B01J23/78 , B01J23/75 , B01J23/755 , B01J23/28 , B01J23/30
CPC分类号： B01J23/78 , B01J21/02 , B01J21/06 , B01J21/10 , B01J21/12 , B01J23/28 , B01J23/30 , B01J23/75 , B01J23/755 , B01J23/85 , B01J31/0205 , B01J31/0247 , B01J35/0006 , B01J35/023 , B01J37/0036 , B01J37/04 , C10G47/26 , C10G49/02 , C10G49/12
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.
摘要翻译：加氢处理助催化剂组合物可以在一个实施方案中包括包含助催化剂颗粒和液体载体的第一组分，和包含分散剂和分散剂稀释剂的第二组分。助催化剂颗粒可以在微米尺寸范围内，并且分散剂可以促进助催化剂颗粒在诸如液体载体，分散剂稀释剂及其组合的材料中的分散。还公开了将加氢助催化剂组合物引入加氢处理系统的方法。

34. 发明申请

US20140166541A1 HYDROPROCESSING CO-CATALYST COMPOSITIONS AND METHODS OF INTRODUCTION THEREOF INTO HYDROPROCESSING UNITS 审中-公开
公开(公告)号：US20140166541A1
公开(公告)日：2014-06-19
申请号：US13715959
申请日：2012-12-14
申请人： Julie Chabot , Bo Kou , Alexander Kuperman
发明人： Julie Chabot , Bo Kou , Alexander Kuperman
IPC分类号： C10G45/04
CPC分类号： C10G45/04 , C10G45/16
摘要： A hydroprocessing co-catalyst composition may comprise in an embodiment a first component comprising co-catalyst particles and a liquid carrier, and a second component comprising a dispersant and a dispersant diluent. The co-catalyst particles may be in the micron size range, and the dispersant may promote dispersion of the co-catalyst particles in materials such as the liquid carrier, the dispersant diluent, and combinations thereof. Methods of introducing a hydroprocessing co-catalyst composition into a hydroprocessing system are also disclosed.

35. 发明授权

US07897035B2 Systems and methods for producing a crude product 有权
标题翻译：用于生产粗产品的系统和方法
公开(公告)号：US07897035B2
公开(公告)日：2011-03-01
申请号：US12212796
申请日：2008-09-18
申请人： Julie Chabot
发明人： Julie Chabot
IPC分类号： C10G45/00
CPC分类号： C10G65/10 , C10G47/26 , C10G65/12
摘要： Systems and methods for hydroprocessing a heavy oil feedstock, the system employs a plurality of contacting zones and separation zones with at least some of the heavy oil feedstock being supplied to at least a contacting zone other than the first contacting zone. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock, forming upgraded products of lower boiling boiling hydrocarbons. In the separation zones, upgraded products are removed overhead and optionally, further treated in an in-line hydrotreater. At least a portion of the non-volatile fractions recovered from at least one of the separation zones is recycled back to the first contacting zone in the system.
摘要翻译：用于加氢处理重油原料的系统和方法，所述系统采用多个接触区域和分离区域，其中至少一些重油原料供应至少于除第一接触区域之外的接触区域。接触区在加氢裂化条件下运行，使用用于升级重油原料的浆料催化剂，形成较低沸点沸点烃的升级产物。在分离区中，升级产物在顶部除去，任选地，在直列加氢处理机中进一步处理。从至少一个分离区回收的至少一部分非挥发性馏分被循环回系统中的第一接触区。

36. 发明授权

US06387334B1 Balanced flow resistance OCR distributor cone 失效
标题翻译：平衡流阻OCR分配锥
公开(公告)号：US06387334B1
公开(公告)日：2002-05-14
申请号：US09216268
申请日：1998-12-18
申请人： William B. Krantz , David E. Earls , Harold J. Trimble , Julie Chabot , Krishniah Parimi
发明人： William B. Krantz , David E. Earls , Harold J. Trimble , Julie Chabot , Krishniah Parimi
IPC分类号： B01J808
CPC分类号： B01J8/003 , B01J8/008 , B01J8/0085 , B01J8/06 , B01J8/44 , B01J2208/00752 , B01J2208/00884 , B01J2208/024
摘要： The invention comprises an OCR catalyst reactor which includes passive spheres and catalyst particles having substantially the same size and separated on opposite sides of a distributor cone by a screen. The use of passive spheres of substantially the same size to the catalyst particles provides for a more uniform distribution of the gas liquid reactants charged into the reactor vessel. The screen is configured such that it provides a separation of the catalyst and the passive spheres while being sized to prevent plugging.
摘要翻译：本发明包括一种OCR催化剂反应器，其包括无源球体和具有基本相同尺寸的催化剂颗粒，并通过筛网在分配器锥体的相对侧上分离。使用与催化剂颗粒基本上相同尺寸的被动球提供了装入反应器容器中的气体液体反应物更均匀的分布。屏幕被配置为使得其提供催化剂和被动球的分离，同时确定尺寸以防止堵塞。

37. 发明授权

US08927448B2 Hydroprocessing catalysts and methods for making thereof 有权
标题翻译：加氢处理催化剂及其制备方法
公开(公告)号：US08927448B2
公开(公告)日：2015-01-06
申请号：US13233491
申请日：2011-09-15
申请人： Bo Kou , Julie Chabot
发明人： Bo Kou , Julie Chabot
IPC分类号： B01J38/48 , C10G47/02 , C10G47/26 , C10G65/00 , C10G65/10 , C10G65/18
CPC分类号： C10G47/02 , C10G47/26 , C10G47/32 , C10G65/00 , C10G65/10 , C10G65/18 , C10G2300/205 , C10G2300/206 , C10G2300/701 , C10G2300/802
摘要： A method to prepare an improved catalyst feed to a system to upgrade heavy oil. The method comprises: providing a spent catalyst that has been used in a hydroprocessing operation has with a solid content ranging from 5 to 50 wt. % in soluble hydrocarbons and having less than 80% but more than 10% of original catalytic activity; removing at least 50% of the soluble hydrocarbons removed in a deoiling step; treating the deoiled spent catalyst with a treating solution containing at least one of plain water, a mineral acid, an oxidizing agent, and combinations thereof to reduce the concentration of at least one metal contaminant in the deoiled spent catalyst by at least 40%. After treatment, the treated deoiled spent catalyst is slurried in a hydrocarbon medium, and fed to the heavy oil upgrade system as part of the catalyst feed system with a fresh slurry catalyst.
摘要翻译：一种制备改进的催化剂进料到系统以升级重油的方法。该方法包括：提供已经在加氢操作中使用的废催化剂的固体含量范围为5-50wt。％的可溶性碳氢化合物，并且具有小于80％但大于10％的原始催化活性; 去除在脱油步骤中去除的至少50％的可溶性烃; 用含有浅水，无机酸，氧化剂及其组合中的至少一种的处理溶液处理脱油的废催化剂，以将去除的废催化剂中的至少一种金属污染物的浓度降低至少40％。处理后，经处理的脱油废催化剂在烃介质中浆化，并作为催化剂进料系统的一部分用新鲜的浆料催化剂进料至重油升级系统。

38. 发明授权

US08236169B2 Systems and methods for producing a crude product 有权
标题翻译：用于生产粗产品的系统和方法
公开(公告)号：US08236169B2
公开(公告)日：2012-08-07
申请号：US12506937
申请日：2009-07-21
申请人： Joseph V Nguyen , Axel Brait , Julie Chabot , Bo Kou , Erin Maris , Rahul S. Bhaduri , Alexander E. Kuperman
发明人： Joseph V Nguyen , Axel Brait , Julie Chabot , Bo Kou , Erin Maris , Rahul S. Bhaduri , Alexander E. Kuperman
IPC分类号： C10G11/00
CPC分类号： C10G65/18 , C10G47/02 , C10G47/26 , C10G47/32 , C10G65/00 , C10G65/10 , C10G2300/1044 , C10G2300/1074 , C10G2300/202 , C10G2300/203 , C10G2300/205 , C10G2300/206 , C10G2300/302 , C10G2300/308 , C10G2300/44 , C10G2300/80
摘要： A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and at least a separation zone to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. At least an additive material selected from inhibitor additives, anti-foam agents, stabilizers, metal scavengers, metal contaminant removers, metal passivators, and sacrificial materials, in an amount of less than 1 wt. % of the heavy oil feedstock, is added to at least one of the contacting zones. In one embodiment, the additive material is an anti-foam agent. In another embodiment, the additive material is a sacrificial material for trapping heavy metals in the heavy oil feed and/or deposited coke, thus prolonging the life of the slurry catalyst.
摘要翻译：公开了一种加氢处理重油原料的方法。该方法以一次通过模式运行，采用多个接触区和至少一个分离区，将至少一部分重油原料转化成低沸点烃，形成升级产物。接触区在加氢裂化条件下运行，使用用于升级重油原料的浆料催化剂。至少一种选自抑制剂添加剂，消泡剂，稳定剂，金属清除剂，金属污染物去除剂，金属钝化剂和牺牲材料的添加剂材料，其量小于1wt。％的重油原料加入到至少一个接触区中。在一个实施方案中，添加剂材料是消泡剂。在另一个实施方案中，添加剂材料是用于在重油进料和/或沉积焦炭中捕获重金属的牺牲材料，从而延长了浆料催化剂的寿命。

39. 发明申请

US20120168351A1 HYDROPROCESSING CATALYSTS AND METHODS FOR MAKING THEREOF 审中-公开
标题翻译：氢化催化剂及其制备方法
公开(公告)号：US20120168351A1
公开(公告)日：2012-07-05
申请号：US13331305
申请日：2011-12-20
申请人： Erin P. Maris , Oleg Mironov , Julie Chabot
发明人： Erin P. Maris , Oleg Mironov , Julie Chabot
IPC分类号： B01J37/20 , B01J27/049 , C10G29/10 , B01J27/188 , C10G29/16 , B01J27/047 , C10G45/04
CPC分类号： B01J23/883 , B01J23/24 , B01J23/85 , B01J23/8872 , B01J23/8873 , B01J27/051 , B01J27/0515 , B01J35/0073 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1095 , B01J37/20 , C10G49/04 , C10G49/06 , C10G49/12 , C10G2300/107 , C10G2300/1077 , C10G2300/205 , C10G2300/301 , C10G2300/701 , C10G2300/703 , C10G2300/802
摘要： An improved process for preparing a slurry catalyst for the upgrade of heavy oil feedstock is provided. The process employs rework material obtained from a process to prepare a hydroprocessing catalyst as part of the metal precursor feed. In one embodiment, the process comprises mixing the rework material with a hydrocarbon diluent to form a slurried metal precursor for subsequent in-situ sulfiding in a heavy oil upgrade process. In another embodiment, the rework is slurried in a hydrocarbon carrier and a sulfiding agent, forming a slurry catalyst. In yet another embodiment, the rework material is mixed directly with a heavy oil feedstock under in-situ sulfiding conditions, forming a slurry catalyst.
摘要翻译：提供了一种用于制备用于重油原料升级的浆料催化剂的改进方法。该方法采用从工艺获得的返工材料来制备加氢处理催化剂作为金属前体原料的一部分。在一个实施方案中，该方法包括将返工材料与烃稀释剂混合以形成用于随后在重油升级过程中原位硫化的浆状金属前体。在另一个实施方案中，返工在烃载体和硫化剂中浆化，形成淤浆催化剂。在另一个实施方案中，返工材料在原位硫化条件下直接与重油原料混合，形成浆料催化剂。

40. 发明申请

US20110017637A1 Systems and Methods for Producing a Crude Product 审中-公开
标题翻译：生产原油产品的系统和方法
公开(公告)号：US20110017637A1
公开(公告)日：2011-01-27
申请号：US12506987
申请日：2009-07-21
申请人： Bruce Reynolds , Julie Chabot
发明人： Bruce Reynolds , Julie Chabot
IPC分类号： C10G47/00 , C10G65/14 , C10G65/10
CPC分类号： C10G47/32 , C10G47/02 , C10G47/26 , C10G65/00 , C10G65/10 , C10G65/18
摘要： A process for hydroprocessing heavy oil feedstock is disclosed. The process operates in once-through mode, employing a plurality of contacting zones and separation zones in sequential mode, parallel mode, or combinations thereof to convert at least a portion of the heavy oil feedstock to lower boiling hydrocarbons, forming upgraded products. The contacting zones operate under hydrocracking conditions, employing a slurry catalyst for upgrading the heavy oil feedstock. In one embodiment, the effluent stream from the contacting zone is sent to a separation zone in series operating at a pressure drop of at most 100 psi from the contacting zone. In another embodiment, the effluent from a contacting zone to the next contacting zone in series for further upgrade, with the next contacting zone having a pressure drop of at most 100 psi, with the pressure drop is not due to a pressure reducing device as in the prior art.
摘要翻译：公开了一种加氢处理重油原料的方法。该方法以一次通过模式操作，以顺序模式，并联模式或其组合使用多个接触区域和分离区域，以将至少一部分重油原料转化成低沸点烃，形成升级产物。接触区在加氢裂化条件下运行，使用用于升级重油原料的浆料催化剂。在一个实施方案中，将来自接触区域的流出物流送入分离区域，该分离区域在接触区域以至多100psi的压力下串联运行。在另一个实施方案中，将来自接触区域的下一个接触区域的流出物串联以进一步升级，下一个接触区域的压力降至最低为100psi，而压降不是由于减压装置如现有技术

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