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31. 发明授权

US5034371A Thermal transfer image recording method and thermal transfer dye donating material 失效
公开(公告)号：US5034371A
公开(公告)日：1991-07-23
申请号：US499751
申请日：1990-03-27
申请人： Mitsugu Tanaka , Seiiti Kubodera
发明人： Mitsugu Tanaka , Seiiti Kubodera
IPC分类号： B41M5/035 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/392 , B41M5/395
CPC分类号： B41M5/3858 , B41M5/392 , B41M5/395 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： A method for recording a thermal transfer image comprising the step of transferring dyes which comprises a yellow dye represented by the general formula (I), a magenta dye represented by the general formula (II), and at least one of a cyan dye represented by the general formula (III) and a cyan dye represented by the general formula (IV), and a thermal transfer dye donating material which has on a support a color material layer containing at least one dye selected from among a yellow dye represented by the general formula (I), a magenta dye represented by the general formula (II), and a cyan dye represented by the general formula (III) and/or a cyand dye represented by the general formula (IV), together with a fluorine-containing compound: ##STR1## wherein R.sup.1 represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an alkoxycarbonyl group, a cyano group, or a carbamoyl group; R.sup.2 represents a hydrogen atom, an alkyl group, or an aryl group; R.sup.3 represents an aryl group, or a heterocyclyl group; and R.sup.4 and R.sup.5 each represents a hydrogen atom, or an alkyl group; ##STR2## wherein R.sup.6, R.sup.7, R.sup.8, R.sup.9 and R.sup.10 each represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, a cyano group, an acylamino group, a sulfonylamino group, an ureido group, an alkoxycarbonylamino group, an alkylthio group, an arylthio group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, an acyl group, or an amino group; R.sup.11 and R.sup.12 each represents a hydrogen atom, an alkyl group or an aryl group; or R.sup.11 and R.sup.12 may combine with each other to form a ring, or R.sup.11 may combine with R.sup.8 to form a ring and/or R.sup.12 may combine with R.sup.9 to form a ring; and X, Y and Z each represents ##STR3## or a nitrogen atom, wherein R.sup.13 represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, or an amino group; or when both X and Y, or both Y and Z are ##STR4## they may combine with each other to form a saturated or unsaturated carbon ring; ##STR5## wherein Q represents atoms necessary to complete a carbon ring constituted by 5 or more member atoms, or a hetero ring constituted by 5 or more member atoms including at least one nitrogen atom; each substituent from R.sup.14 and R.sup.19 has the same meaning as each from R.sup.6 to R.sup.10 ; R.sup.20 and R.sup.21 each has the same meaning as R.sup.11 or R.sup.12 ; or R.sup.20 and R.sup.21 may combine with each other to form a ring, or R.sup.20 may combine with R.sup.17 to form a ring and/or R.sup.21 may combine with R.sup.18 to form a ring; ##STR6## wherein each substituent from R.sup.22 to R.sup.29 has the same meaning as each from R.sup.6 to R.sup.10 ; and R.sup.30 and R.sup.31 each has the same meaning as R.sup.11 or R.sup.12 ; or R.sup.30 and R.sup.31 may combine with each other to form a ring, or R.sup.30 may combine with R.sup.27 to form a ring and/or R.sup.31 may combine with R.sup.28 to form a ring.

32. 发明授权

US5008232A Thermal transfer dye donating material 失效
标题翻译：热转印染料
公开(公告)号：US5008232A
公开(公告)日：1991-04-16
申请号：US461893
申请日：1990-01-08
申请人： Mitsugu Tanaka , Seiiti Kubodera
发明人： Mitsugu Tanaka , Seiiti Kubodera
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/30 , B41M5/388 , B41M5/39 , D06P5/00
CPC分类号： B41M5/39 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer dye donating material, comprising a color material layer formed on a support, said color material layer containing a dye represented by the general formula (I) below: ##STR1## wherein Q.sup.1 is an atomic group having at least one nitrogen atom and forming a five- to seven-membered nitrogen-containing heterocycle together with the carbon atoms to be bonded; R.sup.1 is an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an aminocarbonyl group, or a sulfonyl group; R.sup.2 is a hydrogen atom or an alkyl group; R.sup.3 to R.sup.7 are independently a hydrogen atom, an alkyl group, an alkoxy group, or a halogen atom; X.sup.1 and X.sup.2 are independently an alkylene group; Y.sup.1 is an alkoxy group, a halogen atom, an acylamino group, an alkoxycarbonyl group, an alkoxycarbonyloxy group, a cyano group, an alkoxycarbonylamino group, an aminocarbonylamino group, a carbamoyl group, an acyloxy group, an acyl group or a hydroxy group; Y.sup.2 is a hydrogen atom or groups defined above as Y.sup.1.
摘要翻译：一种热转移染料供体材料，包括形成在载体上的着色材料层，所述着色材料层含有下列通式（I）所示的染料：其中Q1是具有至少一个氮原子并与待键合的碳原子一起形成五至七元含氮杂环; R1是酰基，烷氧基羰基，芳氧基羰基，氨基羰基或磺酰基; R2是氢原子或烷基; R3至R7独立地为氢原子，烷基，烷氧基或卤素原子; X1和X2独立地为亚烷基; Y 1为烷氧基，卤素原子，酰氨基，烷氧基羰基，烷氧基羰基氧基，氰基，烷氧基羰基氨基，氨基羰基氨基，氨基甲酰基，酰氧基，酰基或羟基。 Y2是氢原子或上面定义为Y1的基团。

33. 发明授权

US4973573A Thermal transfer dye-providing material 失效
标题翻译：热转印染料提供材料
公开(公告)号：US4973573A
公开(公告)日：1990-11-27
申请号：US476850
申请日：1990-02-07
申请人： Mitsugu Tanaka , Seiiti Kubodera , Hisashi Mikoshiba
发明人： Mitsugu Tanaka , Seiiti Kubodera , Hisashi Mikoshiba
IPC分类号： B41M5/385 , B41M5/035 , B41M5/26 , B41M5/388 , B41M5/39
CPC分类号： B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/31801
摘要： A thermal transfer dye-providing material is disclosed, which comprises a support having provided thereon a colorant layer, said colorant layer containing a dye represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, a halogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aryl group, an aryloxy group, an aralkyl group, a cyano group, an acylamino group, a sulfonylamino group, a ureido group, an alkoxycarbonylamino group, an alkylthio group, an arylthio group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a sulfonyl group, an acyl group or an amino group, R.sub.3 R.sub.4 each represents an alkylene group, R.sub.5 represents a halogen atom, an alkoxycarbonyl group, an alkoxycarbonyloxy group, a cyano group, an alkoxycarbonylamino group, a ureido group, a carbamoyl group, a sulfonyl group, an acyloxy group or an acyl group, R.sub.6 represents a hydrogen atom or R.sub.5, n represents 0 or an integer of 1 to 3, and X, Y and Z each represents ##STR2## or a nitrogen atom (wherein R.sub.7 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, an alkoxy group, an aryloxy group or an amino group) or, when X and Y, or Y and Z, are ##STR3## they may be bound to each other to form a saturated or unsaturated hydrocarbon ring, with the above-described substituents being optionally further substituted.
摘要翻译：公开了一种热转印染料提供材料，其包括在其上提供着色剂层的载体，所述着色剂层含有由以下通式（I）表示的染料：其中R 1和R 2各自表示氢原子，卤素原子，烷基，环烷基，烷氧基，芳基，芳氧基，芳烷基，氰基，酰氨基，磺酰氨基，脲基，烷氧基羰基氨基，烷硫基，芳硫基，烷氧基羰基，氨基甲酰基，氨磺酰基，磺酰基，酰基或氨基，R3 R4各自表示亚烷基，R5表示卤素原子，烷氧基羰基烷氧基羰基氧基，氰基，烷氧基羰基氨基，脲基，氨基甲酰基，磺酰基，酰氧基或酰基，R6表示氢原子或R5，n表示0或1〜 3，X，Y和Z 各自表示或氮原子（其中，R7表示氢原子，烷基，环烷基，芳烷基，芳基，烷氧基，芳氧基或氨基），或者当X和 Y或Y和Z是它们可以彼此结合形成饱和或不饱和的烃环，上述取代基任选被进一步取代。

34. 发明授权

US4929277A Recording liquid 失效
标题翻译：记录液体
公开(公告)号：US4929277A
公开(公告)日：1990-05-29
申请号：US217205
申请日：1988-07-11
申请人： Mitsugu Tanaka , Takeo Sakai
发明人： Mitsugu Tanaka , Takeo Sakai
IPC分类号： C09D11/00 , C09D11/16
CPC分类号： C09D11/17 , C09D11/36
摘要： A recording liquid comprising an organic solvent and at least one compound represented by formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, a carboxylic acid ester group or a carbamoyl group; R.sub.2 represents a hydrogen atom, an alkyl group or an aryl group; and R.sub.3 represents an aryl group provided that none of R.sub.1, R.sub.2 and R.sub.3 is substituted with a sulfonic acid group. The yellow recording liquid has good color and excellent light resistance with good solubility.
摘要翻译：一种包含有机溶剂和至少一种由式（I）表示的化合物的记录液：其中R 1表示氢原子，烷基，烷氧基，芳基，羧酸酯基或氨基甲酰基; R2表示氢原子，烷基或芳基; 并且R 3表示芳基，条件是R 1，R 2和R 3不被磺酸基取代。黄色记录液具有良好的颜色和优异的耐光性，溶解性好。

35. 发明授权

US4284714A Method of forming a photographic image 失效
标题翻译：形成摄影图像的方法
公开(公告)号：US4284714A
公开(公告)日：1981-08-18
申请号：US148478
申请日：1980-05-09
申请人： Junkichi Ogawa , Mitsugu Tanaka , Minoru Yamada
发明人： Junkichi Ogawa , Mitsugu Tanaka , Minoru Yamada
IPC分类号： G03C1/00 , G03C5/30 , G03C5/305 , G03C7/00
CPC分类号： G03C5/305 , G03C5/3021
摘要： A method is described for forming a black-and-white photographic image consisting essentially of a silver image and a coextensive dye image, in which the maximum density of the image and the fastness of the image to light are greatly improved, by processing a silver halide photosensitive material which contains silver halide in a reduced amount (compared with conventional materials) that has been imagewise exposed to light in the presence of a naphthalene compound containing at least two hydroxy substituents groups on the nucleus thereof and a p-phenylenediamine type developing agent or a precursor of the p-phenylenediamine compound.
摘要翻译：描述了一种用于形成基本上由银图像和共延伸染料图像组成的黑白照相图像的方法，其中图像的最大密度和图像对光的牢度被大大提高，通过处理银卤化物感光材料，其含有在其核上存在有至少两个羟基取代基的萘化合物存在下成像曝光的减少量的卤化银（与常规材料相比）和对苯二胺型显影剂或对苯二胺化合物的前体。

36. 发明授权

US4187110A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4187110A
公开(公告)日：1980-02-05
申请号：US858225
申请日：1977-12-07
申请人： Morio Yagihara , Mitsugu Tanaka , Takeshi Hirose , Toshiaki Aono
发明人： Morio Yagihara , Mitsugu Tanaka , Takeshi Hirose , Toshiaki Aono
IPC分类号： G03C7/26 , C07C67/00 , C07C301/00 , C07C309/72 , C07C313/00 , C07C317/14 , C07C317/24 , C07C317/28 , C07C317/44 , C07C323/22 , C07C323/52 , C07C323/56 , C07C323/66 , C07C323/67 , C07D249/12 , C07D249/18 , C07D257/04 , C07D417/12 , C07D417/14 , C07D487/04 , G03C1/04 , G03C7/305 , G03C7/32 , G03C1/06
CPC分类号： C07D257/04 , C07C205/45 , G03C7/305 , G03C7/30535 , Y10S430/158
摘要： A silver halide photographic light-sensitive material containing a development inhibitor releasing compound, which is capable of forming a substantially colorless product, and which is represented by the following general formula (I): ##STR1## wherein X represents ##STR2## --SO.sub.2 R.sub.1, --SO.sub.2 OR.sub.1, --SO.sub.2 NH.sub.2, --SO.sub.2 NHR.sub.1, --SO.sub.2 N(R.sub.1).sub.2, --CN, --N.sup.+ (R.sub.1).sub.3 or ##STR3## R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.1 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; R represents an aromatic group substituted with at least one of a nitro group, an acyl group, an alkoxycarbonyl group, a cyano group, a sulfamoyl group, a carbamoyl group, an aryloxycarbonyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkoxysulfonyl group and an aryloxysulfonyl group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a developing agent to provide an arylmercapto compound, a heterocyclic mercapto compound, a triazole compound, a benzotriazole compound or a naphthotriazole compound which has a development inhibiting effect.
摘要翻译：含有显影抑制剂释放化合物的卤化银照相感光材料，其能够形成基本上无色的产物，并且由以下通式（I）表示：其中X表示 -SO2R1，-SO2OR1，-SO2NH2，-SO2NHR1，-SO2N（R1）2，-CN，-N +（R1）3或R1表示脂族基团，芳香族基团或杂环基团，可以组合并表示与其连接的氮原子一起形成含氮杂环基所需的原子团; R表示被硝基，酰基，烷氧基羰基，氰基，氨磺酰基，氨基甲酰基，芳氧基羰基，烷基磺酰基，芳基磺酰基，烷氧基磺酰基中的至少一种取代的芳基和芳氧基磺酰基; Y表示与显影剂的氧化物反应后能够从通式（I）表示的化合物中释放的基团，提供芳基巯基化合物，杂环巯基化合物，三唑化合物，苯并三唑化合物或萘并三唑化合物，其具有显影抑制作用。

37. 发明授权

US4157916A Silver halide photographic light-sensitive material 失效
标题翻译：卤化银照相感光材料
公开(公告)号：US4157916A
公开(公告)日：1979-06-12
申请号：US815407
申请日：1977-07-13
申请人： Morio Yagihara , Mitsugu Tanaka , Toshiaki Aono , Takeshi Hirose
发明人： Morio Yagihara , Mitsugu Tanaka , Toshiaki Aono , Takeshi Hirose
IPC分类号： G03C7/26 , C07D249/18 , C07D249/22 , C07D487/04 , G03C7/305 , G03C7/00 , G03C1/76 , G03C5/30
CPC分类号： C07D487/04 , C07D249/18 , C07D249/22 , G03C7/305 , Y10S430/158
摘要： A silver halide photographic light-sensitive material containing a novel development inhibitor releasing coupler compound, capable of forming a substantially colorless product, represented by the following general formula (I): ##STR1## wherein R represents ##STR2## X represents ##STR3## --SO.sub.2 R.sub.2, --SO.sub.2 OR.sub.2, --SO.sub.2 N(R.sub.2).sub.2, --SO.sub.2 NHR.sub.2, --CN, --N.sup.+ (R.sub.2).sub.3 or ##STR4## R.sub.1 and R.sub.2 each represents an aliphatic group, an aromatic group or a heterocyclic group and further two R.sub.2 groups can combine and represent an atomic group necessary to form, together with the nitrogen atom to which they are attached, a nitrogen-containing heterocyclic group; and Y represents a group capable of being released from the compound represented by the general formula (I) upon reaction with the oxidation product of a color developing agent to provide a compound which has a development inhibiting effect and having a triazole ring bonded to the carbon atom through the nitrogen atom at the 1-position thereof.
摘要翻译：含有下述通式（I）表示的能够形成基本无色的产物的新型显影抑制剂释放成色剂化合物的卤化银照相感光材料：其中R表示X表示< 图像> -SO 2 R 2，-SO 2 OR 2，-SO 2 N（R 2）2，-SO 2 NHR 2，-CN，-N +（R 2）3或R 1和R 2各自表示脂族基，芳基或杂环基， R2基团可以组合并且表示与它们所连接的氮原子一起形成含氮杂环基所需的原子团; Y表示与彩色显影剂的氧化物反应后能够从由通式（I）表示的化合物释放的基团，提供具有显影抑制作用的化合物，并且具有与碳键合的三唑环原子通过其1位上的氮原子。

38. 发明授权

US5751504A Digital video and audio signal recording apparatus 失效
标题翻译：数字视频和音频信号记录装置
公开(公告)号：US5751504A
公开(公告)日：1998-05-12
申请号：US638846
申请日：1996-04-29
申请人： Mitsugu Tanaka
发明人： Mitsugu Tanaka
IPC分类号： G11B20/10 , H04N5/92 , H04N5/926 , H04N9/79 , H04N9/804 , H04N9/806 , G11B5/02
CPC分类号： H04N5/9261 , H04N5/926 , H04N9/7921 , H04N9/8063 , H04N9/8042
摘要： A digital signal recording apparatus is arranged to be capable of permitting long-time recording on one and the same recording medium without impairing the quality of audio signals at all. The apparatus has a first mode in which a digital video signal supplied from a video input circuit and having the amount of information not compressed by a video compression circuit is recorded on the recording medium by a recording circuit while all of n channel digital audio signals supplied from an audio input circuit are recorded by the recording circuit; and a second mode in which the digital video signal having the amount of information compressed by the video compression circuit and only part of the n channel digital audio signals supplied from the audio input circuit are recorded by the recording circuit.
摘要翻译：数字信号记录装置被配置为能够在一个相同的记录介质上允许长时间记录，而不损害音频信号的质量。该装置具有第一模式，其中从视频输入电路提供的具有未被视频压缩电路压缩的信息量的数字视频信号通过记录电路记录在记录介质上，同时提供所有n个通道数字音频信号由音频输入电路由记录电路记录; 以及第二模式，其中具有由视频压缩电路压缩的信息量和仅从音频输入电路提供的n个通道数字音频信号的一部分的数字视频信号由记录电路记录。

39. 发明授权

US5541739A Audio signal recording apparatus 失效
标题翻译：音频信号记录装置
公开(公告)号：US5541739A
公开(公告)日：1996-07-30
申请号：US541981
申请日：1995-10-10
申请人： Mitsugu Tanaka
发明人： Mitsugu Tanaka
IPC分类号： G11B20/10 , H04N5/92 , H04N5/926 , H04N9/79 , H04N9/804 , H04N9/806 , H04N5/928
CPC分类号： H04N5/9261 , H04N5/926 , H04N9/7921 , H04N9/8063 , H04N9/8042
摘要： A digital signal recording apparatus is arranged to be capable of permitting long-time recording on the same recording medium without impairing the quality of audio signals. The apparatus has a first mode in which a digital video signal supplied from a video input circuit and having the amount of information not compressed by a video compression circuit is recorded on the recording medium by a recording circuit while all of n channel digital audio signals supplied from an audio input circuit are recorded by the recording circuit; and a second mode in which the digital video signal having the amount of information compressed by the video compression circuit and only part of the n channel digital audio signals supplied from the audio input circuit are recorded by the recording circuit.
摘要翻译：数字信号记录装置被配置为能够允许在同一记录介质上长时间记录而不损害音频信号的质量。该装置具有第一模式，其中从视频输入电路提供的具有未被视频压缩电路压缩的信息量的数字视频信号通过记录电路记录在记录介质上，同时提供所有n个通道数字音频信号由音频输入电路由记录电路记录; 以及第二模式，其中具有由视频压缩电路压缩的信息量和仅从音频输入电路提供的n个通道数字音频信号的一部分的数字视频信号由记录电路记录。

40. 发明授权

US5403811A Thermal transfer dye donating materials 失效
标题翻译：热转印染料
公开(公告)号：US5403811A
公开(公告)日：1995-04-04
申请号：US105946
申请日：1993-08-13
申请人： Hisashi Mikoshiba , Mitsugu Tanaka , Masakazu Morigaki , Seiiti Kubodera
发明人： Hisashi Mikoshiba , Mitsugu Tanaka , Masakazu Morigaki , Seiiti Kubodera
IPC分类号： B41M5/035 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/38
CPC分类号： B41M5/385 , B41M5/3852 , B41M5/3854 , B41M5/388 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： A thermal transfer dye donating material comprising a support having thereon a dye donating layer which contains a thermo-mobile dye, wherein the thermo-mobile dye is a dye which can be represented by the general formula (I) indicated below.A--(L--B).sub.q (I)In this formula, A represents a dye residue which has an absorbance in the visible region and/or infrared region, L represents a divalent linking group or a simple bond, and B represents an atomic grouping which has the effect of suppressing the fading of the dye. Moreover, q is 1 or 2, and when q is 2, L and B may be the same or different.
摘要翻译：一种热转移染料供体材料，其包含其上具有含有热移动染料的染料供体层的载体，其中所述热移动染料是可由下述通式（I）表示的染料。 A-（LB）q（I）在该式中，A表示在可见区和/或红外区具有吸光度的染料残基，L表示二价连接基团或简单键，B表示原子团，具有抑制染料褪色的效果。此外，q为1或2，当q为2时，L和B可以相同或不同。

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