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31. 发明授权

US4064176A Di-substituted meta-terphenyl compounds and resulting polymers 失效
标题翻译：二取代的次三联苯化合物和所得的聚合物
公开(公告)号：US4064176A
公开(公告)日：1977-12-20
申请号：US643836
申请日：1975-12-23
申请人： Guy Rabilloud , Bernard Sillion
发明人： Guy Rabilloud , Bernard Sillion
IPC分类号： C07C45/43 , C08G73/06 , C07C49/76
CPC分类号： C07C45/43 , C07C45/28 , C07C45/46 , C08G73/0694
摘要： New tetracarbonyl compounds of the formula ##STR1## where R is a hydrogen atom, an alkyl radical or an aryl radical. The invention also contemplates the thermostable polymers obtained by reacting an aromatic tetra-amine with at least one of the above tetracarbonyl compounds.
摘要翻译：新型的具有式“IMAGE”+ TR 的四羰基化合物，其中R是氢原子，烷基或芳基。本发明还考虑通过使芳族四胺与至少一种上述四羰基化合物反应而获得的热稳定性聚合物。

32. 发明授权

US4061581A Trimethylolpropane esters useful as base lubricants for motor oils 失效
标题翻译：三羟甲基丙烷酯可用作机油的基础润滑剂
公开(公告)号：US4061581A
公开(公告)日：1977-12-06
申请号：US532237
申请日：1974-12-12
申请人： Gerard Leleu , Pierre Bedague , Bernard Sillion
发明人： Gerard Leleu , Pierre Bedague , Bernard Sillion
IPC分类号： C07C69/00 , C10M20060101 , C10M169/00 , C10M1/48
CPC分类号： C10M3/00 , C10M2207/30 , C10M2215/065
摘要： A trimethylolpropane ester composition useful as lubricant base for motor-car engines is prepared by total esterification of trimethylolpropane by means of a mixture of saturated aliphatic carboxylic acids comprising 6-33% by mole of dicarboxylic acids having 4-19 carbon atoms and 94-67 % by mole of monocarboxylic acids whereof 5-90% consists of sparingly branched acids comprising 15-30 carbon atoms and 95-10% of straight chain acids comprising 2-30 carbon atoms.
摘要翻译：可用作汽车发动机润滑剂底物的三羟甲基丙烷酯组合物是通过三羟甲基丙烷通过含有6-33％（摩尔）具有4-19个碳原子的二羧酸和94-67％的饱和脂族羧酸的混合物单体羧酸的摩尔％，其中5-90％由包含15-30个碳原子的微分支酸和包含2-30个碳原子的95-10％的直链酸组成。

33. 发明授权

US5093202A Method of gluing substrates using a composition comprising an arylaliphatic copolyimide with ether chain formations and an epoxy resin 失效
标题翻译：使用包含ARYLALIPHATIC COPOLYIMIDE与醚链和环氧树脂的组合物制备基材的方法
公开(公告)号：US5093202A
公开(公告)日：1992-03-03
申请号：US561999
申请日：1990-08-02
申请人： Paul Mariaggi , Serge Gonzalez , Guy Rabilloud , Bernard Sillion
发明人： Paul Mariaggi , Serge Gonzalez , Guy Rabilloud , Bernard Sillion
IPC分类号： B32B15/08 , C08G59/00 , C08G59/40 , C08G73/10 , C08L63/00 , C08L79/08 , C09J5/00 , C09J5/06 , C09J179/08
CPC分类号： C09J179/08 , C08G73/1042 , C08G73/105 , C08L63/00 , C08L79/08 , Y10T428/31515 , Y10T428/31522
摘要： Adhesive compositions are described comprising at least an arylaliphatic olyimide with ether chain formations, obtained by the polycondensation reaction of a tetracarboxylic aromatic acid or of one of its derivatives with at least two primary diamines, one of these diamines consisting of a polyether chain ending with the two amine functional groups and at least an epoxy resin possessing more than one epoxy group per molecular.These adhesive compositions can be used particularly for the gluing of films of polymers to thin metal sheets.
摘要翻译：描述了粘合剂组合物，其至少包括具有醚链形成的芳基脂族共聚酰亚胺，其通过四羧酸芳族酸或其衍生物与至少两种伯二胺的缩聚反应获得，这些二胺中的一种由结束于两个胺官能团和至少一个每分子具有多于一个环氧基团的环氧树脂。这些粘合剂组合物可以特别用于将聚合物膜粘合到薄金属片材上。

34. 发明授权

US5064934A Thermosetting polyimide schiff base resins, their preparation and their applications 失效
标题翻译：热固性聚酰亚胺席夫碱树脂，其制备及应用
公开(公告)号：US5064934A
公开(公告)日：1991-11-12
申请号：US502275
申请日：1990-04-02
申请人： Regis Mercier , Thierry Pascal , Bernard Sillion
发明人： Regis Mercier , Thierry Pascal , Bernard Sillion
IPC分类号： C07D209/48 , C08F38/00
CPC分类号： C07D209/48 , C08F38/00
摘要： Thermosetting Schiff base resins, their preparation and their applicationsre described.These thermosetting Schiff base resins can be defined as responding to the general formula: ##STR1## Radicals Ar.sub.1, Ar.sub.2 and Ar.sub.3 are chosen so that the softening temperature of the resins is less than about 150.degree. C.The resins can be prepared by direct condensation of an ethynyl benzaldehyde or acetophenone on a telechelic diamine oligomer obtained by reaction of a diamine containing flexibilizing groups on a derivative of benzhydrol tetracarboxylic acid. These Schiff base resins can be used by bulk thermal polymerization particularly to prepare adhesives or composite matrices.
摘要翻译：描述了热固性席夫碱树脂及其制备及其应用。这些热固性希夫碱树脂可以定义为响应于以下通式：选择Ar1，Ar2和Ar3的自由基，使得树脂的软化温度低于约150℃。树脂可以通过直接冷凝通过在二苯甲醇四羧酸的衍生物上使含有柔性基团的二胺反应得到的遥爪二胺低聚物上的乙炔基苯甲醛或苯乙酮。这些席夫碱树脂可以通过本体热聚合使用，特别是制备粘合剂或复合基质。

35. 发明授权

US4987218A Polybenzhydrol compositions ending with ethylenic unsaturated groups, cross-linked polymides resulting from their thermal polyermization and the use of said compositions 失效
标题翻译：以乙烯基不饱和基团结束的聚二醇化合物组合物，由它们的热多化引起的交联聚酰亚胺和所述组合物的使用
公开(公告)号：US4987218A
公开(公告)日：1991-01-22
申请号：US55287
申请日：1987-05-29
申请人： Jean Malinge , Guy Rabilloud , Bernard Sillion
发明人： Jean Malinge , Guy Rabilloud , Bernard Sillion
IPC分类号： C08F299/02 , C08G73/10 , C08G73/12
CPC分类号： C08G73/1078 , C08G73/10 , C08G73/101
摘要： Polymer compositions comprising poly(benzhydrolimide) chains ending with ethylenic unsaturated groups complying with the general formula: ##STR1## wherein Ar is a divalent aromatic radical and R a hydrogen atom or a monovalent hydrocarbon radical. They can be prepared by reacting, under imidation condition, at least one primary diamine with at least one benzydrol 3,3', 4,4'-tetracarboxylic acid, a bis (ortho-acid-ester) or a tetraester of such acid and with an anhydride, an acid-ester or a diester of dicarboxylic cycloaliphatic acid with ethylenic unsaturation. These compositions may be converted to cross-linked polymides by thermal polyemrization. They can be used in particular for manufacturing composite materials, adhesives, molded articles and protective coatings withstanding high temperatures.
摘要翻译：聚合物组合物包含以乙烯不饱和基团结束的聚（苯甲酰亚胺）链，其符合以下通式：其中Ar为二价芳族基团，R为氢原子或一价烃基。它们可以通过在酰亚胺化条件下使至少一种伯二胺与至少一种苯并三氢呋喃3,3'，4,4'-四羧酸，这种酸的双（邻 - 酸酯）或四酯反应来制备，和与酸酐，酸酯或具有烯属不饱和度的二羧酸脂环族酸的二酯。这些组合物可以通过热聚合转化成交联聚酰亚胺。它们可以特别用于制造复合材料，粘合剂，模制品和耐高温保护涂层。

36. 发明授权

US4931541A Thermosetting quinazolone resins their preparation and their applications 失效
标题翻译：热固性喹唑啉酮树脂的制备及应用
公开(公告)号：US4931541A
公开(公告)日：1990-06-05
申请号：US313679
申请日：1989-02-22
申请人： Regis Mercier , Bernard Sillion
发明人： Regis Mercier , Bernard Sillion
IPC分类号： C07D239/91 , C08F38/00 , C08F138/00 , C08G73/06
CPC分类号： C08G73/0694 , C08F38/00
摘要： Thermosetting quinazolone resins, their preparation and their applicationsre described.These thermosetting quinazolone resins can be defined as having the following general formula: ##STR1## in which Ar.sup.1 is a bivalent mono- or polycyclic aromatic radical and Ar.sup.2 is a bivalent aromatic radical of several simple aromatic rings bound two by two by atoms or bivalent groups.These Ar.sup.1 and Ar.sup.2 radicals are chosen so that the melting or emollescence temperature is between 80.degree. C. and 170.degree. C.The resins can be prepared from condensation of an ethynylarylbenzoxazinone with an aromatic diamine containing flexibilizing groups.These quinazolone resins can be polymerized in bulk in order to prepare adhesives or composite matrices in particular.
摘要翻译：热固性喹唑啉酮树脂及其制备方法及应用。这些热固性喹唑啉酮树脂可以定义为具有以下通式：其中Ar1是二价单环或多环芳族基团，Ar2是几个由原子或二价基团键合的两个简单芳环的二价芳族基团。选择这些Ar1和Ar2基团，使得熔融或发泡温度在80℃和170℃之间。树脂可以由乙炔基芳基苯并恶嗪酮与含有柔性基团的芳族二胺的缩合制备。这些喹唑啉酮树脂可以大量聚合，以便制备粘合剂或复合基质。

37. 发明授权

US4814403A Oligomer compositions of polyaryloxypyridines with acetylenic end groups, their manufacture and lattices obtained by thermal polymerization thereof 失效
标题翻译：具有炔末端基的聚芳氧基吡啶的低聚物组合物，其制备和通过其热聚合获得的晶格
公开(公告)号：US4814403A
公开(公告)日：1989-03-21
申请号：US105745
申请日：1987-10-08
申请人： Annie Dussart-Lermusiaux , Michel Senneron , Guy Rabilloud , Bernard Sillion
发明人： Annie Dussart-Lermusiaux , Michel Senneron , Guy Rabilloud , Bernard Sillion
IPC分类号： C07D213/63 , C07D213/64 , C07D213/643 , C07F7/08 , C08F38/00 , C08F290/00 , C08F299/00 , C08G65/40 , C08G65/48 , C08F26/06
CPC分类号： C07D213/643 , C07F7/0812 , C08G65/4006 , C08G65/48 , C08G2650/48 , C08G2650/60
摘要： Oligomer compositions of polyaryloxypyridine with acetylenic end groups arebtained by formation of an oligomer composition of polyaryloxypyridine with halogenated end groups from an alkaline diphenolate and a dihalogenopyridine, followed with an ethynylation reaction. The average polycondensation degree may range from 1 to 50. Theses compositions can be used to form cross-linked lattices by polyaddition of the ethynyl groups.
摘要翻译：具有炔末端基的聚芳氧基吡啶的低聚物组成通过由碱式二酚盐和二卤代吡啶形成具有卤化端基的聚芳氧基吡啶的低聚物组合物，然后进行乙炔化反应而获得。平均缩聚度可以在1至50之间。这些组合物可用于通过乙炔基的加成形成交联晶格。

38. 发明授权

US4704229A Surface-active compounds of the sulfobetaines family, their manufacture and use, particularly for enhanced oil recovery 失效
标题翻译：磺基甜菜碱家族的表面活性化合物，其制备和用途，特别是用于提高采收率
公开(公告)号：US4704229A
公开(公告)日：1987-11-03
申请号：US767402
申请日：1985-08-20
申请人： Sylvain Brunel , Laurent Germanaud , Pierre Le Perchec , Bernard Sillion
发明人： Sylvain Brunel , Laurent Germanaud , Pierre Le Perchec , Bernard Sillion
IPC分类号： B01F17/18 , C07D265/08 , C09K8/584 , C07C143/14 , B01F17/00 , C07C143/10 , C09K3/00
CPC分类号： C07D265/08 , C09K8/584 , Y10S507/938 , Y10S516/912
摘要： New surface-active compounds of the sulfobetaines group are manufactured. They comply with the general formula: ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is substantially a hydrocarbon radical, each of R.sub.4 and R.sub.5 is a hydrogen atom or substantially a hydrocarbon radical and R.sub.6 is a hydrogen atom or a hydrocarbon radical, R.sub.1 to R.sub.6 radicals containing together from 12 to 30 carbon atoms, n is an integer equal to 2 to 3, Z may be a CH.sub.3 radical or a hydroxy group, p may be 0 or 1 with, when Z is a hydroxy group and p is equal to 1, a value of 1 for m and for q; when Z is a methyl radical, with a value of 1 for p, a value of 2 for m and a value of 0 or 1 for q and, when p=0, a value of 2, 3 or 4 for the sum (m+q).These new surfactants are useful in enhanced oil recovery as micellar systems consisting of aqueous solutions and microemulsions.
摘要翻译：制备磺基甜菜碱基团的新的表面活性化合物。它们符合以下通式：其中R 1，R 2和R 3各自基本上是烃基，R 4和R 5各自为氢原子或基本上烃基，R 6为氢原子或烃基，R 1 包含含有12至30个碳原子的R6基团，n是等于2至3的整数，Z可以是CH 3基或羟基，当Z是羟基时，p可以是0或1，p是等于1，m和q的值为1; 当Z是甲基时，对于p，值为1，对于m，值为2，对于q，值为0或1，当p = 0时，对于和（m）为2,3或4 + q）。这些新的表面活性剂可用于强化油回收，因为由水溶液和微乳液组成的胶束体系。

39. 发明授权

US4645821A Precursor of copolyphthalocyanine-imide lattice, preparation, and the resultant lattice 失效
标题翻译：共聚酞菁 - 酰亚胺晶格的前体，制备和所得的晶格
公开(公告)号：US4645821A
公开(公告)日：1987-02-24
申请号：US758949
申请日：1985-07-25
申请人： Jean Malinge , Guy Rabilloud , Bernard Sillion
发明人： Jean Malinge , Guy Rabilloud , Bernard Sillion
IPC分类号： C08G73/00 , C07D209/48 , C08G73/10 , C08G73/06
CPC分类号： C07D209/48 , C08G73/10 , C08G73/1035
摘要： Aromatic polyimide compositions, precursors of copolyphthalocyanine-imides,heir manufacturing process and the resultant copolyphthalocyanine-imides, are described.These compositions may result for the reaction of 80.degree.-300.degree. C. of an aromatic tetra acid, diester-diacid, tetraester or dianhydride compound of formula: ##STR1## with an aromatic amino-dinitrile ##STR2## and optionally an aromatic diamine NH.sub.2 --Ar--NH.sub.2. A subsequent heating at 200.degree.-300.degree. C. provides, by cross-linking, copolyphthalocyanine-imides, which are hardened resins, stable at 250.degree.-300.degree. C. in continuous use.
摘要翻译：描述了芳族聚酰亚胺组合物，共聚酞菁 - 酰亚胺的前体，它们的制备方法和所得的共聚酞菁 - 酰亚胺。这些组合物可能导致80-300℃的芳香族四酸，二酯 - 二酸，四酯或二酐化合物与芳香族氨基二腈和任选的芳族二胺NH 2 -Ar-NH2。随后在200-300℃下加热，通过交联，共聚酞菁 - 酰亚胺，它们是硬化树脂，在250-300℃下连续使用时稳定。

40. 发明授权

US4473118A Enhanced oil recovery using oxidized crude oil 失效
标题翻译：使用氧化原油提高采收率
公开(公告)号：US4473118A
公开(公告)日：1984-09-25
申请号：US345104
申请日：1982-02-02
申请人： Jean-Pierre Wauquier , Bernard Sillion , Raymond Boulet , Louis Cuiec , Christian Vacher
发明人： Jean-Pierre Wauquier , Bernard Sillion , Raymond Boulet , Louis Cuiec , Christian Vacher
IPC分类号： C09K8/584 , E21B43/22
CPC分类号： C09K8/584 , Y10S507/936
摘要： Enhanced recovery of oil from oil fields is effected by making use of an inexpensive surface-active agent formed by oxidizing a portion of crude oil with an aqueous solution of sodium hypochlorite at a temperature of 20.degree.-180.degree. C. The oxidized crude can be injected in the field in admixture with non-oxidized crude or with water as a micro-emulsion.
摘要翻译：通过使用在20〜-180℃的温度下，用次氯酸钠水溶液氧化一部分原油而形成的廉价的表面活性剂，可以提高油田油的回收率。氧化原油可以是在野外注射与非氧化粗品或水作为微乳液混合。

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