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    • 31. 发明授权
    • Intercalates and expoliates formed with organic pesticide compounds and
compositions containing the same
    • 插入物和植物与有机农药化合物和含有它们的组合物形成
    • US5730996A
    • 1998-03-24
    • US652756
    • 1996-05-23
    • Gary W. BeallSemeon TsipurskyKatherine R. Turk
    • Gary W. BeallSemeon TsipurskyKatherine R. Turk
    • A01N25/08A01N25/10
    • A01N25/08
    • Intercalates formed by contacting an activated layered material, e.g., an activated phyllosilicate, with an intercalant pesticide to intercalate an intercalant pesticide between adjacent platelets of the layered material is disclosed. Sufficient intercalant pesticide is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 .ANG. (as measured after water removal to a maximum of 5% by weight water) up to about 100 .ANG., and preferably in the range of about 10 to about 45 .ANG., so that, if desired, the intercalate can be exfoliated into individual platelets. The intercalate can be combined with an organic liquid to form a viscous composition for delivery of a pesticide compound. Alternatively, the intercalate can be exfoliated prior to combination with the organic liquid. The intercalated complex also can be admixed with solid particles to provide a granular, dust, or wettable powder pesticide composition.
    • 公开了通过使活化的层状材料(例如活化的页硅酸盐)与插入剂农药接触而形成的插层,以在层状材料的相邻片晶之间插入插入剂农药。 在相邻血小板之间吸附足够的嵌入剂杀虫剂以将相邻的血小板膨胀至至多约5安培的水平(在除水至最多5重量%水之后测量)至多约100安培的范围内,优选在 约10至约45个角度,使得如果需要,插层物可以被剥离成单独的血小板。 插层物可以与有机液体组合以形成用于递送农药化合物的粘性组合物。 或者,插入物可以在与有机液体组合之前被剥离。 插层的复合物也可以与固体颗粒混合,以提供颗粒状,粉尘或可湿性粉剂农药组合物。
    • 34. 发明授权
    • Intercalates and exfoliates formed with monomeric ethers and esters; composite materials containing same methods of modifying rheology therewith
    • 用单体醚和酯形成的插层和去角质; 含有与其一起改性流变性的相同方法的复合材料
    • US06287634B1
    • 2001-09-11
    • US08577700
    • 1995-12-22
    • Gary W. BeallSemeon TsipurskyAnatoliy SorokinAnatoliy Goldman
    • Gary W. BeallSemeon TsipurskyAnatoliy SorokinAnatoliy Goldman
    • B05D700
    • C08K9/04C01B33/44
    • Intercalates formed by contacting a layered material, e.g., a phyllosilicate, with an intercalant monomer ether and/or ester to sorb or intercalate the intercalant monomer between adjacent platelets of the layered material. Sufficient intercalant monomer is sorbed between adjacent platelets to expand the adjacent platelets to a spacing of at least about 5 Å (as measured after water removal to a maximum of 5% by weight water), up to about 100 Å and preferably in the range of about 10-45 Å, so that the intercalate easily can be exfoliated into individual platelets. The intercalated complex can be combined with an organic liquid into a viscous carrier material, for delivery of the carrier material, or for delivery of an active compound; or the intercalated complex can be combined with a matrix polymer to form a strong, filled polymer matrix. Alternatively, the intercalated complex can be exfoliated prior to combination with the organic liquid or the matrix polymer.
    • 通过使层状材料(例如页硅酸盐)与嵌入单体醚和/或酯接触而形成的嵌入体,以在层状材料的相邻片晶之间吸附或插入插入剂单体。 在相邻的血小板之间吸附足够的嵌入剂单体以将相邻的血小板膨胀至至少约5埃的水平(在除水后测量为最多5重量%的水),至多约100埃,优选在 约10-45埃,使得插入物容易被剥离成单独的血小板。 插入的复合物可以与有机液体结合成粘性载体材料,用于递送载体材料或递送活性化合物; 或者插层的复合物可以与基质聚合物组合以形成强的,填充的聚合物基质。 或者,插入的复合物可以在与有机液体或基质聚合物组合之前被剥离。