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    • 34. 发明申请
    • ELECTROCHEMICAL DEVICE
    • 电化学装置
    • US20090305144A1
    • 2009-12-10
    • US12373442
    • 2007-07-12
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • H01M6/16
    • H01M10/0567H01M10/052H01M10/0525H01M10/0568H01M10/0569H01M2300/0025
    • There is provided an electrochemical device provided with an electrolytic solution comprising (I) a solvent for dissolving an electrolyte salt comprising (A) a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 wherein Rf1 and Rf2 are the same or different and each is a fluorine-containing alkyl group having 3 to 6 carbon atoms, (B) a cyclic carbonate, and (C) a chain carbonate being compatible with both of the fluorine-containing ether (A) and the cyclic carbonate (B), and (II) an electrolyte salt, in which the solvent (I) for dissolving an electrolyte salt comprises 30 to 60% by volume of the fluorine-containing ether (A), 3 to 40% by volume of the cyclic carbonate (B) and 10 to 67% by volume of the chain carbonate (C) based on the whole solvent (I), and when the electrochemical device is provided with such an electrolytic solution, no phase separation occurs even at low temperature, flame retardancy and heat resistance are excellent, solubility of an electrolyte salt is high, discharge capacity is large, and charge and discharge cycle characteristics are satisfactory.
    • 提供一种具有电解溶液的电化学装置,其包含(I)用于溶解电解质盐的溶剂,其包含(A)由式(1)表示的含氟醚:Rf1-O-Rf2,其中Rf1和Rf2为 相同或不同,分别为具有3〜6个碳原子的含氟烷基,(B)环状碳酸酯,(C)与含氟醚(A)和环状碳酸酯 (B)和(II)电解质盐,其中溶解电解质盐的溶剂(I)含有30〜60体积%的含氟醚(A),3〜40体积%的环状 碳酸酯(B)和基于整个溶剂(I)的链状碳酸酯(C)的10至67体积%,并且当电化学装置设置有这种电解液时,即使在低温下也不发生相分离,火焰 阻燃性和耐热性优异,电解质sal的溶解性 t高,放电容量大,充放电循环特性令人满意。