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    • 2. 发明授权
    • Electrochemical device
    • 电化学装置
    • US08163422B2
    • 2012-04-24
    • US12373442
    • 2007-07-12
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • H01M6/04
    • H01M10/0567H01M10/052H01M10/0525H01M10/0568H01M10/0569H01M2300/0025
    • There is provided an electrochemical device provided with an electrolytic solution comprising (I) a solvent for dissolving an electrolyte salt comprising (A) a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 wherein Rf1 and Rf2 are the same or different and each is a fluorine-containing alkyl group having 3 to 6 carbon atoms, (B) a cyclic carbonate, and (C) a chain carbonate being compatible with both of the fluorine-containing ether (A) and the cyclic carbonate (B), and (II) an electrolyte salt, in which the solvent (I) for dissolving an electrolyte salt comprises 30 to 60% by volume of the fluorine-containing ether (A), 3 to 40% by volume of the cyclic carbonate (B) and 10 to 67% by volume of the chain carbonate (C) based on the whole solvent (I), and when the electrochemical device is provided with such an electrolytic solution, no phase separation occurs even at low temperature, flame retardancy and heat resistance are excellent, solubility of an electrolyte salt is high, discharge capacity is large, and charge and discharge cycle characteristics are satisfactory.
    • 提供一种具有电解溶液的电化学装置,其包含(I)用于溶解电解质盐的溶剂,其包含(A)由式(1)表示的含氟醚:Rf1-O-Rf2,其中Rf1和Rf2为 相同或不同,分别为具有3〜6个碳原子的含氟烷基,(B)环状碳酸酯,(C)与含氟醚(A)和环状碳酸酯 (B)和(II)电解质盐,其中溶解电解质盐的溶剂(I)含有30〜60体积%的含氟醚(A),3〜40体积%的环状 碳酸酯(B)和基于整个溶剂(I)的链状碳酸酯(C)的10至67体积%,并且当电化学装置设置有这种电解液时,即使在低温下也不发生相分离,火焰 阻燃性和耐热性优异,电解质的溶解性 盐高,放电容量大,充放电循环特性令人满意。
    • 3. 发明申请
    • ELECTROLYTIC SOLUTION
    • 电解液
    • US20110008681A1
    • 2011-01-13
    • US12677397
    • 2008-09-12
    • Meiten KohHitomi NakazawaHideo SakataMichiru TanakaAkiyoshi YamauchiAoi Nakazono
    • Meiten KohHitomi NakazawaHideo SakataMichiru TanakaAkiyoshi YamauchiAoi Nakazono
    • H01M10/05
    • H01M10/0525H01G9/038H01G11/58H01G11/60H01G11/64H01M6/164H01M10/0568H01M10/0569H01M2300/0025H01M2300/0034H01M2300/004H01M2300/0042Y02E60/13Y02T10/7011Y02T10/7022
    • There is provided an electrolytic solution causing no phase separation even at low temperatures, being excellent in flame retardancy and noncombustibility, assuring high solubility of an electrolyte salt, having a high discharge capacity, being excellent in charge-discharge cycle characteristics and being suitable for electrochemical devices such as lithium ion secondary batteries. The electrolytic solution comprises a solvent (I) for dissolving an electrolyte salt comprising a fluorine-containing ether (A) represented by the formula: Rf1—O—Rf2 (Rf1 and Rf2 are the same or different, Rf1 is a fluorine-containing alkyl group having 3 to 6 carbon atoms, Rf2 is a fluorine-containing alkyl group having 2 to 6 carbon atoms), at least one fluorine-containing solvent (B) selected from the group consisting of a fluorine-containing cyclic carbonate (B1) and a fluorine-containing lactone (B2), and at least one non-fluorine-containing carbonate (C) selected from the group consisting of (C1) a non-fluorine-containing cyclic carbonate and (C2) a non-fluorine-containing chain carbonate, and an electrolyte salt (II), and the solvent (I) for dissolving an electrolyte salt comprises 20 to 60% by volume of the fluorine-containing ether (A), 0.5 to 30% by volume of the fluorine-containing solvent (B), and 5 to 40% by volume of the non-fluorine-containing cyclic carbonate (C1) and/or 10 to 74.5% by volume of the non-fluorine-containing chain carbonate (C2) based on the whole solvent (I).
    • 提供即使在低温下也不会产生相分离的电解液,阻燃性和不燃性优异,确保电解质盐的高溶解度,具有高放电容量,充放电循环特性优异,适用于电化学 设备如锂离子二次电池。 电解液包含用于溶解包含下式所示的含氟醚(A)的电解质盐的溶剂(I):Rf1-O-Rf2(Rf1和Rf2相同或不同,Rf1是含氟烷基 具有3至6个碳原子的基团,Rf 2是具有2至6个碳原子的含氟烷基),至少一种选自以下的含氟溶剂(B):含氟环状碳酸酯(B1)和 含氟内酯(B2)和至少一种选自(C1)非氟类环状碳酸酯和(C2)非氟系链中的非氟碳酸酯(C) 碳酸酯和电解质盐(II),溶解电解质盐的溶剂(I)含有20〜60体积%的含氟醚(A),0.5〜30体积%的含氟溶剂 (B)和5〜40体积%的无氟环状碳酸酯(C1)a nd /或10〜74.5体积%的无氟链状碳酸酯(C2)。
    • 5. 发明申请
    • ELECTROCHEMICAL DEVICE
    • 电化学装置
    • US20090305144A1
    • 2009-12-10
    • US12373442
    • 2007-07-12
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • Meiten KohHideo SakataHitomi NakazawaMichiru TanakaAkiyoshi Yamauchi
    • H01M6/16
    • H01M10/0567H01M10/052H01M10/0525H01M10/0568H01M10/0569H01M2300/0025
    • There is provided an electrochemical device provided with an electrolytic solution comprising (I) a solvent for dissolving an electrolyte salt comprising (A) a fluorine-containing ether represented by the formula (1): Rf1—O—Rf2 wherein Rf1 and Rf2 are the same or different and each is a fluorine-containing alkyl group having 3 to 6 carbon atoms, (B) a cyclic carbonate, and (C) a chain carbonate being compatible with both of the fluorine-containing ether (A) and the cyclic carbonate (B), and (II) an electrolyte salt, in which the solvent (I) for dissolving an electrolyte salt comprises 30 to 60% by volume of the fluorine-containing ether (A), 3 to 40% by volume of the cyclic carbonate (B) and 10 to 67% by volume of the chain carbonate (C) based on the whole solvent (I), and when the electrochemical device is provided with such an electrolytic solution, no phase separation occurs even at low temperature, flame retardancy and heat resistance are excellent, solubility of an electrolyte salt is high, discharge capacity is large, and charge and discharge cycle characteristics are satisfactory.
    • 提供一种具有电解溶液的电化学装置,其包含(I)用于溶解电解质盐的溶剂,其包含(A)由式(1)表示的含氟醚:Rf1-O-Rf2,其中Rf1和Rf2为 相同或不同,分别为具有3〜6个碳原子的含氟烷基,(B)环状碳酸酯,(C)与含氟醚(A)和环状碳酸酯 (B)和(II)电解质盐,其中溶解电解质盐的溶剂(I)含有30〜60体积%的含氟醚(A),3〜40体积%的环状 碳酸酯(B)和基于整个溶剂(I)的链状碳酸酯(C)的10至67体积%,并且当电化学装置设置有这种电解液时,即使在低温下也不发生相分离,火焰 阻燃性和耐热性优异,电解质sal的溶解性 t高,放电容量大,充放电循环特性令人满意。