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31. 发明授权

US4002480A Photographic silver halide emulsion 失效
标题翻译：摄影卤化银乳剂
公开(公告)号：US4002480A
公开(公告)日：1977-01-11
申请号：US555912
申请日：1975-03-06
申请人： Masanao Hinata , Yuji Mihara , Reiichi Ohi , Keiichi Adachi , Akira Sato
发明人： Masanao Hinata , Yuji Mihara , Reiichi Ohi , Keiichi Adachi , Akira Sato
IPC分类号： G03C1/12 , G03C1/22 , G03C1/28 , G03C1/34 , G03C1/08
CPC分类号： G03C1/34 , G03C1/12 , G03C1/22 , G03C1/28
摘要： A photographic silver halide emulsion containing at least one dinuclear merocyanine sensitizing dye, and at least one compound represented by the following formula: ##STR1## wherein D represents a divalent aromatic group, R.sub.2, R.sub.3, R.sub.4, and R.sub.5 each represents a hydrogen atom, a hydroxyl group, an alkoxyl group, an aryloxy group, a halogen atom, a heterocyclic group, a mercapto group, an alkylthio group, an arylthio group, a heterocyclic thio group, an amino group, an alkylamino group, a cycloalkylamino group, an arylamino group, a heterocyclic amino group, an aralkylamino group, or an aryl group.
摘要翻译：含有至少一种双核部花菁敏化染料的照相卤化银乳剂和至少一种由下式表示的化合物：其中D表示二价芳族基团，R 2，R 3，R 4和R 5各自表示氢原子，羟基，烷氧基，芳氧基，卤素原子，杂环基，巯基，烷硫基，芳硫基，杂环硫基，氨基，烷基氨基，环烷基氨基，芳基氨基，杂环氨基，芳烷基氨基或芳基。

32. 发明授权

US3994733A Silver halide photographic emulsion 失效
标题翻译：卤化银照相乳剂
公开(公告)号：US3994733A
公开(公告)日：1976-11-30
申请号：US531416
申请日：1974-12-10
申请人： Masanao Hinata , Masanaga Ohki , Reiichi Ohi , Akira Ogawa , Akira Sato
发明人： Masanao Hinata , Masanaga Ohki , Reiichi Ohi , Akira Ogawa , Akira Sato
IPC分类号： C09B23/00 , G03C1/28 , G03C1/14
CPC分类号： G03C1/28
摘要： A silver halide photographic emulsion containing the combination of (i) at least one cyanine dye wherein two basic 5-membered and/or 6-membered nitrogen-containing heterocyclic nuclei are linked by methine groups having an odd number of carbon atoms not exceeding 7 and the substituents on the nitrogen atoms in the heterocyclic nuclei are aliphatic groups or aromatic groups with at least one of the substituents on the nitrogen atom being an alkyl group having a sulfo group or a carboxyl group, and (ii) at least one substantially colorless nitrogen-containing heterocyclic organic base selected from the group consisting of a benzothiazole, a benzothiazolone, a naphthothiazole, a naphthothiazolone, and a quinolone in a quantity sufficient to supersensitize.
摘要翻译：含有（i）至少一种花青染料的组合的卤化银照相乳剂，其中两个碱性5元和/或6元含氮杂环核是通过具有奇数个碳原子数不超过7的次甲基和杂环核中的氮原子上的取代基是脂族基团或芳族基团，其中至少一个氮原子上的取代基是具有磺基或羧基的烷基，和（ii）至少一个基本上无色的氮的选自苯并噻唑，苯并噻唑酮，萘并噻唑，萘并噻唑酮和喹诺酮的杂环有机碱，其量足以超敏。

33. 发明授权

US4199360A Method for spectrally sensitizing photographic light-sensitive emulsions 失效
标题翻译：摄影感光乳剂光谱增感方法
公开(公告)号：US4199360A
公开(公告)日：1980-04-22
申请号：US926769
申请日：1978-07-21
申请人： Masanao Hinata , Yuji Mihara , Tadao Shishido , Keiichi Adachi
发明人： Masanao Hinata , Yuji Mihara , Tadao Shishido , Keiichi Adachi
IPC分类号： G03C1/12 , G03C1/28 , G03G5/06 , G03G5/09 , G03C1/76 , G03C1/10 , G03C1/14 , G03C1/19
CPC分类号： G03C1/12 , G03C1/28 , G03G5/067 , G03G5/09
摘要： A method of spectrally sensitizing a photographic light-sensitive emulsion where a water-soluble solution, prepared by dissolving a methine dye having at least one water-soluble group in water in the presence of a "Red Shift Compound", as hereinafter defined, is added to a photographic light-sensitive emulsion to provide a photographic light-sensitive emulsion spectrally sensitized with increased sensitizing efficiency and with reduced fog. The disadvantages caused by the use of high organic solvent contents are avoided and photographic light-sensitive emulsions suitable for high-speed coating are obtained.
摘要翻译：一种对摄影感光乳剂进行光谱增感的方法，其中通过将如下定义的“红移化合物”存在下将具有至少一个水溶性基团的次甲基染料溶解在水中而制备的水溶性溶液为添加到照相感光乳剂中，以提供感光敏感乳剂，其光敏性增加，敏化效率提高，雾度降低。避免使用高有机溶剂含量引起的缺点，并获得适合于高速涂布的照相感光乳剂。

34. 发明授权

US4138266A Method for spectrally sensitizing photographic light-sensitive emulsions 失效
标题翻译：摄影感光乳剂光谱增感方法
公开(公告)号：US4138266A
公开(公告)日：1979-02-06
申请号：US765314
申请日：1977-02-03
申请人： Masanao Hinata , Yuji Mihara , Tadao Shishido , Keiichi Adachi
发明人： Masanao Hinata , Yuji Mihara , Tadao Shishido , Keiichi Adachi
IPC分类号： G03C1/10 , G03C1/12 , G03C1/28 , G03G5/06 , G03G5/09 , G03C1/02
CPC分类号： G03G5/067 , G03C1/12 , G03C1/28 , G03G5/0661 , G03G5/09
摘要： A method of spectrally sensitizing a photographic light-sensitive emulsion where a water-soluble solution, prepared by dissolving a methine dye having at least one water-soluble group in water in the presence of a "Red Shift Compound", as hereinafter defined, is added to a photographic light-sensitive emulsion to provide a photographic light-sensitive emulsion spectrally sensitized with increased sensitizing efficiency and with reduced fog. The disadvantages caused by the use of high organic solvent contents are avoided and photographic light-sensitive emulsions suitable for high-speed coating are obtained.
摘要翻译：一种对摄影感光乳剂进行光谱增感的方法，其中通过将如下定义的“红移化合物”存在下将具有至少一个水溶性基团的次甲基染料溶解在水中而制备的水溶性溶液为添加到照相感光乳剂中，以提供感光敏感乳剂，其光敏性增加，敏化效率提高，雾度降低。避免使用高有机溶剂含量引起的缺点，并获得适合于高速涂布的照相感光乳剂。

35. 发明授权

US4040839A Direct-positive process utilizing a supersensitized silver halide emulsion 失效
标题翻译：使用超敏化卤化银乳剂的直接阳性法
公开(公告)号：US4040839A
公开(公告)日：1977-08-09
申请号：US687819
申请日：1976-05-19
申请人： Junichi Matsuyama , Masanao Hinata , Akira Sato
发明人： Junichi Matsuyama , Masanao Hinata , Akira Sato
IPC分类号： G03C1/485 , G03C1/29 , G03C5/24 , G03C1/28
CPC分类号： G03C1/29
摘要： A silver halide photographic emulsion containing at least one sensitizing dye of the following general formula (I) and at least one sensitizing dye of general formulae (II) and/or (III), in an amount effective to achieve supersensitization: ##STR1## wherein V.sup.1 and V.sup.2, which may be the same or different, each represents a hydrogen atom, halogen atom, trifluoromethyl, cyano, carboxy, alkoxycarbonyl, aminosulfonyl or alkylsulfonyl; W.sup.1 and W.sup.2, which may be the same or different, each represents a hydrogen atom, halogen atom, alkyl, alkoxy, hydroxy, acyloxy or phenyl; R.sup.1 represents alkyl or substituted alkyl; R.sup.2 and R.sup.3, which may be the same or different, each represents alkyl or substituted alkyl, and at least one of R.sup.2 and R.sup.3 represents 1 or 0; substituted alkyl containing a carboxy or sulfo radical; R.sup.4 and R.sup.5, which may be the same or different, each has the same meanings as R.sup.1 ; X.sup.- represents an acid anion; and m represents ##STR2## wherein V.sup.3 and V.sup.4, which may be the same or different, each has the same meaning as V.sup.1 and V.sup.2 ; W.sup.3 and W.sup.4, which may be the same or different, each has the same meaning as W.sup.1 and W.sup.2 ; R.sup.6 has the same meaning as R.sup.1 ; R.sup.7 and R.sup.8, which may be the same or different, each has the same meaning as R.sup.2 and R.sup.3 ; X.sup.- represents an acid anion; and n represents 1 or 0; ##STR3## wherein W.sup.5 and W.sup.6, which may be the same or different, each has the same meaning as W.sup.3 and W.sup.4 ; R.sup.10 and R.sup.11, which may be the same or different, each has the same meaning as R.sup.2 and R.sup.3 ; R.sup.9 represents an alkyl group; X.sup.- represents an acid anion; and p represents 1 or 0.
摘要翻译：含有至少一种以下通式（I）的敏化染料和至少一种通式（II）和/或（III）的敏化染料）的卤化银照相乳液，其量可以有效地达到超敏化：（I）其中V1和V2可以相同或不同，各自表示氢原子，卤素原子，三氟甲基，氰基，羧基，烷氧基羰基，氨基磺酰基或烷基磺酰基; W 1和W 2可以相同或不同，各自表示氢原子，卤素原子，烷基，烷氧基，羟基，酰氧基或苯基; R1代表烷基或取代的烷基; R 2和R 3可以相同或不同，各自表示烷基或取代的烷基，R 2和R 3中的至少一个表示1或0; 含有羧基或磺基的取代烷基; R 4和R 5可以相同或不同，各自具有与R 1相同的含义; X“表示酸性阴离子; 和m表示（II）其中V3和V4可以相同或不同，各自具有与V1和V2相同的含义; W3和W4可以相同或不同，各自具有与W1和W2相同的含义; R6与R1具有相同的含义; R 7和R 8可以相同或不同，各自具有与R 2和R 3相同的含义; X“表示酸性阴离子; n表示1或0; （III）其中W5和W6可以相同或不同，各自具有与W3和W4相同的含义; R10和R11可以相同或不同，各自具有与R 2和R 3相同的含义; R9表示烷基; X“表示酸性阴离子; p表示1或0。

36. 发明授权

US4015989A Color light-sensitive material with spontaneously developable silver halide emulsion containing desensitizing dye 失效
标题翻译：具有自发显影的含有脱敏染料的卤化银乳剂的彩色感光材料
公开(公告)号：US4015989A
公开(公告)日：1977-04-05
申请号：US545671
申请日：1975-01-30
申请人： Yasushi Oishi , Masanao Hinata
发明人： Yasushi Oishi , Masanao Hinata
IPC分类号： G03C7/00 , G03C1/36 , G03C7/30 , G03C8/08 , G03C1/40 , G03C1/48 , G03C1/76
CPC分类号： G03C7/30 , G03C1/36 , G03C7/3003 , G03C7/30541
摘要： A color photographic light-sensitive material which comprises a support having thereon at least one emulsion layer unit comprising;A. a hydrophilic colloid layer containing spontaneously developable silver halide grains which are associated with a coupler capable of reacting with an oxidation product of an aromatic primary amino color developing agent to provide a dye and which are rendered substantially light-insensitive with a desensitizer, andB. an adjacent negative type light-sensitive silver halide emulsion layer associated with a compound capable of reacting with an oxidation product of an aromatic primary amino color developer to release a diffusible development inhibitor.
摘要翻译：一种彩色照相感光材料，其包括其上具有至少一个乳剂层单元的载体，所述乳剂层单元包括： A.含有可自发显影的卤化银颗粒的亲水胶体层，其与能够与芳族伯氨基显色剂的氧化产物反应以提供染料并且与脱敏剂基本上不敏感的成色剂相关联，以及 B.与能够与芳族伯氨基显色剂的氧化产物反应以释放扩散显影抑制剂的化合物相关的相邻的负型感光卤化银乳剂层。

37. 发明授权

US3970461A Fogged, direct-positive silver halide emulsion containing carbocyanine dye having indolenine nucleus 失效
标题翻译：含有具有吲哚宁细胞核的碳菁染料的含氟直接卤化银乳剂
公开(公告)号：US3970461A
公开(公告)日：1976-07-20
申请号：US376997
申请日：1973-07-06
申请人： Keisuke Shiba , Masanao Hinata , Akira Sato , Akira Ogawa , Hirotetu Kato
发明人： Keisuke Shiba , Masanao Hinata , Akira Sato , Akira Ogawa , Hirotetu Kato
IPC分类号： G03C1/18 , G03C1/485 , G03C1/28 , G03C1/08 , G03C1/36
CPC分类号： G03C1/4853 , G03C1/18 , Y10S430/141
摘要： A direct positive silver halide photographic emulsion containing a dye represented by the following general formula: ##SPC1##Wherein R and R.sub.1 are selected from the first group consisting of alkyl, allyl, substituted alkyl, aryl, and substituted aryl groups, at least one of the R and R.sub.1 being an alkyl group substituted with a carboxyl or sulfo radical; R.sub.2 and R.sub.3 are selected from the second group consisting of alkyl, aralkyl and allyl groups; L.sub.1 is selected from the third group consisting of methine and an atomic group capable of combining with R.sub.1, R.sub.2 or R.sub.3 to form a ring; L.sub.2 is methine; L.sub.3 is selected from the fourth group consisting of methine and an atomic group capable of forming a ring with R.sub.1 or a 3,3-substituent of an indolenine ring at the site near to L.sub.3, L.sub.3, such that a ring may be formed by L.sub.1 and L.sub.3 ; x is an anion; n and m are the integers 1 and 2, respectively, such that when said dye forms in intramolecular salt, m is 1; Z is an atomic group capable of completing a benzene ring or a naphthalene ring; and Z.sub.1, is a non-metallic atomic group capable of completing a 5- or 6- member heterocyclic ring.
摘要翻译：含有以下通式表示的染料的直接正性卤化银照相乳剂：

38. 发明授权

US4014702A Silver halide photographic emulsion 失效
标题翻译：卤化银照相乳剂
公开(公告)号：US4014702A
公开(公告)日：1977-03-29
申请号：US597606
申请日：1975-07-21
申请人： Masanao Hinata , Masanaga Ohki , Hartuo Takei , Akira Sato , Akira Ogawa
发明人： Masanao Hinata , Masanaga Ohki , Hartuo Takei , Akira Sato , Akira Ogawa
IPC分类号： C09B23/10 , G03C1/29 , G03C1/08
CPC分类号： C09B23/105 , G03C1/29
摘要： A silver halide photographic emulsion containing a spectrally sensitizing amount of a sensitizing dye represented by the general formula (I) ##STR1## and a sensitizing dye represented by the formula (II) ##STR2## wherein Z.sub.1 and Z.sub.2 each is an atomic group necessary to complete a benzoxazole ring or a naphthoxazole ring; R.sub.1 is an alkyl group or an allyl group; R.sub. 2 is an alkyl group or an allyl group; R.sub.3 is an unsubstituted lower alkyl group, a hydroxyalkyl group or a carboxyalkyl group; R.sub.4 is same as R.sub.1 ; R.sub.5 is an alkyl group, an allyl group or a phenyl group; R.sub.6 is an alkoxycarbonylalkyl group, a hydroxyalkoxyalkyl group, an acyloxyalkoxyalkyl group, an N-(N,N-dialkylaminoalkyl)carbamoylalkyl group, an N-(N,N,N-trialkylammonium)carbamoylalkyl group or an N,N,N-trialkylammoniumalkyl group; X.sup.- is an acid anion; and n is 0 or 1.
摘要翻译：含有光谱增感量的由通式（I）表示的增感染料（I）和由式（II）表示的增感染料的卤化银照相乳剂，其中Z1和Z2分别为是完成苯并恶唑环或萘并恶唑环所必需的原子团; R1是烷基或烯丙基; R 2为烷基或烯丙基; R3是未取代的低级烷基，羟烷基或羧基烷基; R4与R1相同; R5是烷基，烯丙基或苯基; R6是烷氧基羰基烷基，羟基烷氧基烷基，酰氧基烷氧基烷基，N-（N，N-二烷基氨基烷基）氨基甲酰基烷基，N-（N，N，N-三烷基铵）氨基甲酰基烷基或N，N，N-三烷基铵烷基组; X - 是酸性阴离子; n为0或1。

39. 发明授权

US3945832A Fogged, direct-positive silver halide emulsion containing desensitizers and a dimethine optical sensitizing dye 失效
标题翻译：含有脱敏剂的雾状直接卤化银乳剂和二甲基硅氧烷光敏染料
公开(公告)号：US3945832A
公开(公告)日：1976-03-23
申请号：US455095
申请日：1974-03-27
申请人： Keisuke Shiba , Masanao Hinata , Reiichi Ohi , Tadao Shishido
发明人： Keisuke Shiba , Masanao Hinata , Reiichi Ohi , Tadao Shishido
IPC分类号： C09B23/00 , G03C1/485 , G03C1/36 , G03C1/02 , G03C1/28
CPC分类号： G03C1/48523
摘要： A direct positive silver halide photographic emulsion containing1. at least one dimethine dye having the general formula (I): ##EQU1## 2. AT LEAST ONE COMPOUND HAVING THE GENERAL FORMULA (II): ##SPC1##3. at least one compound having the general formula (III) ##EQU2## or the general formula (IV) ##SPC2##wherein Y, Y.sub.o, Z, L.sub.1, L.sub.2, R.sub.o, m, n, X, Z.sub.1, R.sub.1, X.sub.1, a, p, q, Y.sub.1, Y.sub.2, m.sub.1, R.sub.3, r, X.sub.2 and X.sub.3 are as hereinafter defined.
摘要翻译：含有1种的直接正性卤化银照相乳剂。具有一般式（I）的至少一种二甲基染料：YZ + C-L1 = L2-C = CH-CH）m-1N-Ro（I）C ANGLE（X < - >）n-1哟2.至少一种具有通用配方（II）的化合物：3.至少一种具有通式（III）的化合物C --- C Y1并行对偶Y22X2（III）N 其中Y，Yo，Z，L1，L2，Ro，m，n，X，Z1，R1，X1，a，p，q，Y1，Y2， m1，R3，r，X2和X3如下文定义。

40. 发明授权

US3955979A Flash exposure of supersensitized silver halide photographic light-sensitive material 失效
标题翻译：超敏化卤化银照相感光材料的闪光曝光
公开(公告)号：US3955979A
公开(公告)日：1976-05-11
申请号：US561504
申请日：1975-03-24
申请人： Keisuke Shiba , Masanao Hinata , Hirotetu Kato
发明人： Keisuke Shiba , Masanao Hinata , Hirotetu Kato
IPC分类号： G03C1/29 , G03C5/04
CPC分类号： G03C1/29
摘要： A silver halide photographic light-sensitive element suitable for exposure to light for a period of time of less than (preferably) 0.0001 second comprising a support bearing thereon at least one layer of a silver halide photographic emulsion, the silver halide photographic emulsion containing at least one sensitizing dye represented by the following General Formula (I) in combination with at least one sensitizing dye represented by the following General Formula (II): ##SPC1##wherein R.sub.1 and R.sub.2 each represents an alkyl group, at least one of R.sub.1 and R.sub.2 being an alkyl group having a sulfo substituent; ##SPC2##Wherein R.sub.B represents a methyl group or an ethyl group, R.sub.3 and R.sub.4 have the same meaning as R.sub.1 and R.sub.2, at least one of R.sub.3 and R.sub.4 being an alkyl group having a sulfo substituent.
摘要翻译：一种卤化银照相感光元件，其适用于曝光时间小于（优选）0.0001秒的时间，包括在其上承载至少一层卤化银照相乳剂的载体，所述卤化银照相乳剂至少含有一种由以下通式（I）表示的增感染料与由以下通式（II）表示的至少一种敏化染料组合：

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