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31. 发明授权

US4976886A Preparation of organometallic and organobimetallic compounds 失效
标题翻译：有机金属和有机金属化合物的制备
公开(公告)号：US4976886A
公开(公告)日：1990-12-11
申请号：US160388
申请日：1988-02-25
申请人： Robert C. Morrison , Terry L. Rathman
发明人： Robert C. Morrison , Terry L. Rathman
IPC分类号： C07F1/02 , C07F1/04 , C07F3/02 , C07F3/04 , C07F3/06 , C07F5/06
CPC分类号： C07F1/02 , C07F1/04 , C07F3/02
摘要： A process for producing organometallic compositions by reacting an organohalide with a mixture of two metals; one being an alkali metal, the other being selected from magnesium, calcium, barium and zinc in a hydrocarbon solvent containing 0.5 to 2.0 moles of a Lewis Base per mole of organohalide.

32. 发明授权

US5300252A Ether free organometallic amide compositions 失效
标题翻译：醚游离有机金属酰胺组合物
公开(公告)号：US5300252A
公开(公告)日：1994-04-05
申请号：US927689
申请日：1992-08-07
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： C07F3/00 , C07F3/02 , C07F7/10 , C09K3/00
CPC分类号： C07F3/003 , C07F3/02 , C07F7/10
摘要： An ether-free organolithium-lithium organoamide composition represented by the formulaLi.sub.x R.sup.1.sub.a (NR.sup.3 R.sup.4)bwherein R.sup.1, R.sup.3 and R.sup.4 are independently selected from the group of primary, secondary and tertiary alkyl groups containing 2 to 20 carbon atoms, cycloalkyl groups containing 3 to 20 carbon atoms and aryl groups containing 6 to 10 carbon atoms and wherein R.sup.3 and R.sup.4 may also be hydrogen and a hydrocarbon solvent with the proviso that at least one of R.sup.3 and R.sup.4 is other than hydrogen.
摘要翻译：由式LixR1a（NR3R4）b表示的无醚有机锂 - 锂有机酰胺组合物，其中R 1，R 3和R 4独立地选自含有2至20个碳原子的伯，仲和叔烷基，含3至 20个碳原子和含有6至10个碳原子的芳基，其中R3和R4也可以是氢和烃溶剂，条件是R3和R4中的至少一个不是氢。

33. 发明授权

US4944894A Ether free organometallic amide compositions 失效
标题翻译：醚游离有机金属酰胺组合物
公开(公告)号：US4944894A
公开(公告)日：1990-07-31
申请号：US160229
申请日：1988-02-25
申请人： Vijay C. Mehta , Terry L. Rathman , Ramiro Sanchez , Robert C. Morrison
发明人： Vijay C. Mehta , Terry L. Rathman , Ramiro Sanchez , Robert C. Morrison
IPC分类号： C07F3/00 , C07F3/02 , C07F7/10
CPC分类号： C07F7/10 , C07F3/003 , C07F3/02
摘要： An ether free magnesium bisorganoamide of the formulaMg[N(R.sup.1) (R.sup.2)].sub.2wherein R.sup.1 and R.sup.2 are independently selected from hydrogen and alkyl groups containing 2 to 20 carbon atoms with the proviso that at least one of R.sup.1 and R.sup.2 is other than hydrogen or R.sup.1 and R.sup.2 taken together form an alkylene chain of 4 to 20 carbon atoms and a method of manufacture. Also disclosed are lithium-magnesiumorganoamides and organosubstituted lithium-magnesiumorganoamide.
摘要翻译：式Mg [N（R 1）（R 2）] 2的无醚自由基二有机酰胺，其中R 1和R 2独立地选自氢和含有2至20个碳原子的烷基，条件是R 1和R 2中的至少一个是其它的氢或R 1和R 2一起形成4至20个碳原子的亚烷基链和制备方法。还公开了锂 - 镁有机酰胺和有机取代的锂 - 镁有机酰胺。

34. 发明授权

US4429054A Hydrocarbon solvent solutions of complexes of isopropyllithium and ethyllithium 失效
标题翻译：异丙基锂和乙基锂络合物的烃溶剂溶液
公开(公告)号：US4429054A
公开(公告)日：1984-01-31
申请号：US396815
申请日：1982-07-09
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： C07F1/02 , C08F4/46 , C08F4/48 , B01J31/12
CPC分类号： C07F1/02 , C08F4/461 , C08F4/488
摘要： Hydrocarbon, especially aliphatic and/or cycloaliphatic hydrocarbon, solvent solutions of complexes of isopropyllithium and ethyllithium, exemplified by (a) equimolar solutions of isopropyllithium and ethyllithium in n-hexane or cyclohexane, and (b) 25 mole % isopropyllithium and 75 mole % ethyllithium in n-hexane or cyclohexane. The hydrocarbon solvent solutions of said complexes, especially where said solvents are aliphatic or cycloaliphatic, have various advantages over conventionally used hydrocarbon solvent solutions of isopropyllithium as catalysts or initiators in polymerization reactions, telomerization reactions, metalation reactions, halogen-metal interchange reactions, and in the preparation of magnesium alkyls and other organometallics.
摘要翻译：烃，特别是脂族和/或脂环族烃，异丙基锂和乙基锂络合物的溶剂溶液，例如（a）异丙基锂和乙基锂在正己烷或环己烷中的等摩尔溶液，和（b）25摩尔％异丙基锂和75摩尔％乙基锂在正己烷或环己烷中。所述配合物的烃溶剂溶液，特别是所述溶剂是脂族或脂环族的烃溶剂溶液具有优于常规使用的异丙基锂溶剂溶液作为催化剂或引发剂在聚合反应，调聚反应，金属化反应，卤素 - 金属交换反应和烷基镁等有机金属的制备。

35. 发明授权

US6145678A Adjustable, suspended overhead storage rack 失效
标题翻译：可调节的悬挂架空存储架
公开(公告)号：US6145678A
公开(公告)日：2000-11-14
申请号：US099135
申请日：1998-06-18
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： A47B53/00 , A47B96/00 , B65G1/04 , A47F5/08
CPC分类号： A47B96/00 , A47B53/00 , B65G1/0457
摘要： An adjustable storage rack apparatus for suspension from an overhead support, for storage of selected objects, such as boxes, lumber, pipe, sports equipment. First and second hanger members form an inverted U-shaped bracket sized to fit over the overhead support. The first side of each of the first and second hanger members extends below the inverted U-shaped bracket, and the second side of each of the first and second hanger members is bent to form a U-shaped bracket for supporting at least one object therefrom. Respective first and second elongated angle members each have first and second legs extending at right angles, and the first leg of the respective first and second elongated angle members are each adjustably secured to the lower end of the first side of the respective first and second hanger members. A substantially horizontal cross bar is selectively secured to either the first or second legs of each of the first and second elongated angle members, to form a substantially horizontal support therebetween.At least one horizontal planar member may extend between aligned cross bars, to form a platform for receiving at least one object thereon. Where the cross bar(s) extend beyond the first and second elongated angle members, additional horizontal planar members may be secured to the cross bar portion extending beyond the first and second elongated angle members. A ceiling bracket may be used to secure the first hanger support member to the overhead structural support.
摘要翻译：一种用于从架空支架悬挂的可调节的存放架设备，用于存储所选择的物体，例如箱子，木材，管道，运动器材。第一和第二衣架构件形成倒置的U形支架，其尺寸适合装配在架空支架上。第一和第二衣架构件中的每一个的第一侧在倒置的U形支架的下面延伸，并且第一和第二衣架构件中的每一个的第二侧被弯曲以形成用于支撑至少一个物体的U形支架。相应的第一和第二细长角件各自具有以直角延伸的第一和第二腿部，并且相应的第一和第二细长角件的第一腿各自可调节地固定到相应的第一和第二衣架的第一侧的下端会员基本水平的横杆被选择性地固定到第一和第二细长角件中的每一个的第一或第二腿上，以在它们之间形成基本上水平的支撑。至少一个水平平面构件可以在对准的横杆之间延伸，以形成用于在其上接收至少一个物体的平台。当横杆延伸超过第一和第二细长角件时，额外的水平平面构件可以固定到延伸超过第一和第二细长角件的横杆部分。可以使用天花板支架将第一衣架支撑构件固定到顶部结构支撑件。

36. 发明授权

US5052307A Pallet tray system 失效
标题翻译：托盘托盘系统
公开(公告)号：US5052307A
公开(公告)日：1991-10-01
申请号：US427469
申请日：1989-10-26
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： B65D19/38
CPC分类号： B65D19/38 , B65D2519/00029 , B65D2519/00034 , B65D2519/00064 , B65D2519/00099 , B65D2519/00273 , B65D2519/00293 , B65D2519/00323 , B65D2519/00333 , B65D2519/00373 , B65D2519/00567 , B65D2519/00572 , B65D2519/00815 , B65D2519/0096 , Y10S108/901
摘要： A pallet tray system includes a tray attached to a top section of a wooden pallet. The wooden pallet has wings on at least two sides. Each wing has an engagable underside. The tray has a mechanism for engaging the undersides of the wings of the pallet to secure the tray.
摘要翻译：托盘托盘系统包括附接到木托盘顶部的托盘。木托盘至少有两侧有翅膀。每个翼都有一个可以接合的下侧。托盘具有用于接合托盘的翼的下侧以固定托盘的机构。

37. 发明授权

US4460515A Hydrocarbon solvent solutions of complexes of sec-butyllithium and ethyllithium 失效
标题翻译：仲丁基锂和乙基锂络合物的烃溶剂溶液
公开(公告)号：US4460515A
公开(公告)日：1984-07-17
申请号：US395271
申请日：1982-07-06
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： C07C51/15 , C07F1/02 , C07F3/02
CPC分类号： C07F3/02 , C07C51/15 , C07F1/02
摘要： Hydrocarbon, especially aliphatic and/or cycloaliphatic hydrocarbon, solvent solutions of complexes of sec-butyllithium and ethyllithium, exemplified by (a) equimolar solutions of sec-butyllithium and ethyllithium in n-hexane or cyclohexane, (b) 35 mole % sec-butyllithium and 65 molar % ethyllithium in n-hexane or cyclohexane, and (c) 1 mole % sec-butyllithium and 3 mole % ethyllithium in n-hexane or cyclohexane. The thermal stability of the complexes of sec-butyllithium and ethyllithium in the solutions thereof in hydrocarbon solvents has been found to be outstanding. The hydrocarbon solvent solutions, especially where said solvents are aliphatic or cycloaliphatic, have marked advantages over conventionally used hydrocarbon solvent solutions of sec-butyllithium as catalysts or initiators in polymerization reactions, telomerization reactions, metalation reactions, halogen-metal interchange reactions, and in the preparation of magnesium alkyls and other organometallics.
摘要翻译：烃，特别是脂族和/或脂环族烃，仲丁基锂和乙基锂络合物的溶剂溶液，例如（a）仲丁基锂和乙基锂在正己烷或环己烷中的等摩尔溶液，（b）35摩尔％仲丁基锂和65摩尔％乙基锂在正己烷或环己烷中，和（c）1摩尔％仲丁基锂和3摩尔％乙基锂在正己烷或环己烷中的溶液。已经发现，仲烃基锂和乙基锂在烃类溶剂中的溶液的热稳定性是显着的。烃溶剂溶液，特别是所述溶剂是脂族或脂环族烃时，具有优于常规使用的仲丁基锂的烃溶剂溶液作为聚合反应中的催化剂或引发剂，调聚反应，金属化反应，卤素 - 金属交换反应，以及在制备烷基镁等有机金属。

38. 发明授权

US4399078A Hydrocarbon solvent solutions of complexes of N-butyllithium and ethyllithium 失效
标题翻译： N-丁基锂和乙基锂络合物的烃溶剂溶液
公开(公告)号：US4399078A
公开(公告)日：1983-08-16
申请号：US395272
申请日：1982-07-06
申请人： Robert C. Morrison
发明人： Robert C. Morrison
IPC分类号： C07C51/15 , C07F1/02
CPC分类号： C07F1/02 , C07C51/15
摘要： Hydrocarbon, especially aliphatic and/or cycloaliphatic hydrocarbon, solvent solutions of complexes of n-butyllithium and ethyllithium, exemplified by (a) equimolar solutions of n-butyllithium and ethyllithium in n-hexane or cyclohexane, (b) 36 molar % n-butyllithium and 64 mole % ethyllithium in n-hexane or cyclohexane, and (c) 25 mole % n-butyllithium and 75 mole % ethyllithium in n-hexane or cyclohexane. The thermal stability of the complexes of n-butyllithium and ethyllithium in the solutions thereof in hydrocarbon solvents has been found to be outstanding. The hydrocarbon solvent solutions of said complexes, especially where said solvents are aliphatic or cycloaliphatic, have marked advantages over conventionally used hydrocarbon solvent solutions of n-butyllithium as catalysts or initiators in polymerization reactions, telomerization reactions, metalation reactions, halogen-metal interchange reactions, and in the preparation of magnesium alkyls and other organometallics.
摘要翻译：烃，特别是脂族和/或脂环族烃，正丁基锂和乙基锂络合物的溶剂溶液，例如（a）正丁基锂和乙基锂在正己烷或环己烷中的等摩尔溶液，（b）36摩尔％正丁基锂和64摩尔％乙基锂在正己烷或环己烷中，和（c）25摩尔％正丁基锂和75摩尔％乙基锂在正己烷或环己烷中的溶液。已经发现正丁基锂和乙基锂在其溶剂中的溶液中的热稳定性是非常优异的。所述配合物的烃溶剂溶液，特别是所述溶剂是脂族或脂环族的烃溶剂溶液，在聚合反应，调聚反应，金属化反应，卤素 - 金属交换反应中，作为催化剂或引发剂的常规使用的烃溶剂溶液具有显着的优点，以及制备烷基镁等有机金属。

39. 发明授权

US4041088A Recirculation telomerization process and its liquid telomers and liquid telomers produced thereby 失效
标题翻译：循环调聚过程及其液体调节剂和液体调节剂
公开(公告)号：US4041088A
公开(公告)日：1977-08-09
申请号：US739484
申请日：1976-11-08
申请人： Ricardo O. Bach , Robert C. Morrison
发明人： Ricardo O. Bach , Robert C. Morrison
IPC分类号： C08F2/00 , C08F2/38 , C08F2/42 , C08F36/04 , C07C15/02
CPC分类号： C08F2/38 , C08F36/04 , Y10S585/923
摘要： Recirculation process and apparatus for the preparation of normally liquid telomers derived from the reaction of a gaseous taxogen with a solution in a liquid telogen, such as toluene, of an organometal telomerization initiator, such as a mixture or complex of n-butyllithium and potassium t-butoxide, in a container, wherein a controlled stream of the gaseous taxogen is continuously passed through fine apertures, as in a screen, into the liquid telogen solution of said initiator while said telogen solution is passed from said container through a reaction zone in a reaction chamber, whereby to produce the normally liquid telomer, and, thereafter, said liquid telomer is continuously returned to commingle with the solution in the container of said telogen and initiator, and continuously recirculating the contents of said container into said reaction zone for further reaction with said gaseous taxogen until the desired concentration of liquid telomer is produced. The process is most desirably carried out in a controlled manner to prevent any undesirable excess of the taxogen from accumulating during the chain transfer step of the telomerization process. The process also results in the production of novel liquid telomers or liquid telomers having novel and advantageous properties in relation to otherwise generally similar liquid telomers heretofore known to the art.
摘要翻译：用于制备来自气态发酵剂与溶液的液体前体（如甲苯）的有机金属调聚引发剂如正丁基锂和钾的混合物的反应的循环过程和装置在容器中，其中将受控流的气态色素原连续地通过如丝网中的细小孔进入所述引发剂的液体前体溶液中，同时将所述前体溶液从所述容器通过反应区反应室，由此产生正常液体的调聚物，然后使所述液体调聚物连续地返回以与所述洗脱剂和引发剂的容器中的溶液相混合，并将所述容器的内容物连续再循环到所述反应区域中用于进一步的反应与所述气态紫杉醇直到产生所需浓度的液体调聚物。该方法最希望以受控的方式进行，以防止在调聚过程的链转移步骤过程中不必要的过量的发酵剂积累。该方法还导致新型液体调节剂或液体调聚物的生产，其具有与本领域迄今为止已知的其它通用类似的液体调节剂相关的新型和有利的性质。

40. 发明授权

US5141667A Preparation of organometallic and organobimetallic compounds 失效
标题翻译：有机金属和有机金属化合物的制备
公开(公告)号：US5141667A
公开(公告)日：1992-08-25
申请号：US567577
申请日：1990-09-10
申请人： Robert C. Morrison , Terry L. Rathman
发明人： Robert C. Morrison , Terry L. Rathman
IPC分类号： C07F1/02 , C07F1/04 , C07F3/02
CPC分类号： C07F1/04 , C07F1/02 , C07F3/02
摘要： A process for producing organometallic compositions by reacting an organohalide with a mixture of two metals; one being an alkali metal, the other being selected from magnesium, calcium, barium and zinc in a hydrocarbon solvent containing 0.5 to 2.0 moles of a Lewis Base per mole of organohalide.
摘要翻译：一种通过使有机卤化物与两种金属的混合物反应制备有机金属组合物的方法; 一种是碱金属，另一种选自镁，钙，钡和锌，在每摩尔有机卤化物中含有0.5至2.0摩尔路易斯碱的烃溶剂中。

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