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1. 发明授权

US4041088A Recirculation telomerization process and its liquid telomers and liquid telomers produced thereby 失效
标题翻译：循环调聚过程及其液体调节剂和液体调节剂
公开(公告)号：US4041088A
公开(公告)日：1977-08-09
申请号：US739484
申请日：1976-11-08
申请人： Ricardo O. Bach , Robert C. Morrison
发明人： Ricardo O. Bach , Robert C. Morrison
IPC分类号： C08F2/00 , C08F2/38 , C08F2/42 , C08F36/04 , C07C15/02
CPC分类号： C08F2/38 , C08F36/04 , Y10S585/923
摘要： Recirculation process and apparatus for the preparation of normally liquid telomers derived from the reaction of a gaseous taxogen with a solution in a liquid telogen, such as toluene, of an organometal telomerization initiator, such as a mixture or complex of n-butyllithium and potassium t-butoxide, in a container, wherein a controlled stream of the gaseous taxogen is continuously passed through fine apertures, as in a screen, into the liquid telogen solution of said initiator while said telogen solution is passed from said container through a reaction zone in a reaction chamber, whereby to produce the normally liquid telomer, and, thereafter, said liquid telomer is continuously returned to commingle with the solution in the container of said telogen and initiator, and continuously recirculating the contents of said container into said reaction zone for further reaction with said gaseous taxogen until the desired concentration of liquid telomer is produced. The process is most desirably carried out in a controlled manner to prevent any undesirable excess of the taxogen from accumulating during the chain transfer step of the telomerization process. The process also results in the production of novel liquid telomers or liquid telomers having novel and advantageous properties in relation to otherwise generally similar liquid telomers heretofore known to the art.
摘要翻译：用于制备来自气态发酵剂与溶液的液体前体（如甲苯）的有机金属调聚引发剂如正丁基锂和钾的混合物的反应的循环过程和装置在容器中，其中将受控流的气态色素原连续地通过如丝网中的细小孔进入所述引发剂的液体前体溶液中，同时将所述前体溶液从所述容器通过反应区反应室，由此产生正常液体的调聚物，然后使所述液体调聚物连续地返回以与所述洗脱剂和引发剂的容器中的溶液相混合，并将所述容器的内容物连续再循环到所述反应区域中用于进一步的反应与所述气态紫杉醇直到产生所需浓度的液体调聚物。该方法最希望以受控的方式进行，以防止在调聚过程的链转移步骤过程中不必要的过量的发酵剂积累。该方法还导致新型液体调节剂或液体调聚物的生产，其具有与本领域迄今为止已知的其它通用类似的液体调节剂相关的新型和有利的性质。

2. 发明授权

US4206191A Preparation of lithium amide 失效
标题翻译：氨基锂的制备
公开(公告)号：US4206191A
公开(公告)日：1980-06-03
申请号：US970531
申请日：1978-12-18
申请人： Robert C. Morrison , Ricardo O. Bach
发明人： Robert C. Morrison , Ricardo O. Bach
IPC分类号： C01B21/092 , C01D15/00
CPC分类号： C01B21/0926 , C01B3/08 , Y02E60/36
摘要： A low temperature method of preparing finely divided lithium amide. A mixture is first formed of bulk pieces of lithium metal with a catalyst such as active metallic cobalt in an inert liquid aromatic hydrocarbon, such as toluene, at about 0.degree. C. to about -60.degree. C. Anhydrous liquid ammonia is then added, aided by stirring, the lithium metal dissolving, two immiscible phases forming, one a so-called lithium-ammonia bronze solution being the top phase, and the toluene being the bottom phase. The formation of the lithium amide is then effected by raising the temperature under conditions of stirring, hydrogen and excess ammonia being liberated and the lithium amide, generally light grey in color, is formed which separates out in a very finely divided solid state, as a slurry in the toluene, and is recovered.
摘要翻译：制备细分散的氨基化锂的低温方法。混合物首先在大约0℃至大约-60℃的惰性液体芳烃（如甲苯）中由大量锂金属与催化剂如活性金属钴形成，然后加入无水液氨，通过搅拌辅助，锂金属溶解，形成两个不混溶相，一个是所谓的顶级相的氨 - 氨青铜溶液，甲苯是底相。然后通过在搅拌条件下升高温度，释放氢气和过量的氨来实现氨基化锂的形成，并且形成通常为浅灰色的氨基化锂，其以非常精细分散的固体状态分离出来，作为在甲苯中淤浆，并回收。

3. 发明授权

US4049732A Continuous telomerization process and its liquid products 失效
标题翻译：连续调聚过程及其液体产品
公开(公告)号：US4049732A
公开(公告)日：1977-09-20
申请号：US725640
申请日：1976-09-22
申请人： Ricardo O. Bach , Robert C. Morrison
发明人： Ricardo O. Bach , Robert C. Morrison
IPC分类号： C08F2/38 , C07C15/02
CPC分类号： C08F2/38 , Y10S585/922 , Y10S585/926 , Y10S585/931
摘要： Continuous process and apparatus for the preparation of normally liquid telomers derived from the reaction of a liquid telogen, such as toluene, with a polymerizable monomeric taxogen in gaseous form, such as 1,3-butadiene monomer, in the presence of an organometal telomerization initiator, such as a mixture or complex of n-butyllithium and potassium t-butoxide, wherein a controlled stream of the gaseous taxogen is continuously passed through fine apertures, as in a screen, into the liquid telogen containing said initiator disposed in a reaction zone in a reaction chamber, whereby to produce the normally liquid telomer, and, thereafter said telomer is continuously passed through a conduit into an additional reaction zone or zones and reacted in similar manner with additional gaseous taxogen until the desired concentration of liquid telomer is produced. The process is most desirably carried out in a controlled manner to prevent any undesirable excess of the taxogen from accumulating during the chain transfer step of the telomerization process. The process also results in the production of novel liquid telomers or liquid telomers having novel and advantageous properties in relation to otherwise generally similar liquid telomers heretofore known to the art.
摘要翻译：在有机金属调聚引发剂存在下，制备源自液体循环调节剂如甲苯的液体调节剂与气态形式的可聚合单体发酵剂如1,3-丁二烯单体的连续方法和装置，例如正丁基锂和叔丁醇钾的混合物或络合物，其中将气态发酵剂的受控流连续地通过如筛网中的细孔，进入包含设置在反应区中的所述引发剂的液体前体反应室，由此产生正常液体的调聚物，此后，所述调聚物连续地通过导管进入另外的反应区或区域，并以类似的方式与额外的气态紫杉醇反应，直到产生所需浓度的液体调聚物。该方法最希望以受控的方式进行，以防止在调聚过程的链转移步骤过程中不必要的过量的发酵剂积累。该方法还导致新型液体调节剂或液体调聚物的生产，其具有与本领域迄今为止已知的其它通用类似的液体调节剂相关的新型和有利的性质。

4. 发明授权

US5332853A Catalytic alkylation process 失效
标题翻译：催化烷基化工艺
公开(公告)号：US5332853A
公开(公告)日：1994-07-26
申请号：US92319
申请日：1993-07-14
申请人： Robert C. Morrison , Randy W. Hall , B. Troy Dover , Conrad W. Kamienski , John F. Engel
发明人： Robert C. Morrison , Randy W. Hall , B. Troy Dover , Conrad W. Kamienski , John F. Engel
IPC分类号： B01J31/02 , B01J31/12 , C07B61/00 , C07F1/00 , C07F1/02 , C07F7/08 , C07F7/12 , C07F7/04
CPC分类号： C07F1/02 , C07F1/00 , C07F7/0896 , C07F7/122
摘要： This application concerns a process for alkylating, in a hydrocarbon solvent reaction medium, metalloidal substrates such as alkylating a chlorosilane with an alkyllithium containing 3 to 8 carbon atoms by conducting these reactions in the presence of a catalyst selected from primary and secondary alcohols, and their respective metal alkoxides, cyclic ethers, hydrocarbyl ethers, hydrocarbyl silyl ethers, and tertiary amines.
摘要翻译：本申请涉及一种在烃溶剂反应介质中烷基化的方法，例如通过在选自伯醇和仲醇的催化剂存在下进行这些反应而将含有3-8个碳原子的烷基锂烷基化氯代硅烷的金属基底，各自的金属醇盐，环醚，烃基醚，烃基甲硅烷基醚和叔胺。

5. 发明授权

US5320774A Preparation of organometallic amide compositions 失效
标题翻译：有机金属酰胺组合物的制备
公开(公告)号：US5320774A
公开(公告)日：1994-06-14
申请号：US334667
申请日：1989-04-06
申请人： Vijay C. Mehta , Terry L. Rathman , Conrad W. Kamienski , Robert C. Morrison , Randy W. Hall
发明人： Vijay C. Mehta , Terry L. Rathman , Conrad W. Kamienski , Robert C. Morrison , Randy W. Hall
IPC分类号： C07F1/08 , C07F1/00 , C07F3/00 , C07F3/02 , C07F3/04 , C07F3/06 , C07F7/10 , C07F9/28 , C07F9/72 , C07F9/74 , C07F19/00 , C09K3/00
CPC分类号： C07F3/003 , C07F1/005 , C07F7/10
摘要： This invention concerns organometallic amide compositions particularly bimetallic organoamides in liquid hydrocarbon solutions in which one metal is an alkali metal the other an alkaline earth metal, zinc or copper and particularly lithium magnesium bis-diorganoamides, such as lithium magnesium bis-diisopropylamide and processes for preparation of such amides. These novel bimetallic amides have increased solubility in liquid hydrocarbon solvents and improved thermal and precipitation stability at temperatures of 0.degree. C. to 40.degree. C.
摘要翻译：本发明涉及有机金属酰胺组合物，特别是液态烃溶液中的双金属有机酰胺，其中一种金属是碱金属，另一种是碱土金属，锌或铜，特别是锂二异氰酸镁锂，双的这种酰胺。这些新型双金属酰胺在液体烃溶剂中具有增加的溶解度，并且在0℃至40℃的温度下改善了热和沉淀稳定性。

6. 发明授权

US4976886A Preparation of organometallic and organobimetallic compounds 失效
标题翻译：有机金属和有机金属化合物的制备
公开(公告)号：US4976886A
公开(公告)日：1990-12-11
申请号：US160388
申请日：1988-02-25
申请人： Robert C. Morrison , Terry L. Rathman
发明人： Robert C. Morrison , Terry L. Rathman
IPC分类号： C07F1/02 , C07F1/04 , C07F3/02 , C07F3/04 , C07F3/06 , C07F5/06
CPC分类号： C07F1/02 , C07F1/04 , C07F3/02
摘要： A process for producing organometallic compositions by reacting an organohalide with a mixture of two metals; one being an alkali metal, the other being selected from magnesium, calcium, barium and zinc in a hydrocarbon solvent containing 0.5 to 2.0 moles of a Lewis Base per mole of organohalide.

7. 发明授权

US4595779A Stable lithium diisopropylamide and method of preparation 失效
标题翻译：稳定的二异丙基氨基锂及其制备方法
公开(公告)号：US4595779A
公开(公告)日：1986-06-17
申请号：US685318
申请日：1984-12-24
申请人： Robert C. Morrison , Randy W. Hall , Terry L. Rathman
发明人： Robert C. Morrison , Randy W. Hall , Terry L. Rathman
IPC分类号： C07C209/90 , C07C67/00 , C07C209/00 , C07C211/65 , C07F1/02 , C07C85/26 , C07C87/123
CPC分类号： C07C209/90
摘要： The present invention provides a nonpyrophoric and thermally stable form of lithium diisopropylamide which is useful as a reagent in the preparation of pharmaceuticals and specialty chemicals. The preferred composition includes lithium diisopropylamide, a limited amount of tetrahydrofuran in an amount not exceeding one mole per mole of lithium diisopropylamide, and at least one C.sub.2 to C.sub.18 amine.
摘要翻译：本发明提供了非制备和热稳定形式的二异丙基氨基锂，其可用作制备药物和特种化学品的试剂。优选的组合物包括二异丙基氨基锂，有限量的四氢呋喃，其量不超过1摩尔/二异丙基氨基锂和至少一种C 2至C 18胺。

8. 发明授权

US3954894A Organotrilithium polymerization initiators 失效
标题翻译：有机三聚体聚合引发剂
公开(公告)号：US3954894A
公开(公告)日：1976-05-04
申请号：US361467
申请日：1973-05-18
申请人： Conrad W. Kamienski , Robert C. Morrison
发明人： Conrad W. Kamienski , Robert C. Morrison
IPC分类号： C08F4/00 , C07F1/02 , C08F4/42 , C08F4/48 , C08F36/00 , C08F36/04
CPC分类号： C08F4/488 , C07F1/02 , C08F36/04 , Y10S585/906
摘要： Preparation of novel organotrilithium initiators, which are soluble in hydrocarbon media, from disubstituted vinylaromatic compounds and mono- and dilithium organic compounds, said initiators being useful in the polymerization of conjugated dienes and copolymerization of these with vinylaromatic compounds.
摘要翻译：从二取代的乙烯基芳族化合物和单 - 和二锂有机化合物制备可溶于烃介质的新的有机三
亚砜引发剂，所述引发剂可用于共轭二烯的聚合和它们与乙烯基芳族化合物的共聚。

9. 发明授权

US5654371A Anionic polymerization process using functionalized initiators 失效
标题翻译：使用官能化引发剂的阴离子聚合方法
公开(公告)号：US5654371A
公开(公告)日：1997-08-05
申请号：US460308
申请日：1995-06-02
申请人： James A. Schwindeman , Conrad W. Kamienski , Robert C. Morrison
发明人： James A. Schwindeman , Conrad W. Kamienski , Robert C. Morrison
IPC分类号： C08C19/44 , C08F4/08 , C08F4/46 , C08F4/48 , C08F12/04 , C08F12/06 , C08F36/04 , C08F279/02 , C08F8/00
CPC分类号： C08C19/44 , C08F12/04 , C08F12/06 , C08F279/02 , C08F36/04 , C08F4/46
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) (II)wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is defined as a branched or straight chain hydrocarbon tether or connecting group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and n is an integer from 1 to 5. monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译：一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Qn-Z-OA（R1R2R3）（Ⅱ）其中M定义为碱金属，选自锂，钠和钾，Q是通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的饱和或不饱和烃基; Z定义为含有3-25个碳原子的支链或直链烃系链或连接基团，任选含有芳基或取代的芳基; A是选自元素周期表Ⅳa的元素，R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，n是1至5的整数。聚合过程中引发剂的使用以及通过聚合方法制备的聚合物。

10. 发明授权

US5605872A Functionalized amine initiators for anionic polymerization 失效
标题翻译：用于阴离子聚合的官能化胺引发剂
公开(公告)号：US5605872A
公开(公告)日：1997-02-25
申请号：US459585
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
IPC分类号： C08F4/46 , C08F4/48 , C08F12/04 , C08F36/04 , B01J31/12 , B01J31/18
CPC分类号： C08F12/04 , C08F36/04
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译：制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。

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