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31. 发明授权

US08299281B2 Process for making triglyceride plasticizer from crude glycerol 有权
标题翻译：从粗甘油制备甘油三酯增塑剂的方法
公开(公告)号：US08299281B2
公开(公告)日：2012-10-30
申请号：US12661362
申请日：2010-03-16
申请人： Jihad Mohammed Dakka , Edmund J Mozeleski , Lisa Saunders Baugh
发明人： Jihad Mohammed Dakka , Edmund J Mozeleski , Lisa Saunders Baugh
IPC分类号： C09F7/02 , C07C51/16 , C07C51/235 , C07C67/48
CPC分类号： C08K5/0016 , C07C67/08 , C11C3/02 , C07C69/30
摘要： Provided are processes for making, and processes for using triglycerides as plasticizers. Mixed triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with a crude glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. The product selectivity obtained from esterifying with crude glycerol is comparable to that of esterifying with pure glycerol. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供了制备方法和使用甘油三酯作为增塑剂的方法。混合甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 13醛，用氧气和/或空气氧化成酸，回收所得酸，并用粗甘油进行酯化来制备，其中总碳数的三聚物组合物的增塑剂的含量为大于或等于45wt％的20至25。用粗甘油酯化获得的产物选择性与用纯甘油酯化的产物选择性相当。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

32. 发明申请

US20120035308A1 METHODS OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF 审中-公开
标题翻译：制备6-羟基六氢呋喃酮和5-苯甲酰基戊酸及其单体或二氧化钛的方法
公开(公告)号：US20120035308A1
公开(公告)日：2012-02-09
申请号：US13197253
申请日：2011-08-03
申请人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
发明人： Kun Wang , Jihad Mohammed Dakka , Edmund John Mozeleski , Francisco Manuel Benitez , Lisa Saunders Baugh , Allen David Godwin , Diana S. Smirnova , Stephen Zushma
IPC分类号： C08K5/12 , C07C45/28 , C08K5/101 , C07C67/40 , C07C67/08 , C07C69/612 , C07C69/716
CPC分类号： C07C45/53 , C07C51/235 , C07C67/08 , C07C67/29 , C07C67/31 , C07C69/24 , C07C69/738 , C07C407/00 , C07C2601/14 , C08K5/10 , C07C49/82 , C07C409/14 , C07C59/84 , C07C69/732 , C07C69/73 , C07C69/28
摘要： Mono- or diester plasticizers of the formula: wherein A is either —OC(O)R′ or ═O, and X is either —COC(O)R or —C(O)OR, and R and R′ are C3 to C13 alkyl, which are the same or different, formed from cyclohexylbenzene and processes of making them.
摘要翻译：单或二酯增塑剂，其通式为：其中A为-OC（O）R'或= O，X为-COC（O）R或-C（O）OR，R和R'为C 3〜 C13烷基，它们是相同或不同的，由环己基苯形成及其制备方法。

33. 发明授权

US07910772B2 Mixed metal oxide catalysts and processes for their preparation and use 有权
标题翻译：混合金属氧化物催化剂及其制备和使用方法
公开(公告)号：US07910772B2
公开(公告)日：2011-03-22
申请号：US12869275
申请日：2010-08-26
申请人： Kun Wang , James C. Vartuli , Wilfried Jozef Mortier , Jihad Mohammed Dakka , Robert C. Lemon
发明人： Kun Wang , James C. Vartuli , Wilfried Jozef Mortier , Jihad Mohammed Dakka , Robert C. Lemon
IPC分类号： C07C51/16
CPC分类号： B01J35/002 , B01J23/002 , B01J23/28 , B01J27/0576 , B01J37/08 , B01J2523/00 , C07C51/215 , C07C51/252 , C07D301/08 , C07C57/04 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , B01J2523/53
摘要： A catalyst for the oxidation of an alkane, alkene or mixtures thereof. The catalyst includes a mixed-metal oxide having the formula MoaVbNbcTedSbeOf wherein, when a=1, b=0.01 to 1.0, c=0.01 to 1.0, d=0.01 to 1.0, e=0.01 to 1.0, and f is dependent upon the oxidation state of the other elements, the catalyst further characterized by having at least two crystal phases, the first crystal phase being an orthorhombic M1 phase and the second crystal phase being a pseudo-hexagonal M2 phase, the orthorhombic M1 phase present in an amount between greater than 60 weight percent to less than 90 weight percent. The catalysts disclosed herein exhibit a chemisorption of NH3 of less than about 0.2 mmole per gram of metal oxide.
摘要翻译：用于氧化烷烃，烯烃或其混合物的催化剂。催化剂包括具有式MoaVbNbcTedSbeOf的混合金属氧化物，其中当a = 1时，b = 0.01至1.0，c = 0.01至1.0，d = 0.01至1.0，e = 0.01至1.0，f取决于氧化其他元素的状态，催化剂的特征还在于具有至少两个结晶相，第一晶相是正交的M 1相，第二晶相是拟六方晶系的M 2相，正交晶相M1相位存在于较大的超过60重量％至小于90重量％。本文公开的催化剂表现出每克金属氧化物小于约0.2毫摩尔的NH 3的化学吸附。

34. 发明申请

US20100159177A1 Triglyceride plasticizer and process of making 有权
标题翻译：甘油三酯增塑剂及其制备方法
公开(公告)号：US20100159177A1
公开(公告)日：2010-06-24
申请号：US12653744
申请日：2009-12-17
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Enock Berluche
IPC分类号： C08L91/00 , C07C51/16 , C07C57/00 , B32B1/08 , B32B27/04 , A61M1/00
CPC分类号： C08L91/00 , C08K5/103 , Y10T428/139 , Y10T442/20 , C08L27/06 , C08L67/00 , C08L75/04 , C08L31/04 , C08L33/00
摘要： Provided are compositions, processes for making, and processes for using triglycerides as plasticizers. Triglyceride plasticizers can be produced by recovery of linear or branched C4 to C10 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.
摘要翻译：提供组合物，制备方法和使用甘油三酯作为增塑剂的方法。甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 10醛，用氧和/或空气氧化成酸，回收所得酸，并用甘油进行酯化来制备，其中三酯的总碳数对于大于或等于45重量％的增塑剂，基团为20至25。这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

35. 发明授权

US07326815B2 Selective oxidation of alkylbenzenes 失效
标题翻译：烷基苯的选择性氧化
公开(公告)号：US07326815B2
公开(公告)日：2008-02-05
申请号：US11318731
申请日：2005-12-27
申请人： Jihad Mohammed Dakka , Doron Levin , Jon Edmond Randolph Stanat
发明人： Jihad Mohammed Dakka , Doron Levin , Jon Edmond Randolph Stanat
IPC分类号： C07C45/53 , C07C37/08
CPC分类号： C07C409/08 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C49/08 , C07C49/10 , C07C39/04
摘要： The present invention relates to a process for producing phenol and a ketone of general formula R1COCH2R3 (I), in which R1 and R2 each independently represent an alkyl group having from 1 to 4 carbon atoms, said process comprising: (a) providing an alkylbenzene feedstock comprising (i) an alkylbenzene of general formula (II) in which R1 and R2 have the same meaning as in formula (I) and (ii) at least one structural isomer of said alkylbenzene of formula (II) in an amount of at least 0.7% of the weight of alkylbenzene of formula (II), (b) submitting the alkylbenzene feedstock to oxidation conditions in the presence of oxygen and in the presence of a cyclic imide of formula (III): in which X represents a carbonyl (CO) group or a sulfonyl (SO2) group, n is 0, 1, 2, 3 or 4, R3 is one or several groups selected from a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an amino group and R4 is a hydrogen atom, an alkaline metal cation or an alkaline earth metal cation, or in the presence of N,N′,N″-trihydroxyisocyanuric acid (THICA), to produce a product comprising a hydroperoxide of general formula (IV) in which R1 and R2 have the same meaning as in formula (I), and (c) converting the hydroperoxide of formula (IV) into phenol and a ketone of formula (I).
摘要翻译：本发明涉及一种制备通式为R 1，R 2，R 3，R 3（I）的苯酚和酮的方法，其中R 各个独立地表示具有1至4个碳原子的烷基，所述方法包括：（a）提供烷基苯原料，其包含（i）烷基苯，其中R 1和R 2 2的通式（II）具有与式（I）中相同的含义和（ii）所述烷基苯的至少一种结构异构体（II）的量为至少0.7％的式（II）的烷基苯的重量，（b）将烷基苯原料在氧气存在下并在式（III）的环状酰亚胺存在下，：其中X表示羰基（CO）基团或磺酰基（SO 2 H 2）基团，n为0,1,2,3或4，R 3为一个或选自氢原子，卤素原子，烷基，烷氧基，氨基的数个基团并且R 4是氢原子，碱金属阳离子或碱土金属阳离子，或在N，N'，N“ - 三羟基异氰尿酸（THICA）的存在下，产生包含通式（IV）的氢过氧化物的产物，其中R 1和R 2具有与式（I）中相同的含义，和（c）将氢过氧化物式（IV）转化成苯酚和式（I）的酮。

36. 发明授权

US09586898B2 Oxidation of cyclohexylbenzene 有权
标题翻译：环己基苯氧化
公开(公告)号：US09586898B2
公开(公告)日：2017-03-07
申请号：US13819951
申请日：2011-08-16
申请人： Jihad Mohammed Dakka , Francisco Manuel Benitez , Bryan Amrutlal Patel , Edmund John Mozeleski
发明人： Jihad Mohammed Dakka , Francisco Manuel Benitez , Bryan Amrutlal Patel , Edmund John Mozeleski
IPC分类号： C07C409/14 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C45/32 , C07C51/00 , C07C249/04 , C07D201/02 , C08G69/00
CPC分类号： C07C409/14 , C07C2/74 , C07C37/08 , C07C45/32 , C07C45/53 , C07C51/00 , C07C249/04 , C07C407/00 , C07C2601/14 , C07D201/02 , C08G69/00 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a feed comprising cyclohexylbenzene, the feed is contacted with oxygen and an oxidation catalyst in a plurality of reaction zones connected in series, the contacting being conducted under conditions being effective to oxidize part of the cyclohexylbenzene in the feed to cyclohexylbenzene hydroperoxide in each reaction zone. At least one of the plurality of reaction zones has a reaction condition that is different from another of the plurality of reaction zones. The different reaction conditions may include one or more of (a) a progressively decreasing temperature and (b) a progressively increasing oxidation catalyst concentration as the feed flows from one reaction zone to subsequent reaction zones in the series.
摘要翻译：在用于氧化包含环己基苯的进料的方法中，将进料与串联连接的多个反应区中的氧和氧化催化剂接触，在有效地将进料中的环己基苯的一部分氧化成环己基苯氢过氧化物的条件下进行在每个反应区。多个反应区中的至少一个具有与多个反应区中的另一个不同的反应条件。不同的反应条件可以包括（a）逐渐降低的温度和（b）随着进料从一个反应区流向该系列中的后续反应区的逐渐增加的氧化催化剂浓度中的一个或多个。

37. 发明授权

US09169181B2 Production of cyclohexylbenzene hydroperoxide 有权
标题翻译：生产环己基苯氢过氧化物
公开(公告)号：US09169181B2
公开(公告)日：2015-10-27
申请号：US14007281
申请日：2011-11-28
申请人： Kun Wang , Edmund John Mozeleski , Jihad Mohammed Dakka
发明人： Kun Wang , Edmund John Mozeleski , Jihad Mohammed Dakka
IPC分类号： C07C45/53 , C07C407/00 , C07C37/08
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C407/003 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene hydroperoxide, cyclohexylbenzene is contacted with oxygen to produce a reaction product comprising cyclohexylbenzene hydroperoxide and unreacted cyclohexylbenzene. The reaction product is then maintained under conditions such that crystals of cyclohexylbenzene hydroperoxide form and separate from the reaction product. The cyclohexylbenzene hydroperoxide crystals are then recovered from the reaction product.
摘要翻译：在制备环己基苯氢过氧化物的方法中，使环己基苯与氧气接触以产生包含环己基苯氢过氧化物和未反应的环己基苯的反应产物。然后将反应产物保持在使得环己基苯氢过氧化物的晶体形成并与反应产物分离的条件下。然后从反应产物中回收环己基苯氢过氧化物晶体。

38. 发明申请

US20140148620A1 Process for Producing Phenol 有权
标题翻译：生产苯酚的方法
公开(公告)号：US20140148620A1
公开(公告)日：2014-05-29
申请号：US13822033
申请日：2011-08-25
申请人： Teng Xu , George Harry Gamble , Jihad Mohammed Dakka , Lorenzo Cophard DeCaul
发明人： Teng Xu , George Harry Gamble , Jihad Mohammed Dakka , Lorenzo Cophard DeCaul
IPC分类号： C07C37/07
CPC分类号： C07C37/07 , B01J23/38 , B01J23/40 , B01J23/58 , B01J35/023 , B01J37/0201 , C07C2/74 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2601/14 , Y02P20/52 , C07C39/04 , C07C49/403 , C07C409/14 , C07C13/28
摘要： In a process for the dehydrogenation of cyclohexanone to produce phenol, cyclohexanone is contacted in a reaction zone under dehydrogenation conditions with a dehydrogenation catalyst comprising (i) a support comprising silica; and (ii) a dehydrogenation component comprising at least one metal selected from Group 10 of Periodic Table of Elements. Contact of the dehydrogenation catalyst with the cyclohexanone is then terminated and the dehydrogenation catalyst is contacted with an inert gas and/or hydrogen at a temperature of at least 300° C. Contact of the dehydrogenation catalyst with additional cyclohexanone is subsequently reestablished.
摘要翻译：在环己酮脱氢生产苯酚的方法中，环己酮在脱氢条件下在反应区与脱氢催化剂接触，脱氢催化剂包括（i）包含二氧化硅的载体; 和（ii）包含选自元素周期表第10族的至少一种金属的脱氢组分。然后终止脱氢催化剂与环己酮的接触，脱氢催化剂在至少300℃的温度下与惰性气体和/或氢气接触。随后重新建立脱氢催化剂与另外的环己酮的接触。

39. 发明授权

US08604114B2 Aromatic acylation with cyclic anhydride for plasticizer production 有权
标题翻译：用环状酸酐进行芳香族酰化，用于增塑剂生产
公开(公告)号：US08604114B2
公开(公告)日：2013-12-10
申请号：US12840715
申请日：2010-07-21
申请人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smirnova , Jörg Friedrich Wilhelm Weber , Stephen Zushma
发明人： Jihad Mohammed Dakka , Edmund John Mozeleski , Lisa Saunders Baugh , Karla Schall Colle , Allen David Godwin , Diana S. Smirnova , Jörg Friedrich Wilhelm Weber , Stephen Zushma
IPC分类号： C08G73/10 , C08K5/00 , C07C69/76
CPC分类号： C08K5/12 , C07C51/31 , C07C67/08 , C07C67/31 , C07C69/73 , C07C69/732 , C07C69/738 , C07C2602/10 , C08K5/10 , C07C59/84 , C07C59/86
摘要： Provided is a process for making non-phthalate plasticizers, by acylating an aromatic compound with a succinic anhydride to form a keto-acid, and then esterifying the keto-acid with C4-C13 OXO-alcohols to form a plasticizer compound. The aromatic rings of the aromatic compound may also be optionally hydrogenated.
摘要翻译：提供了制备非邻苯二甲酸酯增塑剂的方法，通过用琥珀酸酐酰化芳族化合物以形成酮酸，然后用C4-C13OXO-醇酯化酮酸以形成增塑剂化合物。芳族化合物的芳环也可以任选氢化。

40. 发明授权

US08309780B2 Process for making olefin oligomers and alkyl benzenes in the presence of mixed metal oxide catalysts 有权
标题翻译：在混合金属氧化物催化剂存在下制备烯烃低聚物和烷基苯的方法
公开(公告)号：US08309780B2
公开(公告)日：2012-11-13
申请号：US12005027
申请日：2007-12-21
申请人： Jihad Mohammed Dakka , Jeffrey T. Elks , James C. Vartuli
发明人： Jihad Mohammed Dakka , Jeffrey T. Elks , James C. Vartuli
IPC分类号： C07C2/10 , C07C2/66
CPC分类号： C07C2/10 , B01J23/002 , B01J23/10 , B01J23/30 , B01J23/888 , B01J27/16 , B01J27/1804 , B01J27/1853 , B01J27/188 , B01J37/03 , B01J2523/00 , C07C2/66 , C07C2521/06 , C07C2523/10 , C07C2523/30 , C07C2523/745 , C07C2529/48 , B01J2523/48 , B01J2523/69 , B01J2523/842 , B01J2523/3712 , B01J2523/31 , B01J2523/51
摘要： Provided is a process for oligomerizing n-olefins. The process has the step of reacting (oligomerizing) an amount of one or more n-olefins in the presence of a catalytically effective amount of a two or more metal oxides at a temperature effective to effect oligomerization. The two or more metal oxides are represented by the formula MOn/M′On′. M and M′, are, independently, selected from the group consisting of Al, Ce, Fe, P, W, Zr, and combinations thereof. M and M′ are different metals or combinations of metals. “n” and “n′” are positive numbers and vary stoichiometrically depending on the valency of M and M′, respectively. Provided is also a process for alkylation of an alkylatable aromatic compound. The process has the step of contacting an amount of one or more n-olefins with an amount of aromatic compound in the presence of a catalytically effective amount of the two or more metal oxides at a temperature effective to effect alkylation of the aromatic compound.
摘要翻译：提供了一种使正烯烃低聚的方法。该方法在有效地进行低聚反应的温度下，在催化有效量的两种或更多种金属氧化物的存在下，使一定量的一种或多种正构烯烃反应（低聚）。两种或更多种金属氧化物由式MOn / M'On'表示。 M和M'独立地选自Al，Ce，Fe，P，W，Zr及其组合。 M和M'是不同的金属或金属的组合。 n和n'分别为正数，并且化学计量学上取决于M和M'的化合价。还提供了可烷基化芳族化合物的烷基化方法。该方法具有在有效量的芳族化合物烷基化的温度下，在催化有效量的两种或更多种金属氧化物的存在下，使一定量的一种或多种正构烯烃与一定量芳族化合物接触的步骤。

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