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31. 发明申请

US20050009986A1 New 3,4-alkylenedioxy-thiophene copolymers 有权
标题翻译：新的3,4-亚烷基二氧基 - 噻吩共聚物
公开(公告)号：US20050009986A1
公开(公告)日：2005-01-13
申请号：US10844551
申请日：2004-05-12
申请人： Bert Groenendaal , Frank Louwet
发明人： Bert Groenendaal , Frank Louwet
IPC分类号： C08G61/12 , C09D165/00 , C08F20/58
CPC分类号： C08G61/126 , C09D165/00 , H01G11/48 , H01G11/56 , Y02E60/13
摘要： An aqueous dispersion of a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion; a preparation process therefor; its use for coating; a printing ink containing the aqueous dispersion; an electro-conductive layer containing a copolymer of at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof; and an antistatic layer containing a copolymer of at least one 3,4-alkylenedioxy-thiophene compound with a solubility in water at 25° C. of less than 2.2 g/L with at least one 3,4-alkylenedioxythiophene compound with a solubility in water at 25° C. of at least 2.2 g/L and a polyanion derived from an aqueous dispersion thereof.
摘要翻译：至少一种3,4-二亚烷基二氧噻吩化合物在25℃下在水中的溶解度小于2.2g / L的共聚物的水分散体与至少一种在水中溶解度为25的3,4-亚烷基二氧噻吩化合物至少2.2g / L的聚阴离子; 其准备过程; 其用于涂料; 含有水分散体的印刷油墨; 含有至少一种在25℃下在水中的溶解度低于2.2g / L的3,4-亚烷基二氧噻吩化合物与至少一种在水中溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的导电层在25℃下为至少2.2g / L，衍生自其水分散体的聚阴离子; 以及含有至少一种在25℃下在水中溶解度小于2.2g / L的3,4-亚烷基二氧基 - 噻吩化合物与至少一种具有溶解度的3,4-亚烷基二氧噻吩化合物的共聚物的抗静电层 25℃下的水至少为2.2g / L，衍生自其水分散体的聚阴离子。

32. 发明授权

US06632472B2 Redispersable latex comprising a polythiophene 有权
标题翻译：包含聚噻吩的可再分散胶乳
公开(公告)号：US06632472B2
公开(公告)日：2003-10-14
申请号：US09892011
申请日：2001-06-26
申请人： Frank Louwet , Raf Samijn
发明人： Frank Louwet , Raf Samijn
IPC分类号： C09D1102
CPC分类号： C09D11/52 , C08G61/126 , C09D11/106 , C09D165/00
摘要： A redispersible or soluble product, optionally having a solids content higher than 10% by weight, obtainable by freeze drying an aqueous dispersion of a latex comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene; a printing ink comprising the above product; a coating dispersion or solution comprising the above product; and a method for making an antistatic or electroconductive layer comprising the steps of redispersing or diluting the above product by adding water or an organic solvent so as to obtain a dispersion or solution, optionally adding other ingredients to the coating solution or dispersion and applying the dispersion or solution to an object.
摘要翻译：通过将包含聚阴离子和取代或未取代的噻吩的聚合物或共聚物的胶乳的水分散体冷冻干燥，可再分散或可溶性产品，任选地具有高于10重量％的固体含量; 包含上述产品的印刷油墨; 包含上述产品的涂料分散体或溶液; 以及制造抗静电或导电层的方法，包括以下步骤：通过加入水或有机溶剂对上述产物进行再分散或稀释，以获得分散体或溶液，任选地向涂布溶液或分散体中加入其它成分并施加该分散体或解决方案。

33. 发明授权

US06427595B1 Heat-sensitive imaging element for making lithographic printing plates comprising polymer particles with a specific particle size 失效
标题翻译：用于制造平版印刷版的热敏成像元件，其包含特定粒度的聚合物颗粒
公开(公告)号：US06427595B1
公开(公告)日：2002-08-06
申请号：US08989469
申请日：1997-12-12
申请人： Marc Van Damme , Joan Vermeersch , Frank Louwet , Raf Samijn
发明人： Marc Van Damme , Joan Vermeersch , Frank Louwet , Raf Samijn
IPC分类号： B41N114
CPC分类号： B41C1/1025 , B41C2201/04 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/24 , B41C2210/262
摘要： According to the present invention there is provided a heat-sensitive imaging element for making lithographic printing plates. The heat-sensitive imaging element comprises an image-forming layer comprising hydrophobic thermoplastic polymer particles having a specific particle size and polydispersity for obtaining printing plates with an improved sensitivity, excellent developability, high throughput and less scumming.
摘要翻译：根据本发明，提供了一种用于制造平版印刷版的热敏成像元件。热敏成像元件包括图像形成层，其包含具有特定粒度和多分散性的疏水性热塑性聚合物颗粒，用于获得具有改进的灵敏度，优异的显影性，高通量和较少浮渣的印刷版。

34. 发明授权

US5917003A Process for producing polymers of .alpha.,.omega.-unsaturated conjugated compounds, and high molecular weight conjugated polymers thus obtainable 失效
标题翻译：制备α，ω-不饱和共轭化合物的聚合物的方法和由此获得的高分子量共轭聚合物
公开(公告)号：US5917003A
公开(公告)日：1999-06-29
申请号：US304134
申请日：1994-09-12
申请人： Joanes Gelan , Dirk Vanderzande , Frank Louwet
发明人： Joanes Gelan , Dirk Vanderzande , Frank Louwet
IPC分类号： H05B33/20 , C08G61/00 , C08G61/02 , C09K11/06 , H01L51/50 , H05B33/12 , C08G69/08
CPC分类号： C08G61/02
摘要： A process for producing polymers of .alpha., .omega.-unsaturated conjugated compounds, which includes reacting a compound of the formula (I),B--A--C (I)whereinB denotes a sp.sup.3 -hybridized carbon atom carrying at least one hydrogen atom,A denotes a conjugated-.pi.-system or a --CH.dbd.CH--group, andC denotes a carbon atom carrying at least one leaving group,with a base in a solvent. On reaction of the base with the compound of the formula (I) a polymer is formed as a by-product essentially soluble in the solvent and a solid is formed as a by-product which is essentially insoluble in the solvent. According to the process, chemically and thermally stable, high molecular weight polymers of high purity and high regularity are obtained in good yield. If the products of the process carry groups that undergo elimination, forming double bonds, high quality electroluminescent materials can be prepared.
摘要翻译：一种制备α，ω-不饱和共轭化合物的聚合物的方法，其包括使式（I）的化合物，BAC（I），其中B表示携带至少一个氢原子的sp3-杂化的碳原子，A表示共轭 - π系或-CH = CH-基，C表示携带至少一个离去基团的碳原子，在溶剂中含有碱。在碱与式（I）化合物的反应中，形成聚合物作为基本上可溶于溶剂的副产物，并且固体形成为基本上不溶于溶剂的副产物。根据该方法，获得了高纯度和高规则性的化学和热稳定的高分子量聚合物。如果该方法的产物携带消除的组，形成双键，则可以制备高品质的电致发光材料。

35. 发明申请

US20080050534A1 UV-PHOTOPOLYMERIZABLE COMPOSITION FOR PRODUCING ORGANIC CONDUCTIVE LAYERS, PATTERNS OR PRINTS 有权
标题翻译：用于生产有机导电层，图案或印刷品的紫外光可聚合组合物
公开(公告)号：US20080050534A1
公开(公告)日：2008-02-28
申请号：US11836581
申请日：2007-08-09
申请人： Frank Louwet , Louis Bollens
发明人： Frank Louwet , Louis Bollens
IPC分类号： B05D3/06 , C08J3/28 , C09D11/10
CPC分类号： C09D165/00 , C09D5/24 , C09D11/101 , G03F7/027 , G03F7/093 , G03F7/16 , H01B1/127 , H01L51/0022 , H01L51/0036 , H01L51/0037 , H05K3/105
摘要： A composition comprising a polyanion and a polymer or copolymer of a substituted or unsubstituted thiophene as a solution or as a dispersion in a liquid medium and at least one compound with at least two vinyl groups, wherein said liquid medium comprises at least one non-aqueous solvent and has less than 30% by weight of water; and said composition comprises more than 0.1% by weight of the polymer or copolymer of a substituted or unsubstituted thiophene and is capable of UV-photopolymerization due to said composition comprising at least one vinyl-compound capable of initiating UV-photopolymerization and/or at least one UV-photoinitiator; an ink with the composition of the composition; and a process for producing a layer or pattern on an object with the composition.
摘要翻译：一种组合物，其包含聚阴离子和取代或未取代的噻吩作为溶液或作为液体介质中的分散体的聚合物或共聚物和至少一种具有至少两个乙烯基的化合物，其中所述液体介质包含至少一种非水性并且具有小于30重量％的水; 并且所述组合物包含大于0.1重量％的取代或未取代的噻吩的聚合物或共聚物，并且由于所述组合物包含至少一种能够引发UV-光聚合的乙烯基化合物和/或至少一种UV-光引发剂; 具有组合物组成的油墨; 以及用于在具有该组成的物体上产生层或图案的工艺。

36. 发明授权

US07122130B2 Composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and non-aqueous solvent 有权
公开(公告)号：US07122130B2
公开(公告)日：2006-10-17
申请号：US10894441
申请日：2004-07-19
申请人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
发明人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
IPC分类号： H01B1/12
CPC分类号： H01B1/128 , C08J3/09 , C08J2365/00 , C08L65/00 , C09D5/24 , C09D11/033 , C09D11/36 , C09D11/52 , C09D165/00 , Y10T428/2809
摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.

37. 发明授权

US07048874B2 Process for preparing an aqueous or non-aqueous solution or dispersion of a polythionphene or thiophene copolymer 有权
标题翻译：制备聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的方法
公开(公告)号：US07048874B2
公开(公告)日：2006-05-23
申请号：US10308567
申请日：2002-12-03
申请人： Frank Louwet , Bert Groenendaal
发明人： Frank Louwet , Bert Groenendaal
IPC分类号： H01B1/00 , C08G61/12 , C09D165/00
CPC分类号： C08G61/126 , C08G2261/122 , C08G2261/1424 , C08G2261/1426 , C08G2261/1452 , C08G2261/3223 , C08G2261/43 , C08G2261/51 , C08G2261/794 , C09D165/00 , H01G9/028 , H01G11/48 , Y02E60/13 , Y10T428/31533 , C08L25/18
摘要： A process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer, containing structural units according to formula (I): in which R1 and R2 independently of one another represent hydrogen or a C1-5-alkyl group or together form an optionally substituted C1-5-alkylene residue, comprising the step of: preparing the polythiophene or thiophene copolymer with an initiator in a reaction medium in the presence of polyanions under oxidizing or reducing conditions under an inert atmosphere such that when said initiator is added less than 3 mg of oxygen per litre of the reaction medium is present in the reaction medium; an aqueous or non-aqueous solution or dispersion prepared therewith; the use of an aqueous or non-aqueous dispersion or solution comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer for coating an object; a printable paste containing the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer; and an electroconductive or an antistatic layer prepared using an aqueous or non-aqueous solution or dispersion comprising the aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer.
摘要翻译：一种制备含有根据式（I）的结构单元的聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的方法：其中R 1和R 2 = >彼此独立地表示氢或C 1-5 - 烷基或一起形成任选取代的C 1-5 - 亚烷基残基，包括以下步骤：制备聚噻吩或噻吩共聚物与反应介质中的聚噻吩或噻吩共聚物在聚阴离子存在下，在惰性气氛下在氧化或还原条件下，使得每当该反应介质中加入小于3mg的氧气时，中; 用其制备的水性或非水溶液或分散体; 使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水分散体或溶液来涂覆物体; 含有聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的可印刷浆料; 以及使用包含聚噻吩或噻吩共聚物的水溶液或非水溶液或分散体的水性或非水溶液或分散体制备的导电或抗静电层。

38. 发明授权

US06887556B2 Material for making a conductive pattern 失效
标题翻译：制作导电图案的材料
公开(公告)号：US06887556B2
公开(公告)日：2005-05-03
申请号：US10316274
申请日：2002-12-11
申请人： Johan Lamotte , Frank Louwet , Tom Cloots , Huub Van Aert
发明人： Johan Lamotte , Frank Louwet , Tom Cloots , Huub Van Aert
IPC分类号： H01B1/12 , H01L51/00 , H01L51/30 , H01L51/40 , H05K3/02 , H05K3/10 , D06N7/04
CPC分类号： H05K3/105 , H01B1/127 , H01L51/0021 , H01L51/0036 , H05K3/02 , Y10T428/24355 , Y10T428/24802 , Y10T428/269 , Y10T428/2933 , Y10T428/2971 , Y10T428/31855
摘要： A material for making a conductive pattern, the material comprising a support and a heat-differentiable element, the heat-differentiable element comprising an outermost layer containing a polyanion and an intrinsically conductive polymer and optionally a second layer contiguous with the outermost layer, characterized in that the outermost layer and/or the optional second layer contains hydrophobic thermocoagulable latex particles in a weight ratio range with respect to the intrinsically conductive polymer in the range of 20:1 to 1:5, the hydrophobic thermocoagulable latex particles are capable upon heating of increasing the conductivity of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and/or changing the removability of the heated parts of the outermost layer relative to the unheated parts of the outermost layer and the heat-differentiable element does not comprise a di- or polyhydroxy organic compound or an aprotic compound with a dielectric constant, ∈, ≧15; a method of making a conductive pattern on a support therewith; and a use of the material for making a conductive pattern in making an electronic circuit in the production of an electric or semiconductor device such as a printed circuit board, an integrated circuit, a display or touch screen, an electroluminescent device or a photovoltaic cell.
摘要翻译：一种用于制造导电图案的材料，该材料包括支撑体和可热分解的元件，该热可分离元件包括含有聚阴离子和本征导电聚合物的最外层，以及任选地与最外层邻接的第二层，其特征在于最外层和/或任选的第二层含有相对于本征导电聚合物的重量比范围为20:1至1:5的疏水性热凝胶乳胶颗粒，疏水性热凝胶乳颗粒能够加热增加最外层的加热部分相对于最外层的未加热部分的导电性和/或改变最外层的加热部分相对于最外层和可热分散元件的未加热部分的可去除性不包含二 - 或多羟基有机化合物或具有夹层的非质子化合物三次常数∈，> = 15; 在其上的支撑件上形成导电图案的方法; 以及在制造诸如印刷电路板，集成电路，显示器或触摸屏，电致发光器件或光伏电池的电气或半导体器件中的电子电路中制造导电图案的材料的用途。

39. 发明申请

US20050042556A1 Process for preparing a substantially transparent conductive layer configuration 失效
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US20050042556A1
公开(公告)日：2005-02-24
申请号：US10645160
申请日：2003-08-21
申请人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
发明人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
IPC分类号： H01B1/12 , H01B1/22 , H01L51/00 , H01L51/30 , H01L51/52 , H05K3/10 , G03C1/46
CPC分类号： H05K3/106 , H01B1/127 , H01B1/22 , H01L51/0021 , H01L51/0037 , H01L51/445 , H01L51/5203 , H05K2201/0329 , Y02E10/549
摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.
摘要翻译：一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述固有导电聚合物任选含有由式（I）表示的结构单元：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基或一起表示任选取代的C 1-4亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

40. 发明申请

US20050040372A1 Composition containing a polymer or copolymer of a 3,4-dialkoxythiophene and non-aqueous solvent 有权
标题翻译：含有3,4-二烷氧基噻吩和非水溶剂的聚合物或共聚物的组合物
公开(公告)号：US20050040372A1
公开(公告)日：2005-02-24
申请号：US10894441
申请日：2004-07-19
申请人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
发明人： Jean-Piere Tahon , Roger Van den Bogaert , Bert Groenendaal , Frank Louwet
IPC分类号： B05D5/00 , H01B1/00
CPC分类号： H01B1/128 , C08J3/09 , C08J2365/00 , C08L65/00 , C09D5/24 , C09D11/033 , C09D11/36 , C09D11/52 , C09D165/00 , Y10T428/2809
摘要： A method for preparing a composition containing between 0.08 and 3.0% by weight of polymer or copolymer of a 3,4-dialkoxythiophene in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, a polyanion and at least one non-aqueous solvent from a dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion in water which is prepared in the substantial absence of oxygen, comprising in the following order the steps of: i) mixing at least one of the non-aqueous solvents with the aqueous dispersion of the polymer or copolymer of (3,4-dialkoxythiophene) and the polyanion; and ii) evaporating water from the mixture prepared in step i) until the content of water therein is reduced by at least 65% by weight; a printing ink, printing paste or coating composition, capable of yielding layers with enhanced conductivity at a given transparency, prepared according to the above-described method; a coating process with the coating composition thereby producing a layer with enhanced conductivity at a given transparency; and a printing process with the printing ink or paste thereby producing a layer with enhanced conductivity at a given transparency.
摘要翻译：一种制备含有0.08至3.0重量％的3,4-二烷氧基噻吩的聚合物或共聚物的组合物的方法，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧 - 亚烷基 - 氧桥，聚阴离子和至少一种非水溶剂，其由（3,4-二烷氧基噻吩）的聚合物或共聚物和聚阴离子在水中的分散体组成，其在基本上不存在氧的情况下制备，包括以下步骤： i）将至少一种非水溶剂与（3,4-二烷氧基噻吩）和聚阴离子的聚合物或共聚物的水分散体混合; 和ii）从步骤i）中制备的混合物蒸发水，直到其中的水含量降低至少65重量％; 印刷油墨，印刷浆料或涂料组合物，其能够产生根据上述方法制备的在给定透明度下具有增强的导电性的层; 所述涂料组合物由此在给定的透明度下产生具有增强的导电性的层; 以及具有印刷油墨或糊料的印刷方法，从而在给定的透明度下产生具有增强的导电性的层。

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