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1. 发明授权

US06333145B1 Method for preparing a conductive polythiophene layer at low temperature 有权
标题翻译：在低温下制备导电聚噻吩层的方法
公开(公告)号：US06333145B1
公开(公告)日：2001-12-25
申请号：US09433971
申请日：1999-11-04
申请人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
发明人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
IPC分类号： G03C185
CPC分类号： H01B1/127 , H01G9/028 , H01G11/48 , H01G11/56 , H01L51/5203 , Y02E60/13
摘要： A method for producing a polymeric conductive layer on an object comprising the steps of: providing an aqueous composition containing a polythiophene, a polyanion compound and an aprotic compound with a dielectric constant, &egr;, ≧15, applying said composition to said object forming a layer and drying said layer to form a conductive polymeric layer on said object, characterised in that during said production said object and said layer are kept at a temperature below 100° C. and said conductive polymeric layer has a resistivity of at most 2 k&OHgr;/square.
摘要翻译：一种用于在物体上制备聚合物导电层的方法，包括以下步骤：提供含有聚噻吩，聚阴离子化合物和介质常数εi= 15的非质子化合物的水性组合物，将所述组合物施加到所述物体上形成层和干燥所述层以在所述物体上形成导电聚合物层，其特征在于，在所述生产期间，所述物体和所述层保持在低于100℃的温度，并且所述导电聚合物层具有至多2kOMEGA /平方的电阻率。

2. 发明申请

US20050042556A1 Process for preparing a substantially transparent conductive layer configuration 失效
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US20050042556A1
公开(公告)日：2005-02-24
申请号：US10645160
申请日：2003-08-21
申请人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
发明人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
IPC分类号： H01B1/12 , H01B1/22 , H01L51/00 , H01L51/30 , H01L51/52 , H05K3/10 , G03C1/46
CPC分类号： H05K3/106 , H01B1/127 , H01B1/22 , H01L51/0021 , H01L51/0037 , H01L51/445 , H01L51/5203 , H05K2201/0329 , Y02E10/549
摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.
摘要翻译：一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述固有导电聚合物任选含有由式（I）表示的结构单元：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基或一起表示任选取代的C 1-4亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

3. 发明授权

US06197418B1 Electroconductive glass laminate 有权
标题翻译：导电玻璃层压板
公开(公告)号：US06197418B1
公开(公告)日：2001-03-06
申请号：US09458829
申请日：1999-12-13
申请人： Tom Cloots , Frank Louwet , Hieronymus Andriessen , Bart Verlinden , Jean-Pierre Tahon , Leo Vermeulen , Luc Leenders , Rudi Goedeweeck
发明人： Tom Cloots , Frank Louwet , Hieronymus Andriessen , Bart Verlinden , Jean-Pierre Tahon , Leo Vermeulen , Luc Leenders , Rudi Goedeweeck
IPC分类号： B32B1710
CPC分类号： H05B33/28 , H01L51/5203 , Y10T428/26 , Y10T428/265 , Y10T428/266 , Y10T428/31507 , Y10T428/31616 , Y10T428/31627 , Y10T428/3163 , Y10T428/31645 , Y10T428/31649
摘要： A material is disclosed which comprises a substrate and an organic electroconductive layer provided on said substrate, characterised in that the substrate is a laminate comprising a glass layer and a support. The glass layer is preferably a flexible glass layer having a thickness from 10 to 500 &mgr;m. The material can be used as an electrode in electric or semiconductor devices thereby providing an improved lifetime, e.g. displays, photovoltaic cells or light-emitting diodes.
摘要翻译：公开了一种材料，其包括基板和设置在所述基板上的有机导电层，其特征在于，所述基板是包括玻璃层和支撑体的层压体。玻璃层优选为厚度为10〜500μm的柔性玻璃层。该材料可以用作电或半导体器件中的电极，从而提供改善的寿命，例如，显示器，光伏电池或发光二极管。

4. 发明授权

US07026079B2 Process for preparing a substantially transparent conductive layer configuration 失效
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US07026079B2
公开(公告)日：2006-04-11
申请号：US10645160
申请日：2003-08-21
申请人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
发明人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
IPC分类号： G03C1/89 , G03C5/29 , G03C8/28 , G03C8/52 , G03C8/32
CPC分类号： H05K3/106 , H01B1/127 , H01B1/22 , H01L51/0021 , H01L51/0037 , H01L51/445 , H01L51/5203 , H05K2201/0329 , Y02E10/549
摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.
摘要翻译：一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述第一层含有任选含有由式（I）表示的结构单元的固有导电聚合物：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基，或者一起表示任选取代的C 1 -C 4烷基， 1-4个亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

5. 发明授权

US07147936B2 Layer configuration with improved stability to sunlight exposure 有权
标题翻译：层状结构具有改善的阳光照射的稳定性
公开(公告)号：US07147936B2
公开(公告)日：2006-12-12
申请号：US10642933
申请日：2003-08-18
申请人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
发明人： Frank Louwet , Geert Van Dyck , Johan Loccufier , Bert Groenendaal , Hieronymus Andriessen
IPC分类号： C07D211/021 , H01L51/50
CPC分类号： C08G61/126 , C08L25/08 , C08L2666/06 , C09J165/00 , H01G11/48 , H01G11/56 , Y02E60/13 , Y10S428/917
摘要： A layer configuration on a support, the layer configuration comprising a layer containing a polymer containing optionally substituted 3,4-alkylenedioxythiophene structural units, in which the two alkoxy groups may be the same or different or together represent an optionally substituted oxy-alkylene-oxy bridge, and a compound selected from the group consisting of polyphosphoric acids, polyphosphoric acid salts, thia-alkanedicarboxylic acids, cyclohexadiene compounds and polyhydroxy-compounds selected from the group consisting of tetronic acid derivatives; ortho-dihydroxybenzene compounds with at least one sulpho group, compounds according to formula (I): HO—CH2—CH(OH)—(CH2)m—S—CH2—C(R1)(R2)—CH2—S—(CH2)n—CH(OH)—CH2—OH (I) wherein R1 and R2 are independently H, —OH or alkyl, and n and m are independently 1, 2 or 3; compounds according to formula (II): HO—(CH2)p—S—CH2—S—(CH2)q—OH (II) wherein p and q are independently 2, 3 or 4; compounds hydrolyzable to tetronic acid derivatives; compounds hydrolyzable to compounds according to formula (I); and sulpho-substituted 2-thia-alkyl-benzimidazole compounds.
摘要翻译：在支撑体上的层构型，该层构型包括含有含有任选取代的3,4-亚烷基二氧噻吩结构单元的聚合物的层，其中两个烷氧基可以相同或不同，或一起代表任选取代的氧基 - 桥，以及选自多磷酸，多磷酸盐，硫杂烷二羧酸，环己二烯化合物和选自由以下组成的组的多羟基化合物的化合物：四氢酸衍生物; 具有至少一个磺酸基的邻二羟基苯化合物，根据式（I）的化合物：<？in-line-formula description =“In-line formula”end =“lead”？> HO-CH 2 -CH（OH） - （CH 2 CH 2）m -S- CH 2 -C（R 1）（R 2） - CH 2 -S-（CH 2）n - （CH 2）n - （CH 2） -CH 2 -O-OH（I）<β在线公式描述=“在线式”末端=“尾”→其中R 1和R 2， SUP> 2独立地是H，-OH或烷基，n和m独立地是1,2或3; 根据式（II）的化合物：<？in-line-formula description =“In-line Formulas”end =“lead”？> HO-（CH 2） > -S-CH 2 -S-（CH 2）2 -O-OH（II）<β在线配方说明书=“ 其中p和q独立地为2,3或4; 可水解成四氢酸衍生物的化合物; 可水解成根据式（I）的化合物的化合物的化合物; 和磺基取代的2-硫代 - 烷基 - 苯并咪唑化合物。

6. 发明授权

US06927298B2 3,4-alkylenedioxythiophenedioxide compounds and polymers comprising monomeric units thereof 失效
标题翻译： 3,4-亚烷基二氧基噻吩二氧化物化合物和包含其单体单元的聚合物
公开(公告)号：US06927298B2
公开(公告)日：2005-08-09
申请号：US10649761
申请日：2003-08-27
申请人： Bert Groenendaal , Frank Louwet , Hieronymus Andriessen
发明人： Bert Groenendaal , Frank Louwet , Hieronymus Andriessen
IPC分类号： C07D333/36 , C07D333/64 , C07D495/02 , C07D495/04 , C08G61/12 , C08G65/34 , C08G75/00 , C08G75/32
CPC分类号： C07D495/04 , C08G61/126 , H01G11/48 , Y02E60/13
摘要： A 3,4-alkylenedioxythiophenedioxide compound represented by formula (I): in which: A represents a C1-5-alkylene bridge; R represents an optionally substituted C1-24-alkyl, C3-18-cycloalkyl, C1-18-alkoxy or polyethylene oxide group (optionally with at least one substituent selected from the group consisting of an alcohol, amide, ether, ester or sulphonate group) or an optionally substituted aryl group; a polymer comprising monomeric units represented by formula (I); an aqueous dispersion of a polymer comprising monomeric units corresponding to at least one compound according to formula (I) and a polyanion; a chemical polymerization process for preparing the aqueous dispersion comprising the steps of: (i) providing a solution of a polyanion; (ii) adding a compound according to formula (I) and a thiophene or pyrrole compound to the solution provided in step (i); and (iii) adding an oxidizing or reducing system to the mixture provided in step (ii); a printable paste containing the aqueous dispersion; an electroconductive layer containing the polymer; the use of the electroconductive layer in a light emitting diode; an antistatic layer containing the polymer; and an electroconductive pattern and a process for preparing the electroconductive pattern.
摘要翻译：由式（I）表示的3,4-亚烷基二氧基噻吩二氧化物化合物：其中：A表示C 1-5烷基亚烷基桥; R代表任选取代的C 1-14 - 烷基，C 3-18 - 环烷基，C 1-18 - 烷氧基或聚环氧乙烷基（任选地具有至少一个选自醇，酰胺，醚，酯或磺酸酯基的取代基）或任选取代的芳基; 包含由式（I）表示的单体单元的聚合物; 包含对应于至少一种根据式（I）的化合物和聚阴离子的单体单元的聚合物的水分散体; 用于制备水分散体的化学聚合方法，包括以下步骤：（i）提供聚阴离子的溶液; （ii）将式（I）化合物和噻吩或吡咯化合物加入到步骤（i）中提供的溶液中; 和（iii）向步骤（ii）中提供的混合物中加入氧化或还原体系; 含有水分散体的可印刷浆料; 含有聚合物的导电层; 在发光二极管中使用导电层; 含有聚合物的抗静电层; 导电图案和制备导电图案的方法。

7. 发明授权

US06811885B1 Acid stable aqueous dispersion of metal particles and applications 失效
标题翻译：酸性稳定的金属颗粒水分散体和应用
公开(公告)号：US06811885B1
公开(公告)日：2004-11-02
申请号：US09584489
申请日：2000-06-01
申请人： Hieronymus Andriessen , Frank Louwet
发明人： Hieronymus Andriessen , Frank Louwet
IPC分类号： B32B1510
CPC分类号： C23C26/00 , C23C18/31 , C23C30/00 , G11B5/7025 , G11B5/70605 , G11B5/714 , G11B5/72 , H01F1/0027 , H01F1/442 , H01F41/16 , Y10T428/31681 , Y10T428/31703 , Y10T428/31971
摘要： Aqueous coating compositions containing acid stable metal dispersions, prepared by chemical reduction in aqueous medium, are obtained by using a N-quaternized cellulose derivative as binder. They can be used for the preparation of heat mode recording layers, magnetic layers and conductive layers.
摘要翻译：通过使用N-季铵化纤维素衍生物作为粘合剂，得到含有酸稳定金属分散体的含水涂料组合物，其通过水性介质中的化学还原制备。它们可用于制备热模式记录层，磁性层和导电层。

8. 发明申请

US20100221662A1 HEAT-SENSITIVE IMAGING ELEMENT 有权
标题翻译：热感成像元件
公开(公告)号：US20100221662A1
公开(公告)日：2010-09-02
申请号：US11993105
申请日：2006-06-19
申请人： Paul Callant , Hieronymus Andriessen , Alex Williamson , Christel Geukens , Jos Louwet
发明人： Paul Callant , Hieronymus Andriessen , Alex Williamson , Christel Geukens , Jos Louwet
IPC分类号： G03F7/004 , C07D209/04 , G03F7/20
CPC分类号： B41C1/1008 , B41C1/10 , B41C1/1025 , B41C1/1041 , B41C2210/04 , B41C2210/06 , B41C2210/08 , B41C2210/22 , B41C2210/24 , B41M5/465 , C09B23/0066 , C09B23/0091 , C09B23/083 , C09B23/086 , C09B23/10
摘要： A heat-sensitive imaging element includes an IR dye having a structure according to Formula I, wherein at least one of the Rd groups is a group which is transformed by a chemical reaction, induced by exposure to IR-radiation or heat, into a group which is a stronger electron-donor than the Rd; or wherein at least one of the Ra groups is a group which is transformed by a chemical reaction, induced by exposure to IR-radiation or heat, into a group which is a stronger electron-acceptor than the Ra. The imaging element is able to form a visible print-out image with a high contrast directly after image-wise exposure by IR-radiation or heating.
摘要翻译：热敏成像元件包括具有式I结构的IR染料，其中至少一个Rd基团是通过暴露于IR辐射或加热诱导的化学反应转化成基团的基团其比Rd更强的电子给体; 或其中Ra基团中的至少一个是通过暴露于IR辐射或加热诱导的化学反应转化成为比Ra更强的电子受体的基团。成像元件能够通过IR辐射或加热在直接成像曝光之后直接形成具有高对比度的可视打印图像。

9. 发明申请

US20100021846A1 NEGATIVE WORKING, HEAT-SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR 有权
标题翻译：负面工作，感应式光刻印刷机前置
公开(公告)号：US20100021846A1
公开(公告)日：2010-01-28
申请号：US12439585
申请日：2007-10-10
申请人： Paul Callant , Hieronymus Andriessen , Alexander Williamson
发明人： Paul Callant , Hieronymus Andriessen , Alexander Williamson
IPC分类号： G03F7/20 , G03F7/004
CPC分类号： B41M5/366 , B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/06 , B41C2210/22 , B41C2210/24
摘要： A heat-sensitive negative-working lithographic printing plate precursor comprising: a support having a hydrophilic surface or which is provided with a hydrophilic layer; and an image-recording layer comprising hydrophobic thermoplastic polymer particles, an infrared light absorbing dye and a dye; wherein said dye has a specified structure and a most bathochromic light absorption peak between 451 nm and 750 nm.
摘要翻译：一种热敏负性平版印刷版原版，其包含：具有亲水表面的或具有亲水层的载体; 和包含疏水性热塑性聚合物颗粒，红外光吸收染料和染料的图像记录层; 其中所述染料具有特定的结构和在451nm与750nm之间的最红细光吸收峰。

10. 发明申请

US20090258314A1 NEGATIVE WORKING, HEAT SENSITIVE LITHOGRAPHIC PRINTING PLATE PRECURSOR 有权
标题翻译：负极工作，感光感光印刷机
公开(公告)号：US20090258314A1
公开(公告)日：2009-10-15
申请号：US12300805
申请日：2007-05-22
申请人： Hieronymus Andriessen , Steven Lezy , Hubertus Van Aert , Joan Vermeersch
发明人： Hieronymus Andriessen , Steven Lezy , Hubertus Van Aert , Joan Vermeersch
IPC分类号： G03F7/004 , G03F7/20 , B41F1/18
CPC分类号： B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , Y10S430/145
摘要： A heat-sensitive negative-working lithographic printing plate precursor include a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye; wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm; the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.80 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fraction; and—the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60-%.
摘要翻译：热敏负性平版印刷版原版包括具有亲水性表面的或具有亲水层的涂层和设置在其上的涂层的涂层，该涂层包括图像记录层，该图像记录层包括疏水性热塑性聚合物颗粒，粘合剂，和红外吸收染料; 其中所述疏水热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40nm; 通过流体力学分数测量，不考虑任选的抗衡离子的IR染料的量大于0.80mg / m 2热塑性聚合物颗粒的总表面; 和 - 相对于成像层的成分的总重量，疏水性热塑性聚合物颗粒的量为至少60％。

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