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    • 31. 发明专利
    • Hydrogen production plant
    • 氢生产厂
    • JP2004189542A
    • 2004-07-08
    • JP2002359386
    • 2002-12-11
    • Babcock Hitachi Kkバブコック日立株式会社
    • MIYATA TERUFUMIOKANO TETSUROYATABE HIROSHIIKEDA SATOSHIKAKO HIROYUKIIMADA NORIYUKIIWASAKI YUKINORI
    • C01B3/38C10K3/04H01M8/06
    • Y02E60/50
    • PROBLEM TO BE SOLVED: To provide a hydrogen production plant which can correspond to a change in loads and a change in CO concentration, and can reduce CO in reformed gas by a simple constitution.
      SOLUTION: The hydrogen production plant is provided with a controller 27 where the flow rate F of air added to the inflow side of a CO oxidizer 23 is controlled by an air feeder 25, and, at the time when the temperature of reformed gas is equal to or higher than a set temperature TH, the flow rate F of oxygen or oxygen-containing gas to be added is reduced, and, at the time when it is lower than a set temperature TL, the flow rate F is increased. Thus, the amount of CO as a heat generation source increases or reduces in accordance with a change in the amount of the reformed gas caused by a change in loads and a change in the concentration of CO, and, even if the temperature of the reformed gas is made off from the set temperature, the amount of oxygen is increased or reduced in accordance with the same and heat generation value can be controlled, so that the temperature T of the reformed gas can be controlled to the range from the set temperature TL to TH.
      COPYRIGHT: (C)2004,JPO&NCIPI
    • 要解决的问题:提供一种可以对应于负载变化和CO浓度变化的氢气生产设备,并且可以通过简单的结构来减少重整气体中的CO。 解决方案:氢气生产设备设置有控制器27,其中添加到CO氧化器23的流入侧的空气的流量F由空气供给器25控制,并且在重整的温度 气体等于或高于设定温度TH,则要添加的氧气或含氧气体的流量F降低,并且在低于设定温度TL时,流量F增加 。 因此,作为发热源的CO的量根据由负载变化和CO浓度的变化引起的重整气体的量的变化而增加或减少,并且即使重整的 从设定温度排出气体,根据相同的量增加或减少氧气的量,并且可以控制发热量,使得可以将重整气体的温度T控制在从设定温度TL 到TH。 版权所有(C)2004,JPO&NCIPI
    • 33. 发明专利
    • Wastewater treatment device and method
    • 废水处理装置及方法
    • JP2013208542A
    • 2013-10-10
    • JP2012080060
    • 2012-03-30
    • Babcock Hitachi Kkバブコック日立株式会社
    • MITSUI YOSHIAKIIMADA NORIYUKIOMINE SHIGETOKATAGAWA ATSUSHI
    • C02F1/28B01D53/50B01D53/64B01D53/77B01J20/20B01J20/26B01J45/00C02F1/42
    • PROBLEM TO BE SOLVED: To provide an inexpensive wastewater treatment device of a wet type flue gas desulfurization system, which prevents re-release of mercury contained in an exhaust gas in desulfurization thereof and performs the treatment for reducing the mercury concentration in a gypsum generated when desulfurizing in an absorption tower, and to provide a wastewater treatment method using the device.SOLUTION: A wastewater treatment device of a flue gas desulfurization system is provided with: a sulfur oxide-absorbing part 6 which introduces an exhaust gas including sulfur oxide from a combustion apparatus with a boiler and has a spray nozzle for spraying a lime stone-containing absorbent liquid; an absorbent liquid-storing part 11 provided below the absorbing part; a filter part 68 having a smaller hole size than the grain size of a mercury absorbent at a position dividing the inside of the liquid-storing part 11 vertically in two; a mercury absorbent-supplying part 60 provided above the level of the absorbent liquid in the liquid-storing part 11 on the upper portion of the filter part 68; and a first absorbent liquid extraction part for extracting the absorbent liquid in the liquid-storing part 11 to the lower part of the filter part 68 to supply the liquid to an absorbent liquid circulation path.
    • 要解决的问题:为了提供一种廉价的湿法烟气脱硫系统的废水处理装置,其防止在其脱硫中排出的废气中的汞的再释放,并且进行用于降低在当生成的石膏时产生的石膏中的汞浓度的处理 在吸收塔中脱硫,并提供使用该装置的废水处理方法。解决方案:烟道气脱硫系统的废水处理装置具有:硫氧化物吸收部6,其从包含硫的氧化物引入包含硫氧化物的废气 具有锅炉的燃烧装置,并具有用于喷射含石灰的吸收剂液体的喷嘴; 设置在吸收部下方的吸收性液体储存部11; 过滤器部分68具有比在两个液体储存部分11的内部垂直分隔的位置处具有比水银吸收剂的粒度小的孔尺寸; 设置在过滤器部68的上部的液体储存部11中的吸收剂液面上方的吸水剂供给部60; 以及第一吸收液体提取部分,用于将液体储存部分11中的吸收液体提取到过滤部分68的下部,以将液体供应到吸收液体循环路径。
    • 35. 发明专利
    • Exhaust gas treatment apparatus and exhaust gas treatment method
    • 排气处理设备和排气处理方法
    • JP2013078742A
    • 2013-05-02
    • JP2011220861
    • 2011-10-05
    • Babcock Hitachi Kkバブコック日立株式会社
    • IMADA NORIYUKIKATAGAWA ATSUSHI
    • B01D53/50B01D53/14B01D53/18B01D53/68B01D53/77F28F21/06
    • PROBLEM TO BE SOLVED: To provide an exhaust gas treatment apparatus capable of reducing makeup water supplied to a wet desulfurization apparatus with a simple structure.SOLUTION: In an exhaust gas treatment apparatus including a wet desulfurization apparatus 5 removing sulfur oxide by spraying absorption liquid to exhaust gas from a boiler 1, a heat recovery heat exchanger 45 is provided at an upstream side of the wet desulfurization apparatus 5, a reheating heat exchanger 46 heating the exhaust gas by a heat medium from the heat recovery heat exchanger 45 is provided at a downstream side of the wet desulfurization apparatus 5, and circulation piping 52 communicating with a heat transfer pipe between the heat recovery heat exchanger 45 and the reheating heat exchanger 46 is provided to circulate the heat medium therein. A heat removal heat exchanger 48 is provided at a heat medium flow passage of the circulation piping 52 from the reheating heat exchanger 46 to the heat recovery heat exchanger 45. By supplying drain water from a drain water recovery part 49 at a lower part of a gas duct of the heat recovery heat exchanger 45 to the wet desulfurization apparatus 5, exhaust gas temperature introduced to the wet desulfurization apparatus 5 is lowered to reduce makeup water, and the drain water is efficiently used as the makeup water of the wet desulfurization apparatus.
    • 要解决的问题:提供一种能够以简单的结构减少供给湿式脱硫装置的补充水的排气处理装置。 解决方案:在包括湿式脱硫装置5的废气处理装置中,通过将来自锅炉1的废气喷射吸收液体除去硫氧化物,在湿式脱硫装置5的上游侧设置有热回收热交换器45 在湿式脱硫装置5的下游侧设有从热回收用热交换器45向热介质加热排气的再热交换器46,在热回收热交换器5的与传热管连通的循环配管52 45,并且提供再热换热器46以使其中的热介质循环。 排气热交换器48设置在循环配管52的热介质流路上,从再热化热交换器46向热回收热交换器45供给。在排水回收部49的下部设有排水 向湿式脱硫装置5的热回收用热交换器45的气体管道,引入湿式脱硫装置5的排气温度降低,减少补充水,并且有效地将排水用作湿式脱硫装置的补充水。 版权所有(C)2013,JPO&INPIT
    • 36. 发明专利
    • Exhaust gas treating system
    • 排气处理系统
    • JP2012143699A
    • 2012-08-02
    • JP2011003360
    • 2011-01-11
    • Babcock Hitachi Kkバブコック日立株式会社
    • IMADA NORIYUKIODA NAOKI
    • B01D53/50B01D53/18B01D53/62B01D53/77C01B32/50F23J15/00F25J1/00
    • Y02C10/04Y02E20/326Y02E20/344
    • PROBLEM TO BE SOLVED: To suppress decrease in desulfurization performance and mercury removal performance of a desulfurization apparatus with a simple constitution while suppressing an equipment cost.SOLUTION: An exhaust gas treating system is equipped with a boiler 1 which burns fuel with combustion gas obtained by mixing oxygen-rich gas and circulation exhaust gas, a dust collector 5 which is disposed at a first flue 13 where the exhaust gas exhausted from the boiler 1 flows, a wet desulfurization apparatus 7 in which the exhaust gas flowing in the flue at a downstream side of the dust collector 5 is guided and is subjected to desulfurization treatment, an exhaust gas recirculation duct 17 which guides a part of the exhaust gas extracted from the flue by branching the flue at a downstream side of the dust collector 5 to the boiler 1, and a COseparation means 9 which separates COby compressing the exhaust gas flowing in the flue at a downstream side of the desulfurization apparatus 7. Water separated at the process for compressing the exhaust gas by the COseparation means 9 is supplied to absorption liquid which is used by being circulated in the desulfurization apparatus 7.
    • 要解决的问题:为了在抑制设备成本的同时以简单的结构抑制脱硫装置的脱硫性能和除汞性能的降低。 解决方案:废气处理系统配备有通过将富氧气体和循环废气混合而获得的燃烧气体燃烧燃料的锅炉1,设置在第一烟道13处的集尘器5, 从锅炉1排出的湿式脱硫装置7,其中在集尘器5的下游侧的烟道中流动的排气被引导并进行脱硫处理的湿式脱硫装置7,引导一部分的排气再循环管道17 通过将集尘器5的下游侧的烟道分流到锅炉1,从烟道中排出的废气和分离CO 2 < =“POST”> 2 ,通过压缩在脱硫装置7的下游侧的烟道中流动的废气。在通过CO 分离装置9被提供给吸收液体 用于在脱硫装置7中循环使用。版权所有(C)2012年,JPO&INPIT
    • 37. 发明专利
    • Flue gas treatment apparatus and flue gas treatment method
    • 燃气处理设备和燃气处理方法
    • JP2012050931A
    • 2012-03-15
    • JP2010195615
    • 2010-09-01
    • Babcock Hitachi Kkバブコック日立株式会社
    • SHIMODAIRA WAKAKOMITSUI YOSHIAKIIMADA NORIYUKIODA NAOKI
    • B01D53/50B01D53/14B01D53/62B01D53/77C01B32/50
    • Y02C10/06Y02P20/152
    • PROBLEM TO BE SOLVED: To provide a flue gas treatment apparatus increasing desulfurizing efficiency in an exhaust gas in a flue gas treatment apparatus provided with a COrecovery device.SOLUTION: The flue gas treatment apparatus includes: an absorption tower having an absorbing part introducing the exhaust gas from combustion equipment in which a boiler is included and bringing it into gas-liquid contact with an adsorbent which contains limestone or limestone-containing slurry, a storage part storing the adsorbent which absorbs a sulfur oxide in the exhaust gas in the absorbing part, and a circulating part circulating the adsorbent in the storage part to the absorbing part; a carbon dioxide recovery part recovering carbon dioxide in the exhaust gas from which the sulfur oxide is removed in the absorption tower; and a carbon dioxide supply part supplying carbon dioxide into the adsorbent in the absorption tower. By supplying carbon dioxide into the adsorbent, pH of the adsorbent is reduced to increase oxidation efficiency of calcium sulfite, thereby increasing the desulfurizing efficiency. Effective use of carbon dioxide is promoted by supplying the recovered carbon dioxide into the adsorbent.
    • 要解决的问题:提供一种提供具有CO 2 恢复装置的烟道气处理装置中的废气中的脱硫效率的烟道气处理装置。 解决方案:烟道气处理装置包括:吸收塔,其具有从包括锅炉的燃烧设备引入废气并将其与含有石灰石或含石灰石的吸附剂气液接触的吸收部分 浆料,储存在吸收部分中吸收废气中的硫氧化物的吸附剂的储存部分和将储存部分中的吸附剂循环到吸收部分的循环部分; 回收二氧化碳的二氧化碳回收部,其中所述废气中的氧化硫在所述吸收塔中被除去; 以及向吸收塔中的吸附剂供给二氧化碳的二氧化碳供给部。 通过向吸附剂中提供二氧化碳,减少吸附剂的pH以提高亚硫酸钙的氧化效率,从而提高脱硫效率。 通过将回收的二氧化碳供应到吸附剂来促进二氧化碳的有效利用。 版权所有(C)2012,JPO&INPIT
    • 38. 发明专利
    • Burner
    • 刻录机
    • JP2011012866A
    • 2011-01-20
    • JP2009156521
    • 2009-07-01
    • Babcock Hitachi KkElectric Power Dev Co Ltdバブコック日立株式会社電源開発株式会社
    • IMADA NORIYUKISATO YASUSHIUEDA AKIOTAKEDA MAKOTOSANTO MASANORINISHIDA TAKAHIROTSUTSUMI GO
    • F23D1/00
    • PROBLEM TO BE SOLVED: To prevent crack or high temperature corrosion of a burner, due to thermal stress, by suppressing formation of a high temperature field in the vicinity of the burner.SOLUTION: The burner is equipped with: a fuel nozzle 3 which blows out powdery fuel carried by a carrier gas; an oxidizer supply pipe line 9 provided concentrically to the fuel nozzle 3 to surround its outer circumference; a cooling water supply pipe line 13 provided to surround the oxidizer supply pipe line; and an annular supply pipe line (11) concentrically interposed between the oxidizer supply pipe line 9 and the cooling water pipe line 13 to supply gas not including oxidizer. The burner is also equipped with: a means which guides the powdery fuel carried by the carrier gas to a solid and gas separator 53 to perform solid and gas separation, supplies gas with the higher concentration of powdery fuel after separation to the base end side of the fuel nozzle, and supplies gas with the lower concentration of powdery fuel to the annular supply pipe line.
    • 要解决的问题:为了防止由于热应力引起的燃烧器的裂纹或高温腐蚀,通过抑制燃烧器附近的高温场的形成。解决方案:燃烧器配备有:燃料喷嘴3,其喷射 由载气携带的粉状燃料; 与燃料喷嘴3同心地设置以包围其外周的氧化剂供给管路9; 设置为包围氧化剂供给管路的冷却水供给管路13; 以及同心地插入在氧化剂供给管路9和冷却水管路13之间的环状供给管路(11),供给不含有氧化剂的气体。 该燃烧器还配备有:将载气携带的粉状燃料引导到固体和气体分离器53以进行固体和气体分离的装置,在分离后将较高浓度的粉末状燃料的气体分离到基础端侧 燃料喷嘴,并将具有较低浓度的粉末燃料的气体供应到环形供应管线。
    • 40. 发明专利
    • Boiler plant
    • 锅炉厂
    • JP2010127605A
    • 2010-06-10
    • JP2008306608
    • 2008-12-01
    • Babcock Hitachi Kkバブコック日立株式会社
    • SHIMODAIRA WAKAKOIMADA NORIYUKIMORIMOTO NOBUO
    • F23J15/00B01D53/50B01D53/64B01D53/77B01D53/94
    • Y02A50/2348
    • PROBLEM TO BE SOLVED: To maintain the mercury adsorption performance of flying ash and reduce the concentration of mercury in exhaust gas discharged from a boiler plant.
      SOLUTION: The boiler plant includes: a boiler 1 having, at the outlet side, a rear heat transfer part 5 for recovering the heat of exhaust gas obtained by burning fossil fuel; NOx removal equipment 11 for removing nitrogen oxides in exhaust gas discharged from the boiler 1; a heat exchanger 13 for cooling the exhaust gas discharged from the NOx removal equipment 11; an electric dust collector 29 for collecting flying ash including mercury in the exhaust gas discharged from the heat exchanger 13; and wet type desulphurization equipment 31 for removing sulfur oxides in the exhaust gas discharged from the electric dust collector 29. Flying ash collected by at least one of the rear heat transfer part 5 and the heat exchanger 13 is supplied to the upstream side of the electric dust collector 29, and the mercury in the exhaust gas is adsorbed and removed by the flying ash.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:保持飞灰的汞吸附性能,降低锅炉厂排放废气中汞的浓度。 锅炉设备包括:锅炉1,在出口侧具有后部传热部分5,用于回收通过燃烧化石燃料获得的废气的热量; 用于去除从锅炉1排出的废气中的氮氧化物的NOx去除装置11; 用于冷却从NOx去除设备11排出的废气的热交换器13; 电除尘器29,用于收集从热交换器13排出的废气中包含汞的飞灰; 以及用于除去从集尘器29排出的排气中的硫氧化物的湿式脱硫设备31.由后部传热部5和热交换器13中的至少一个收集的飞灰供给到电气 集尘器29,废气中的汞被飞灰吸附除去。 版权所有(C)2010,JPO&INPIT