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    • 31. 发明授权
    • Fiber-reactive azo dyes, their preparation and their use
    • 纤维反应偶氮染料,其制备及其用途
    • US07087730B2
    • 2006-08-08
    • US10523241
    • 2003-07-15
    • Athanassios TzikasBernhard MüllerGeorg Roentgen
    • Athanassios TzikasBernhard MüllerGeorg Roentgen
    • C09B62/507C09B62/08D06P1/384C09D11/02
    • C09B62/4411
    • Reactive dyes of formula (I), wherein A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, Q1, and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1–C4alkyl, (Q3)n denotes n substituents selected from the group C1–C4alkyl, C1–C4alkoxy, halogen and sulfo, X is halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl, hydroxy, C1–C4alkoxy unsubstituted or substituted in the alkyl moiety, phenoxy unsubstituted or substituted in the phenyl moiety, C1–C4alkylthio unsubstituted or substituted in the alkyl moiety, unsubstituted or substituted amino, or an N-heterocycle which may or may not contain further hetero atoms, Y is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, k is a number 2, 3, 4, 5 or 6, m is a number 0 or 1, and n is a number 0, 1 or 2, with the proviso that when A denotes a monoazo chromophore it is not directly linked to the triazinyl radical through a hydroxynaphthalenesulfonic acid coupling component and does not denote a radical of formula (II), are suitable for dyeing cellulosic or nitrogen-containing fiber materials
    • 式(I)的活性染料,其中A是单偶氮,多偶氮,金属络合物偶氮,蒽醌,酞菁,甲an或二恶嗪发色团,Q 1和Q 2的基团, (III)各自独立地为另一个氢或未取代或取代的C 1 -C 4烷基,(Q 3 N) / SUB>表示选自C 1 -C 4烷基,C 1 -C 4烷基,C 1 -C 4烷基, 烷氧基,卤素和磺基,X是卤素,3-羧基吡啶-1-基,3-氨基甲酰基吡啶-1-基,羟基,未取代的或未取代的C 1 -C 4烷氧基 在烷基部分被取代的苯基部分中未取代或取代的苯氧基,未取代或未取代的烷基部分的未取代或取代的未取代或取代的氨基的C 1 -C 4 - 可以含有或可以不含有其它杂原子的N-杂环,Y是乙烯基或基团-CH 2 -CH 2 -O-U,U是在碱性条件下可除去的基团 ,k是麻木 呃2,3,4,5或6,m是数字0或1,n是数字0,1或2,条件是当A表示单偶氮发色团时,它不直接与三嗪基直接连接, 羟基萘磺酸偶联组分并不表示式(II)的基团,适用于染色纤维素或含氮纤维材料
    • 32. 发明申请
    • Fibre-Reactive Dyes, Their Preparation and Their Use
    • 纤维活性染料及其制备及其应用
    • US20140026333A1
    • 2014-01-30
    • US14009574
    • 2012-03-05
    • Georg RoentgenLaszlo FeketeMichael Nicollet
    • Georg RoentgenLaszlo FeketeMichael Nicollet
    • D06P1/384C09B62/513
    • D06P1/384C07C317/44C09B29/30C09B62/4415C09B62/475C09B62/51C09B62/513C09D11/328D06P3/666D06P5/30
    • Reactive dyes of formula (1), wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, one of the radicals D1 and D2 is a radical of the formula (2), the other one of the radicals D1 and D2 is a radical of the formula (3a), or (3b), wherein (R3)n denotes n identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Z1 is a radical of the formula —SO2—Y (4a), —CONH—(CH2)p—SO2—Y (4b), —NH—CO—CH(Hal)-CH2-Hal (4c), —NH—CO—C(Hal)═CH2 (4d), or (4e), wherein X1 is halogen, T1 independently has the definition of X1, is a non-fibre-reactive substituent or is a fibre-reactive radical of the formula (5a), —NH—(CH2)2-3—SO2—Y (5b), or —NH—(CH2)2-3—O—(CH2)2-3—SO2—Y (5c), R4 is hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)0-2 denotes from 0 to 2 identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Hal is halogen, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, k is the number 0, 1 or 2, m is the number 2, 3 or 4, n is the number 0, 1 or 2, and p is the number 2, 3 or 4, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    • 式(1)的活性染料,其中R 1和R 2各自独立于另一个氢或未取代或取代的C 1 -C 4烷基,基团D 1和D 2之一是式(2)的基团,另一个基团 D1和D2是式(3a)或(3b)的基团,其中(R3)n表示n个相同或不同的选自C1-C4烷基,C1-C4烷氧基和磺基的取代基,Z1是式 -SO 2 -Y(4a),-CONH-(CH 2)p -SO 2 -Y(4b),-NH-CO-CH(Hal)-CH 2 - Hal(4c),-NH-CO-C(Hal) CH2(4d)或(4e),其中X1是卤素,T1独立地具有X1的定义,是非纤维反应性取代基或者是式(5a)的纤维反应性基团,-NH-(CH 2 )2-3-SO2-Y(5b)或-NH-(CH2)2-3-O-(CH2)2-3-SO2-Y(5c),R4是氢或未取代或取代的C1-C4烷基, (R5)0-2表示0至2个相同或不同的取代基,如C1-C4烷基,C1-C4烷氧基和磺基,Hal为卤素,Y为乙烯基或-CH2-CH2-U基团,U为 是的 在碱性条件下可以去除,k是数字0,1或2,m是数字2,3或4,n是数字0,1或2,p是数字2,3或4,适用于染色 含纤维素或含酰胺基的纤维材料。
    • 33. 发明授权
    • Red reactive dyes, their preparation and their use
    • 红色活性染料,其制备及其用途
    • US08066809B2
    • 2011-11-29
    • US12377059
    • 2007-07-31
    • Georg RoentgenLaszlo Fekete
    • Georg RoentgenLaszlo Fekete
    • C09D11/02C09B62/01B05D5/06
    • C09B62/4415C09D11/17C09D11/18C09D11/32C09D11/328D06P1/382D06P3/663D06P5/30
    • Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fiber-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fiber materials.
    • 其中R 1和R 2彼此独立地是氢或未取代的或取代的C 1 -C 4烷基,D是式X 1和X 2的重氮组分的基团彼此独立的基团的反应性染料是卤素,T是纤维反应性基团 式(R3)0-2表示0-2个与卤素,C1-C4烷基,C1-C4烷氧基和磺基相同或不同的取代基,Z是乙烯基或-CH2-CH2-U基团,U是一个基团 在碱性条件下是可去除的,Q是-CH(Hal)-CH 2 - Hal或-C(Hal)= CH 2基团,Hal是卤素,n是数字0,1或2,m和q独立地是 另一个数字0或1,适用于染色含纤维素或含酰胺基的纤维材料。