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    • 3. 发明授权
    • Heat-sensitive coating compositions based on resorcinyl triazine derivatives
    • 基于间苯二酚三嗪衍生物的热敏涂料组合物
    • US08865620B2
    • 2014-10-21
    • US12529718
    • 2008-03-05
    • Allan Francis CunninghamThomas EhlisJean-Luc BirbaumPascal HayozKamalesh Pai Fondekar
    • Allan Francis CunninghamThomas EhlisJean-Luc BirbaumPascal HayozKamalesh Pai Fondekar
    • B41M5/333C09D5/26C08K5/3492C09D7/00
    • B41M5/3335B41M5/3336C08K5/3492C09D5/26C09D7/41Y10T428/24802
    • The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 and R15 can be the same or different and can be hydrogen, C1-10-alkyl, C3-8-cycloalkyl or C2-10-alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain color developers.
    • 本发明提供热敏涂料组合物,其包含式(1)的显色剂或其混合物,其中R 1可以是氢,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基或SO 3 H ,R2和R3可以相同或不同,可以是氢,卤素,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基,OR 6,NR 7 R 8,SR 9,SO 3 H或COOR 10和 R4和R5可以相同或不同,可以是氢,卤素,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基,OR 6,NR 7 R 8或SR 9,R 6,R 7,R 8 ,R 9和R 10可以相同或不同,并且可以是氢,C 1-30 - 烷基,C 3-8 - 环烷基,C 2-10 - 烯基或芳基,其中C 1-20 - 烷基可以是未取代的或被一个或多个 C 3-8 - 环烷基,C 2-10 - 烯基,苯基,卤素,OR 11,NR 12 R 13,SR 14,SO 3 H或COOR 15,芳基可以是未被取代的或被一个或多个卤素取代,C 1-10烷基,卤代C 1-10 - 烷基,C 3-8 - 环烷基C2-10 - 烯基,苯基,OR11,NR12R13,SR14,SO3H或COOR15,其中 在R 11,R 12,R 13,R 14和R 15可以相同或不同,可以是氢,C 1-10 - 烷基,C 3-8 - 环烷基或C 2-10 - 烯基,一种制备这些组合物的方法, 涂覆这些组合物的基材,用这些组合物涂布的基材,使用这些组合物制备标记的基材的方法,通过后一方法获得的标记的底物和某些显色剂。
    • 4. 发明申请
    • HEAT-SENSITIVE COATING COMPOSITIONS BASED ON RESORCINYL TRIAZINE DERIVATIVES
    • 基于间苯二酚衍生物的热敏涂料组合物
    • US20110311786A1
    • 2011-12-22
    • US12529718
    • 2008-03-05
    • Allan Francis CunninghamThomas EhlisJean-Luc BirbaumPascal HayozKamalesh Pai Fondekar
    • Allan Francis CunninghamThomas EhlisJean-Luc BirbaumPascal HayozKamalesh Pai Fondekar
    • B41M5/28C08K5/3492B05D3/06C09D129/04C09D109/08B05D3/02C07D251/24C09D133/08
    • B41M5/3335B41M5/3336C08K5/3492C09D5/26C09D7/41Y10T428/24802
    • The present invention provides heat-sensitive coating compositions, which comprise a colour developer of formula (1) or mixtures thereof wherein R can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 and R15 can be the same or different and can be hydrogen, C1-10-alkyl, C3-8-cycloalkyl or C2-10-alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain colour developers.
    • 本发明提供热敏涂料组合物,其包含式(1)的显色剂或其混合物,其中R可以是氢,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基或SO 3 H ,R2和R3可以相同或不同,可以是氢,卤素,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基,OR 6,NR 7 R 8,SR 9,SO 3 H或COOR 10和 R4和R5可以相同或不同,可以是氢,卤素,C 1-20烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基,OR 6,NR 7 R 8或SR 9,R 6,R 7,R 8 ,R 9和R 10可以相同或不同,并且可以是氢,C 1-30 - 烷基,C 3-8 - 环烷基,C 2-10 - 烯基或芳基,其中C 1-20 - 烷基可以是未取代的或被一个或多个 C 3-8 - 环烷基,C 2-10 - 烯基,苯基,卤素,OR 11,NR 12 R 13,SR 14,SO 3 H或COOR 15,芳基可以是未被取代的或被一个或多个卤素取代,C 1-10烷基,卤代C 1-10 - 烷基,C 3-8 - 环烷基C2-10 - 烯基,苯基,OR11,NR12R13,SR14,SO3H或COOR15,其中 在R 11,R 12,R 13,R 14和R 15可以相同或不同,可以是氢,C 1-10 - 烷基,C 3-8 - 环烷基或C 2-10 - 烯基,一种制备这些组合物的方法, 涂覆这些组合物的基材,用这些组合物涂布的基材,使用这些组合物制备标记的基材的方法,通过后一方法获得的标记的底物和某些显色剂。