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    • 1. 发明申请
    • Mixtures of Reactive Dyes and Their Use
    • 活性染料的混合物及其用途
    • US20140173835A1
    • 2014-06-26
    • US14236364
    • 2012-06-19
    • Georg RoentgenAthanassios TzikasHubert Jean-Luc ChristnacherLaszlo Fekete
    • Georg RoentgenAthanassios TzikasHubert Jean-Luc ChristnacherLaszlo Fekete
    • C09B62/533C09B62/513
    • C09B62/533C09B62/4415C09B62/513C09B67/0055D06P1/38D06P3/248D06P3/66
    • Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-containing fibre materials.
    • 包含至少一种式(1)的活性染料与至少一种式(2)的活性染料的染料混合物,其中基团A和B中的一个表示NH 2,基团A和B中的另一个表示 OH,D是苯或萘基,R 1是氢,羟基,磺基,C 1 -C 4烷基或被烷基部分被羟基或硫酸酯取代的C 1 -C 4烷氧基,R 2是氢,C 1 -C 4烷基,C 1 -C 4烷氧基, C 2 -C 4烷酰基氨基或脲基,R 3是C 1 -C 4烷基,(R 4)0-2表示0至2个相同或不同的选自C 1 -C 4烷基,C 1 -C 4烷氧基或磺基,X 1为卤素,3-羧基吡啶-1-基, 吡啶-1-基或3-氨基甲酰基吡啶-1-基,Y 1,Y 2,Y 3,Y 4和Y 5各自独立地为其它乙烯基或基团-CH 2 CH 2 -U,U是在碱性条件下可除去的基团,h,k,l,m 和n各自独立于数字0,1或2中的另一个,并且p和q各自独立于数字0或1中的另一个,适用于染色和印刷c 纤维素或含氮纤维材料。
    • 3. 发明申请
    • Fibre-Reactive Dyes, Their Preparation and Their Use
    • 纤维活性染料及其制备及其应用
    • US20140026333A1
    • 2014-01-30
    • US14009574
    • 2012-03-05
    • Georg RoentgenLaszlo FeketeMichael Nicollet
    • Georg RoentgenLaszlo FeketeMichael Nicollet
    • D06P1/384C09B62/513
    • D06P1/384C07C317/44C09B29/30C09B62/4415C09B62/475C09B62/51C09B62/513C09D11/328D06P3/666D06P5/30
    • Reactive dyes of formula (1), wherein R1 and R2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, one of the radicals D1 and D2 is a radical of the formula (2), the other one of the radicals D1 and D2 is a radical of the formula (3a), or (3b), wherein (R3)n denotes n identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Z1 is a radical of the formula —SO2—Y (4a), —CONH—(CH2)p—SO2—Y (4b), —NH—CO—CH(Hal)-CH2-Hal (4c), —NH—CO—C(Hal)═CH2 (4d), or (4e), wherein X1 is halogen, T1 independently has the definition of X1, is a non-fibre-reactive substituent or is a fibre-reactive radical of the formula (5a), —NH—(CH2)2-3—SO2—Y (5b), or —NH—(CH2)2-3—O—(CH2)2-3—SO2—Y (5c), R4 is hydrogen or unsubstituted or substituted C1-C4alkyl, (R5)0-2 denotes from 0 to 2 identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, Hal is halogen, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, k is the number 0, 1 or 2, m is the number 2, 3 or 4, n is the number 0, 1 or 2, and p is the number 2, 3 or 4, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    • 式(1)的活性染料,其中R 1和R 2各自独立于另一个氢或未取代或取代的C 1 -C 4烷基,基团D 1和D 2之一是式(2)的基团,另一个基团 D1和D2是式(3a)或(3b)的基团,其中(R3)n表示n个相同或不同的选自C1-C4烷基,C1-C4烷氧基和磺基的取代基,Z1是式 -SO 2 -Y(4a),-CONH-(CH 2)p -SO 2 -Y(4b),-NH-CO-CH(Hal)-CH 2 - Hal(4c),-NH-CO-C(Hal) CH2(4d)或(4e),其中X1是卤素,T1独立地具有X1的定义,是非纤维反应性取代基或者是式(5a)的纤维反应性基团,-NH-(CH 2 )2-3-SO2-Y(5b)或-NH-(CH2)2-3-O-(CH2)2-3-SO2-Y(5c),R4是氢或未取代或取代的C1-C4烷基, (R5)0-2表示0至2个相同或不同的取代基,如C1-C4烷基,C1-C4烷氧基和磺基,Hal为卤素,Y为乙烯基或-CH2-CH2-U基团,U为 是的 在碱性条件下可以去除,k是数字0,1或2,m是数字2,3或4,n是数字0,1或2,p是数字2,3或4,适用于染色 含纤维素或含酰胺基的纤维材料。
    • 4. 发明授权
    • Red reactive dyes, their preparation and their use
    • 红色活性染料,其制备及其用途
    • US08066809B2
    • 2011-11-29
    • US12377059
    • 2007-07-31
    • Georg RoentgenLaszlo Fekete
    • Georg RoentgenLaszlo Fekete
    • C09D11/02C09B62/01B05D5/06
    • C09B62/4415C09D11/17C09D11/18C09D11/32C09D11/328D06P1/382D06P3/663D06P5/30
    • Reactive dyes of formula wherein R1 and R2 independently of one another are hydrogen or unsubstituted or substituted C1-C4alkyl, D is a radical of a diazo component of the formula X1 and X2 independently of one another are halogen, T is a fiber-reactive radical of the formula (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group, Hal is halogen, n is the number 0, 1 or 2, and m and q are independently of one another the number 0 or 1, are suitable for dyeing cellulosic or amide-group-containing fiber materials.
    • 其中R 1和R 2彼此独立地是氢或未取代的或取代的C 1 -C 4烷基,D是式X 1和X 2的重氮组分的基团彼此独立的基团的反应性染料是卤素,T是纤维反应性基团 式(R3)0-2表示0-2个与卤素,C1-C4烷基,C1-C4烷氧基和磺基相同或不同的取代基,Z是乙烯基或-CH2-CH2-U基团,U是一个基团 在碱性条件下是可去除的,Q是-CH(Hal)-CH 2 - Hal或-C(Hal)= CH 2基团,Hal是卤素,n是数字0,1或2,m和q独立地是 另一个数字0或1,适用于染色含纤维素或含酰胺基的纤维材料。
    • 10. 发明申请
    • MIXTURES OF REACTIVE DYES AND THEIR USE IN A METHOD FOR TRICHROMATIC DYEING OR PRINTING
    • 反应性染料的混合物及其在三色染色或印刷方法中的应用
    • US20100077555A1
    • 2010-04-01
    • US12513464
    • 2007-10-30
    • Georg RoentgenAthanassios TzikasHubert Jean Luc Christnacher
    • Georg RoentgenAthanassios TzikasHubert Jean Luc Christnacher
    • C09B62/095C09B62/012
    • C09B62/4407C09B62/4413C09B62/4415C09B67/005C09B67/0059
    • Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein Q1 is C1-C4alkyl, halogen or a radical —SO2—Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo, Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2 and R3 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2 and X3 are each independently of the others halogen, 3-carboxypyridin-1-yl, 3-carbamoylpyridin-1-yl or a non-fibre-reactive substituent, and T1, T2 and T3 are each independently of the others a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R4)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fibre materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.
    • 染料混合物,其包含至少一种下式的染料和至少一种下式基团的染料,其中Q 1是C 1 -C 4烷基,卤素或基团-SO 2 -Z,Q 2和Q 3各自独立地为C 1 -C 4烷氧基,Q 4 C1-C4烷氧基,C1-C4烷基,卤素或磺基,Q5是C1-C4烷氧基,C1-C4烷基,C1-C4烷酰基氨基,脲基,卤素或磺基,R1,R2和R3各自独立地是氢或未取代的或取代的C1 -C 1-4烷基,k和q各自独立于数字0或1中的另一个,n和p各自独立于数字0,1或2中的另一个,m是数字0,1,2或3,t是 1,2或3个,X1,X2和X3各自独立地为卤素,3-羧基吡啶-1-基,3-氨基甲酰基吡啶-1-基或非纤维反应性取代基,T1,T2和T3 各自独立地为非纤维反应性取代基或具有下式的纤维反应性基团其中(R4)0-2表示0至2个相同或不同的取代基,基团卤素 ,C 1 -C 4烷基,C 1 -C 4烷氧基和磺基,Z是乙烯基或基团-CH 2 -CH 2 -U,U是在碱性条件下可除去的基团,Q是基团-CH(Hal)-CH 2 - Hal或-C( Hal)= CH2,Hal是卤素,特别适用于纤维素纤维材料的二色或三色染色或印花,并且具有良好的再现性和良好的全面牢固性的产量染色或印花。