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31. 发明授权

US4777087A Heat stabilized silicone elastomers 失效
标题翻译：热稳定硅酮弹性体
公开(公告)号：US4777087A
公开(公告)日：1988-10-11
申请号：US18372
申请日：1987-02-24
申请人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
发明人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
IPC分类号： C08K3/24 , C08K3/00 , C08K3/30 , C08K3/32 , C08K5/00 , C08K5/36 , C08K5/59 , C08L83/00 , C08L83/04 , C08L83/05 , C08L83/07 , G03G15/20 , B32B3/26
CPC分类号： G03G15/2057 , C08K5/0091 , Y10T428/249995 , Y10T428/31663
摘要： A silicone composition curable to a heat stabilized silicone elastomer comprising at least one polyorganosiloxane having the formula: ##STR1## where R is hydrogen or substituted or unsubstituted alkyl, alkenyl or aryl having less than 19 carbon atoms, each of A and D may be any of methyl, hydroxy or vinyl groups,0 350,a complex comprising a transition metal salt of at least one polydentate chelating ligand having the formula: ##STR2## where each R.sub.1 may be an alkyl biradical having 1 to 6 carbon atoms or an aryl biradical having less than 19 carbon, atoms R'.sub.1, is an X' substituted R.sub.1, each of Z and E may be any of carboxy thiocarboxy, dithiocarboxy, or --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, --S(R.sub.2) where each R.sub.2 may be any of hydrogen or an alkyl radical having 1 to 6 carbon atoms or any aryl radical having less than 19 carbon atoms, X' may be any of hydrogen, carboxy, thiocarboxy, dithiocarboxy, --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, or --S(R.sub.2), X is --N(R.sub.2)--, --A.sub.s (R.sub.2)--, or --S-- and p is 0 to 4 present in the composition in an amount sufficient to inhibit oxidative degradation of the polyorganosiloxane and a finely divided filler and effective amounts of crosslinking agent and catalyst. The complex may be predispersed in a polyorganosiloxane oil having a viscosity within a range of to 50 to 100,000 centistokes. In a preferred embodiment for use in an electrostatographic reproducing machine a fuser member is made with an addition curable polyorganosiloxane and the complex is bis (ethylene diamine) copper (II) sulfate initially predispersed in a low viscosity silicone oil and subsequently dispersed in a higher viscosity silicone oil.
摘要翻译：包含至少一种具有下式的聚有机硅氧烷的硅氧烷组合物：其中R是氢或具有少于19个碳原子的取代或未取代的烷基，烯基或芳基，A和D中的每一个可以是任何的甲基，羟基或乙烯基，0 <（m / n）≤1和m + n> 350，包含至少一种具有下式的多齿螯合配位体的过渡金属盐的络合物：其中每个R 1 可以是具有1至6个碳原子的烷基双原子或具有少于19个碳原子的芳基双原子，R 1'是X'取代的R 1，Z和E各自可以是羧基硫代羧基，二硫代羧基或-N （R2）2，-As（R2）2，-S（R2）其中R2可以是氢或具有1-6个碳原子的烷基或任何具有少于19个碳原子的芳基，X'可以是氢，羧基，硫代羧基，二硫代羧基，-N（R2）2，-As（R2）2或-S（R2）中的任一个，X是-N（R2） - ，--As（R2） - 或-S - 和p是0到4存在于公司其量足以抑制聚有机硅氧烷和细碎填料的氧化降解和有效量的交联剂和催化剂。络合物可以预先分散在粘度在50至100,000厘沲范围内的聚有机硅氧烷油中。在用于静电复制机的优选实施方案中，定影构件由可加成固化的聚有机硅氧烷制成，并且络合物是最初预先分散在低粘度硅油中的双（乙二胺）硫酸铜（II），随后以更高的粘度分散硅油。

32. 发明授权

US06743561B2 Functional fusing agent 失效
标题翻译：功能融合剂
公开(公告)号：US06743561B2
公开(公告)日：2004-06-01
申请号：US10254814
申请日：2002-09-25
申请人： George J. Heeks , Santokh S. Badesha , Samuel Kaplan , David J. Gervasi , Che C. Chow , Arnold W. Henry
发明人： George J. Heeks , Santokh S. Badesha , Samuel Kaplan , David J. Gervasi , Che C. Chow , Arnold W. Henry
IPC分类号： G03G1320
CPC分类号： C08G77/388 , C09D183/08 , G03G15/2025 , G03G2215/2093 , Y10S428/906 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： Disclosed is a fusing release agent comprising the reaction product of a primary- or secondary-amino-functionalized polyorganosiloxane oil and a low molecular weight, non-sterically-hindered aldehyde or ketone.
摘要翻译：公开了一种熔融脱模剂，其包含初级或仲氨基官能化的聚有机硅氧烷油和低分子量非空间位阻醛或酮的反应产物。

33. 发明授权

US06566027B2 Tertiary amine functionalized fuser fluids 失效
标题翻译：叔胺官能化定影液
公开(公告)号：US06566027B2
公开(公告)日：2003-05-20
申请号：US09839554
申请日：2001-04-20
申请人： Samuel Kaplan , Clifford O. Eddy , Arnold W. Henry , Santokh S. Badesha , George J. Heeks , Che C. Chow , David H. Pan , Louis D. Fratangelo , David J. J. Fraser , Yu-hsing Chin
发明人： Samuel Kaplan , Clifford O. Eddy , Arnold W. Henry , Santokh S. Badesha , George J. Heeks , Che C. Chow , David H. Pan , Louis D. Fratangelo , David J. J. Fraser , Yu-hsing Chin
IPC分类号： G03G1320
CPC分类号： G03G15/2057 , C09D183/08 , Y10T428/2927 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964 , Y10T428/31663
摘要： Disclosed is a fuser member comprising a substrate, a layer thereover comprising a polymer, and, on the polymeric layer, a coating of a release agent comprising polyorganosiloxanes having tertiary amino functional groups on at least some of the molecules thereof.
摘要翻译：公开了一种定影器构件，其包括基底，其上包含聚合物的层，并且在聚合物层上，包含在其至少一些分子上具有叔氨基官能团的聚有机硅氧烷的包衣。

34. 发明授权

US06485835B1 Functional fusing agent 有权
标题翻译：功能融合剂
公开(公告)号：US06485835B1
公开(公告)日：2002-11-26
申请号：US09375030
申请日：1999-08-16
申请人： George J. Heeks , Santokh S. Badesha , Samuel Kaplan , David J. Gervasi , Che C. Chow , Arnold W. Henry
发明人： George J. Heeks , Santokh S. Badesha , Samuel Kaplan , David J. Gervasi , Che C. Chow , Arnold W. Henry
IPC分类号： B32B108
CPC分类号： C08G77/388 , C09D183/08 , G03G15/2025 , G03G2215/2093 , Y10S428/906 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： Disclosed is a fusing release agent comprising the reaction product of a primary- or secondary-amino-functionalized polyorganosiloxane oil and a low molecular weight, non-sterically-hindered aldehyde or ketone
摘要翻译：公开了一种熔融脱模剂，其包含初级或仲氨基官能化的聚有机硅氧烷油与低分子量的非空间位阻的醛或酮的反应产物

35. 发明授权

US06297302B1 Stabilized fluorosilicone materials 有权
标题翻译：稳定氟硅材料
公开(公告)号：US06297302B1
公开(公告)日：2001-10-02
申请号：US09375592
申请日：1999-08-17
申请人： George J. Heeks , David J. Gervasi , Arnold W. Henry , Santokh S. Badesha
发明人： George J. Heeks , David J. Gervasi , Arnold W. Henry , Santokh S. Badesha
IPC分类号： C08K516
CPC分类号： C08K5/5425 , C08K5/098 , C08K5/14 , C08K5/17 , C08L83/08 , Y10T428/3154 , C08L83/00 , C08L2666/28
摘要： Disclosed is a composition comprising a crosslinked product of a liquid composition which comprises (a) a fluorosilicone, (b) a crosslinking agent and (c) a thermal stabilizing agent comprising a reaction product of (i) a cyclic unsaturated-alkyl-group-substituted polyorganosiloxane, (ii) a linear unsaturated-alkyl-group-substituted polyorganosiloxane, and (iii) a metal acetylacetonate or metal oxalate compound. The crosslinked fluorosilicones can be employed as intermediate or outer layers of electrostatographic fuser members, electrostatographic intermediate transfer belt materials and the like. They are useful in applications wherein materials possessing desirable release characteristics, surface energies, electrical characteristics, oil resistance properties, or solvent resistance properties exhibited by fluorosilicone elastomers are desirable. They are also useful in applications wherein fluorosilicones are exposed to high temperatures, since the stabilizing components reduce the generation of toxic effluents such as trifluoropropionaldehyde and formaldehyde, which can form when methyl-methyl crosslinking of the polymer occurs, and increase temperature stability.
摘要翻译：公开了包含液体组合物的交联产物的组合物，其包含（a）氟硅酮，（b）交联剂和（c）热稳定剂，其包含以下反应产物：（i）环状不饱和烷基 - 取代的聚有机硅氧烷，（ii）线性不饱和烷基取代的聚有机硅氧烷，和（iii）金属乙酰丙酮化物或金属草酸盐化合物。交联氟硅氧烷可以用作静电定影部件，静电中间转印带材料等的中间或外层。它们可用于其中具有期望的释放特性，表面能，电特性，耐油性能或由氟硅氧烷弹性体显示的耐溶剂性能的材料。它们也可用于将氟硅氧烷暴露于高温的应用中，因为稳定组分可减少有机污染物的产生，例如三氟丙醛和甲醛，当聚合物发生甲基 - 甲基交联时可形成，并提高温度稳定性。

36. 发明授权

US06261688B1 Tertiary amine functionalized fuser fluids 有权
公开(公告)号：US06261688B1
公开(公告)日：2001-07-17
申请号：US09378154
申请日：1999-08-20
申请人： Samuel Kaplan , Clifford O. Eddy , Arnold W. Henry , Santokh S. Badesha , George J. Heeks , Che C. Chow , David H. Pan , Louis D. Fratangelo , David J. J. Fraser , Yu-hsing Chin
发明人： Samuel Kaplan , Clifford O. Eddy , Arnold W. Henry , Santokh S. Badesha , George J. Heeks , Che C. Chow , David H. Pan , Louis D. Fratangelo , David J. J. Fraser , Yu-hsing Chin
IPC分类号： B32B2520
CPC分类号： G03G15/2057 , C09D183/08 , Y10T428/2927 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964 , Y10T428/31663
摘要： Disclosed is a fuser member comprising a substrate, a layer thereover comprising a polymer, and, on the polymeric layer, a coating of a release agent comprising polyorganosiloxanes having tertiary amino functional groups on at least some of the molecules thereof.

37. 发明授权

US6045961A Thermally stable silicone fluids 失效
标题翻译：热稳定的硅油
公开(公告)号：US6045961A
公开(公告)日：2000-04-04
申请号：US375968
申请日：1999-08-17
申请人： George J. Heeks , David J. Gervasi , Arnold W. Henry , Santokh S. Badesha
发明人： George J. Heeks , David J. Gervasi , Arnold W. Henry , Santokh S. Badesha
IPC分类号： G03G15/20 , G03G21/00
CPC分类号： G03G15/2025 , G03G2215/2093 , Y10T428/3154
摘要： Disclosed is a fuser release agent comprising (a) a polyorganosiloxane, and (b) a stabilizing agent comprising a reaction product of (i) a metal acetylacetonate or metal oxalate compound, (ii) a linear unsaturated-alkyl-group-substituted polyorganosiloxane, and (iii) a cyclic unsaturated-alkyl-group-substituted polyorganosiloxane.
摘要翻译：公开了一种定影剂脱模剂，其包含（a）聚有机硅氧烷和（b）稳定剂，其包含（i）金属乙酰丙酮化物或草酸金属盐化合物的反应产物，（ii）线性不饱和烷基取代的聚有机硅氧烷，和（iii）环状不饱和 - 烷基取代的聚有机硅氧烷。

38. 发明授权

US5830939A Viscosity reduction method 失效
标题翻译：粘度降低法
公开(公告)号：US5830939A
公开(公告)日：1998-11-03
申请号：US637914
申请日：1996-04-25
申请人： Santokh S. Badesha , Robert M. Ferguson , Marko D. Saban , Sonja Hadzidedic , Arnold W. Henry , George J. Heeks , Nam S. Ro , John Abate
发明人： Santokh S. Badesha , Robert M. Ferguson , Marko D. Saban , Sonja Hadzidedic , Arnold W. Henry , George J. Heeks , Nam S. Ro , John Abate
IPC分类号： B01F17/54 , C08F290/06 , C08G81/02 , C09D183/10 , C08K5/05 , B01J13/00 , C08K5/101 , C08L83/08
CPC分类号： C09D183/10 , B01F17/0071 , C08F290/068 , C08G81/024 , Y10S524/916
摘要： There is disclosed a viscosity reduction method including: (a) forming an azeotropic mixture including water and a liquid capable of forming the azeotropic mixture with the water in a coating composition comprised of the water, a solvent, and a polymeric material selected from the group consisting of a fluorohydrocarbon polymer and a grafted elastomer composed of a polyorganosiloxane bonded to a fluoroelastomer; and (b) agitating the coating composition including the azeotropic mixture, thereby reducing the viscosity of the coating composition.
摘要翻译：公开了一种粘度降低方法，其包括：（a）在由水，溶剂和选自下组的聚合材料组成的涂料组合物中形成共沸混合物，其包括水和能够与水形成共沸混合物的液体由氟烃聚合物和由与氟弹性体结合的聚有机硅氧烷组成的接枝弹性体组成; 和（b）搅拌包含共沸混合物的涂料组合物，从而降低涂料组合物的粘度。

39. 发明授权

US5787329A Organic coated development electrodes and methods thereof 失效
标题翻译：有机涂层显影电极及其方法
公开(公告)号：US5787329A
公开(公告)日：1998-07-28
申请号：US841136
申请日：1997-04-29
申请人： John R. Laing , Edward J. Gutman , J. Stephen Kittelberger , John G. VanDusen , Suresh K. Ahuja , Merlin E. Scharfe , Richard L. Schank , Mark J. Hirsch , Santokh S. Badesha , Arnold W. Henry , George J. Heeks
发明人： John R. Laing , Edward J. Gutman , J. Stephen Kittelberger , John G. VanDusen , Suresh K. Ahuja , Merlin E. Scharfe , Richard L. Schank , Mark J. Hirsch , Santokh S. Badesha , Arnold W. Henry , George J. Heeks
IPC分类号： C09D201/00 , G03G15/08
CPC分类号： G03G15/0803 , G03G2215/0621 , G03G2215/0643
摘要： An apparatus and process for reducing accumulation of toner from the surface of an electrode member in a development unit of an electrostatographic printing apparatus by providing an organic coating on at least a portion of the electrode member.
摘要翻译：一种用于通过在电极构件的至少一部分上提供有机涂层来减少调色剂从静电印刷装置的显影单元中的电极构件的表面积累的装置和方法。

40. 发明授权

US5736250A Crosslinked latex polymer surfaces and methods thereof 失效
标题翻译：交联乳胶聚合物表面及其方法
公开(公告)号：US5736250A
公开(公告)日：1998-04-07
申请号：US694121
申请日：1996-08-08
申请人： George J. Heeks , Santokh S. Badesha , Clifford O. Eddy , Arnold W. Henry
发明人： George J. Heeks , Santokh S. Badesha , Clifford O. Eddy , Arnold W. Henry
IPC分类号： C08L27/16 , C08L83/04 , G03G15/16 , G03G15/20 , B32B9/04 , B25F5/02 , G03G13/20
CPC分类号： G03G15/2057 , C08L27/16 , G03G15/1685 , C08L83/04 , Y10S428/906 , Y10T428/31663
摘要： Crosslinked fluorocarbon elastomer surfaces comprised of a fluorocarbon elastomer and an amino siloxane and a method for providing a crosslinked fluorocarbon elastomer surface on a fuser member supporting substrate which includes mixing together an acid acceptor, an emulsifier, water, and amino siloxane with a latex fluorocarbon elastomer are provided.
摘要翻译：由氟碳弹性体和氨基硅氧烷构成的交联碳氟化合物弹性体表面和在定影器构件支撑基底上提供交联的碳氟化合物弹性体表面的方法，其包括将酸受体，乳化剂，水和氨基硅氧烷与胶乳氟烃弹性体被提供。

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