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    • 26. 发明申请
    • METHOD OF PRODUCING (METH) ACRYLIC ACID DERIVATIVE POLYMER FOR RESIST
    • 生产(甲基)丙烯酸衍生物聚合物抗体的方法
    • WO2004050728A2
    • 2004-06-17
    • PCT/JP2003/015348
    • 2003-12-01
    • TOKYO OHKA KOGYO CO., LTD.KUBOTA, NaotakaIWAI, TakeshiHADA, Hideo
    • KUBOTA, NaotakaIWAI, TakeshiHADA, Hideo
    • C08F220/00
    • G03F7/0397C08F220/10Y10T428/31935
    • There is provided a photoresist composition capable of forming a resist pattern with minimal LER, and a method of forming a resist pattern. This method is a method of producing a (meth)acrylic acid derivative polymer for use as a resist by radical polymerization of a monomer mixture comprising (al) a (meth)acrylate ester with an acid dissociable, dissolution inhibiting group, and (a2) a (meth)acrylate ester with a lactone unit, wherein (al) and (a2) utilize compounds such that when each compound (al) and (a2) is individually subjected to homopolymerization, under identical conditions to the radical polymerization, and a residual monomer ratio is determined 10 minutes after the start of the homopolymerization, the difference between the minimum residual monomer ratio and the maximum residual monomer ratio is no more than 15 mol%.
    • 提供了能够以最小的LER形成抗蚀剂图案的光致抗蚀剂组合物以及形成抗蚀剂图案的方法。 该方法是通过包含(a1)(甲基)丙烯酸酯与酸解离性溶解抑制基团的单体混合物进行自由基聚合而制造用作抗蚀剂的(甲基)丙烯酸衍生物聚合物的方法,(a2) 具有内酯单元的(甲基)丙烯酸酯,其中(a1)和(a2)利用化合物使得当在自由基聚合的相同条件下各化合物(a1)和(a2)各自进行均聚时, 在均聚开始10分钟后测定单体比例,最小残余单体比例与最大残余单体比例之间的差异不大于15摩尔%。