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    • 29. 发明授权
    • Method for catalytic reduction of nitrogen oxides
    • 催化还原氮氧化物的方法
    • US07175822B2
    • 2007-02-13
    • US10485072
    • 2002-07-29
    • Tadao Nakatsuji
    • Tadao Nakatsuji
    • B01D53/56
    • B01J21/063B01D53/9413B01D2255/1021B01D2255/1025B01D2255/2065B01D2255/2066B01D2255/20738B01D2255/20746B01D2255/20753B01D2255/20784B01J23/63B01J23/894B01J37/0244
    • The invention provides a catalyst structure for catalytic reduction of nitrogen oxides in exhaust gases by supplying and subjecting fuel to combustion with periodic rich/lean excursions and contacting the resulting exhaust gases with the catalyst structure, wherein the catalyst structure comprises, on an inactive substrate: (A) an outer catalyst layer comprising an outer layer catalyst component wherein the outer layer catalyst component comprises a first catalyst component comprising a mixture or a composite oxide (except mixtures or composite oxides of cerium oxides and zirconium oxides) of (a) ceria and (b) at least one oxide of at least one element selected from zirconium, gadolinium, terbium, samarium and lanthanum, and a second catalyst component comprising (c) at least one catalyst component selected from rhodium, palladium and their oxides, and (B) an inner catalyst layer comprising an inner layer catalyst component wherein the inner layer catalyst component comprises (a) at least one catalyst component selected from platinum, rhodium, palladium and their oxides, and (b) a carrier material.
    • 本发明提供了一种催化还原废气中的氮氧化物的催化剂结构,该催化剂结构通过以周期性的富/贫偏移供应和使燃料燃烧并使得到的废气与催化剂结构接触,其中催化剂结构包含在非活性基底上: (A)包含外层催化剂组分的外催化剂层,其中外层催化剂组分包括第一催化剂组分,其包含(a)二氧化铈和(a)二氧化铈的混合物或复合氧化物(氧化铈和氧化锆的混合物或复合氧化物) (b)选自锆,钆,铽,钐和镧中的至少一种元素的至少一种氧化物和第二催化剂组分,其包含(c)至少一种选自铑,钯及其氧化物的催化剂组分和(B )包含内层催化剂组分的内催化剂层,其中所述内层催化剂组分包含(a) 一种选自铂,铑,钯及其氧化物的催化剂组分,和(b)载体材料。