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21. 发明授权

US06500537B1 Non-sticking composite materials for office automation equipment 失效
标题翻译：办公自动化设备不粘复合材料
公开(公告)号：US06500537B1
公开(公告)日：2002-12-31
申请号：US09423045
申请日：2000-01-21
申请人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Hisato Sanemasa , Tetsuo Shimizu
发明人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Hisato Sanemasa , Tetsuo Shimizu
IPC分类号： B32B2732
CPC分类号： G03G15/0233 , C08F214/184 , C09D127/18 , C09J127/12 , G03G15/1685 , G03G15/2057 , Y10T428/2878 , Y10T428/3154 , Y10T428/31931
摘要： A non-sticking composite material for office automation equipment which is produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and is excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain removing property, chemical resistance, rust-preventive property, antibacterial property, resistance to energy ray and abrasion resistance. The non-sticking composite material for office automation equipment is produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group.
摘要翻译：一种用于办公自动化设备的不粘合复合材料，其通过向基材施加包含具有优异粘合性的含氟聚合物的材料而不需要复杂的步骤并且具有优异的耐热性，不粘附性防污性，防油斥性，除污性，耐化学腐蚀性，防锈性，抗菌性，耐光能耐受性和耐磨性。办公自动化设备用的不粘合复合材料是通过将具有官能团的含氟乙烯性聚合物的材料应用于基材而制造的，该材料通过以下方法制备：（a）将0.05〜30摩尔％含有至少一个选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基的官能团的含氟乙烯性单体，和（b）70〜99.95摩尔％的氟 - 含有不具有官能团的烯属单体。

22. 发明申请

US20060008652A1 Curable fluorine-containing polymer, curable resin composition prepared from same and antireflection film 有权
公开(公告)号：US20060008652A1
公开(公告)日：2006-01-12
申请号：US11226355
申请日：2005-09-15
申请人： Takayuki Araki , Mihoko Ohashi , Yoshito Tanaka , Tetsuo Shimizu
发明人： Takayuki Araki , Mihoko Ohashi , Yoshito Tanaka , Tetsuo Shimizu
IPC分类号： B05D3/02 , B32B27/00 , C08F114/18 , C08F118/00
CPC分类号： C09D127/12 , C08F8/00 , C08F8/14 , C08F16/32 , C08F214/18 , C08F290/04 , Y10T428/3154 , C08F14/18
摘要： There are provided a curable fluorine-containing polymer which can realize a high hardness by photo-curing while maintaining a low refractive index, an antireflection film possessing improved scratch resistance and abrasion resistance while maintaining a reflection reducing effect, and an antireflection-treated article provided with such an antireflection film. The curable fluorine-containing polymer has a number average molecular weight of from 500 to 1,000,000 and is represented by the formula (1): AM (1) in which the structural unit M is a structural unit derived from a fluorine-containing ethylenic monomer and represented by the formula (M): wherein X1 and X2 are the same or different and each is H or F; X3 is H, F, CH3 or CF3; X4 and X5 are the same or different and each is H, F or CF3; Rf is an organic group in which 1 to 3 of Y1 (Y1 is a monovalent organic group having 2 to 10 carbon atoms and an ethylenic carbon-carbon double bond at its end) are bonded to a fluorine-containing alkyl group having 1 to 40 carbon atoms or a fluorine-containing alkyl group having 2 to 100 carbon atoms and ether bond; a is 0 or an integer of from 1 to 3; b and c are the same or different and each is 0 or 1, the structural unit A is a structural unit derived from a monomer copolymerizable with the fluorine-containing ethylenic monomer represented by the formula (M), and the structural unit M and the structural unit A are contained in amounts of from 0.1 to 100% by mole and from 0 to 99.9% by mole, respectively.

23. 发明授权

US06908724B2 Fluorine-containing polymer having acid-reactive group and chemically amplifying type photoresist composition prepared from same 有权
标题翻译：具有酸反应性基团的含氟聚合物和由其制备的化学放大型光致抗蚀剂组合物
公开(公告)号：US06908724B2
公开(公告)日：2005-06-21
申请号：US10262893
申请日：2002-10-03
申请人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
发明人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
IPC分类号： G03F7/004 , G03F7/038 , G03F7/039 , G03F7/075
CPC分类号： G03F7/039 , G03F7/0045 , G03F7/0046 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397 , G03F7/0758 , Y10S430/106 , Y10S430/108
摘要： There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom.The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: —(M1)—(M2)—(A)—, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99% by mole of the structural unit M1, from 1 to 99% by mole of the structural unit M2 and from 0 to 98% by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.
摘要翻译：提供了一种具有酸反应性基团的新型含氟聚合物，其具有对真空紫外区域（157nm）中的能量射线（放射线）的高透明性，并且还提供了含氟基础聚合物由聚合物制备并适用于由其获得的光致抗蚀剂和化学放大型抗蚀剂组合物。聚合物的数均分子量为1,000〜1,000,000，由下式表示： - （M1） - （M2） - （A） - ，其中M1是具有酸不稳定性或酸可降解官能团的结构单元 M2是含氟丙烯酸酯的结构单元，A是来自其它可共聚单体的结构单元，M1 / M2的摩尔比为1〜99/99〜1，聚合物的含量为1〜99％结构单元M1的摩尔数，结构单元M2的1〜99摩尔％和结构单元A1的0〜98摩尔％。含氟基础聚合物的材料包括具有酸反应性基团的含氟聚合物如上述聚合物，并且适用于光致抗蚀剂，化学放大型抗蚀剂组合物由那些聚合物和材料获得。

24. 发明授权

US06838139B2 Heat-resistant material and coating material for OA equipments having flexibility 有权
标题翻译：具有柔性的OA设备的耐热材料和涂料
公开(公告)号：US06838139B2
公开(公告)日：2005-01-04
申请号：US10241490
申请日：2002-09-12
申请人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Norihito Otsuki , Masami Kato , Tetsuo Shimizu
发明人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Norihito Otsuki , Masami Kato , Tetsuo Shimizu
IPC分类号： C08F214/26 , C08F293/00 , C08L53/00 , C09D153/00 , G03G15/20 , B32B27/00
CPC分类号： C08F214/262 , C08F293/00 , C08L53/00 , C09D153/00 , G03G15/2057 , Y10T428/1352
摘要： It is possible to provide the heat resistant material and coating material for OA equipment which comprise a fluorine-containing multi-segment polymer having heat resistance, abrasion resistance, non-sticking property against toner and oil resistance in addition to flexibility and are used particularly on surfaces of fuser roll and belt. Those materials comprise a fluorine-containing multi-segment polymer having an elastomeric fluorine-containing polymer chain segment A and a non-elastomeric fluorine-containing polymer chain segment B, and the elastomeric fluorine-containing polymer chain segment A comprises not less than 90% by mole of perhaloolefin unit as a recurring unit and imparts flexibility to the whole polymer.
摘要翻译：可以提供包含含氟多层聚合物的OA设备的耐热材料和涂层材料，其具有耐热性，耐磨性，对调色剂的不粘附性和耐油性以及柔性，并且特别用于定影辊和皮带的表面。这些材料包括具有弹性体含氟聚合物链段A和非弹性含氟聚合物链段B的含氟多段聚合物，弹性体含氟聚合物链段A包含不少于90％的全卤代烯烃单元作为重复单元，并赋予整个聚合物柔性。

25. 发明授权

US06737164B2 Composite materials for cookware 失效
标题翻译：炊具复合材料
公开(公告)号：US06737164B2
公开(公告)日：2004-05-18
申请号：US09380499
申请日：1999-09-03
申请人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Hisato Sanemasa , Tetsuo Shimizu
发明人： Takayuki Araki , Yoshito Tanaka , Masahiro Kumegawa , Noritoshi Oka , Hisato Sanemasa , Tetsuo Shimizu
IPC分类号： B32B2708
CPC分类号： A47J36/02 , C08F214/20 , C08F216/04 , C08F220/00 , C09D127/12 , C09D127/18 , Y10T428/3154 , Y10T428/31544
摘要： Composite materials for cooking apparatuses which are produced by applying, to a substrate, a material comprising a fluorine-containing polymer having an excellent adhesive property to the substrate without necessitating complicated steps and are excellent in heat resistance, non-sticking property, stain-proofing property, water- and oil-repelling property, stain-removing property, chemical resistance, rust-preventing property, antibacterial property, resistance to energy ray and abrasion resistance. The composite materials for cooking apparatuses are produced by applying, to the substrate, the material comprising a fluorine-containing ethylenic polymer having functional group which is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of hydroxyl, carboxyl, a carboxylic salt group, a carboxylic ester group and epoxy, and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers having no functional group mentioned above.
摘要翻译：用于烹饪设备的复合材料是通过向衬底施加包含具有优异粘合性的含氟聚合物的材料而制成的，而不需要复杂的步骤，并且具有优异的耐热性，不粘附性，防污染性性能，防油和排斥性能，去污性，耐化学腐蚀性，防锈性，抗菌性，耐光能和耐磨性。用于烹饪设备的复合材料是通过向基材施加含有具有官能团的含氟乙烯性聚合物的材料制造的，所述官能团通过使（a）0.05〜30摩尔％的含氟乙烯性聚合物中的至少一种具有选自羟基，羧基，羧酸盐基，羧酸酯基和环氧基中的至少一种官能团的单体，和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体，没有上述功能组。

26. 发明授权

US06726994B1 Structural member of fluorine-containing polymer having adhesive property at high temperature and sliding material produced by using same 失效
标题翻译：在高温下具有粘合性的含氟聚合物的结构构件和使用它的滑动材料
公开(公告)号：US06726994B1
公开(公告)日：2004-04-27
申请号：US09856066
申请日：2001-05-17
申请人： Takayuki Araki , Tsuyoshi Miyamori , Masaji Komori , Yoshito Tanaka , Masahiro Kumegawa
发明人： Takayuki Araki , Tsuyoshi Miyamori , Masaji Komori , Yoshito Tanaka , Masahiro Kumegawa
IPC分类号： B32B1508
CPC分类号： B32B27/08 , B32B27/06 , B32B27/20 , B32B2307/306 , B32B2323/04 , B32B2379/08 , C09D161/06 , C09D179/08 , C10M169/00 , C10M2201/041 , C10M2201/066 , C10M2213/062 , C10M2217/0403 , C10M2217/0443 , C10N2230/06 , C10N2240/02 , C10N2250/141 , C23C28/00 , F16C33/201 , H01G7/021 , Y02T10/7022 , Y10T428/31504 , Y10T428/31533 , Y10T428/3154 , Y10T428/31544 , Y10T428/31678 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31942
摘要： The structural member of the present invention comprises (A) a layer which comprises a fluorine-containing polymer and does not contain an adhesive material other than the fluorine-containing polymer substantially and (B) a substrate, in which the layer (A) is adhered directly to the substrate (B) without interposing a binder therebetween and a longitudinal shear strength between the layer (A) comprising a fluorine-containing polymer and the substrate (B) is not less than 0.98 N/mm2 at 150° C. The structural member comprising a fluorine-containing polymer and a substrate adhered to each other, particularly the structural member having improved adhesive strength at high temperature and the sliding material produced by using the structural member are provided.
摘要翻译：本发明的结构体包含（A）包含含氟聚合物的层，基本上不含含氟聚合物以外的粘合剂材料，（B）基材，其中层（A）为在不插入粘合剂的情况下直接粘附到基板（B）上，并且包括含氟聚合物的层（A）和基板（B）之间的纵向剪切强度在150°时不小于0.98N / mm 2 C.包含含氟聚合物和彼此粘合的基材的结构件，特别是具有改善的高温粘合强度的结构件和使用结构件制成的滑动材料。

27. 发明授权

US06479161B1 Fluorine-containing adhesive and adhesive film and laminated article made by using the same 有权
标题翻译：含氟粘合剂和粘合膜以及使用它们制成的层压制品
公开(公告)号：US06479161B1
公开(公告)日：2002-11-12
申请号：US09425000
申请日：1999-12-03
申请人： Takayuki Araki , Shigehito Sagisaka , Yoshito Tanaka , Masahiro Kumegawa
发明人： Takayuki Araki , Shigehito Sagisaka , Yoshito Tanaka , Masahiro Kumegawa
IPC分类号： B32B2704
CPC分类号： B32B1/08 , B32B7/12 , B32B15/043 , C09J127/16 , Y10T428/3154 , Y10T428/31544 , Y10T428/31649 , Y10T428/31699 , Y10T428/31743 , Y10T428/3175 , Y10T428/31855 , Y10T428/31909
摘要： A fluorine-containing adhesive comprising a fluorine-containing ethylenic polymer (A) having functional group which has a crystalline melting point or glass transition temperature of not more than 270° C. and is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of carboxyl and a carboxylic salt group and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have the above-mentioned functional group and is copolymerizable with the component (a). To provide the fluorine-containing adhesive maintaining chemical resistance, solvent resistance, weather resistance and stain-proofing property and giving direct strong adhesion particularly to a substrate of metal, glass, resin, etc. and an adhesive film and laminated article which are produced from the fluorine-containing adhesive.
摘要翻译：含有具有官能团的含氟乙烯性聚合物（A）的含氟粘合剂，其具有结晶熔点或玻璃化转变温度不高于270℃，并且通过（a）0.05〜30摩尔％的至少一种具有至少一个选自羧基和羧酸盐基团的官能团的含氟乙烯性单体和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体，其中，不具有上述官能团并且可与组分（a）共聚。提供维持耐化学性，耐溶剂性，耐候性和防污性的含氟粘合剂，特别是对金属，玻璃，树脂等的基材和粘合剂膜和层压制品的直接强粘合性，其由含氟粘合剂。

28. 发明授权

US07211635B2 Optical material containing curable fluorine-containing polymer 有权
标题翻译：含有可固化含氟聚合物的光学材料
公开(公告)号：US07211635B2
公开(公告)日：2007-05-01
申请号：US10654971
申请日：2003-09-05
申请人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
发明人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
IPC分类号： C08F16/24
CPC分类号： C08K5/0091 , C08K5/098 , G02B6/1221 , H01S3/17 , H01S3/178 , C08L27/12
摘要： There can be obtained a suitable optical material which has a stable structure with a rare earth metal ion while maintaining transparency in a region of from visible light to near infrared light. The optical material is obtained by curing a fluorine-containing resin composition comprising (I) a fluorine-containing prepolymer and (II) a compound containing a rare earth metal ion and/or a rare earth metal element, wherein the fluorine-containing prepolymer (I) is a curable fluorine-containing polymer which: (1) is a non-crystalline polymer having a fluorine content of not less than 25% by weight and (2) has a cure site in a side chain of the polymer and/or at an end of a trunk chain of the polymer.
摘要翻译：可以获得具有稀土金属离子稳定结构的合适的光学材料，同时保持从可见光到近红外光的区域的透明度。光学材料通过固化含有（I）含氟预聚物和（II）含有稀土金属离子和/或稀土金属元素的化合物的含氟树脂组合物而获得，其中含氟预聚物（ I）是可固化的含氟聚合物，其中：（1）是氟含量不小于25重量％的非结晶聚合物，和（2）在聚合物的侧链中具有固化位点和/或在聚合物的主链的末端。

29. 发明授权

US07106940B2 Fluorine-containing material for optical waveguide 失效
标题翻译：用于光波导的含氟材料
公开(公告)号：US07106940B2
公开(公告)日：2006-09-12
申请号：US11043204
申请日：2005-01-27
申请人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
发明人： Takayuki Araki , Yoshito Tanaka , Mihoko Ohashi
IPC分类号： G02B6/138 , G03C1/73
CPC分类号： C08F299/00 , C08F290/00 , G02B6/1221
摘要： There is provided a material which can give a high elasticity and heat resistance to an optical waveguide member by photo-curing while maintaining transparency in a near infrared region and further makes it possible to use a film forming process by a spin coating method and a process for producing a waveguide by photolithograph, to obtain a waveguide having a large area and to produce an optical waveguide having reduced water absorption, and further there can be provided an optical waveguide member and an optical waveguide device. Namely, there are provided a fluorine-containing optical waveguide material comprising a curable fluorine-containing prepolymer (I) which is a non-crystalline polymer having a fluorine content of not less than 25% by weight and has a carbon-carbon double bond in a polymer side chain and/or at an end of a polymer trunk chain, an optical waveguide member which is a cured article of the optical waveguide material and an optical waveguide device comprising the optical waveguide member.
摘要翻译：提供了一种能够通过光固化赋予光波导构件高弹性和耐热性的材料，同时保持近红外区域的透明性，并且还可以通过旋涂法和方法使用成膜方法通过光刻制造波导，得到面积大的波导管，制造吸水率降低的光波导，并且还可以提供光波导部件和光波导器件。即，提供了含氟系预聚物（I）的含氟光波导材料，其为氟含量为25重量％以上且具有碳 - 碳双键的非结晶性聚合物聚合物侧链和/或在聚合物主链的末端，作为光波导材料的固化物的光波导部件和包括光波导部件的光波导装置。

30. 发明申请

US20050287471A1 Novel fluorine-containing polymer having acid-reactive group and chemically amplifying type photoresist composition prepared from same 审中-公开
标题翻译：具有酸反应性基团的新型含氟聚合物和由其制备的化学放大型光致抗蚀剂组合物
公开(公告)号：US20050287471A1
公开(公告)日：2005-12-29
申请号：US11033954
申请日：2005-01-13
申请人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
发明人： Takayuki Araki , Meiten Koh , Yoshito Tanaka , Takuji Ishikawa , Hirokazu Aoyama , Tetsuo Shimizu
IPC分类号： G03F7/004 , G03F7/038 , G03F7/039 , G03F7/075 , G03C1/76
CPC分类号： G03F7/039 , G03F7/0045 , G03F7/0046 , G03F7/0382 , G03F7/0392 , G03F7/0395 , G03F7/0397 , G03F7/0758 , Y10S430/106 , Y10S430/108
摘要： There is provided a novel fluorine-containing polymer having an acid-reactive group which has a high transparency against energy rays (radioactive rays) in a vacuum ultraviolet region (157 nm), and further there are provided a material for fluorine-containing base polymer prepared from the polymer and suitable for a photoresist and a chemically amplifying type resist composition obtained therefrom. The polymer has a number average molecular weight of from 1,000 to 1,000,000 and represented by the formula: -(M1)-(M2)-(A)-, wherein M1 is a structural unit having an acid-labile or acid-degradable functional group, M2 is a structural unit of fluorine-containing acryl ester, A is a structural unit derived from other copolymerizable monomer, the percent by mole ratio M1/M2 is 1 to 99/99 to 1 and the polymer comprises from 1 to 99% by mole of the structural unit M1, from 1 to 99% by mole of the structural unit M2 and from 0 to 98% by mole of the structural unit A1. The material for fluorine-containing base polymer comprises a fluorine-containing polymer having an acid-reactive group such as the above-mentioned polymer and is suitable for a photoresist, and the chemically amplifying type resist composition is obtained from those polymer and material.
摘要翻译：提供了一种具有酸反应性基团的新型含氟聚合物，其具有对真空紫外区域（157nm）中的能量射线（放射线）的高透明性，并且还提供了含氟基础聚合物由聚合物制备并适用于由其获得的光致抗蚀剂和化学放大型抗蚀剂组合物。聚合物的数均分子量为1,000〜1,000,000，由下式表示： - （M1） - （M2） - （A） - ，其中M1是具有酸不稳定性或酸可降解官能团的结构单元 M2是含氟丙烯酸酯的结构单元，A是来自其它可共聚单体的结构单元，M1 / M2的摩尔比为1〜99/99〜1，聚合物的含量为1〜99％结构单元M1的摩尔数，结构单元M2的1〜99摩尔％和结构单元A1的0〜98摩尔％。含氟基础聚合物的材料包括具有酸反应性基团的含氟聚合物如上述聚合物，并且适用于光致抗蚀剂，化学放大型抗蚀剂组合物由那些聚合物和材料获得。

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