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21. 发明授权

US06733658B2 EU-1 zeolite catalyst and a process for the reduction of the pour point of feeds containing paraffins 失效
标题翻译： EU-1沸石催化剂和降低含有链烷烃的进料的倾点的方法
公开(公告)号：US06733658B2
公开(公告)日：2004-05-11
申请号：US09103528
申请日：1998-06-24
申请人： Eric Benazzi , Nathalie George-Marchal , Christophe Gueret , Patrick Briot , Alain Billon , Pierre Marion
发明人： Eric Benazzi , Nathalie George-Marchal , Christophe Gueret , Patrick Briot , Alain Billon , Pierre Marion
IPC分类号： C10G4716
CPC分类号： B01J29/7023 , B01J29/04 , B01J29/7446 , B01J29/7846 , B01J2229/16 , B01J2229/32 , B01J2229/37 , B01J2229/42 , C01B39/026 , C10G45/64 , C10G2300/1022 , C10G2300/1048 , C10G2300/1059 , C10G2300/1077 , C10G2300/301 , C10G2300/304 , C10G2300/4018
摘要： The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising an EU-1 zeolite and at least one hydro-dehydrogenating element, at a temperature which is in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils and other feeds requiring a reduction of pour point. The invention also concerns an EU-1 zeolite from which a portion of elements T (Al, Ga, Fe or B) have been removed and which has an Si/T atomic ratio of at least 10.
摘要翻译：本发明涉及一种改进含有多于10个碳原子的链烷烃的进料的倾点的方法，其中待处理的进料与包含EU-1沸石的催化剂和至少一种加氢脱氢的催化剂接触元素，温度范围为170℃至500℃，压力范围为1至250巴，小时空间速度为0.05至100小时-1，在存在氢气比例为50〜2000升/升饲料。所得油具有良好的倾点和高粘度指数（VI）。该方法也适用于需要降低倾点的瓦斯油和其他进料。本发明还涉及一部分元素T（Al，Ga，Fe或B）被去除并且其Si / T原子比至少为10的EU-1沸石。

22. 发明授权

US06198015B1 Catalyst based on a molecular sieve and a process for selective hydroisomerisation of long linear and/or slightly branched paraffins using that catalyst 失效
标题翻译：基于分子筛的催化剂和使用该催化剂的长线性和/或稍微支化的链烷烃的选择性加氢异构化的方法
公开(公告)号：US06198015B1
公开(公告)日：2001-03-06
申请号：US09034350
申请日：1998-03-04
申请人： Christian Marcilly , Eric Benazzi , Nathalie George-Marchal
发明人： Christian Marcilly , Eric Benazzi , Nathalie George-Marchal
IPC分类号： C07C513
CPC分类号： C10G45/64 , B01J29/46
摘要： The invention concerns a process for selective hydroisomerization of compounds with an n-alkane chain containing more than 10 carbon atoms, in which the compound to be treated is brought into contact with a catalyst comprising at least one hydro-dehydrogenating element and at least one molecular sieve having a one- or two-dimensional pore network, the accessible pore openings of which are delimited by 10 oxygen atoms, and a distance termed the bridging distance between the pores of less then 0.70 nm, and the zeolite is such that a catalyst which undergoes a standard n-heptadecane isomerization test has, for a conversion of 95%, a selectivity of at least 70% for isomerized products, and the catalyst contains at least 5% by weight of at least one hydro-dehydrogenating element selected from the group formed by non noble GVIII metals, GVIB metals, and niobium, and the catalyst preferably contains phosphorous. The sieve is preferably a NU-10, NU-23, NU-87, EU-13 or Theta-1 zeolite.
摘要翻译：本发明涉及一种使含有多于10个碳原子的正烷烃链选择性加氢异构化的方法，其中待处理化合物与包含至少一个加氢脱氢元素的催化剂和至少一个分子具有一维或二维孔网的筛，其可及孔的开口由10个氧原子界定，并且称为孔之间的桥接距离小于0.70nm的距离，并且沸石使得催化剂进行标准的正十七烷异构化试验对于异构化产物具有至少70％的选择性为95％的转化率，并且催化剂含有至少5重量％的至少一种选自组中的加氢脱氢元件由非贵金属GVIII金属，GVIB金属和铌形成，并且催化剂优选含有磷。筛优选为NU-10，NU-23，NU-87，EU-13或Theta-1沸石。

23. 发明授权

US06221239B1 Process for transforming a gas oil cut to produce a dearomatised and desulphurised fuel with a high cetane number 有权
标题翻译：用于转换瓦斯油切割以产生具有高十六烷值的脱芳香和脱硫燃料的方法
公开(公告)号：US06221239B1
公开(公告)日：2001-04-24
申请号：US09480628
申请日：2000-01-10
申请人： Frédéric Morel , Henri Delhomme , Nathalie George-Marchal
发明人： Frédéric Morel , Henri Delhomme , Nathalie George-Marchal
IPC分类号： C10G6508
CPC分类号： C10G65/08 , C10G2400/04
摘要： A process for transforming a gas oil cut into a dearomatised fuel with a high cetane number comprises at least one first, deep desulphurisation and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatisation, in which the desulphurised and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.
摘要翻译：将切割成具有高十六烷值的脱芳构化燃料的瓦斯油转化的方法包括至少一个第一，深度脱硫和深度脱氮步骤，其中瓦斯油馏分和氢气通过包含矿物载体的催化剂，至少一种 VIB族金属或金属化合物，至少一种VIII族金属或金属化合物，以及磷或至少一种磷化合物，以及至少一个随后的第二步，脱芳化，其中来自第一步骤的脱硫和脱氮产物通过氢气在包含矿物载体和至少一种VIII族贵金属或贵金属化合物的催化剂上。

24. 发明授权

US6042716A Process for transforming a gas oil cut to produce a dearomatised and desulphurised fuel with a high cetane number 失效
标题翻译：用于转换瓦斯油切割以产生具有高十六烷值的脱芳香和脱硫燃料的方法
公开(公告)号：US6042716A
公开(公告)日：2000-03-28
申请号：US992486
申请日：1997-12-18
申请人： Frederic Morel , Henri Delhomme , Nathalie George-Marchal
发明人： Frederic Morel , Henri Delhomme , Nathalie George-Marchal
IPC分类号： B01J23/42 , B01J27/19 , C10G45/08 , C10G45/52 , C10G65/08 , C10G69/02
CPC分类号： C10G65/08 , C10G2400/04
摘要： A process for transforming a gas oil cut into a dearomatized fuel with a high cetane number comprises at least one first, deep desulphurization and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatization, in which the desulphurized and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.
摘要翻译：将切割成含有高十六烷值的脱气燃料的瓦斯油转化为至少一个第一，深度脱硫和深度脱氮步骤，其中将所述瓦斯油馏分和氢气通过含有矿物载体的催化剂，至少一种 VIB族金属或金属化合物，至少一种VIII族金属或金属化合物，以及磷或至少一种磷化合物，以及至少一个随后的第二步，脱芳化，其中来自第一步骤的脱硫和脱氮产物通过，氢气在包含矿物载体和至少一种VIII族贵金属或贵金属化合物的催化剂上。

25. 发明授权

US06451198B2 Process for transforming a gas oil cut to produce a dearomatized and desulphurized fuel with a high cetane number 有权
标题翻译：用于转换瓦斯油切割以产生具有高十六烷值的脱芳烃和脱硫燃料的方法
公开(公告)号：US06451198B2
公开(公告)日：2002-09-17
申请号：US09813946
申请日：2001-03-22
申请人： Frédéric Morel , Henri Delhomme , Nathalie George-Marchal
发明人： Frédéric Morel , Henri Delhomme , Nathalie George-Marchal
IPC分类号： C10G6508
CPC分类号： C10G65/08 , C10G2400/04
摘要： A process for transforming a gas oil cut into a dearomatized fuel with a high cetane number comprises at least one first, deep desulphurization and deep denitrogenation step in which the gas oil cut and hydrogen are passed over a catalyst comprising a mineral support, at least one group VIB metal or metal compound, at least one group VIII metal or metal compound, and phosphorous or at least one phosphorous compound, and at least one subsequent second step, dearomatization, in which the desulphurized and denitrogenated product from the first step is passed with hydrogen over a catalyst comprising a mineral support and at least one group VIII noble metal or noble metal compound.
摘要翻译：将切割成含有高十六烷值的脱气燃料的瓦斯油转化为至少一个第一，深度脱硫和深度脱氮步骤，其中将所述瓦斯油馏分和氢气通过含有矿物载体的催化剂，至少一种 VIB族金属或金属化合物，至少一种VIII族金属或金属化合物，以及磷或至少一种磷化合物，以及至少一个随后的第二步，脱芳化，其中来自第一步骤的脱硫和脱氮产物通过，氢气在包含矿物载体和至少一种VIII族贵金属或贵金属化合物的催化剂上。

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