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21. 发明授权

US07795347B2 Multi-branched polymer, process for producing the same, and applications thereof 有权
标题翻译：多支化聚合物，其制备方法及其应用
公开(公告)号：US07795347B2
公开(公告)日：2010-09-14
申请号：US10797144
申请日：2004-03-11
申请人： Hideyuki Kaneko , Tomoaki Matsugi , Shin-Ichi Kojoh , Shingo Matsuo , Nobuo Kawahara , Norio Kashiwa
发明人： Hideyuki Kaneko , Tomoaki Matsugi , Shin-Ichi Kojoh , Shingo Matsuo , Nobuo Kawahara , Norio Kashiwa
IPC分类号： C08F10/00 , C08F255/00 , C08F293/00 , C08F295/00
CPC分类号： C08F290/042
摘要： A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.
摘要翻译：通过聚合或反应各种极性单体和各种极性单体的组合，有效地制备了包含多个聚烯烃链和极性聚合物链并具有多支链结构的一组聚合物，例如嵌段结构，接枝结构和星形结构，它们的聚合物即通过使用含官能团的聚烯烃作为大分子引发剂，大分子单体或反应性聚合物的极性聚合物链。得到的多支链聚合物具有块状结构，接枝结构或星形结构等特定形状，具有聚烯烃和极性聚合物两者的性质，因此在膜和相容剂的各种用途中表现出有用的性能，如一种新型聚烯烃基聚合物。

22. 发明申请

US20090043050A1 PROPYLENE COPOLYMER, POLYPROPYLENE COMPOSITION AND USES THEREOF, TRANSITION METAL COMPOUND AND OLEFIN POLYMERIZATION CATALYST 有权
标题翻译：丙烯共聚物，聚丙烯组合物及其用途，过渡金属化合物和烯烃聚合催化剂
公开(公告)号：US20090043050A1
公开(公告)日：2009-02-12
申请号：US12185547
申请日：2008-08-04
申请人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Hoya , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
发明人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Hoya , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
IPC分类号： C08L23/20
CPC分类号： C08F210/06 , C08F4/65927 , C08L23/142 , Y10S428/91 , Y10S526/943 , Y10T428/1328 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938 , C08L2666/06 , C08F210/08 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/26
摘要： A polypropylene composition containing a propylene/1-butene random copolymer which contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point of from 40 to 75° C. and a crystallization rate at 45° C. of 10 minutes or less, and satisfying the following relation, 146 exp (−0.022M)≧Tm≧125 exp (−0.032M), and an olefin catalyst for preparation thereof.
摘要翻译：一种含丙烯-1-丁烯无规共聚物的聚丙烯组合物，其含有60〜90摩尔％的丙烯单元和10〜40摩尔％的1-丁烯单元，三重态全同立构规整度为85％以上97.5％以下，，分子量分布为1至3，特性粘度为0.1至12dl / g，熔点为40至75℃，结晶速率为45℃为10分钟以下，以及满足以下关系：146exp（-0.022M）> = Tm> = 125exp（-0.032M），以及用于其制备的烯烃催化剂。

23. 发明申请

US20080312461A1 PROPYLENE COPOLYMER, POLYPROPYLENE COMPOSITION AND USES THEREOF, TRANSITION METAL COMPOUND AND OLEFIN POLYMERIZATION CATALYST 有权
标题翻译：丙烯共聚物，聚丙烯组合物及其用途，过渡金属化合物和烯烃聚合催化剂
公开(公告)号：US20080312461A1
公开(公告)日：2008-12-18
申请号：US12185555
申请日：2008-08-04
申请人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Takayasu , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kwawi , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
发明人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Takayasu , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kwawi , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
IPC分类号： C07F17/00
CPC分类号： C08F210/06 , C08F4/65927 , C08L23/142 , Y10S428/91 , Y10S526/943 , Y10T428/1328 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938 , C08L2666/06 , C08F210/08 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/26
摘要： A transition metal compound represented by the following formula (2a):
摘要翻译：由下式（2a）表示的过渡金属化合物：

24. 发明申请

US20060276607A1 Propylene copolymer, polypropylene composition, and uses thereof, transition metal compounds and catalyst for olefin polymerization 有权
公开(公告)号：US20060276607A1
公开(公告)日：2006-12-07
申请号：US10550017
申请日：2003-12-26
申请人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Takayasu , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
发明人： Shigenobu Ikenaga , Keiji Okada , Hiroshi Takayasu , Norihide Inoue , Naritoshi Hirota , Hiromu Kaneyoshi , Munehito Funaya , Koji Kawai , Nobuo Kawahara , Shinichi Kojoh , Norio Kashiwa , Ryoji Mori
IPC分类号： C08F110/14 , C08F210/04
CPC分类号： C08F210/06 , C08F4/65927 , C08L23/142 , Y10S428/91 , Y10S526/943 , Y10T428/1328 , Y10T428/31909 , Y10T428/31913 , Y10T428/31938 , C08L2666/06 , C08F210/08 , C08F2500/15 , C08F2500/03 , C08F2500/17 , C08F2500/26
摘要： The present invention provides a propylene/1-butene random copolymer (PBR) having excellent flexibility, impact resistance, heat resistance and low-temperature heat-seal properties, a polypropylene composition containg the copolymer, a sheet, film or stretched film comprising the composition and a composite film having a layer of the composition. The propylene/1-butene random copolymer contains 60 to 90 mol % of propylene units and 10 to 40 mol % of 1-butene units and has a triad isotacticity of not less than 85% and not more than 97.5%, a molecular weight distribution (Mw/Mn) of from 1 to 3, an intrinsic viscosity of from 0.1 to 12 dl/g, a melting point (Tm) of from 40 to 120° C., and satisfies the following relation 146 exp(−0.022M)≧Tm≧125 exp(−0.032M) wherein Tm represents a melting point and M (mol %) represents a content of 1-butene constituent units. The invention, further, provides a transition metal compound useful as an olefin polymerization catalyst and an olefin polymerization catalyst containing the transition metal compound. The transition metal compound is represented by the following formula (2a): wherein each of R1 and R3 is hydrogen, R2 and R4 are selected from a hydrocarbon group and silicon-containing group, R5 to R13 are selected from hydrogen, a hydrocarbon group and silicon-containing group, and adjacent substituent groups R5 to R12 may be linked to form a ring. R14 is an aryl group, and R13 and R14 may be linked to form a ring. M is a Group 4 transition metal, Y is a carbon atom, Q is halogen, etc, and j is an integer of 1 to 4.

25. 发明授权

US5654248A Catalyst for polymerizing alpha-olefins and process for polymerization 失效
标题翻译：用于聚合α-烯烃的催化剂和聚合方法
公开(公告)号：US5654248A
公开(公告)日：1997-08-05
申请号：US433545
申请日：1995-05-02
申请人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
发明人： Mamoru Kioka , Akinori Toyota , Norio Kashiwa , Toshiyuki Tsutsui
IPC分类号： C08F4/02 , C08F4/60 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/10 , C08F110/02 , B01J31/00 , B01J37/00
CPC分类号： C08F10/10 , C08F110/02 , C08F4/65912 , C08F4/65916 , C08F4/65925
摘要： A prepolymerized solid catalyst for gaseous phase or slurry polymerization of alpha olefins is disclosed. The catalyst comprises a porous carrier having a particle size of 20 to 200 microns onto which has been deposited an aluminoxane and a transition metal compound having at least one cycloalkadienyl group, the transition metal being from group 4 of the Periodic Table. The transition metal is present in an amount of 0.003 to 3 mmol/gm of carrier, and the aluminum to transition metal atomic ratio is from 15 to 1000. This catalyst is then prepolymerized with 0.2 to 30 gm of an alpha olefin per gram of catalyst to form the final prepolymerized solid catalyst having an intrinsic viscosity of 0.2 to 20 dl/gm as measured in decalin at 135 deg C.
摘要翻译：公开了一种用于α-烯烃的气相或淤浆聚合的预聚合固体催化剂。催化剂包括粒径为20-200微米的多孔载体，其上沉积有铝氧烷和具有至少一个环二烯基的过渡金属化合物，过渡金属来自元素周期表第4族。过渡金属的存在量为0.003至3mmol / gm的载体，铝与过渡金属的原子比为15至1000.然后将该催化剂与每克催化剂0.2至30gm的α-烯烃预聚合以形成在135℃萘烷中测得的特性粘度为0.2-20dl / gm的最终预聚固体催化剂

26. 发明授权

US5523358A Modified polyolefin particles and process for preparation thereof 失效
标题翻译：改性聚烯烃颗粒及其制备方法
公开(公告)号：US5523358A
公开(公告)日：1996-06-04
申请号：US235419
申请日：1994-04-22
申请人： Toshiyuki Hirose , Hajime Inagaki , Mamoru Kioka , Akinori Toyota , Norio Kashiwa
发明人： Toshiyuki Hirose , Hajime Inagaki , Mamoru Kioka , Akinori Toyota , Norio Kashiwa
IPC分类号： C08F255/00 , C08J3/09 , C08J3/11 , C08L23/26
CPC分类号： C08F255/00
摘要： A process for preparation of modified polyolefin particles which comprises contacting and reacting(A) 100 wt. parts of polyolefin particles with(B) 0.01 to 50 wt. parts of at least one ethylenic unsaturated compound selected from the group consisting of carboxyl group-containing ethylenic unsaturated compounds or their carboxylic anhydrides or their carboxylic acid derivatives, hydroxyl group-containing ethylenic unsaturated compounds, amino-group-containing ethylenic unsaturated compounds, and glycidyl group-containing ethylenic unsaturated compounds,in the presence of(C) more than 10 wt. parts to not more than 50 wt. parts of a medium of a liquid state at ordinary temperature whose solubility in water at 20.degree. C. is 0.5 wt. % or less and which is capable of swelling the polyolefin, and(D) 0.01 to 10 wt. parts of a radical initiator; andmodified polyolefin particles prepared by the aforesaid process.
摘要翻译：一种制备改性聚烯烃颗粒的方法，其包括使（A）100重量％（B）0.01〜50wt。至少一种选自含羧基的烯属不饱和化合物或其羧酸酐或其羧酸衍生物，含羟基的烯属不饱和化合物，含氨基的烯属不饱和化合物和缩水甘油基中的至少一种烯属不饱和化合物在（C）大于10重量％存在下，含有基团的烯属不饱和化合物。部分至不超过50wt。常温下液态介质的一部分在20℃下在水中的溶解度为0.5wt。％以下，能够使聚烯烃溶胀，（D）0.01〜10重量％部分自由基引发剂; 和通过上述方法制备的改性聚烯烃颗粒。

27. 发明授权

US5028671A Process for polymerization of olefins and polymerization catalyst 失效
标题翻译：烯烃和聚合催化剂聚合方法
公开(公告)号：US5028671A
公开(公告)日：1991-07-02
申请号：US430081
申请日：1989-11-01
申请人： Mamoru Kioka , Norio Kashiwa
发明人： Mamoru Kioka , Norio Kashiwa
IPC分类号： C08F4/64 , C08F4/646 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： A catalyst formed from(A) a solid titanium catalyst component containing magnesium, titanium, halogen and a polycarboxylic acid ester as essential ingredients and being obtained by contacting a magnesium compound, a titanium compound and a polycarboxylic acid ester,(B) an organoaluminum compound, and(C) an organosilicon compound represented by the following formula (1)SiR.sup.1 R.sup.2 (OR.sup.3).sub.2 (1) wherein R.sup.1 is selected from the class consisting of linear alkyl groups having at least 3 carbon atoms and arylalkyl groups in which the alkyl moiety has a secondary or tertiary alpha-carbon atom, R.sup.2 is selected from the class consisting of alkyl groups and arylalkyl groups in which the alkyl moiety has a secondary or tertiary alpha-carbon atom, and R.sup.3 is a hydrocarbon group, with the proviso that when R.sup.1 is a linear alkyl group having at least 3 carbon atoms and R.sup.2 is an alkyl group, the alkyl group for R.sup.2 is a linear alkyl group having at least 3 carbon atoms,and process for production thereof.

28. 发明授权

US4931526A .alpha.-olefinic random copolymer and production process thereof 失效
标题翻译： α-烯烃无规共聚物及其制备方法
公开(公告)号：US4931526A
公开(公告)日：1990-06-05
申请号：US269577
申请日：1988-11-10
申请人： Junichi Yoshitake , Hiroaki Kitani , Takeshi Muranaka , Akira Mizuno , Norio Kashiwa
发明人： Junichi Yoshitake , Hiroaki Kitani , Takeshi Muranaka , Akira Mizuno , Norio Kashiwa
IPC分类号： C08F4/64 , C08F4/60 , C08F110/14 , C08F210/14 , C08F210/18
CPC分类号： C08F210/14 , C08F110/14
摘要： An .alpha.-olefinic random copolymer containing an .alpha.-olefin component having 5 to 10 carbon atoms and an .alpha.,.omega.-nonconjugated diene component having 6 to 20 carbon atoms, and optionally, a straight .alpha.-olefin component having 2 to 20 carbon atoms, wherein the copolymer comprises:(i) 70 to 99.9% by weight of a recurring unit (a) derived from the .alpha.-olefin, 0.1 to 30% by weight of a recurring unit (b) derived from the .alpha.,.omega.-nonconjugated diene and 0 to 20% by weight of a recurring unit (c) derived from the straight .alpha.-olefin component;(ii) an inherent viscosity [.eta.] measured in decalin at 135.degree. C. of from 0.5 to 10 dl/g;(iii) a crystallinity [Xc] measured by the X-ray diffraction method of from 0 to 50%;(iv) a glass transition temperature [Tg] of from 30.degree. to 60.degree. C.; and(v) an iodine value of from 0 to 10.

29. 发明授权

US4778870A Random 1-butene/ethylene copolymer 失效
标题翻译：随机1-丁烯/乙烯共聚物
公开(公告)号：US4778870A
公开(公告)日：1988-10-18
申请号：US792668
申请日：1985-10-29
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F210/00 , C08F210/08 , C08F210/16
CPC分类号： C08F210/08
摘要： A random 1-butene/ethylene copolymer comprising 1-butene and ethylene, said copolymer having the following characteristics (A) to (I):(A) it comprises 50 to 99 mole % of the 1-butene component and 1 to 50 mole % of the ethylene component,(B) it has an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.5 to 6 dl/g,(C) it has a melting point [Tm], measured by a differential scanning calorimeter, of from 30.degree. to 130.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 1 to 60%,(E) the amount [W.sub.1 in % by weight] of that portion of it which is soluble in boiling methyl acetate is not more than 2%, and(F) the amount [W.sub.2 in % by weight] of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5.times.[.eta.].sup.-1.2.
摘要翻译：包含1-丁烯和乙烯的无规1-丁烯/乙烯共聚物，所述共聚物具有以下特征（A）至（I）：（A）它包含50-99摩尔％的1-丁烯组分和1-50摩尔乙烯成分的％，（B）在135℃萘烷中测定的特性粘度η为0.5〜6dl / g，（C）熔点[Tm] 差示扫描量热仪为30〜130℃，（D）通过X射线衍射法测定的结晶度为1〜60％，（E）[W1重量％以上] 可溶于沸腾乙酸甲酯的那部分不大于2％，（F）其部分的[W2重量％]可溶于1:1体积的丙酮和在10℃的正癸烷小于5×η-1.2。

30. 发明授权

US4726999A Laminated structure comprising a substrate layer composed of a crystalline propylene resin and a heat-sealable layer composed of a crystalline propylene random copolymer composition 失效
标题翻译：包括由结晶丙烯树脂构成的基材层和由结晶丙烯无规共聚物组合物构成的可热封层的层压结构
公开(公告)号：US4726999A
公开(公告)日：1988-02-23
申请号：US792659
申请日：1985-10-29
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： B32B27/32 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/20 , C09J123/10 , C09J123/16 , C08J5/18
CPC分类号： C08L23/142 , B32B27/32 , C08L23/20 , C09J123/10 , C09J123/16 , C08L23/12 , Y10T428/1334 , Y10T428/1352 , Y10T428/265 , Y10T428/2826 , Y10T428/31913
摘要： A laminated structure comprising a substrate layer of a crystalline propylene resin and, positioned in direct contact with at least one surface of said substrate layer, a heat-sealable layer of a crystalline random propylene copolymer composition, wherein the crystalline random propylene copolymer composition is a mixture composed of(I) a crystalline random propylene copolymer of a major amount of propylene with a minor amount of another alpha-olefin, and(II) a random copolymer consisting essentially of more than 60 to 99 mole % of 1-butene and less than 40 to 1 mole % of propylene,the weight ratio of (I)/(II) being from 5/95 to 90/10, and the radom copolymer (II) has(A) an intrinsic viscosity [.eta.], determined in decalin at 135.degree. C., of 0.5 to 6 dl/g,(B) a DSC melting point (Tm), measured by a differential scanning calorimeter, of 50 to 130.degree. C., (C) a degree of crystallinity, measured by X-ray diffractometry, of 5 to 60%,(D) a boiling methyl acetate-soluble content (W.sub.1) of not more than 2% by weight based on the weight of the copolymer (II), and(E) an n-decane/acetone (1:1 by volume) mixture-soluble content (W.sub.2) of less than 4.times.[.eta.].sup.-1.2 in % by weight based on the weight of the copolymer (II);and a crystalline random propylene copolymer composition used for the said laminated structure.
摘要翻译：一种层压结构，其包括结晶丙烯树脂的基底层，并且与所述基底层的至少一个表面直接接触，结晶无规丙烯共聚物组合物的可热封层，其中所述结晶无规丙烯共聚物组合物为由（I）主要量的丙烯与少量另外的α-烯烃的结晶无规丙烯共聚物组成的混合物，和（II）基本上由大于60至99摩尔％的1-丁烯组成的无规共聚物（I）/（II）的重量比为5/95至90/10，天线共聚物（II）的摩尔比为（A）的特性粘度η为在135℃下的十氢化萘为0.5〜6dl / g，（B）通过差示扫描量热计测定的DSC熔点（Tm）为50〜130℃，（C）结晶度，测定通过X射线衍射测定为5〜60％，（D）沸点乙酸甲酯可溶物含量（W1）o f以共聚物（II）的重量计不超过2重量％，和（E）小于4xη的正癸烷/丙酮（体积比1:1）的混合物可溶物含量（W2） -1.2重量％，基于共聚物（II）的重量; 和用于所述层压结构的结晶无规丙烯共聚物组合物。

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