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1. 发明授权

US4764583A Melt-moldable wholly aromatic polyester 失效
标题翻译：可熔融的全芳族聚酯
公开(公告)号：US4764583A
公开(公告)日：1988-08-16
申请号：US24087
申请日：1987-03-10
申请人： Kunisuke Fukui , Masanori Motooka
发明人： Kunisuke Fukui , Masanori Motooka
IPC分类号： C08G63/60 , C08G63/66
CPC分类号： C08G63/605
摘要： A melt-moldable wholly aromatic polyester comprising (A) aromatic hydroxycarboxylic acid residues, (B) aromatic diol residues, (C) 4,4'-dihydroxydiphenyl ether residues represented by the following formula ##STR1## and (D) aromatic dicarboxylic acid residues, and a melt-moldable wholly aromatic polyester comprising (A) aromatic hydroxycarboxylic acid residues, (C)' aromatic diol residues represented by the following formula--O--Ar.sup.4 --O--wherein Ar.sup.4 represents a group at least 60 mole % of which consists of a group of the following formula (a) ##STR2## or a group of the formula (a) and a group of the following formula (b) ##STR3## and (D) aromatic dicarboxylic acid residues.
摘要翻译：包含（A）芳族羟基羧酸残基的可熔融模制的全芳族聚酯，（B）芳族二醇残基，（C）由下式表示的4,4'-二羟基二苯基醚残基和（D）芳族二羧酸残基和可熔融成型的全芳族聚酯，其包含（A）芳族羟基羧酸残基，（C）由下式-O- Ar 4 -O-表示的芳族二醇残基，其中Ar 4表示至少60摩尔％的基团（a）或式（a）的基团和下述式（b）的基团和（D）芳族二羧酸残基组成的组。

2. 发明授权

US4801672A Random 1-butene copolymer 失效
标题翻译：随机1-丁烯共聚物
公开(公告)号：US4801672A
公开(公告)日：1989-01-31
申请号：US792596
申请日：1985-10-29
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08F210/08 , C08F210/14
CPC分类号： C08F210/08
摘要： A random 1-butene copolymer comprising 1-butene and an alpha-olefin having 5 to 20 carbon atoms, said copolymer having the following characteristics (A) to (I):(A) it comprises 50 to 99 mole % of the 1-butene component and 1 to 50 mole % of the alpha-olefin component,(B) it has an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.5 to 6 dl/g,(C) it has a melting point [Tm], measured by a differential scanning calorimeter, of from 30.degree. to 120.degree.0 C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 5 to 60%,(E) the amount [W.sub.1 in % by weight] of that portion of it which is soluble in boiling methyl acetate is not more than 2%, and(F) the amount [W.sub.2 in % by weight] of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5.times.[.eta.].sup.-1.2.
摘要翻译：包含1-丁烯和碳原子数5〜20的α-烯烃的无规1-丁烯共聚物，所述共聚物具有以下特性（A）〜（I）：（A）含有50〜99摩尔％丁烯组分和1至50摩尔％的α-烯烃组分，（B）其在135℃萘烷中测得的特性粘度η为0.5至6dl / g，（C）它具有通过差示扫描量热计测定的熔点[Tm]为30〜120℃，（D）通过X射线衍射测定的结晶度为5〜60％（E）可溶于沸腾乙酸甲酯的那部分的[W1重量％]不超过2％，（F）可溶于沸石的部分的[W2重量％] 在10℃下丙酮和正癸烷的1:1体积比的混合物小于5×η-1.2。

3. 发明授权

US4659792A Process for production of 4-methyl-1-pentene polymer or copolymer 失效
标题翻译：制备4-甲基-1-戊烯聚合物或共聚物的方法
公开(公告)号：US4659792A
公开(公告)日：1987-04-21
申请号：US814166
申请日：1985-12-23
申请人： Norio Kashiwa , Kunisuke Fukui
发明人： Norio Kashiwa , Kunisuke Fukui
IPC分类号： C08F2/00 , C08F2/04 , C08F4/00 , C08F4/02 , C08F4/60 , C08F10/00 , C08F10/14
CPC分类号： C08F10/00 , Y10S526/904
摘要： A process for producing a polymer or copolymer of 4-methyl-1-pentene, which comprises polymerizing 4-methyl-1-pentene or copolymerizing 4-methyl-1-pentene with up to about 20 mole % of an olefin having 2 to 20 carbon atoms in the presence of a catalyst comprising(A) a solid highly active titanium catalyst component composed of magnesium, titanium, halogen and a diester of a dicarboxylic acid,(B) an organoaluminum compound, and(C) an organosilicon compound represented by the following formulaR.sup.1.sub.3 Si(OR.sup.2) wherein each of R.sup.1 and R.sup.2 represents a hydrocarbon group with 1 to 5 carbon atoms, and the three R.sup.1 groups may be identical or different,wherein prior to the polymerization or copolymerization, a methylpentene is pre-polymerized or pre-copolymerized in the presence of a catalyst comprising the catalyst component (A), a part of the catalyst component (B) and a part of the catalyst component (C) to form about 1 to about 1000 grams, per millimole of titanium atom, of a methylpentene polymer or copolymer.
摘要翻译：一种制备4-甲基-1-戊烯的聚合物或共聚物的方法，该方法包括聚合4-甲基-1-戊烯或共聚4-甲基-1-戊烯与最多约20摩尔％的具有2至20个烯烃的烯烃（A）由镁，钛，卤素和二羧酸的二酯组成的固体高活性钛催化剂组分，（B）有机铝化合物，和（C）由（B）的有机硅化合物表示的有机硅化合物下式R 13 Si（OR 2）其中R 1和R 2各自表示具有1至5个碳原子的烃基，并且三个R 1基团可以相同或不同，其中在聚合或共聚之前，将甲基戊烯预聚合或在包含催化剂组分（A），催化剂组分（B）的一部分和催化剂组分（C）的一部分的催化剂的存在下预共聚，以形成每摩尔钛原子约1至约1000克的甲基戊烯 ymer或共聚物。

4. 发明授权

US4239871A Process for polymerization of butene 失效
标题翻译：丁烯聚合方法
公开(公告)号：US4239871A
公开(公告)日：1980-12-16
申请号：US96420
申请日：1979-11-21
申请人： Kunisuke Fukui
发明人： Kunisuke Fukui
IPC分类号： C08F2/00 , C08F2/04 , C08F2/14 , C08F2/18 , C08F4/00 , C08F4/60 , C08F4/64 , C08F110/08
CPC分类号： C08F110/08 , Y10S526/922
摘要： A process for the polymerization of butene-1 in a liquid aliphatic hydrocarbon medium in the presence of a catalyst composed of a titanium trihalide and an organoaluminum compound which comprises initially polymerizing a minor part of the butene-1 at a temperature within a range sufficiently low that a slurry of polymer in said medium is produced and then increasing the temperature of polymerization so that the greater part of the butene-1 is polymerized within a high temperature range higher than that of the initial polymerization but not at a temperature so high that the polymer formed dissolves in said medium, characterized in that (1) the initial polymerization is carried out at a temperature of not more than 20.degree. C. in the presence of said titanium trihalide in an amount of not less than 50 millimoles and up to 1,000 millimoles per liter of said medium, and then (2) the polymerization is carried out in the presence or absence of said medium at a temperature of 25.degree. C. to less than 48.degree. C. in the presence of said titanium trihalide in an amount up to one-fifth of that of the initial polymerization.
摘要翻译：在由三卤化钛和有机铝化合物组成的催化剂存在下，在液体脂族烃介质中聚合丁烯-1的方法，其包括在足够低的范围内的温度下首先聚合少量的丁烯-1 产生聚合物在所述介质中的浆料，然后提高聚合温度，使得大部分丁烯-1在比初始聚合高的高温范围内聚合，但不是在如此高的温度下聚合，形成的聚合物溶解在所述介质中，其特征在于：（1）初始聚合在不超过20℃的温度下在所述三卤化钛存在下以不低于50毫摩尔和高达1,000 毫升/升所述培养基，然后（2）聚合在存在或不存在所述培养基的情况下在25℃至更低的温度下进行在所述三卤化钛的存在下，其量高达初始聚合的五分之一。

5. 发明授权

US5336747A Random 1-butene/ethylene copolymer 失效
标题翻译：随机1-丁烯/乙烯共聚物
公开(公告)号：US5336747A
公开(公告)日：1994-08-09
申请号：US961854
申请日：1992-10-16
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08F210/08 , C08F210/16
CPC分类号： C08F210/08
摘要： A highly crystalline semi-rigid random 1-butene/ethylene copolymer consisting of 1-butene and ethylene, said copolymer having the following characteristics (A) to (K);(A) it consists of 99 to 90 mole % of the 1-butene component and 1 to 10 mole % of the ethylene component,(B) it has an intrinsic viscosity (.eta.), measured in decalin at 130.degree. C., of from 0.5 to 6 dl/g,(C) it has a DSC melding point (Tm) measured by a differential scanning calorimeter, of from 100.degree. to 120.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 20 to 58%,(E) the amount (W.sub.1 in % by weight) of that portion of it which is soluble in boiling methyl acetate is not more than 2%,(F) the amount (W.sub.2 in % by weight) of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5 .times. (.eta.).sup.-1.2,(G) it has a yield strength of 30 to 180 kg/cm.sup.2,(H) it has a tensile strength at break of 200 to 800 kg/cm.sup.2,(I) it has an elongation at break of from 350 to 800%,(J) it has a torsional rigidity of 200 to 2000 kg/cm.sup.2 and(K) it has a Young's modulus of 400 to 4000 kg/cm.sup.2.
摘要翻译：由1-丁烯和乙烯组成的高结晶半刚性无规1-丁烯/乙烯共聚物，所述共聚物具有以下特征（A）至（K）; （A）由99〜90摩尔％的1-丁烯成分和1〜10摩尔％的乙烯成分组成，（B）其在130℃的萘烷中测定的特性粘度（η）为（C）通过差示扫描量热计测得的DSC熔点（Tm）为100〜120℃，（D）具有通过X射线测定的结晶度衍生物为20〜58％（E）可溶于沸腾乙酸甲酯的部分的量（W1重量％）为2％以下（F）量（W 2以％计，重量）可溶于丙酮和正癸烷的1:1体积比的混合物在10℃下的该部分小于5×（eta）-1.2（G），其屈服强度为30 （H），断裂时的拉伸强度为200〜800kg / cm 2，（I）断裂伸长率为350〜800％，（J）扭转刚性为200 至2000kg / cm 2，（K），其杨氏模量为400〜4000kg / cm 2。

6. 发明授权

US4942087A Films of wholly aromatic polyester and processes for preparation thereof 失效
标题翻译：全芳族聚酯薄膜及其制备方法
公开(公告)号：US4942087A
公开(公告)日：1990-07-17
申请号：US285015
申请日：1988-12-16
申请人： Masanori Motooka , Kazuyuki Takimoto , Kunisuke Fukui
发明人： Masanori Motooka , Kazuyuki Takimoto , Kunisuke Fukui
IPC分类号： C08G63/60 , C08J5/18 , C08G63/02 , B32B27/36 , C08G69/08
CPC分类号： C08J5/18 , C08G63/605 , C08J2367/00 , Y10T428/26 , Y10T428/31786
摘要： Disclosed herein are (1) a film of a liquid crystalline wholly aromatic polyester which is non-oriented and transparent, which film can be prepared by dissolving a liquid crystalline wholly aromatic polyester in a solvent, casting the resulting solution to form a film and volatirizing the solvent from the film as cast and (2) a film of a liquid crystalline wholly aromatic polyester which is oriented and polarizing, which film can be prepared by orienting the above-mentioned non-oriented film by drawing or heating.

7. 发明授权

US4734328A Crystalline random propylene copolymer composition and composite laminate comprising said composition 失效
标题翻译：包含所述组合物的结晶无规丙烯共聚物组合物和复合层压材料
公开(公告)号：US4734328A
公开(公告)日：1988-03-29
申请号：US29365
申请日：1987-03-23
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08L23/10 , C08L23/14 , C08L23/20 , C09J123/10 , C09J123/20 , C08L23/08 , B32B27/06 , B32B27/08
CPC分类号： C08L23/10 , C08L23/142 , C08L23/20 , C09J123/10 , C09J123/20 , Y10T428/264 , Y10T428/265 , Y10T428/31913
摘要： A crystalline random propylene copolymer composition comprising (i) a crystalline random propylene copolymer comprising 99 to 85 mole % of propylene and 1 to 15 mole % of an alpha-olefin other than propylene and (ii) a random 1-butene copolymer comprising ethylene and 1-butene, the weight ratio of the copolymer (i) to the copolymer (ii) being in the range of from 5:95 to 90:10, said random 1-butene copolymer (ii) satisfying the following conditions:(A) it comprises 1 to 50 mole % of the ethylene component and 50 to 99 mole % of the 1-butene component,(B) it has an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.5 to 6 dl/g,(C) it has a melting point [Tm], measured by a differential scanning calorimeter, of from 30.degree. to 130.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 1 to 60%,(E) the amount [W.sub.1 in % by weight] of that portion of it which is soluble in boiling methyl acetate is not more than 2%, and(F) the amount [W.sub.2 in % by weight] of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5.times.[.eta.].sup.-1.2.
摘要翻译：一种结晶无规丙烯共聚物组合物，其包含（i）结晶无规丙烯共聚物，其包含99至85摩尔％的丙烯和1至15摩尔％的除丙烯以外的α-烯烃，和（ii）包含乙烯和 1-丁烯，共聚物（i）与共聚物（ii）的重量比在5:95至90:10的范围内，所述随机1-丁烯共聚物（ii）满足以下条件：（A）它包含1至50摩尔％的乙烯组分和50至99摩尔％的1-丁烯组分，（B）其在135℃的十氢化萘中测得的特性粘度η为0.5至6 dl / g，（C）通过差示扫描量热计测定的熔点[Tm]为30〜130℃，（D）通过X射线衍射法测定其结晶度， 1〜60％，（E）可溶于沸腾乙酸甲酯的部分的量[W1以重量％计）不超过2％，（F）[W 2％在10℃下可溶于1:1体积比的丙酮和正癸烷的混合物的那部分重量比小于5×η-1.2。

8. 发明授权

US4146591A Process for producing 4-methyl-1-pentene copolymer composition 失效
标题翻译：生产4-甲基-1-戊烯共聚物组合物的方法
公开(公告)号：US4146591A
公开(公告)日：1979-03-27
申请号：US901714
申请日：1978-05-01
申请人： Kunisuke Fukui , Ikuo Hirai
发明人： Kunisuke Fukui , Ikuo Hirai
IPC分类号： C08F297/08 , C08L23/20
CPC分类号： C08F297/08 , C08L23/20
摘要： A process for producing a 4-methyl-1-pentene copolymer composition by sequential polymerization, which comprises[I] a step of polymerizing 4-methyl-1-pentene in the presence or absence of a minor amount of a C.sub.6 -C.sub.18 linear 1-olefin in a hydrocarbon liquid medium in the presence of a catalyst comprising a transition metal compound and an organometallic compound of a metal of Groups I to III of the periodic table to form reaction product containing a 4-methyl-1-pentene polymer or copolymer (A) having a 4-methyl-1-pentene content of at least about 90% by weight; and[II] a step of further copolymerizing 4-methyl-1-pentene, 1-hexane and a C.sub.7 -C.sub.10 linear 1-olefin in the presence of the reaction product containing the polymer or copolymer (A) to form a rubbery copolymer (B) having a 4-methyl-1-pentene content of about 30 to about 70% by weight, a 1-hexene content of about 10 to about 60 and a C.sub.7 -C.sub.10 linear 1-olefin content of about 10 to about 60% by weight, the content of the copolymer (B) being about 5 to about 20% by weight based on the total weight of the polymer or copolymer (A) and the copolymer (B).

9. 发明授权

US4778870A Random 1-butene/ethylene copolymer 失效
标题翻译：随机1-丁烯/乙烯共聚物
公开(公告)号：US4778870A
公开(公告)日：1988-10-18
申请号：US792668
申请日：1985-10-29
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F210/00 , C08F210/08 , C08F210/16
CPC分类号： C08F210/08
摘要： A random 1-butene/ethylene copolymer comprising 1-butene and ethylene, said copolymer having the following characteristics (A) to (I):(A) it comprises 50 to 99 mole % of the 1-butene component and 1 to 50 mole % of the ethylene component,(B) it has an intrinsic viscosity [.eta.], measured in decalin at 135.degree. C., of from 0.5 to 6 dl/g,(C) it has a melting point [Tm], measured by a differential scanning calorimeter, of from 30.degree. to 130.degree. C.,(D) it has a crystallinity, measured by X-ray diffractometry, of from 1 to 60%,(E) the amount [W.sub.1 in % by weight] of that portion of it which is soluble in boiling methyl acetate is not more than 2%, and(F) the amount [W.sub.2 in % by weight] of that portion of it which is soluble in a 1:1 by volume mixture of acetone and n-decane at 10.degree. C. is less than 5.times.[.eta.].sup.-1.2.
摘要翻译：包含1-丁烯和乙烯的无规1-丁烯/乙烯共聚物，所述共聚物具有以下特征（A）至（I）：（A）它包含50-99摩尔％的1-丁烯组分和1-50摩尔乙烯成分的％，（B）在135℃萘烷中测定的特性粘度η为0.5〜6dl / g，（C）熔点[Tm] 差示扫描量热仪为30〜130℃，（D）通过X射线衍射法测定的结晶度为1〜60％，（E）[W1重量％以上] 可溶于沸腾乙酸甲酯的那部分不大于2％，（F）其部分的[W2重量％]可溶于1:1体积的丙酮和在10℃的正癸烷小于5×η-1.2。

10. 发明授权

US4726999A Laminated structure comprising a substrate layer composed of a crystalline propylene resin and a heat-sealable layer composed of a crystalline propylene random copolymer composition 失效
标题翻译：包括由结晶丙烯树脂构成的基材层和由结晶丙烯无规共聚物组合物构成的可热封层的层压结构
公开(公告)号：US4726999A
公开(公告)日：1988-02-23
申请号：US792659
申请日：1985-10-29
申请人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
发明人： Masaki Kohyama , Takeshi Muranaka , Kunisuke Fukui , Norio Kashiwa
IPC分类号： B32B27/32 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/16 , C08L23/20 , C09J123/10 , C09J123/16 , C08J5/18
CPC分类号： C08L23/142 , B32B27/32 , C08L23/20 , C09J123/10 , C09J123/16 , C08L23/12 , Y10T428/1334 , Y10T428/1352 , Y10T428/265 , Y10T428/2826 , Y10T428/31913
摘要： A laminated structure comprising a substrate layer of a crystalline propylene resin and, positioned in direct contact with at least one surface of said substrate layer, a heat-sealable layer of a crystalline random propylene copolymer composition, wherein the crystalline random propylene copolymer composition is a mixture composed of(I) a crystalline random propylene copolymer of a major amount of propylene with a minor amount of another alpha-olefin, and(II) a random copolymer consisting essentially of more than 60 to 99 mole % of 1-butene and less than 40 to 1 mole % of propylene,the weight ratio of (I)/(II) being from 5/95 to 90/10, and the radom copolymer (II) has(A) an intrinsic viscosity [.eta.], determined in decalin at 135.degree. C., of 0.5 to 6 dl/g,(B) a DSC melting point (Tm), measured by a differential scanning calorimeter, of 50 to 130.degree. C., (C) a degree of crystallinity, measured by X-ray diffractometry, of 5 to 60%,(D) a boiling methyl acetate-soluble content (W.sub.1) of not more than 2% by weight based on the weight of the copolymer (II), and(E) an n-decane/acetone (1:1 by volume) mixture-soluble content (W.sub.2) of less than 4.times.[.eta.].sup.-1.2 in % by weight based on the weight of the copolymer (II);and a crystalline random propylene copolymer composition used for the said laminated structure.
摘要翻译：一种层压结构，其包括结晶丙烯树脂的基底层，并且与所述基底层的至少一个表面直接接触，结晶无规丙烯共聚物组合物的可热封层，其中所述结晶无规丙烯共聚物组合物为由（I）主要量的丙烯与少量另外的α-烯烃的结晶无规丙烯共聚物组成的混合物，和（II）基本上由大于60至99摩尔％的1-丁烯组成的无规共聚物（I）/（II）的重量比为5/95至90/10，天线共聚物（II）的摩尔比为（A）的特性粘度η为在135℃下的十氢化萘为0.5〜6dl / g，（B）通过差示扫描量热计测定的DSC熔点（Tm）为50〜130℃，（C）结晶度，测定通过X射线衍射测定为5〜60％，（D）沸点乙酸甲酯可溶物含量（W1）o f以共聚物（II）的重量计不超过2重量％，和（E）小于4xη的正癸烷/丙酮（体积比1:1）的混合物可溶物含量（W2） -1.2重量％，基于共聚物（II）的重量; 和用于所述层压结构的结晶无规丙烯共聚物组合物。

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