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21. 发明授权

US4810599A Structure suitable for solid electrochemical elements 失效
标题翻译：结构适用于固体电化学元素
公开(公告)号：US4810599A
公开(公告)日：1989-03-07
申请号：US172166
申请日：1988-03-23
申请人： Shigeo Kondo , Naoshi Yasuda , Masaki Nagata , Tadashi Sotomura
发明人： Shigeo Kondo , Naoshi Yasuda , Masaki Nagata , Tadashi Sotomura
IPC分类号： G02F1/15 , H01G9/02 , H01G11/56 , H01M4/62 , H01M6/18
CPC分类号： H01G9/038 , G02F1/1525 , H01G11/56 , H01M4/621 , H01M6/18 , H01M6/181 , Y02E60/13
摘要： A structure comprising a pair of electrode sheets and an electrolyte sheet, the latter being sandwiched in between the former, wherein each of the pair of electrode sheets comprises a mixture comprising an insulating elastomer and an electrode active substance powder and/or an inorganic solid electrolyte powder, in which mixture the electrode active substance powder and/or the inorganic solid electrolyte powder are dispersed in a volume fraction of 75-95% in the insulating elastomer, and said electrolyte sheet comprises a mixture of an inorganic solid electrolyte powder and an insulating elastomer and optionally an electrode active substance powder, in which mixture the inorganic solid electrolyte powder and optionally the electrode active substance powder are dispersed in a volume fraction of 55-95% in the insulating elastomer. Each of said electrode sheet and said electrolyte sheet may further comprise a reticulate material sheet, the openions of which are filled with the mixture. The structure is excellent in ion-conductivity, processability, productivity, storage stability and flexibility and enables one to make solid electrolyte cells, solid electric double layer capacitors and solid electrochromic display thinner and larger in area.
摘要翻译：一种结构，包括一对电极片和电解质片，后者被夹在前者之间，其中每对电极片包括包含绝缘弹性体和电极活性物质粉末和/或无机固体电解质的混合物粉末，其中电极活性物质粉末和/或无机固体电解质粉末在绝缘弹性体中以75-95％的体积分数分散，并且所述电解质片材包含无机固体电解质粉末和绝缘体的混合物弹性体和任选的电极活性物质粉末，其中无机固体电解质粉末和任选的电极活性物质粉末在绝缘弹性体中以55-95％的体积分数分散。所述电极片和所述电解质片中的每一个可以进一步包括网状材料片，其开口填充有混合物。该结构具有优异的离子传导性，加工性，生产率，储存稳定性和柔韧性，使得固体电解质电池，固体双电层电容器和固体电致变色显示器的面积更薄更大。

22. 发明授权

US4148976A Solid state lithium-iodine primary battery 失效
标题翻译：固态锂碘一次电池
公开(公告)号：US4148976A
公开(公告)日：1979-04-10
申请号：US922049
申请日：1978-07-05
申请人： Satoshi Sekido , Tadashi Sotomura , Yoshito Ninomiya
发明人： Satoshi Sekido , Tadashi Sotomura , Yoshito Ninomiya
IPC分类号： H01M4/60 , H01M6/18
CPC分类号： H01M4/60 , H01M6/182 , Y10T29/49108
摘要： A solid-state primary cell comprising a lithium anode, an iodine cathode containing a charge transfer complex and a solid lithium iodide electrolyte doped with a 1-normal-alkyl-pyridinium iodide. The anode surface can be coated with LiOH or Li.sub.3 N. The iodine cathode comprises a complex of iodine and 1-normal-alkyl-pyridinium iodide and preferably contains titanium dioxide powder, alumina gel powder or silica gel powder admixed with the complex.
摘要翻译：包含锂阳极，含有电荷转移络合物的碘阴极和掺杂有1-正烷基 - 碘化吡啶鎓的固体碘化锂电解质的固态初级电池。阳极表面可以涂覆LiOH或Li3N。碘阴极包含碘和1-正烷基 - 吡啶鎓碘化物的络合物，并且优选含有与络合物混合的二氧化钛粉末，氧化铝凝胶粉末或硅胶粉末。

23. 发明申请

US20050221169A1 Battery and method for generating electricity 有权
标题翻译：电池和发电方法
公开(公告)号：US20050221169A1
公开(公告)日：2005-10-06
申请号：US11135283
申请日：2005-05-24
申请人： Tadashi Sotomura
发明人： Tadashi Sotomura
IPC分类号： H01L31/04 , H01M2/38 , H01M4/02 , H01M4/36 , H01M4/38 , H01M4/42 , H01M4/60 , H01M4/66 , H01M6/30 , H01M8/04 , H01M12/00 , H01M12/04 , H01M12/06 , H01M14/00
CPC分类号： H01M6/30 , H01M2/38 , H01M4/38 , H01M4/42 , H01M4/48 , H01M4/50 , H01M4/583 , H01M4/60 , H01M4/661 , H01M8/04082 , H01M8/04276 , H01M12/04 , H01M2004/027 , H01M2004/028 , Y02P70/56
摘要： A positive electrode, a negative electrode, and an electrolyte intervening between the positive electrode and the negative electrode are employed, and a molecule capable of being excited due to absorption of light and electrochemically oxidizing carbohydrate is provided at at least either the negative electrode or the electrolyte, with production of electromotive force occurring between the positive electrode and the negative electrode as a result of supply of carbohydrate while the molecule is irradiated with light and oxidization of carbohydrate by the molecule at the negative electrode. This method makes it possible for the chemical energy which carbohydrates possess to be directly utilized as electrical energy.
摘要翻译：采用在正极和负极之间插入的正极，负极和电解质，能够在负极或负极的至少一方具有由于吸收光而被激发而进行电化学氧化的碳分子电解质，由于供给碳水化合物而在正极和负极之间产生电动势，而分子被光照射并且在负极处被分子氧化碳水化合物。这种方法使碳水化合物所具有的化学能直接用作电能。

24. 发明授权

US5518841A Composite cathode 失效
标题翻译：复合阴极
公开(公告)号：US5518841A
公开(公告)日：1996-05-21
申请号：US190931
申请日：1994-02-03
申请人： Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Miyamoto , Kenichi Takeyama
发明人： Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Miyamoto , Kenichi Takeyama
IPC分类号： H01M4/02 , H01M4/36 , H01M4/48 , H01M4/60 , H01M10/34
CPC分类号： H01M4/364 , H01M4/36 , H01M4/60 , H01M10/345 , H01M2004/028 , H01M2300/0025 , H01M4/485 , Y10T29/49115
摘要： A composite cathode for a battery is disclosed. In addition, a method is disclosed for producing said composite cathode which can be configured in a battery. The method comprises steps or (1) preparing a solution or an organic disulfide compound in 2-pyrrolidone or its derivative, (2) adding polyaniline to the solution to dissolve, thereby obtaining a homogeneous liquid, and then (3) removing at least a part of the 2-pyrrolidone or its derivative from the homogeneous liquid to obtain a solid product wherein the organic disulfide compound and the polyaniline are homogeneously mixed.
摘要翻译：公开了一种用于电池的复合阴极。此外，公开了一种用于制造可配置在电池中的复合阴极的方法。该方法包括以下步骤：（1）在2-吡咯烷酮或其衍生物中制备溶液或有机二硫化物，（2）将聚苯胺加入溶液中溶解，从而得到均匀的液体，然后（3）至少除去来自均相液体的部分2-吡咯烷酮或其衍生物，得到固体产物，其中有机二硫化物化合物和聚苯胺均匀混合。

25. 发明授权

US5324599A Reversible electrode material 失效
标题翻译：可逆电极材料
公开(公告)号：US5324599A
公开(公告)日：1994-06-28
申请号：US826000
申请日：1992-01-27
申请人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
发明人： Noboru Oyama , Katsuhiko Naoi , Tadashi Sotomura , Hiroshi Uemachi , Yoshiko Sato , Teruhisa Kanbara , Kenichi Takeyama
IPC分类号： H01M4/60 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01M10/052 , H01M10/0565 , H01M4/60
摘要： The present invention provides an electrode material comprising a combination of a compound having a disulfide group and a conductive polymer, or a conductive polymer having a disulfide group, wherein an S-S bond of the disulfide group is cleaved by the electrolytic reduction to form a sulfur-metal ion bond or a sulfur-proton bond, and the sulfur-metal ion bond or the sulfur-proton bond re-forms an S-S bond by the electrolytic oxidation. The present invention also provides a lithium rechargeable battery comprising a cathode, a solid electrolyte, and an anode, wherein the cathode is made of a composition containing as its main components lithium thiolate having a sulfur-lithium ion bond capable of forming a disulfide bond by the electrolytic oxidation and a .pi. electron conjugated conductive polymer; or a composition containing as its main component a .pi. electron conjugated conductive polymer having a sulfur-lithium ion bond capable of forming a disulfide bond by electrolytic oxidation; the solid electrolyte is a composition containing a salt containing lithium, or a polymer containing the salt; and the anode is made of a composition containing as its main components aluminium or an alloy containing aluminium, and carbon.
摘要翻译：本发明提供了包含具有二硫化物的化合物和导电性聚合物的组合的电极材料或具有二硫键的导电性聚合物，其中通过电解还原将二硫键的SS键切割，形成硫 - 金属离子键或硫质子键，硫金属离子键或硫质子键通过电解氧化而重新形成SS键。本发明还提供一种锂可再充电电池，其包含阴极，固体电解质和阳极，其中阴极由含有能够形成二硫键的硫 - 锂离子键的硫醇锂的组成的组合物制成电解氧化和π电子共轭导电聚合物; 或含有通过电解氧化形成二硫键的具有硫 - 锂离子键的π电子共轭导电聚合物作为其主要成分的组合物; 固体电解质是含有含锂的盐或含有该盐的聚合物的组合物; 并且阳极由含有铝或含有铝的合金和碳的主要成分的组合物制成。

26. 发明授权

US4977007A Solid electrochemical element and production process therefor 失效
标题翻译：固体电化学元件及其生产工艺
公开(公告)号：US4977007A
公开(公告)日：1990-12-11
申请号：US097367
申请日：1987-09-08
申请人： Shigeo Kondo , Tadashi Sotomura
发明人： Shigeo Kondo , Tadashi Sotomura
IPC分类号： H01M12/00 , G02F1/15 , H01G9/00 , H01G9/155 , H01M4/02 , H01M6/18
CPC分类号： H01G9/155 , G02F1/1525 , H01M4/02 , H01M6/18 , H01M6/188 , Y02E60/13 , Y10T428/239 , Y10T428/24917 , Y10T428/25 , Y10T428/2933 , Y10T428/30 , Y10T428/31786 , Y10T428/31913 , Y10T428/31935
摘要： A solid electrochemical element which is flexible and has improved resistance to environmental exposure includes at least one solid electrolyte sheet which is flexible, has a pair of opposing surfaces, and is comprised of solid electrolyte particles and a plastic resin, which plastic resin was coated on each particle of the solid electrolyte particles prior to formation of the at least one solid electrolyte; and at least two electrode sheets comprised of an electrode material, one of the at least two electrode sheets being provided on each of the pair of opposing surfaces of the at least one solid electrolyte sheet, wherein an ion conductive path is formed between the pair of opposing surfaces of the at least one solid electrolyte sheet by virtual contact of the solid electrolyte particles and the electrode material. A process for producing the solid electrochemical element uses, as starting materials, (a) solid electrolyte particles coated with a thin layer of a plastic resin and (b) electrode material particles coated with a thin layer of a plastic resin, and preferably includes a step of crushing the solid electrolyte particles by pressing.
摘要翻译：柔性并且具有改善的耐环境暴露性的固体电化学元件包括至少一种柔性的固体电解质片，具有一对相对表面，并且由固体电解质颗粒和塑料树脂构成，该塑料树脂被涂覆在所述固体电解质颗粒的每个颗粒在形成所述至少一种固体电解质之前; 以及至少两个由电极材料组成的电极片，所述至少两个电极片中的至少一个电极片中的一个设置在所述至少一个固体电解质片的所述一对相对表面中的每一个上，其中在所述一对电极片之间形成离子传导路径通过固体电解质颗粒和电极材料的虚拟接触，至少一个固体电解质片的相对表面。固体电化学元件的制造方法使用（a）涂覆有塑料树脂薄层的固体电解质颗粒和（b）涂覆有塑料树脂薄层的电极材料颗粒，优选包括通过压制粉碎固体电解质颗粒的步骤。

27. 发明授权

US4828945A Solid electrolyte sheet and process for producing the same 失效
标题翻译：固体电解质片及其制造方法
公开(公告)号：US4828945A
公开(公告)日：1989-05-09
申请号：US172165
申请日：1988-03-23
申请人： Masaki Nagata , Naoshi Yasuda , Shigeo Kondo , Tadashi Sotomura
发明人： Masaki Nagata , Naoshi Yasuda , Shigeo Kondo , Tadashi Sotomura
IPC分类号： C08K3/16 , H01G9/02 , H01G11/56 , H01M6/18 , H01M6/22
CPC分类号： H01G9/038 , C08K3/16 , H01G11/56 , H01M6/18 , H01M6/181 , H01M6/22 , Y02E60/13
摘要： A solid electrolyte sheet comprising an ion-conductive inorganic solid electrolyte and an insulating elastomer, wherein the inorganic solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95% and which sheet has a hardness (ASTM A) of 65-96 and a thickness of 10-250 .mu.m, or a solid electrolyte sheet comprising a non-conductive reticulate material and a mixture of an ion-conductive inorganic solid electrolyte powder and an insulating elastomer, in which mixture the solid electrolyte powder is uniformly dispersed in the insulating elastomer in a volume fraction of 55-95%, at least the openings of the reticulate material being filled with said mixture. Said solid electrolyte sheets are superior in ion-conductivity, processability, productivity, storage stability and flexibility and are suitable for use in thin and large electrochemical elements.
摘要翻译：一种固体电解质片，包括离子传导性无机固体电解质和绝缘弹性体，其中所述无机固体电解质粉末以55-95％的体积分数均匀地分散在所述绝缘弹性体中，并且所述片的硬度（ASTM A）为 65-96和10-250μm的厚度，或包含非导电网状材料和离子传导无机固体电解质粉末和绝缘弹性体的混合物的固体电解质片，其中固体电解质粉末是均匀地分散在绝缘弹性体中，体积分数为55-95％，网状材料的至少开口填充有所述混合物。所述固体电解质片材的离子传导性，加工性，生产率，储存稳定性和柔软性都优异，适用于薄型和大型电化学元件。

28. 发明授权

US06576370B1 Positive electrode and lithium battery using the same 失效
标题翻译：正极和锂电池使用相同
公开(公告)号：US06576370B1
公开(公告)日：2003-06-10
申请号：US09557420
申请日：2000-04-21
申请人： Yasushi Nakagiri , Yasuhiko Bito , Hiromu Matsuda , Tadashi Sotomura , Yoshinori Toyoguchi
发明人： Yasushi Nakagiri , Yasuhiko Bito , Hiromu Matsuda , Tadashi Sotomura , Yoshinori Toyoguchi
IPC分类号： H01M458
CPC分类号： H01M4/583 , H01M4/364 , H01M4/5815 , H01M4/60 , H01M10/05 , H01M2300/0025
摘要： The present invention provides a positive electrode, which contains at least one organic sulfide compound selected from the group consisting of a thiolato compound and a thiol compound, and at least one selected from the group consisting of sulfur and a lithium sulfide represented by Formula (1): (LixS)n, where 0 0, a method of manufacturing the positive electrode, and a lithium battery using the positive electrode. Compared with the prior art lithium battery, the lithium battery using the positive electrode of the present invention has a greater capacity and a higher voltage. The positive electrode of the present invention effectively suppresses escape of the positive electrode active material from the positive electrode during charge and discharge operations and thus actualizes a secondary battery of high energy density having a less decrease in service capacity.
摘要翻译：本发明提供一种正极，其含有选自由硫醇化合物和硫醇化合物组成的组中的至少一种有机硫化合物，以及选自由式（1）表示的硫和硫化锂中的至少一种）：（LixS）n，其中0 0，制造正极的方法和使用正极的锂电池。与现有技术的锂电池相比，使用本发明的正极的锂电池具有更大的容量和更高的电压。本发明的正极在充放电操作中有效地抑制了正极活性物质从正极逸出，从而实现了具有较低的使用能力降低的高能量密度的二次电池。

29. 发明授权

US5413883A Reversible electrochemical electrode 失效
标题翻译：可逆电化学电极
公开(公告)号：US5413883A
公开(公告)日：1995-05-09
申请号：US146401
申请日：1993-11-01
申请人： Hiroshi Uemachi , Tadashi Sotomura , Kenichi Takeyama , Nobuyoshi Koshida
发明人： Hiroshi Uemachi , Tadashi Sotomura , Kenichi Takeyama , Nobuyoshi Koshida
IPC分类号： C23C14/22 , C23C14/20 , C23C14/48 , H01M4/139 , H01M4/60 , H01M10/05
CPC分类号： H01M4/60
摘要： A reversible electrochemical electrode applicable for a battery, sensor, memory or display device is made by ion-implanting a conductive solid polymer such as polyaniline with ions of alkaline or alkaline earth metal. A wide variety of selections and combinations of materials of the conductive solid polymer and ion is possible. In addition, n-type doping is possible.
摘要翻译：用于电池，传感器，存储器或显示装置的可逆电化学电极通过离子注入诸如聚苯胺的导电固体聚合物与碱金属或碱土金属的离子来制备。导电固体聚合物和离子的各种选择和材料的组合是可能的。此外，可以进行n型掺杂。

30. 发明授权

US5413882A Composite electrode 失效
标题翻译：复合电极
公开(公告)号：US5413882A
公开(公告)日：1995-05-09
申请号：US950476
申请日：1992-09-24
申请人： Hiroshi Uemachi , Yoshiko Sato , Tadashi Sotomura , Kenichi Takeyama
发明人： Hiroshi Uemachi , Yoshiko Sato , Tadashi Sotomura , Kenichi Takeyama
IPC分类号： C25B3/04 , C08G75/14 , G02F1/155 , H01M4/137 , H01M4/60 , H01M6/18
CPC分类号： C08G75/14 , G02F1/155 , H01M4/60 , H01M6/181
摘要： A reversible electrode is provided comprising mainly organic disulfide compounds and having applications in such electrochemical devices as batteries, electrochromic displays, sensors, memories, etc. Large current charge/discharge is realized at room temperature with charge/discharge characteristics of excellent reversibility. Its structure is a composition combining organic disulfide compounds with disulfide bonding and conducting polymers. In other words, conducting polymers after being subjected to an electrolysis are put together with organic disulfide compounds. Thus, due to the effect of composition with conducting polymers, the oxidation/reduction reactions of organic disulfide compounds are accelerated and a reversible electrode characterized by utilization of a high energy density of organic disulfide compounds and the possibility of a large current charge/discharge is realized.
摘要翻译：提供主要包含有机二硫化物的可逆电极，并且可用于诸如电池，电致变色显示器，传感器，存储器等的电化学装置中。在室温下实现大电流充电/放电，具有极好的可逆性的充电/放电特性。其结构是结合有机二硫化物与二硫键和导电聚合物的组合物。换句话说，进行电解后的导电聚合物与有机二硫化物组合在一起。因此，由于组成与导电聚合物的作用，有机二硫化物化合物的氧化/还原反应加快，特征在于利用有机二硫化物的高能量密度和大电流充电/放电的可能性的可逆电极是实现了

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