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21. 发明申请

US20110118526A1 PROCESS FOR INDUSTRIAL ISOLATION OF PROPENE 失效
标题翻译：工业分离丙烯的方法
公开(公告)号：US20110118526A1
公开(公告)日：2011-05-19
申请号：US13003839
申请日：2009-07-17
申请人： Markus Schubert , Ingo Richter , Ulrich Mueller , Frank Poplow , William Dolan , Christoph Kiener
发明人： Markus Schubert , Ingo Richter , Ulrich Mueller , Frank Poplow , William Dolan , Christoph Kiener
IPC分类号： C07C7/12
CPC分类号： C07C7/12 , C07C11/06
摘要： A process for the industrial isolation of propene from a gas stream comprising at least propene and propane, which involves contacting of the gas stream with an adsorbent having a porous metal organic framework having at least one at least bidentate organic compound coordinated to at least one metal ion, with the adsorbent becoming laden with propane and the gas stream therefore having an increased proportion of propene, wherein the W least bidentate organic compound is an imidazolate which is unsubstituted or has one or more substituents selected independently from of halogen, C1-6-alkyl, phenyl, NH2, NH(C1-6-alkyl), N(C1-6-alkyl)2, OH, O-phenyl and O—C1-6-alkyl.
摘要翻译：一种用于从包含至少丙烯和丙烷的气流中工业分离丙烯的方法，其包括使气流与具有多孔金属有机骨架的吸附剂接触，所述多孔金属有机骨架具有与至少一种金属配位的至少二齿有机化合物离子，吸附剂变得装满丙烷，因此气流具有增加的丙烯比例，其中W最小二齿有机化合物是未被取代的或具有一个或多个独立地选自卤素，C 1-6 - 烷基，苯基，NH 2，NH（C 1-6 - 烷基），N（C 1-6 - 烷基）2，OH，O-苯基和O-C 1-6 - 烷基。

22. 发明授权

US07714179B2 Method for the production of C5 aldehydes and propene from a C4 stream containing 1-butene and 2-butene 有权
标题翻译：从含有1-丁烯和2-丁烯的C4流中生产C5醛和丙烯的方法
公开(公告)号：US07714179B2
公开(公告)日：2010-05-11
申请号：US11661543
申请日：2005-08-06
申请人： Marcus Sigl , Markus Schubert , Jürgen Stephan , Rainer Papp , Frank Poplow
发明人： Marcus Sigl , Markus Schubert , Jürgen Stephan , Rainer Papp , Frank Poplow
IPC分类号： C07C6/00 , C07C45/49
CPC分类号： C07C6/04 , C07C7/13 , C07C45/50 , C07C11/06 , C07C11/08 , C07C47/02
摘要： Processes for preparing a C5 aldehyde and propene are disclosed, the processes comprising: (a) providing a feedstream, the feedstream comprising butane, 1-butene, 2-butene and 1,3-butadiene, the 1,3-butadiene present in the feedstream in an amount up to 1000 ppm; (b) contacting the feedstream with hydrogen and carbon monoxide in the presence of a hydroformylation catalyst to form a 2-butene-rich butane stream and a C5 aldehyde; (c) separating the 2-butene-rich butane stream and the C5 aldehyde; and (d) contacting the 2-butene-rich butane stream with ethene in the presence of a metathesis catalyst to form a propene-containing hydrocarbon stream.
摘要翻译：公开了制备C5醛和丙烯的方法，所述方法包括：（a）提供进料流，所述进料流包含丁烷，1-丁烯，2-丁烯和1,3-丁二烯，所述1,3-丁二烯存在于进料流量高达1000 ppm; （b）在加氢甲酰化催化剂存在下使进料流与氢气和一氧化碳接触以形成富含2-丁烯的丁烷流和C5醛; （c）分离富含2-丁烯的丁烷流和C5醛; 和（d）在复分解催化剂存在下使富含2-丁烯的丁烷流与乙烯接触以形成含丙烯烃流。

23. 发明申请

US20070083066A1 Method for the production of 1,7-octadiene and use thereof 审中-公开
标题翻译： 1,7-辛二烯的制备方法及其用途
公开(公告)号：US20070083066A1
公开(公告)日：2007-04-12
申请号：US10572077
申请日：2004-09-17
申请人： Volker Bohm , Michael Roper , Jurgen Stephan , Regina Benfer , Markus Schubert , Jorn Karl , Klaus Ebel , Oliver Lober , Martin Volland
发明人： Volker Bohm , Michael Roper , Jurgen Stephan , Regina Benfer , Markus Schubert , Jorn Karl , Klaus Ebel , Oliver Lober , Martin Volland
IPC分类号： C07C45/68 , C07C45/49 , C07C5/08
CPC分类号： C07C49/587 , C07C6/06 , C07C45/50 , C07C45/62 , C07C45/73 , C07C49/385 , C07C2521/04 , C07C2523/20 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/74 , C07C11/12 , C07C47/12 , C07C49/12
摘要： The invention relates to a method for the production of 1,7 octadiene by reacting metathesis of cyclohexene with ethylene. The invention also relates to the production of 1,10-decandiol by hydroformulating 1,7 octadiene produced according to said method. The invention further relates to a method for the production of muscone or olefinically unsaturated analogs thereof using 1,10 decandiol which is obtainable in said manner.
摘要翻译：本发明涉及通过使环己烯的复分解与乙烯反应制备1,7辛二烯的方法。本发明还涉及通过根据所述方法制备的1,7辛二烯加氢制备1,10-癸二醇。本发明还涉及使用可以所述方式获得的1,10-癸二醇生产肌醇或其烯属不饱和类似物的方法。

24. 发明申请

US20060183627A1 Method for regenerating re2o7 doped catalyst supports 审中-公开
标题翻译：再生Re2o7掺杂催化剂载体的方法
公开(公告)号：US20060183627A1
公开(公告)日：2006-08-17
申请号：US10547293
申请日：2004-02-16
申请人： Jurgen Stephan , Markus Schubert , Christian Weichert , Wilhelm Ruppel , Peter Resch , Soeren Zimdahl , Frank Mrzena , Andreas Molitor , Stefan Berg , Mathias Fohrmann
发明人： Jurgen Stephan , Markus Schubert , Christian Weichert , Wilhelm Ruppel , Peter Resch , Soeren Zimdahl , Frank Mrzena , Andreas Molitor , Stefan Berg , Mathias Fohrmann
IPC分类号： B01J38/12
CPC分类号： B01J23/92 , B01J23/36 , B01J38/12 , B01J38/14 , C07C6/04 , Y02P20/584
摘要： Method of regenerating an Re2O7-doped supported catalyst which has been deactivated by use in the metathesis of a hydrocarbon mixture comprising C2-C6-olefins (C2-6= feed) (deactivated catalyst), which comprises treating the deactivated catalyst with an inert gas (regeneration gas K1) at from 400 to 800° C. and subsequently treating the deactivated catalyst which has been pretreated with regeneration gas K1 with an oxygen-containing gas (regeneration gas K2).
摘要翻译：通过在包含C 2 -C 6烷基的烃混合物的复分解中使用已经失活的Re 2 O 2 O 7重掺合载体催化剂的再生方法， C 6 - 6 - 烯烃（C 2-6）进料）（失活催化剂），其包括用惰性气体处理失活的催化剂（再生气体K 1），然后用含氧气体（再生气体K 2）处理已经用再生气体K 1预处理的失活催化剂。

25. 发明授权

US08563464B2 Use of porous metal-organic framework materials for color marking of filters 失效
标题翻译：使用多孔金属 - 有机骨架材料进行过滤器的颜色标记
公开(公告)号：US08563464B2
公开(公告)日：2013-10-22
申请号：US12521337
申请日：2007-12-17
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Marcus Guzmann , Juergen Huff , Joerg Pastre
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Marcus Guzmann , Juergen Huff , Joerg Pastre
IPC分类号： B01J20/22 , B01D46/00 , C25B3/12
CPC分类号： B01J20/226 , B01J2220/49
摘要： The present invention relates to the use of a porous metal-organic framework material comprising at least one, at least bidentate, organic compound bound to at least one metal ion by coordination, the at least one metal ion, the at least one, at least bidentate, organic compound, or if appropriate a further component, being a coloring component, as sorbent and for permanent color marking of a filter.
摘要翻译：本发明涉及多孔金属 - 有机骨架材料的用途，所述多孔金属 - 有机骨架材料包含通过配位与至少一种金属离子结合的至少一种至少二齿的有机化合物，至少一种金属离子，至少一种金属离子二齿，有机化合物，或适当的另一组分，作为着色组分，作为吸附剂，并用于过滤器的永久颜色标记。

26. 发明授权

US08323610B2 Catalyst for the oxidation of SO2 to SO3 有权
标题翻译：用于将SO2氧化成SO 3的催化剂
公开(公告)号：US08323610B2
公开(公告)日：2012-12-04
申请号：US13084934
申请日：2011-04-12
申请人： Michael Krämer , Markus Schubert , Thomas Lautensack , Thomas Hill , Reinhard Körner , Frank Rosowski , Jürgen Zühlke
发明人： Michael Krämer , Markus Schubert , Thomas Lautensack , Thomas Hill , Reinhard Körner , Frank Rosowski , Jürgen Zühlke
IPC分类号： C01B17/79 , B01J23/22 , B01J27/053 , B01J37/00 , B01J37/02
CPC分类号： B01J27/055 , B01J21/08 , B01J23/22 , B01J35/023 , B01J37/0018 , B01J37/0201 , C01B17/79
摘要： The invention relates to a catalyst for the oxidation of SO2 to SO3. The catalyst contains an active substance which contains vanadium, alkali metal compounds and sulfate applied to a support. The support contains naturally occurring diatomaceous earth, wherein the support contains at least one relatively soft naturally occurring uncalcined diatomaceous earth which has a percentage reduction of at least 35% in its D50 value determined in a particle size determination according to the dry method in comparison with the wet method.
摘要翻译：本发明涉及用于将SO 2氧化成SO 3的催化剂。催化剂含有一种活性物质，其中含有钒，碱金属化合物和硫酸盐。载体含有天然存在的硅藻土，其中载体含有至少一种相对软的天然存在的未煅烧的硅藻土，其在根据干法测定的颗粒尺寸中测定的D50值的百分比降低至少为35％湿法。

27. 发明授权

US08163949B2 Method for electrochemical production of a crystalline porous metal organic skeleton material 有权
标题翻译：电化学生产结晶多孔金属有机骨架材料的方法
公开(公告)号：US08163949B2
公开(公告)日：2012-04-24
申请号：US12987548
申请日：2011-01-10
申请人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
发明人： Ulrich Mueller , Hermann Puetter , Michael Hesse , Markus Schubert , Helge Wessel , Juergen Huff , Marcus Guzmann
IPC分类号： C07F1/00 , C07F3/00 , C07F15/00
CPC分类号： C25B3/12 , B01D53/02 , B01D2253/204 , B01J20/226 , B01J20/28014 , B01J20/28042 , B01J31/1691 , B01J31/1805 , B01J31/1815 , B01J31/2239 , B01J31/226 , B01J2531/16 , B01J2531/26 , B01J2531/842 , C01B3/0015 , C01B21/0455 , C01B23/0057 , F17C11/005 , H01M8/04216 , Y02C10/08 , Y02E60/327 , Y02E60/328 , Y02P20/133 , Y02P70/56 , Y10S95/90 , Y10S502/526
摘要： A method of electrochemically preparing a crystalline, porous, metal-organic framework material comprising at least one at least bidentate organic compound coordinately bound to at least one metal ion, in a reaction medium comprising the at least one bidentate organic compound, wherein at least one metal ion is provided in the reaction medium by the oxidation of one anode comprising the corresponding metal.
摘要翻译：一种在包含至少一种二齿有机化合物的反应介质中电化学制备结晶多孔的金属 - 有机骨架材料的方法，其包含与至少一种金属离子配位结合的至少二齿有机化合物，其中至少一种金属离子通过包含相应金属的一个阳极的氧化在反应介质中提供。

28. 发明授权

US08057584B2 Pressurised gas container or storage means containing a gas pressurised container with filter means 有权
标题翻译：加压气体容器或包含具有过滤装置的气体加压容器的储存装置
公开(公告)号：US08057584B2
公开(公告)日：2011-11-15
申请号：US12299330
申请日：2007-04-26
申请人： Markus Schubert , Ulrich Müller , Michael Hesse , Kerstin Schierle-Arndt , Kai Oertel , Ian Faye , Thorsten Allgeier , Jan-Michael Graehn
发明人： Markus Schubert , Ulrich Müller , Michael Hesse , Kerstin Schierle-Arndt , Kai Oertel , Ian Faye , Thorsten Allgeier , Jan-Michael Graehn
IPC分类号： F17C11/00 , B01D53/02
CPC分类号： F17C11/005 , F17C11/007 , F17C2205/0341 , F17C2270/0168 , Y10S502/526
摘要： Hydrogen or methane gas pressure container having a minimum volume of 1 m3 a prescribed maximum filling pressure, has a filter through which oxygen, methane respectively, can flow during uptake. The filter has an adsorbent for adsorbing impurities selected from the group consisting of a higher hydrocarbon, ammonia, an odorous substance, hydrogen sulfide and a mixture of two or more of these substances. The pressure container and the filter comprise porous metal organic frameworks as adsorbent.
摘要翻译：具有规定的最大填充压力的最小体积为1m 3的氢气或甲烷气体压力容器具有分别在吸收期间氧气，甲烷可以通过其的过滤器。过滤器具有用于吸附选自高级烃，氨，恶臭物质，硫化氢和这些物质中的两种或更多种的混合物的杂质的吸附剂。压力容器和过滤器包括作为吸附剂的多孔金属有机骨架。

29. 发明申请

US20100331176A1 USE OF POROUS METAL-ORGANIC FRAMEWORK MATERIALS FOR COLOR MARKING OF FILTERS 失效
标题翻译：使用多孔金属有机框架材料进行过滤颜色标记
公开(公告)号：US20100331176A1
公开(公告)日：2010-12-30
申请号：US12521337
申请日：2007-12-17
申请人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Marcus Guzmann , Juergen Huff , Joerg Pastre
发明人： Markus Schubert , Ulrich Mueller , Christoph Kiener , Marcus Guzmann , Juergen Huff , Joerg Pastre
IPC分类号： B01J20/22
CPC分类号： B01J20/226 , B01J2220/49
摘要： The present invention relates to the use of a porous metal-organic framework material comprising at least one, at least bidentate, organic compound bound to at least one metal ion by coordination, the at least one metal ion, the at least one, at least bidentate, organic compound, or if appropriate a further component, being a coloring component, as sorbent and for permanent color marking of a filter.
摘要翻译：本发明涉及多孔金属 - 有机骨架材料的用途，所述多孔金属 - 有机骨架材料包含通过配位与至少一种金属离子结合的至少一种至少二齿的有机化合物，至少一种金属离子，至少一种金属离子二齿，有机化合物，或适当的另一组分，作为着色组分，作为吸附剂，并用于过滤器的永久颜色标记。

30. 发明申请

US20090171107A1 PROCESS FOR PREPARING POROUS METAL ORGANIC FRAMEWORKS 有权
标题翻译：制备多孔金属有机框架的方法
公开(公告)号：US20090171107A1
公开(公告)日：2009-07-02
申请号：US12300902
申请日：2007-05-11
申请人： Hermann Pütter , Markus Schubert , Ingo Richter , Ulrich Müller , Natalia Trukhan
发明人： Hermann Pütter , Markus Schubert , Ingo Richter , Ulrich Müller , Natalia Trukhan
IPC分类号： C07F1/08
CPC分类号： C25B3/12
摘要： The present invention relates to a process for preparing a porous metal organic framework comprising at least two organic compounds coordinated to at least one metal ion, which comprises the steps (a) oxidation of at least one anode comprising the metal corresponding to at least one metal ion in a reaction medium in the presence of at least one first organic compound which is an optionally substituted monocyclic, bicyclic or polycyclic saturated or unsaturated hydrocarbon in which at least two ring carbons have been replaced by heteroatoms selected from the group consisting of N, O and S to form a reaction intermediate comprising the at least one metal ion and the first organic compound; and (b) reaction of the reaction intermediate at a prescribed temperature with at least one second organic compound which coordinates to the at least one metal ion, with the second organic compound being derived from a dicarboxylic, tricarboxylic or tetracarboxylic acid.
摘要翻译：本发明涉及一种制备多孔金属有机骨架的方法，所述多孔金属有机骨架包括与至少一种金属离子配位的至少两种有机化合物，其包括以下步骤：（a）至少一个阳极的氧化，所述至少一个阳极包含对应于至少一种金属在至少一种第一有机化合物存在下的反应介质中，所述第一有机化合物是任选取代的单环，双环或多环饱和或不饱和烃，其中至少两个环碳已经被选自N，O 和S形成包含所述至少一种金属离子和所述第一有机化合物的反应中间体; 和（b）将反应中间体在规定温度下与至少一种与至少一种金属离子配位的第二有机化合物反应，第二有机化合物衍生自二羧酸，三羧酸或四羧酸。

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