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    • 27. 发明授权
    • Substrates provided with a microstructured surface, methods for the production thereof, and their use
    • 具有微结构表面的基板,其制造方法及其用途
    • US06649266B1
    • 2003-11-18
    • US09959023
    • 2001-10-15
    • Frank GrossMartin MennigPeter W. OliveiraHelmut SchmidtStefan Sepeur
    • Frank GrossMartin MennigPeter W. OliveiraHelmut SchmidtStefan Sepeur
    • B32B1700
    • C09K3/18B05D1/40B05D5/08B08B17/06B08B17/065B29C59/026B29C2059/023Y10T428/31Y10T428/315Y10T428/31612Y10T428/31663
    • Substrates provided with a microstructured surface have a surface layer which (a) comprises a composition comprising condensates of one or more hydrolysable compounds of at least one element M from main groups III to V and/or transition groups II to IV of the Periodic Table of the Elements, at least some of these compounds containing not only hydrolysable groups A but also non-hydrolysable, carbon-containing groups B and the total molar ratio of groups A to groups B in the parent monomeric starting compounds being from 10:1 to 1:2, from 0.1 to 100 mol % of the groups B being groups B′ containing on average from 5 to 30 fluorine atoms which are attached to one or more aliphatic carbon atoms distanced from M by at least two atoms, and (b) has a microstructuring of such kind that the contact angle with respect to water or hexadecane is at least 5° higher than the contact angle of a corresponding smooth surface. The substrates provided with a microstructured surface are particularly suitable as transparent or translucent easy-to-clean systems.
    • 提供有微结构化表面的底物具有表面层,其表面层包含一种组合物,该组合物包含至少一种元素M的主要组III至V的一种或多种可水解化合物的缩合物和/或周期表的转变基团II至IV的组合物 元素,这些化合物中的至少一些化合物不仅含有可水解基团A,而且含有不可水解的含碳基团B,并且母体单体起始化合物中基团A与基团B的总摩尔比为10:1至1 2,0.1〜100摩尔%的基团B为含有平均5〜30个氟原子的基团B',其通过至少两个原子与一个或多个与M离开的一个或多个脂族碳原子连接,(b)具有 这种微结构化使得相对于水或十六烷的接触角比相应的光滑表面的接触角高至少5°。具有微结构化表面的基底特别合适 作为透明或半透明的易于清洁的系统。
    • 30. 发明授权
    • Composite materials based on vegetable materials
    • 基于植物材料的复合材料
    • US06352610B1
    • 2002-03-05
    • US09297573
    • 1999-05-03
    • Helmut SchmidtMartin MennigGerhard Jonschker
    • Helmut SchmidtMartin MennigGerhard Jonschker
    • C09J700
    • C09C3/12C01P2004/64C03C17/007C03C2217/445C03C2217/475C09D183/04C08L2666/54
    • A composite material is described which is characterized by a substrate based on vegetable materials, in particular vegetable fibers, vegetable fiber raw materials or vegetable fiber semifinished products, and by a nanocomposite which is in functional contact with said substrate and is obtainable by surface modification of a) colloidal inorganic particles with b) one or more silanes of the general formula (I) Rx—Si—A4−x  (I) where the radicals A are identical or different and are hydroxyl groups or groups which can be removed hydrolytically, except methoxy, the radicals R are identical or different and are groups which cannot be removed hydrolytically and x is 0, 1, 2 or 3, where x≧1 in at least 50 mol % of the silanes; under the conditions of the sol-gel process with a below-stoichiometric amount of water, based on the hydrolysable groups which are present, with formation of a nanocomposite sol, and further hydrolysis and condensation of the nanocomposite sol, if desired, before it is brought into contact with the substrate, followed by curing.
    • 描述了一种复合材料,其特征在于基于植物材料,特别是植物纤维,植物纤维原料或植物纤维半成品的基底,以及与所述基底功能接触的纳米复合材料,可通过表面改性 )胶体无机颗粒,b)一种或多种通式(I)的硅烷,其中基团A相同或不同,并且是羟基或可除去甲氧基的基团,基团R相同或不同,为基团 其不能水解除去,x是0,1,2或3,其中在至少50mol%的硅烷中x> = 1;在具有低于化学计量的水的溶胶 - 凝胶法的条件下,基于 在存在的可水解基团上形成纳米复合溶胶,并且如果需要,在纳米复合溶胶进入其中之前进一步水解和缩合纳米复合溶胶 ct与基材,然后固化。