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21. 发明授权

US5516746A Image-forming method and an ink ribbon and a printing sheet used for the method 失效
标题翻译：图像形成方法和用于该方法的色带和印刷纸
公开(公告)号：US5516746A
公开(公告)日：1996-05-14
申请号：US420624
申请日：1995-04-12
申请人： Kengo Ito
发明人： Kengo Ito
IPC分类号： B41M5/382 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/50 , B41M5/52 , B41M5/035
CPC分类号： B41M5/5218 , B41M5/385 , B41M5/39 , Y10S428/913 , Y10S428/914 , Y10T428/259
摘要： A method for forming images by a thermal transfer process. The method comprises the steps of providing a printing sheet having an image-receiving layer on one side thereof, providing an ink ribbon having a dye layer comprising a hydrophilic cationic dye, contacting the ink ribbon with the image-receiving layer, and applying a thermal energy to the ink ribbon in an imagewise pattern to thermally transfer the dye from the ink ribbon to the image-receiving layer. The image-receiving layer comprises at least a layer compound which has ion exchangeability with the cationic dye, so that the dye image is fixed through the ion exchange. Since the dye is bonded to the layer compound through ion exchange, the dye is fixed comparable to that of silver salt photography. A thermal transfer system using the ink ribbon and the printing sheet is also described.
摘要翻译：一种通过热转印工艺形成图像的方法。该方法包括以下步骤：在其一侧提供具有图像接收层的印刷片，提供具有包含亲水性阳离子染料的染料层的墨带，使墨带与图像接收层接触，并施加热能够以成像图案将色带热转印到墨带上的图像接收层。图像接收层至少包含与阳离子染料具有离子交换性的层化合物，使得染料图像通过离子交换固定。由于染料通过离子交换与层化合物结合，所以染料固定与银盐摄影相当。还描述了使用墨带和印刷纸的热转印系统。

22. 发明授权

US5462910A Composition for fixing water-color ink, cover film for thermal transfer image using composition for fixing water color-ink, and thermal transfer image recorded medium 失效
标题翻译：用于固定水彩油墨的组合物，使用用于固定水彩色油墨的组合物的热转印图像用覆盖膜和热转印图像记录介质
公开(公告)号：US5462910A
公开(公告)日：1995-10-31
申请号：US290718
申请日：1994-08-12
申请人： Kengo Ito , Motohiro Mizumachi , Yoshio Fujiwara , Satoru Shinohara
发明人： Kengo Ito , Motohiro Mizumachi , Yoshio Fujiwara , Satoru Shinohara
IPC分类号： B41M5/00 , B41M5/382 , B41M5/52 , B41M7/00 , B41M7/02 , B41M5/035 , B41M5/38
CPC分类号： B41M5/38264 , B41M5/52 , B41M7/0027 , B41M7/02 , B41M5/5218 , B41M5/5254 , Y10S428/913 , Y10S428/914 , Y10T428/24802
摘要： A composition for fixing water-color ink for fixing a water-color ink is disclosed. The composition for fixing a water-color ink contains an ion exchanger, such as, a clay based interlayer compound or an ion-exchange resin. The composition for fixing water-color ink contains a water absorptive resin or a heat-melting resin as a binder. A cover film for thermal transfer is formed by forming a water-color ink fixing layer consisting of the composition for fixing water-color ink peelably on a base material. An adhesive layer or a heat-melting resin layer is formed on the water-color ink fixing layer. The cover film for thermal transfer image is superposed and thermo-compression bonded onto a thermal transfer image or a thermal transfer image having a protective layer, with the water-color ink fixing layer, the adhesive layer or the heat-melting resin layer facing the thermal transfer image or the thermal transfer image having the protective layer. The water-color ink fixing layer is transferred and stacked onto the cover film for thermal transfer image.
摘要翻译：公开了一种用于固定用于固定水彩墨水的水彩墨水的组合物。用于固定水彩墨的组合物含有离子交换剂，例如粘土基层间化合物或离子交换树脂。用于固定水彩墨的组合物含有吸水树脂或作为粘合剂的热熔树脂。通过形成水溶性油墨定影层，形成用于热转印的覆盖膜，该水性油墨定影层由用于将水性油墨可剥离地固定在基材上的组合物构成。在水彩油墨定影层上形成粘合层或热熔树脂层。用于热转印图像的覆盖膜叠加并热压粘合到热转印图像或具有保护层的热转印图像上，水彩油墨定影层，粘合剂层或加热熔融树脂层面向热转印图像或具有保护层的热转印图像。将水彩墨水定影层转印并堆叠在用于热转印图像的覆盖膜上。

23. 发明授权

US5356854A Dye and dye carrier ink ribbon for thermal dye transfer hard copy 失效
标题翻译：染料和染料载体墨带用于热染料转印硬拷贝
公开(公告)号：US5356854A
公开(公告)日：1994-10-18
申请号：US828130
申请日：1992-01-30
申请人： Kengo Ito
发明人： Kengo Ito
IPC分类号： B41J31/00 , B41M5/035 , B41M5/26 , B41M5/385 , B41M5/388 , B41M5/39 , B41M5/38
CPC分类号： B41M5/385 , B41M5/39 , Y10S428/913 , Y10S428/914
摘要： Cationic dyes and dye carrier ink ribbons are disclosed which is used in thermal dye transfer hard copy system. A counter ion (anion) of hydrophilic cationic dyes such as a halogen ion is replaced by anionic surface active agent such a dodecylbezenesulfonate ion through ion exchange treatment to obtain a dye having a structure of the following formula. The dye is used to form a coloring layer on a PETP film to obtain a dye carrier ink ribbon for thermal dye transfer systems. ##STR1##
摘要翻译：公开了用于热染料转移硬拷贝系统中的阳离子染料和染料载体墨带。通过离子交换处理将诸如卤素离子的亲水性阳离子染料的抗衡离子（阴离子）替换为阴离子表面活性剂，例如十二烷基乙磺酸根离子，得到具有下式结构的染料。染料用于在PETP膜上形成着色层，得到用于热染料转移体系的染料载体墨带。

24. 发明授权

US5179065A Recording material with a display composition including a coloring pigment 失效
标题翻译：具有包含着色颜料的显示组合物的记录材料
公开(公告)号：US5179065A
公开(公告)日：1993-01-12
申请号：US892137
申请日：1992-06-02
申请人： Kengo Ito
发明人： Kengo Ito
IPC分类号： B41M5/20 , G02F1/15
CPC分类号： G02F1/15 , B41M5/20 , Y10S428/913 , Y10T428/24876 , Y10T428/24893
摘要： Disclosed herein is a display composition which comprises a dye and a clay mineral in which quaternary ammonium ions are bound between layers through ion exchange, said display composition undergoing reversible color development and color fading through the oxidation and reduction of said dye, the oxidation causing said dye to form a color and to be bound between the layers of said clay mineral through ion exchange with said quaternary ammonium ions, the reduction causing the dye to discolor and to be desorbed out of the interlaminar space of the clay mineral and also causing the quaternary ammonium ions to be bound again between the layers through ion exchange. Disclosed also herein are a coloring pigment and recording material which employ the display composition.
摘要翻译：本文公开了一种显示组合物，其包含染料和粘土矿物，其中季铵离子通过离子交换结合在层之间，所述显示组合物经历可逆显色和通过所述染料的氧化和还原的褪色，导致所述染料以形成颜色并通过与所述季铵离子的离子交换结合在所述粘土矿物的层之间，所述还原使染料变色并从粘土矿物的层间空间中解吸并且还引起季铵离子通过离子交换再次结合在层之间。本文还公开了使用显示组合物的着色颜料和记录材料。

25. 发明授权

US4496646A Photosensitive imaging material 失效
标题翻译：感光成像材料
公开(公告)号：US4496646A
公开(公告)日：1985-01-29
申请号：US557167
申请日：1983-11-29
申请人： Kengo Ito
发明人： Kengo Ito
IPC分类号： G03F7/031 , G03F7/28 , G03C1/68 , G03C5/00 , G03C5/24
CPC分类号： G03F7/031 , G03F7/28 , Y10S430/106 , Y10S430/12 , Y10S430/121
摘要： A photosensitive imaging material utilizing changes in adhesive properties due to light, wherein an alloxazin derivative represented by the general formula: ##STR1## [wherein R's may be the same or different from each other and each represents an alkyl group having 1 to 20 carbon atoms or a phenylalkyl group represented by the formula: ##STR2## (wherein n is an integer of 1 or more)] is used as a photopolymerization initiator, thereby enhancing the photographic speed and photographic sensitivity of the photosensitive material.Further, in order that the photosensitive material can possess image halftone reproducibility per se, the photosensitive material may be made into a composite material in which a photosensitive layer additionally containing a tertiary amine as a sensitizer is laminated on a hardened layer formed by hardening a photosensitive composition. The photosensitive imaging material of this invention thus constructed can be employed as a copying material for recording or reproducing projected images from a cathode ray tube or a fiber tube.
摘要翻译： PCT No.PCT / JP83 / 00107 Sec。 371日期1983年11月29日 102（e）1983年11月29日PCT PCT提交1983年4月7日PCT公布。公开号WO83 / 03687 日期：1983年10月27日。一种光敏成像材料，其利用由于光引起的粘合性质的变化，其中由以下通式表示的环氧烷衍生物：其中R可以彼此相同或不同，并且各自表示烷基作为光聚合引发剂，可以使用具有1〜20个碳原子的基团或由下式表示的苯基烷基（其中n为1以上的整数）]，从而提高感光材料的感光速度和照相感光度。此外，为了感光材料本身可以具有图像半色调再现性本身，感光材料可以制成复合材料，其中将另外含有作为敏化剂的叔胺的光敏层层压在通过硬化光敏剂形成的硬化层上组成。如此构造的本发明的感光成像材料可以用作用于从阴极射线管或纤维管记录或再现投影图像的复印材料。

26. 发明授权

US09920214B2 Solvent-based paint composition and fluorine-containing copolymer 有权
公开(公告)号：US09920214B2
公开(公告)日：2018-03-20
申请号：US14008259
申请日：2012-03-30
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
IPC分类号： C09D127/18 , C09D127/12 , C08F214/18 , C09D131/04 , C08F214/26 , C08F218/08 , C08F220/64 , C08F216/14
CPC分类号： C09D127/18 , C08F214/18 , C08F214/186 , C08F214/267 , C08F216/1416 , C08F218/08 , C08F220/64 , C09D127/12 , C09D131/04
摘要： Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2═CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C═CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.

27. 发明申请

US20150240012A1 METHOD FOR PRODUCING FLUORINE-CONTAINING COPOLYMER 审中-公开
标题翻译：生产含氟聚合物的方法
公开(公告)号：US20150240012A1
公开(公告)日：2015-08-27
申请号：US14008617
申请日：2012-03-28
申请人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
发明人： Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
IPC分类号： C08F218/08
CPC分类号： C08F218/08 , C08F2/26 , C08F14/18 , C08F214/00 , C08F214/182 , C08F214/186 , C08F214/188 , C08F214/24 , C08F214/245 , C08F214/26 , C08F214/265 , C08F14/26
摘要： The present invention provides a method for producing a copolymer containing a perhaloolefin and vinyl acetate by a novel emulsion polymerization method. The present invention relates to a method for producing a perhaloolefin-vinyl acetate copolymer by emulsion polymerization of at least a perhaloolefin having two carbon atoms and vinyl acetate in the presence of a hydrocarbon emulsifier or in the absence of an emulsifier, provided that the hydrocarbon emulsifier excludes a compound (1) represented by the formula (1): wherein R1 and R2 are the same as or different from each other and each represent a C4 to 12 unfluorinated saturated hydrocarbon group; M represents an alkali metal, an ammonium salt, or an amine salt.
摘要翻译：本发明提供一种通过新的乳液聚合法制备含有全卤代烯烃和乙酸乙烯酯的共聚物的方法。本发明涉及一种通过在烃类乳化剂的存在下或不存在乳化剂的情况下通过至少具有两个碳原子的全卤代烯烃和乙酸乙烯酯的乳液聚合制备全卤代烯烃 - 乙酸乙烯酯共聚物的方法，条件是烃类乳化剂不包括由式（1）表示的化合物（1）：其中R1和R2彼此相同或不同，并且各自表示C4至12个未氟饱和烃基; M表示碱金属，铵盐或胺盐。

28. 发明授权

US06177501B1 Printing paper, dye-receiving layer forming composition for preparing it, ink composition suitable for it, and image forming method using them 失效
公开(公告)号：US06177501B1
公开(公告)日：2001-01-23
申请号：US08967558
申请日：1997-11-12
申请人： Kengo Ito , Yoshio Fujiwara
发明人： Kengo Ito , Yoshio Fujiwara
IPC分类号： C08K322
CPC分类号： B41M5/5218 , B41M2205/12 , C09D11/328 , Y10S260/38 , Y10T428/24893 , Y10T428/24917 , Y10T428/259 , Y10T428/31855 , Y10T428/31928 , Y10T428/31935 , Y10T428/31971 , Y10T428/31978 , Y10T428/31982 , Y10T428/31986
摘要： Color images with high fixation comparable to that of silver salt photographic images are formed on printing papers, using aqueous ink compositions by ink jet recording. Color images thus formed have high saturation and high resolution. An intercalated compound capable of fixing water-soluble dyes to a printing paper due to the intercalation based on ion-exchanging between them is incorporated into the dye-receiving layer 2 of the paper, on which color images are formed by ink jet recording using an aqueous ink composition containing a water-soluble dye. The content of the intercalated compound in the layer 2 is from 10 to 90% by weight. As the intercalated compound, montmorillonoids are preferred when water-soluble cationic dyes are used while hydrotalcite-group minerals are preferred when water-soluble anionic dyes are used. FIG. 1 is selected.

29. 发明授权

US6063836A Printing paper, dye-receiving layer forming composition for preparing it, ink composition suitable for it, and image forming method using them 失效
标题翻译：用于制备它的印刷纸，染料接收层形成组合物，适用于其的油墨组合物和使用它们的成像方法
公开(公告)号：US6063836A
公开(公告)日：2000-05-16
申请号：US684039
申请日：1996-07-19
申请人： Kengo Ito , Yoshio Fujiwara
发明人： Kengo Ito , Yoshio Fujiwara
IPC分类号： B41M5/00 , B41J2/01 , B41M5/50 , B41M5/52 , C08K3/00 , C08K5/00 , C09D11/00 , C09D11/328 , C09D11/10
CPC分类号： B41M5/5218 , C09D11/328 , B41M2205/12 , Y10S260/38 , Y10T428/24893 , Y10T428/24917 , Y10T428/259 , Y10T428/31855 , Y10T428/31928 , Y10T428/31935 , Y10T428/31971 , Y10T428/31978 , Y10T428/31982 , Y10T428/31986
摘要： Color images with high fixation comparable to that of silver salt photographic images are formed on printing papers, using aqueous ink compositions by ink jet recording. Color images thus formed have high saturation and high resolution. An intercalated compound capable of fixing water-soluble dyes to a printing paper due to the intercalation based on ion-exchanging between them is incorporated into the dye-receiving layer 2 of the paper, on which color images are formed by ink jet recording using an aqueous ink composition containing a water-soluble dye. The content of the intercalated compound in the layer 2 is from 10 to 90% by weight. As the intercalated compound, montmorillonoids are preferred when water-soluble cationic dyes are used while hydrotalcite-group minerals are preferred when water-soluble anionic dyes are used.
摘要翻译：使用水性墨水组合物通过喷墨记录在印刷纸上形成具有与银盐照相图像相当的高固色度的彩色图像。如此形成的彩色图像具有高饱和度和高分辨率。通过基于它们之间的离子交换的嵌入，能够将水溶性染料固定在印刷纸上的嵌入化合物被并入到纸的染料接收层2中，在该染料接受层2中通过喷墨记录形成彩色图像，含有水溶性染料的水性油墨组合物。层2中的插层化合物的含量为10〜90重量％。作为插层化合物，当使用水溶性阳离子染料时，优选蒙脱石，而当使用水溶性阴离子染料时，优选水滑石族矿物。

30. 发明授权

US5656759A Hydrophobic cationic dye compounds 失效
标题翻译：疏水性阳离子染料化合物
公开(公告)号：US5656759A
公开(公告)日：1997-08-12
申请号：US484760
申请日：1995-06-07
申请人： Kengo Ito , Masanobu Hida , Kaori Isaji
发明人： Kengo Ito , Masanobu Hida , Kaori Isaji
IPC分类号： B41M5/385 , B41M5/39 , C07D265/38 , C09B19/00 , C09B23/14 , C09B23/16 , C09B69/06 , D06P5/13 , C07D273/00
CPC分类号： C07D265/38 , B41M5/385 , B41M5/39 , C09B19/00 , C09B23/143 , C09B23/166 , C09B69/06 , B41M5/3854
摘要： When the counter ion of hydrophilic cationic dyes is substituted with an organic anion including a sulfosuffinate anion such as diethylhexylsulfonate anion, an alkylbenzenesulfonate anion such as a dodecylbenzenesulfonate, an alkylsulfate anion such as a laurylsulfate anion, or a soap anion such as a laurylsulfate anion, the cationic dyes are imparted with hydrophobicity. An ink layer 3 containing the hydrophobic cationic dye is formed on a support 2 to provide a thermal transfer ink ribbon 10.
摘要翻译：当亲水性阳离子染料的抗衡离子被包括磺基松香酸阴离子的有机阴离子如二乙基己基磺酸盐阴离子，烷基苯磺酸盐阴离子如十二烷基苯磺酸盐，烷基硫酸盐阴离子如月桂基硫酸盐阴离子，或皂阴离子如月桂基硫酸盐阴离子，阳离子染料赋予疏水性。在支撑体2上形成含有疏水性阳离子染料的油墨层3，以提供热转印色带10。

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