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    • 21. 发明专利
    • Fluorescent x-ray analysis method
    • 荧光X射线分析方法
    • JP2008164546A
    • 2008-07-17
    • JP2006356831
    • 2006-12-29
    • Horiba Ltd株式会社堀場製作所
    • TANAKA SATORUKAMETANI AYA
    • G01N23/223G01N1/28
    • PROBLEM TO BE SOLVED: To provide a fluorescent X-ray analysis method which performs high-sensitivity qualitative analyses and high-accuracy quantitative analysis of elements contained in a solid sample, only by carrying out simple pretreatments.
      SOLUTION: A solid sample, such as, a powder sample is weighed, the weighed solid sample is dissolved in a liquid, such as an acid, to prepare a solution, the fluorescent X-ray analysis of the solubilized sample adjusted in the concentration of the solid sample in the solution is performed, and the element to be analyzed in the solubilized sample is calculated by using a calibration curve to be converted to the concentration of the analyzed in the solid sample. The effects of the main component or the matrix of the solid sample is lowered, to quantify the element with high accuracy with the same effects as those of glass beads methods. Even the elements that do not completely dissolve in the solution, can be analyzed, simply by performing the fluorescent X-ray analysis of a solution in which a precipitate is dispersed, a filtered precipitate, or a precipitate that has sedimented in the solution.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种荧光X射线分析方法,其仅通过进行简单的预处理来进行固体样品中包含的元素的高灵敏度定性分析和高精度定量分析。 < P>解决方案:称量固体样品如粉末样品,将称重的固体样品溶解在液体如酸中以制备溶液,将溶解样品的荧光X射线分析调整为 进行固体样品在溶液中的浓度,并且通过使用校正曲线计算待溶解样品中要分析的元素,以将其转化为固体样品中分析的浓度。 降低固体样品的主要成分或基质的影响,以与玻璃珠方法相同的效果,以高精度量化该元素。 即使是不完全溶解在溶液中的元素也可以简单地通过对其中分散有沉淀物的溶液进行荧光X射线分析,过滤的沉淀物或沉淀在溶液中的沉淀物进行分析。 版权所有(C)2008,JPO&INPIT
    • 22. 发明专利
    • Icp analysis method
    • ICP分析方法
    • JP2005017249A
    • 2005-01-20
    • JP2003186468
    • 2003-06-30
    • Horiba LtdMurata Mfg Co Ltd株式会社堀場製作所株式会社村田製作所
    • TANAKA SATORUDAIDOJI HIDEHIROTAMURA TOSHIYUKINISHIMURA MASATOTANIGUCHI SAKIKO
    • G01N21/73
    • PROBLEM TO BE SOLVED: To provide an ICP analysis method for accurately analyzing components when using a spray chamber made of resin to analyze the plurality of components including Si in a hydrofluoric-acid coexistent specimen solution.
      SOLUTION: In this ICP analysis method, the hydrofluoric-acid coexistent specimen solution 13 is supplied to a plasma torch 19 via the spray chamber 1 made of resin to analyze silicon or components including silicon in the specimen solution 13. In order to enhance the wettability of an inner wall of the spray chamber 1, a chemical for reducing surface tension is added to at least any of a standard solution, the specimen solution 13, or a cleaning liquid 14, supplied to the spray chamber 1.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种ICP分析方法,用于在使用由树脂制成的喷雾室时准确地分析组分,以分析包含氢氟酸共存样品溶液中的Si的多种成分。 解决方案:在该ICP分析方法中,将氢氟酸共存样品溶液13经由由树脂制成的喷雾室1供给到等离子体焰炬19,以分析样品溶液13中的硅或包含硅的组分。为了 提高喷雾室1的内壁的润湿性,将至少提供给喷雾室1的标准溶液,试样溶液13或清洗液14中的至少任意一种添加用于降低表面张力的化学品。

      版权所有(C)2005,JPO&NCIPI

    • 23. 发明专利
    • Icp emission spectrophotometer
    • JP2004212166A
    • 2004-07-29
    • JP2002380968
    • 2002-12-27
    • Horiba Ltd株式会社堀場製作所
    • TANAKA SATORUDAIDOJI HIDEHIRO
    • G01N21/73H05H1/30H05H1/42
    • PROBLEM TO BE SOLVED: To provide an emission spectrophotometer capable of reducing the cost for purge processing by shortening the gas purge processing time, and having improved detection accuracy. SOLUTION: This ICP (inductively coupled plasma) emission spectrophotometer has a light emitting part 1 for emitting light in plasma flame from a measuring component element included in a measuring object sample, and a detection part 8 for detecting emission spectrum intensity, and performs quantitative analysis of the measuring component element by using the emission spectrum intensity. The spectrophotometer is provided with an input line 22 for allowing purge gas to flow into the detection part 8, and an output line 24 for allowing the purge gas flowing into the detection part 8 to flow out, and is constituted so that the purge gas is allowed to flow into the detection part 8 through the input line 22 and then to flow out from the output line 24, and that the gas flowing out is guided to the light emitting part 1. By this constitution, when the input line and the output line are opened, the purge gas is allowed to flow into the detection part through the input line, and the detection part is purged by the gas, and if the gas pressure exceeds, for example, a room temperature atmospheric pressure, the gas is allowed to flow out from the input line, and thereby the purge gas always flows in the detection part, and deterioration of the purge gas in the detection part is reduced. Hereby, the detection performance is stabilized, and the detection accuracy of the emission spectrum from the light emitting part is heightened. COPYRIGHT: (C)2004,JPO&NCIPI
    • 25. 发明专利
    • ANALYTICAL METHOD FOR CARBON AND/OR SULFUR IN SOLID SAMPLE
    • JPH10260175A
    • 1998-09-29
    • JP8447697
    • 1997-03-17
    • HORIBA LTD
    • OGURA YOSHIKOOKAYAMA JUNJITANAKA SATORU
    • G01N31/12G01N1/22G01N33/20
    • PROBLEM TO BE SOLVED: To obtain an analytical method in which a carbon component and a sulfur component can be analyzed with high accuracy by a method wherein an Ni foil or an Al foil is placed on a fine powder sample which is put into a heating container and it is heated and oxidized in a heating furnace while oxygen is being supplied. SOLUTION: A heating container 1 is placed in a resistance heating furnace, an Ni foil 3 is placed on a fine powder sample 2 inside the heating container 1, and tin particles 4 are placed on it. The weight of the fine powder sample 2 composed of, e.g. SiO is set at about 0.05g, the weight of the tin particles 4 is set at about 0.7g, the weight of the Ni foil 3 is set at about 0.1g, and its shape size is set at about 6×55×0.1mm. Oxygen gas flows inside the resistance heating furnace at a considerable speed. The surface of the fine powder sample 2 which is easy to float is pressed by the Ni foil 3, the flow of the oxygen on the surface of the fine powder sample 2 is stabilized, carbon and sulfur are easy to react so as to prevent them from being scattered, and the fine powder sample 2 is burned completely. Thereby, a carbon component and a sulfur component can be measured with high accuracy.