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21. 发明授权

US4017611A Control of insects with 3-hydroxymethacrylic acid methyl ester dimethylthionophosphate 失效
标题翻译：用3-羟基甲基丙烯酸甲酯二硫代磷酸二甲酯控制昆虫
公开(公告)号：US4017611A
公开(公告)日：1977-04-12
申请号：US621454
申请日：1975-10-10
申请人： Ernst Beriger , Ladislaus Pinter
发明人： Ernst Beriger , Ladislaus Pinter
IPC分类号： A01N57/12 , C07F9/173 , A01N9/36
CPC分类号： A01N57/12 , C07F9/173
摘要： The compound of the formula ##STR1## its manufacture and use in pest control.
摘要翻译：化学式为“IMAGE”，其制造和用于病虫害防治。

22. 发明授权

US3991140A O-ethyl-S-(n)-propyl-s-carbamoylalkyl dithiophosphates 失效
标题翻译： O-乙基-S-（n） - 丙基-s-氨基甲酰基烷基二硫代磷酸酯
公开(公告)号：US3991140A
公开(公告)日：1976-11-09
申请号：US496430
申请日：1974-08-09
申请人： Ernst Beriger
发明人： Ernst Beriger
IPC分类号： A01N57/12 , C07C209/48 , C07C233/00 , C07F9/165 , C07F9/17 , C07F9/38 , C07F9/40 , C08K5/20 , C09K5/08 , A01N9/36
CPC分类号： A01N57/12 , C07C209/48 , C07C255/00 , C07F9/1651 , C08K5/20 , C09K5/08 , C10M3/00
摘要： S-carbamoylalkyl-O-ethyl-S-(n)-propyldithiophosphoric esters having the formula ##EQU1## wherein R.sub.1 represents hydrogen, methyl or allyl and R.sub.2 represents --CH.sub.2 OCH.sub.3, --C.sub.2 H.sub.4 OCH.sub.3, --C.sub.3 H.sub.6 OCH.sub.3, --CH.sub.2 CN, C.sub.2 H.sub.4 CN, --OCH.sub.3 or allyl a process for their manufacture and their use in pest control.
摘要翻译：具有式C 2 H 5 OOR 1的S-氨基甲酰基烷基-O-乙基-S-（n） - 丙基二硫代磷酸酯平行角PS-CH2-CO-N角（n）C3H7SR2其中R1表示氢，甲基或烯丙基，R2表示-CH2OCH3，-C2H4OCH3 ，-C 3 H 6 OCH 3，-CH 2 CN，C 2 H 4 CN，-OCH 3或烯丙基，其制备方法及其在害虫防治中的应用。

23. 发明授权

US3968222A Insecticidal O,S-dialkyl esters of pyridylthio-and-pyridyldithio-phosphoric acids 失效
标题翻译：杀虫剂O，S-二烷基酯的吡啶硫基 - 和 - 吡啶基二硫代磷酸
公开(公告)号：US3968222A
公开(公告)日：1976-07-06
申请号：US541539
申请日：1975-01-16
申请人： Jozef Drabek , Ernst Beriger , Beat Bohner
发明人： Jozef Drabek , Ernst Beriger , Beat Bohner
IPC分类号： A01N57/16 , C07F9/58 , A01N9/36
CPC分类号： A01N57/16 , C07F9/585
摘要： Pyridylthio- or dithiophosphoric acid esters of the formula ##EQU1## wherein R.sub.1 represents n-propyl, isobutyl, sec.-butyl or n-pentyl,R.sub.2 represents hydrogen, chlorine, bromine, cyano, nitro, (C.sub.1 -C.sub.4 -alkoxy)carbonyl, mono(C.sub.1 -C.sub.4 -alkyl)carbamoyl or di(C.sub.1 -C.sub.4 -alkyl)carbamoyl,R.sub.3 represents hydrogen, chlorine, bromine or methyl, andX represents oxygen or sulphur and their use for combating pests are disclosed.
摘要翻译：式X C2H5O的吡啶硫基 - 或二硫代磷酸酯平行角PO（I）R1S其中R1表示正丙基，异丁基，仲丁基或正戊基，R 2表示氢，氯，溴，氰基，硝基，（C 1 -C 1-4 - 烷氧基）羰基，单（C 1 -C 4 - 烷基）氨基甲酰基或二（C 1 -C 4 - 烷基）氨基甲酰基，R 3表示氢，氯，溴或甲基，X表示氧或硫，它们用于防治害虫披露

24. 发明授权

US5648487A Process for the preparation of aminotriazine derivatives 失效
标题翻译：氨基三嗪衍生物的制备方法
公开(公告)号：US5648487A
公开(公告)日：1997-07-15
申请号：US460474
申请日：1995-06-02
申请人： Ernst Beriger , Haukur Kristinsson
发明人： Ernst Beriger , Haukur Kristinsson
IPC分类号： C07D253/06 , C07D271/10 , C07D271/113 , C07D401/12 , C07D413/06
CPC分类号： C07D253/06 , C07D271/113 , C07D401/12 , C07D413/06
摘要： A process for the preparation of a compound of the formula ##STR1## where Z and R are defined herein. A compound of formula II ##STR2## where R.sub.1 defined herein, is reacted with hydrazine hydrate and then subjected to hydrolysis to form the compound of formula I ##STR3## and the compound of the formula I is reacted with the aldehyde of the formula ##STR4## into the resulting compound of the formula IV.
摘要翻译：其中Z和R在本文中定义的式（IV）化合物的方法。将式II化合物（II）其中本文定义的R 1与水合肼反应，然后进行水解以形成式I化合物（I），并且将式I化合物与式（VI）的醛转化成所得式IV的化合物。

25. 发明授权

US5324842A Process for the preparation of aminotriazine derivatives 失效
标题翻译：氨基三嗪衍生物的制备方法
公开(公告)号：US5324842A
公开(公告)日：1994-06-28
申请号：US991672
申请日：1992-12-16
申请人： Ernst Beriger , Haukur Kristinsson
发明人： Ernst Beriger , Haukur Kristinsson
IPC分类号： C07D253/06 , C07D271/10 , C07D271/113 , C07D401/12 , C07D413/06 , C07D271/07
CPC分类号： C07D253/06 , C07D271/113 , C07D401/12 , C07D413/06
摘要： The invention relates to a process for the preparation of a compound of formula ##STR1## useful as intermediate for the preparation of pesticides, wherein R is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 10 halogen atoms or by from 1 to 3 radicals selected from the group consisting of C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio and phenyl, phenyl or phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, which comprises reacting with hydrazine hydrate a compound of formula ##STR2## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.1 -C.sub.4 alkyl substituted by from 1 to 9 chlorine atoms, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 alkylsulfinyl, C.sub.1 -C.sub.3 alkylsulfonyl, phenyl, phenyl substituted by from 1 to 3 radicals selected from the group consisting of halogen, methyl, ethyl, methoxy, methylthio and nitro, or pyridyl, and subjecting to hydrolysis the resulting compound of formula ##STR3##
摘要翻译：本发明涉及制备式（I）化合物的方法，其可用作制备农药的中间体，其中R是氢，C 1 -C 6烷基，C 3 -C 6环烷基，被1至 10个卤素原子或1至3个选自C 1 -C 3烷氧基，C 1 -C 3烷硫基和苯基的基团，苯基或被1至3个选自卤素，甲基，乙基，甲氧基，甲硫基和硝基，其包括与水合肼反应其中R 1是氢，C 1 -C 4烷基，C 3 -C 6环烷基，被1至9个氯原子取代的C 1 -C 4烷基，C 1 -C 3烷氧基，C 1 C 3烷硫基，C 1 -C 3烷基亚磺酰基，C 1 -C 3烷基磺酰基，苯基，被1至3个选自卤素，甲基，乙基，甲氧基，甲硫基和硝基或吡啶基的基取代的苯基，并将所得化合物公式（III）

26. 发明授权

US5162349A Nematocidal and fungicidal compositions 失效
标题翻译：杀虫剂和杀真菌剂组合物
公开(公告)号：US5162349A
公开(公告)日：1992-11-10
申请号：US408837
申请日：1989-09-18
申请人： Ernst Beriger , Wolfgang Eckhardt
发明人： Ernst Beriger , Wolfgang Eckhardt
IPC分类号： A01N43/82 , A01N43/824 , C07D271/10 , C07D271/113 , C07D285/12 , C07D285/125 , C07D417/04
CPC分类号： C07D271/113 , A01N43/82 , C07D285/125 , C07D417/04
摘要： Mercapto-bis-[1,3,4-oxa- and -thiadiazoles] ##STR1## in which X.sub.1 and X.sub.2 independently of one another are oxygen or sulfur, R.sub.1 is hydrogen or C.sub.1 -C.sub.5 alkyl which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or cyano; C.sub.3 -C.sub.7 alkenyl which is unsubstituted or substituted by halogen; or C.sub.3 -C.sub.7 alkynyl which is unsubstituted or substituted by halogen,R.sup.2 is hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.3 alkoxy which is unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkylthio which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.7 alkenylthio which is unsubstituted or substituted by halogen, C.sub.3 -C.sub.7 alkylnylthio which is unsubstituted or substituted by halogen, --SH, phenyl which is unsubstituted or substituted by halogen or ##STR2## in which R.sub.3 and R.sub.4 are C.sub.1 -C.sub.3 alkyl, and processes for the preparation of the compounds of the formula I are described.The compounds of the formula I have nematocidal and microbicidal properties. Nematocidal compositions which contain at least one active substance of the formula I as the active substance and furthermore processes for the use of the active substances and the compositions in combating nematodes and fungi which are harmful to plants are described.
摘要翻译：其中X 1和X 2彼此独立地是氧或硫，R 1是氢或C 1 -C 5烷基的巯基 - 双 - [1,3,4-氧杂 - 噻二唑]（I）卤素，C 1 -C 3烷氧基或氰基; 未被取代或被卤素取代的C3-C7链烯基; 或未取代或被卤素取代的C 3 -C 7炔基，R 2是氢，C 1 -C 5烷基，未被取代或被卤素取代的C 1 -C 3烷氧基，未被取代或被卤素取代的C 1 -C 3烷硫基，未取代或取代的C 3 -C 7链烯基未取代或被卤素取代的C 3 -C 7烷基硫基，-SH，未被取代或被卤素取代的苯基或其中R 3和R 4为C 1 -C 3烷基的化合物，以及制备式我被描述式I的化合物具有杀线虫和杀微生物的性质。描述了含有至少一种式I活性物质作为活性物质的杀伤组合物，并且还描述了使用活性物质和组合物来防治对植物有害的线虫和真菌的方法。

27. 发明授权

US5013745A Nematicidal compositions 失效
标题翻译：杀线虫组合物
公开(公告)号：US5013745A
公开(公告)日：1991-05-07
申请号：US408838
申请日：1989-09-18
申请人： Ernst Beriger , Wolfgang Eckhardt
发明人： Ernst Beriger , Wolfgang Eckhardt
IPC分类号： A01N43/82 , C07D271/10 , C07D271/113 , C07D285/12 , C07D285/125 , C07D413/04 , C07D417/04 , G04B37/10
CPC分类号： A01N43/82 , C07D271/113 , C07D285/125 , C07D413/04 , C07D417/04 , G04B37/10
摘要： 2-Mercapto-1,3,4-oxadiazoles and 2-mercapto-1,3,4-thiadiazoles of the formula I ##STR1## in which X.sub.1 and X.sub.2 independently of one another are oxygen or sulfur, R.sub.1 is difluoromethyl or 3,4,4-trifluoro-3-butenyl, R.sub.2 is hydrogen or C.sub.1 -C.sub.3 alkyl and R.sub.3 is hydrogen, C.sub.1 -C.sub.5 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, C.sub.3 -C.sub.7 alkenyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, C.sub.3 -C.sub.7 alkynyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.3 alkoxy, or phenyl which is unsubstituted or substituted by halogen, NO.sub.2, CF.sub.3, C.sub.1 -C.sub.3 -alkyl or C.sub.1 -C.sub.3 alkoxy, or wherein, furthermore, R.sub.2 and R.sub.3 together can form the methylene chain (--CH.sub.2 --)n as a constituent of a 5- or 6-membered ring with the heteroatom X.sub.1, in which n is 3 or 4, and processes for the preparation of the compounds of the formula I are described.The compounds of the formula I have nematicidal properties. Nematicidal compositions which contain at least one active substance of the formula I as the active substance and furthermore methods of using the active substances and the compositions for controlling nematodes are described.
摘要翻译：式I的2-巯基-1,3,4-恶二唑和2-巯基-1,3,4-噻二唑其中X1和X2彼此独立地是氧或硫，R1是二氟甲基或3,4,4-三氟-3-丁烯基，R 2是氢或C 1 -C 3烷基，R 3是氢，未被取代或被卤素或C 1 -C 3烷氧基取代的C 1 -C 5烷基，未被取代或被卤素取代的C 3 -C 7链烯基或C1-C3烷氧基，未被取代或被卤素或C1-C3烷氧基取代的C3-C7炔基，或未被取代或被卤素，NO2，CF3，C1-C3-烷基或C1-C3烷氧基取代的苯基，或者其中R2 和R3一起可以形成作为与杂原子X1（其中n为3或4）的5或6元环的组成的亚甲基链（-CH 2 - ）n，以及制备式我被描述式I的化合物具有杀线虫性质。描述了含有至少一种式I活性物质作为活性物质的杀线虫剂组合物，以及使用活性物质和组合物控制线虫的方法。

28. 发明授权

US4910210A Nematicidal compositions 失效
标题翻译：杀线虫组合物
公开(公告)号：US4910210A
公开(公告)日：1990-03-20
申请号：US285846
申请日：1988-12-16
申请人： Ernst Beriger , Wolfgang Eckhardt
发明人： Ernst Beriger , Wolfgang Eckhardt
IPC分类号： A01N43/82 , A01N43/824 , C07D285/12 , C07D285/125 , C07D417/12
CPC分类号： C07D285/125 , A01N43/82 , C07D417/12
摘要： Novel compounds of the formula ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.12 alkyl that is unsubstituted or substituted by halogen, phenyl, C.sub.1 -C.sub.3 alkoxy or by hydroxy, C.sub.1 -C.sub.3 alkyl that is substituted by carbonyl, O-alkylcarboxy, amino or by a heterocycle, unsubstituted or halo-substituted C.sub.3 -C.sub.7 cycloalkyl or unsubstituted cyclopropylmethyl, unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkenyl, unsubstituted or halo-substituted C.sub.3 -C.sub.7 alkynyl, benzyl that is unsubstituted or mono-, di-or tri-substituted in the nucleus by C.sub.1 -C.sub.4 alkyl, halogen, nitro, cyano or by trifluoromethyl, or is the radical R.sub.2 --(O--CH.sub.2 --CH.sub.2 --)n wherein R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl and n is a number from 1 to 3, as active ingredients for controlling nematodes that parasitise plants and for preventing damage to cultivated plants caused by nematode attack.
摘要翻译：式（I）的新型化合物，其中R 1是未被取代或被卤素，苯基，C 1 -C 3烷氧基或羟基取代的C 1 -C 12烷基，被羰基，O-烷基羧基，氨基或被烷基取代的C 1 -C 3烷基未取代或未取代的或未取代的或未被取代的C 3 -C 7炔基，未被取代的或被卤素取代的C 3 -C 7炔基，在核中未被取代或单，二或三取代的苄基或C 1 -C 4烷基，卤素，硝基，氰基或三氟甲基，或其中R 2为氢或C 1 -C 4烷基且n为1至3的数的基团R 2 - （O-CH 2 -CH 2 - ）n作为活性成分用于控制寄生植物的线虫和防止由线虫攻击引起的对栽培植物的损害。

29. 发明授权

US4861367A 2-Mercapto-5-pyrazinyl-1,3,4-oxadiazoles or 2-mercapto-5-pyrazinyl-1,3,4-thiadiazoles as nematicides 失效
标题翻译： 2-巯基-5-吡嗪基-1,3,4-恶二唑或2-巯基-5-吡嗪基-1,3,4-噻二唑作为杀线虫剂
公开(公告)号：US4861367A
公开(公告)日：1989-08-29
申请号：US172884
申请日：1988-03-25
申请人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger
发明人： Robert Nyfeler , Wolfgang Eckhardt , Ernst Beriger
IPC分类号： A01N43/82 , A01N43/824 , C07D413/04 , C07D417/04
CPC分类号： C07D413/04 , A01N43/82 , C07D417/04
摘要： 2-Mercapto-5-pyrazinyl-1,3,4-oxadiazoles and 2-mercapto-5-pyrazinyl-1,3,4-thiadiazoles of formula I ##STR1## wherein X is oxygen or sulfur,R' is C.sub.1 -C.sub.5 alkyl, unsubstituted or substituted by halogen, C.sub.1 -C.sub.3 alkoxy or cyano; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkenyl; unsubstituted or halogen-substituted C.sub.3 -C.sub.7 alkynyl,R is C.sub.1 -C.sub.3 alkyl, unsubstituted C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 alkoxy which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy; halogen, cyano, hydroxy, amino or amino which is substituted by one or two C.sub.1 -C.sub.3 alkyl groups; or is aminocarbonyl; andn is 0, 1, 2 or 3, the preparation thereof and novel intermediates for their synthesis are disclosed.The compounds of formula I have nematicidal properties. Nematicidal compositions which contain at least one compound of formula I as active ingredient, methods of using said compounds and of the compositions containing them for controlling nematodes are also disclosed.
摘要翻译： 2-巯基-5-吡嗪基-1,3,4-恶二唑和式I的2-巯基-5-吡嗪基-1,3,4-噻二唑其中X是氧或硫，R'是 C1-C5烷基，未取代或被卤素，C1-C3烷氧基或氰基取代; 未取代或卤素取代的C 3 -C 7链烯基; 未取代的或卤素取代的C3-C7炔基，R是C1-C3烷基，未取代的C1-C3烷氧基或被卤素或C1-C3烷氧基取代的C1-C3烷氧基; 卤素，氰基，羟基，氨基或被一个或两个C 1 -C 3烷基取代的氨基; 或是氨基羰基; 并且n为0,1,2或3，其制备及其合成的新中间体被公开。式I的化合物具有杀线虫性质。还公开了含有至少一种式I化合物作为活性成分的杀线虫剂组合物，使用所述化合物和含有它们的组合物用于控制线虫的方法。

30. 发明授权

US4123551A 2,2-Disubstituted-phenylcarbamoyl-6-hydroxy-m-dioxin-4-one derivatives having insecticidal properties 失效
标题翻译：具有杀虫性能的2,2-二取代 - 苯基氨基甲酰基-6-羟基 - 间二恶英-4-酮衍生物
公开(公告)号：US4123551A
公开(公告)日：1978-10-31
申请号：US758260
申请日：1977-01-10
申请人： Ernst Beriger
发明人： Ernst Beriger
IPC分类号： A01N43/32 , C07D319/06 , C07D319/08 , A01N9/28
CPC分类号： C07D319/08 , C07D319/06
摘要： Compounds of the formula I ##STR1## wherein R.sub.1 represents a phenyl group substituted by one or two members selected from the group consisting of halogen, alkyl having at most 3 carbon atoms, trifluoromethyl, nitro and cyano; and either(i) R.sub.2 represents an alkyl group having at most 5 carbon atoms andR.sub.3 represents a methyl group or(ii) R.sub.2 and R.sub.3 together represent a tetramethylene or pentamethylene group;With the proviso that, when R.sub.2 and R.sub.3 both represent methyl groups or when R.sub.2 and R.sub.3 together represent a tetramethylene or pentamethylene group, R.sub.1 may not represent a 3-chlorophenyl, 4-chlorophenyl, 3,4-dichlorophenyl or 4-fluorophenyl group, possess valuable insecticidal properties.
摘要翻译：式I的化合物其中R 1表示被一个或两个选自卤素，最多3个碳原子的烷基，三氟甲基，硝基和氰基的基团取代的苯基; （I）R 2表示具有5个以下碳原子的烷基，R 3表示甲基或（II）R 2，R 3一起表示四亚甲基或五亚甲基; 当R2和R3都表示甲基时，或当R2和R3一起表示四亚甲基或五亚甲基时，R 1可以不表示3-氯苯基，4-氯苯基，3,4-二氯苯基或4-氟苯基，具有有价值的杀虫性能。

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