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21. 发明申请

US20100133513A1 NANOPARTICLE / NANOTUBE-BASED NANOELECTRONIC DEVICES AND CHEMICALLY-DIRECTED ASSEMBLY THEREOF 有权
标题翻译：基于纳米基/纳米管的纳米电子器件及其化学成分
公开(公告)号：US20100133513A1
公开(公告)日：2010-06-03
申请号：US11910521
申请日：2007-02-02
申请人： Howard K. Schmidt
发明人： Howard K. Schmidt
IPC分类号： H01L31/0352 , H01L31/18
CPC分类号： B82Y20/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , H01L31/035227 , H01L31/1085 , H01L51/0049 , H01L51/0595 , Y10S977/712 , Y10S977/743 , Y10S977/806
摘要： According to some embodiments, the present invention provides a nanoelectronic device based on a nanostructure that may include a nanotube with first and second ends, a metallic nanoparticle attached to the first end, and an insulating nanoparticle attached to the second end. The nanoelectronic device may include additional nanostructures so a to form a plurality of nanostructures comprising the first nanostructure and the additional nanostructures. The plurality of nanostructures may arranged in a network comprising a plurality of edges and a plurality of vertices, wherein each edge comprises a nanotube and each vertex comprises at least one insulating nanoparticle and at least one metallic nanoparticle adjacent the insulating nanoparticle. The combination of at least one edge and at least one vertex comprises a diode. The device may be an optical rectenna.
摘要翻译：根据一些实施方案，本发明提供了一种基于纳米结构的纳米电子器件，其可以包括具有第一和第二末端的纳米管，附着到第一端的金属纳米颗粒和附着到第二末端的绝缘纳米颗粒。纳米电子器件可以包括另外的纳米结构，从而形成包含第一纳米结构和另外的纳米结构的多个纳米结构。多个纳米结构可以布置在包括多个边缘和多个顶点的网络中，其中每个边缘包括纳米管，并且每个顶点包括至少一个绝缘纳米颗粒和与绝缘纳米颗粒相邻的至少一个金属纳米颗粒。至少一个边缘和至少一个顶点的组合包括二极管。该装置可以是光学整流天线。

22. 发明申请

US20080213162A1 Amplification of Carbon Nanotubes Via Seeded-Growth Methods 失效
标题翻译：通过种子生长方法扩增碳纳米管
公开(公告)号：US20080213162A1
公开(公告)日：2008-09-04
申请号：US10575352
申请日：2004-10-14
申请人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
发明人： Richard E. Smalley , Irene M. Marek , Robert H. Hauge , Andrew R. Barron , James M. Tour , Howard K. Schmidt , W. Edward Billups , Christopher A. Dyke , Valerie C. Moore , Elizabeth Whitsitt , Robin E. Anderson , Ramon Colorado , Michael P. Stewart , Douglas C. Ogrin
IPC分类号： C09C1/44
CPC分类号： B82Y40/00 , B01J23/881 , B01J27/22 , B82Y30/00 , C01B3/0021 , C01B32/162 , C01B32/172 , C01B32/176 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/36 , Y02E60/325
摘要： The present invention is directed towards methods (processes) of providing large quantities of carbon nanotubes (CNTs) of defined diameter and chirality (i.e., precise populations). In such processes, CNT seeds of a pre-selected diameter and chirality are grown to many (e.g., hundreds) times their original length. This is optionally followed by cycling some of the newly grown material back as seed material for regrowth. Thus, the present invention provides for the large-scale production of precise populations of CNTs, the precise composition of such populations capable of being optimized for a particular application (e.g., hydrogen storage). The present invention is also directed to complexes of CNTs and transition metal catalyst precurors, such complexes typically being formed en route to forming CNT seeds.
摘要翻译：本发明涉及提供大量具有规定直径和手性（即，精确群体）的大量碳纳米管（CNT）的方法（方法）。在这种方法中，预先选择的直径和手性的CNT种子生长到其原始长度的许多（例如，数百）倍。随后可以将一些新生成的材料循环回种子材料再生。因此，本发明提供了大规模生产精确的碳纳米管群体，能够针对特定应用（例如，氢存储）优化的这些群体的精确组成。本发明还涉及CNT和过渡金属催化剂前体的复合物，这些络合物通常在形成CNT晶种途中形成。

23. 发明申请

US20080105648A1 Carbon nanotube substrates and catalyzed hot stamp for polishing and patterning the substrates 失效
标题翻译：碳纳米管基底和用于抛光和图案化基底的催化热印
公开(公告)号：US20080105648A1
公开(公告)日：2008-05-08
申请号：US11300031
申请日：2005-12-14
申请人： Yuhuang Wang , Robert H. Hauge , Howard K. Schmidt , Myung Jong Kim , W. Carter Kittrell
发明人： Yuhuang Wang , Robert H. Hauge , Howard K. Schmidt , Myung Jong Kim , W. Carter Kittrell
IPC分类号： H01B13/00 , C03C25/68
CPC分类号： B82Y40/00 , B82Y30/00 , C01B32/168 , C01B2202/02 , Y10S977/745
摘要： The present invention is generally directed to catalyzed hot stamp methods for polishing and/or patterning carbon nanotube-containing substrates. In some embodiments, the substrate, as a carbon nanotube fiber end, is brought into contact with a hot stamp (typically at 200-800° C.), and is kept in contact with the hot stamp until the morphology/patterns on the hot stamp have been transferred to the substrate. In some embodiments, the hot stamp is made of material comprising one or more transition metals (Fe, Ni, Co, Pt, Ag, Au, etc.), which can catalyze the etching reaction of carbon with H2, CO2, H2O, and/or O2. Such methods can (1) polish the carbon nanotube-containing substrate with a microscopically smooth finish, and/or (2) transfer pre-defined patterns from the hot stamp to the substrate. Such polished or patterned carbon nanotube substrates can find application as carbon nanotube electrodes, field emitters, and field emitter arrays for displays and electron sources.
摘要翻译：本发明一般涉及用于研磨和/或构图含碳纳米管的基底的催化热印方法。在一些实施方案中，作为碳纳米管纤维端的基底与热印模（通常在200-800℃）接触，并且与热印模保持接触，直到热的形态/图案印章已经转移到基材上。在一些实施例中，热压印由包含一种或多种过渡金属（Fe，Ni，Co，Pt，Ag，Au等）的材料制成，其可以催化碳与H 2的蚀刻反应， CO 2，H 2 O和/或O 2。这样的方法可以（1）用微观平滑光洁度抛光含碳纳米管的基材，和/或（2）将预定义的图案从热印刷转印到基材上。这种抛光或图案化的碳纳米管基底可以用作碳纳米管电极，场致发射体和用于显示器和电子源的场发射极阵列。

24. 发明授权

US5504767A Doped diamond laser 失效
标题翻译：掺杂金刚石激光
公开(公告)号：US5504767A
公开(公告)日：1996-04-02
申请号：US406306
申请日：1995-03-17
申请人： Keith D. Jamison , Howard K. Schmidt
发明人： Keith D. Jamison , Howard K. Schmidt
IPC分类号： H01S3/16
CPC分类号： H01S3/16 , H01S3/163
摘要： A solid state laser is provided having as the laser medium diamond and an optically active dopant element which is found to lase in the solid matrix. The dopant is preferably titanium, vanadium, chromium, iron, cobalt, nickel, zinc, zirconium, niobium, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and uranium. Erbium is especially preferred. The laser medium is formed as dopants are added by ion implantation to a diamond crystal as the diamond is grown by chemical vapor deposition.
摘要翻译：提供固体激光器，其具有作为激光介质金刚石和发现在固体基质中的光学活性掺杂元素。掺杂剂优选为钛，钒，铬，铁，钴，镍，锌，锆，铌，镉，铪，钽，钨，铼，锇，铱，铂，金，汞，铈，镨，钕，ium，钐，铕，钆，铽，镝，钬，铒，ium，镱和铀。铒是特别优选的。形成激光介质，因为当金刚石通过化学气相沉积生长时，通过离子注入将掺杂剂添加到金刚石晶体。

25. 发明申请

US20220316445A1 SkyPipes for Renewable Water and Power Production 有权
公开(公告)号：US20220316445A1
公开(公告)日：2022-10-06
申请号：US17714043
申请日：2022-04-05
申请人： Howard K. Schmidt
发明人： Howard K. Schmidt
IPC分类号： F03D9/37 , B01D5/00
摘要： An apparatus for condensing water and producing electricity. In one embodiment, the apparatus may comprise a plurality of fabricated tubes, wherein the tubes may be filled with and enclose hydrogen, helium, or combinations thereof, and wherein the tubes may be bonded together lengthwise in a circular assembly to provide a cylindrical structure comprising a central bore. Further, the apparatus may comprise and a ground structure, wherein a lower portion of the cylindrical structure may be tethered to the ground structure.

26. 发明申请

US20170171691A1 ENVIRONMENT-AWARE CROSS-LAYER COMMUNICATION PROTOCOL IN UNDERGROUND OIL RESERVOIRS 审中-公开
公开(公告)号：US20170171691A1
公开(公告)日：2017-06-15
申请号：US15370740
申请日：2016-12-06
申请人： Ian F. Akyildiz , Howard K. Schmidt , Shih-Chun Lin
发明人： Ian F. Akyildiz , Howard K. Schmidt , Shih-Chun Lin
IPC分类号： H04W4/00 , H04W24/02
CPC分类号： H04W24/02 , G06F8/30 , H04W4/38 , H04W4/70 , H04W84/18
摘要： Example computer-implemented methods, computer-readable media, and computer systems are described for providing communication protocol architecture or framework for magnetic induction (MI)-based communications in wireless underground sensor networks (WUSNs), for example, in underground oil reservoirs. In some aspects, environment information of an underground region that affects the transmission qualities of MI communications is evaluated. A protocol stack is identified. The protocol stack includes a number of layers for MI communications among a number of sensors in a WUSN in the underground region. A cross-layer framework and the distributed protocol are built to jointly optimize communication functionalities of the plurality of layers based on the evaluation.

27. 发明申请

US20110144386A1 Graphene Compositions and Drilling Fluids Derived Therefrom 有权
标题翻译：石墨烯组合物和钻井液
公开(公告)号：US20110144386A1
公开(公告)日：2011-06-16
申请号：US12812169
申请日：2009-01-08
申请人： James M. Tour , Howard K. Schmidt , Condell D. Doyle , Dmitry V. Kosynkin , Jay R. Lomeda
发明人： James M. Tour , Howard K. Schmidt , Condell D. Doyle , Dmitry V. Kosynkin , Jay R. Lomeda
IPC分类号： C07C63/00 , C07C25/24 , C07C205/45 , C07C43/235 , C07C17/281 , C01B31/00
CPC分类号： C09K8/032 , B82Y30/00 , B82Y40/00 , C01B32/192 , C01B32/194 , C01B32/23 , C01B2204/04 , C01B2204/28 , C09K8/035 , C09K8/62 , Y10S977/734 , Y10S977/737 , Y10S977/738
摘要： Drilling fluids comprising graphenes and nanoplatelet additives and methods for production thereof are disclosed. Graphene includes graphite oxide, graphene oxide, chemically-converted graphene, and functionalized chemically-converted graphene. Derivatized graphenes and methods for production thereof are disclosed. The derivatized graphenes are prepared from a chemically-converted graphene through derivatization with a plurality of functional groups. Derivatization can be accomplished, for example, by reaction of a chemically-converted graphene with a diazonium species. Methods for preparation of graphite oxide are also disclosed.
摘要翻译：公开了包含石墨烯和纳米血小板添加剂的钻井液及其生产方法。石墨烯包括氧化石墨，氧化石墨烯，化学转化的石墨烯和官能化的化学转化的石墨烯。公开了衍生化的石墨烯及其生产方法。衍生的石墨烯通过具有多个官能团的衍生化由化学转化的石墨烯制备。衍生化可以通过例如化学转化的石墨烯与重氮物质的反应来实现。还公开了制备氧化石墨的方法。

28. 发明申请

US20110110843A1 NEAT CARBON NANOTUBE ARTICLES PROCESSED FROM SUPER ACID SOLUTIONS AND METHODS FOR PRODUCTION THEREOF 审中-公开
标题翻译：从超酸溶液中处理的碳纳米管制品及其生产方法
公开(公告)号：US20110110843A1
公开(公告)日：2011-05-12
申请号：US12740529
申请日：2008-10-29
申请人： Matteo Pasquali , Wen-Fang Hwang , Howard K. Schmidt , Natneal Behabtu , Virginia Davis , A. Nicholas G. Parra-Vasquez , Micah J. Green , Richard Booker , Colin c. Young , Hua Fan
发明人： Matteo Pasquali , Wen-Fang Hwang , Howard K. Schmidt , Natneal Behabtu , Virginia Davis , A. Nicholas G. Parra-Vasquez , Micah J. Green , Richard Booker , Colin c. Young , Hua Fan
IPC分类号： D01F9/12 , C01B31/02 , B29C47/00 , B82Y30/00 , B82Y40/00
CPC分类号： D01F11/12 , B29C48/0018 , B29C48/05 , B29C48/11 , B29C48/475 , B29C48/919 , B29K2105/162 , B29K2105/167 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/04 , C01B2202/06 , C01B2202/28 , C01B2202/34 , D01D5/06 , D01F9/12
摘要： Articles comprising neat, aligned carbon nanotubes and methods for production thereof are disclosed. The articles and methods comprise extrusion of a super acid solution of carbon nanotubes followed by removal of the super acid solvent. The articles may be processed by wet-jet wet spinning, dry-jet wet spinning, and coagulant co-flow extrusion techniques.
摘要翻译：公开了包含整齐排列的碳纳米管的制品及其生产方法。制品和方法包括挤出碳纳米管的超酸溶液，然后除去超酸溶剂。制品可以通过湿喷湿纺，干喷湿法纺丝和凝结剂共流挤出技术加工。

29. 发明授权

US07893513B2 Nanoparticle/nanotube-based nanoelectronic devices and chemically-directed assembly thereof 有权
标题翻译：基于纳米颗粒/纳米管的纳米电子器件及其化学指向的组装
公开(公告)号：US07893513B2
公开(公告)日：2011-02-22
申请号：US11910521
申请日：2007-02-02
申请人： Howard K. Schmidt
发明人： Howard K. Schmidt
IPC分类号： H01L27/14
CPC分类号： B82Y20/00 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/15 , H01L31/035227 , H01L31/1085 , H01L51/0049 , H01L51/0595 , Y10S977/712 , Y10S977/743 , Y10S977/806
摘要： According to some embodiments, the present invention provides a nanoelectronic device based on a nanostructure that may include a nanotube with first and second ends, a metallic nanoparticle attached to the first end, and an insulating nanoparticle attached to the second end. The nanoelectronic device may include additional nanostructures so a to form a plurality of nanostructures comprising the first nanostructure and the additional nanostructures. The plurality of nanostructures may arranged in a network comprising a plurality of edges and a plurality of vertices, wherein each edge comprises a nanotube and each vertex comprises at least one insulating nanoparticle and at least one metallic nanoparticle adjacent the insulating nanoparticle. The combination of at least one edge and at least one vertex comprises a diode. The device may be an optical rectenna.
摘要翻译：根据一些实施方案，本发明提供了一种基于纳米结构的纳米电子器件，其可以包括具有第一和第二末端的纳米管，附着到第一端的金属纳米颗粒和附着到第二末端的绝缘纳米颗粒。纳米电子器件可以包括另外的纳米结构，从而形成包含第一纳米结构和另外的纳米结构的多个纳米结构。多个纳米结构可以布置在包括多个边缘和多个顶点的网络中，其中每个边缘包括纳米管，并且每个顶点包括至少一个绝缘纳米颗粒和与绝缘纳米颗粒相邻的至少一个金属纳米颗粒。至少一个边缘和至少一个顶点的组合包括二极管。该装置可以是光学整流天线。

30. 发明申请

US20100176349A1 REDOX FRACTIONATION OF SINGLE-WALLED CARBON NANOTUBES 审中-公开
标题翻译：单壁碳纳米管的氧化还原分解
公开(公告)号：US20100176349A1
公开(公告)日：2010-07-15
申请号：US12443213
申请日：2007-09-27
申请人： Howard K. Schmidt , Robert H. Hauge , Noe T. Alvarez
发明人： Howard K. Schmidt , Robert H. Hauge , Noe T. Alvarez
IPC分类号： H01B1/04 , C01B31/00 , B07B13/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/172 , C01B32/174 , C01B2202/02 , C01B2202/22 , C01B2202/36
摘要： A method for separating fractions of single-walled carbon nanotubes includes exposing a solution containing fractions of single-walled carbon nanotubes to a reducing agent and separating the resulting reaction products. An alternate method for separating fractions of single-walled carbon nanotubes includes exposing a solution containing fractions of single-walled carbon nanotubes to an oxidizing agent and separating the resulting reaction products. A third method for separating fractions of single-walled carbon nanotubes includes exposing a solution containing fractions of substantially non-functionalized single-walled carbon nanotubes to a charge transfer complex agent and separating the resulting reaction products. These methods allow the production of single-walled carbon nanotubes of approximately 95 to 99% metallic and semiconducting types.
摘要翻译：分离单壁碳纳米管部分的方法包括将含有单壁碳纳米管的溶液暴露于还原剂中并分离所得的反应产物。用于分离单壁碳纳米管部分的替代方法包括将含有单壁碳纳米管的溶液暴露于氧化剂中并分离所得的反应产物。用于分离单壁碳纳米管级分的第三种方法包括将含有基本上非官能化的单壁碳纳米管馏分的溶液暴露于电荷转移络合剂并分离所得反应产物。这些方法允许生产约95至99％的金属和半导体类型的单壁碳纳米管。

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