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21. 发明申请

US20130112268A1 FILM CONTAINING AN ODOURLESS FLUORINATED ACRYLIC POLYMER FOR PHOTOVOLTAIC USE 审中-公开
标题翻译：含有无光氟化丙烯酸聚合物的电影用于光伏使用
公开(公告)号：US20130112268A1
公开(公告)日：2013-05-09
申请号：US13522037
申请日：2011-01-11
申请人： Anthony Bonnet , Francois Beaume , Stephane Bizet , Nicolas Devaux
发明人： Anthony Bonnet , Francois Beaume , Stephane Bizet , Nicolas Devaux
IPC分类号： C08K3/22 , H01L31/048
CPC分类号： C08K3/22 , C08J3/201 , C08J5/18 , C08J2327/16 , C08L27/16 , H01L31/049 , Y02E10/50
摘要： The present invention relates to a composition consisting of a fluoropolymer and a white inorganic filler, said composition being intended for the manufacture of monolayer films opaque to visible tight and to UV radiation, useable in particular in the field of photovoltaic cells. The polymeric composition consists of a fluoropolymer and zinc oxide (ZnO), said filler being present in said composition in a weight proportion of 20 to 40%, preferably 20 to 35%. The use of this filler serves on the one hand to avoid the addition of acrylic polymers to the fluoropolymer, and on the other hand, to use processing temperatures that are compatible with the manufacture of a monolayer film by extrusion blow moulding, that is, a temperature of about 220 to 260° C., thereby serving to prevent the degradation of the fluoropolymer.
摘要翻译：本发明涉及一种由氟聚合物和白色无机填料组成的组合物，所述组合物旨在用于制造对于可见的紧密和紫外线辐射不透明的单层膜，特别是在光伏电池领域中。聚合物组合物由氟聚合物和氧化锌（ZnO）组成，所述填料以20-40％，优选20-35％的重量比存在于所述组合物中。使用这种填料一方面是为了避免向含氟聚合物中加入丙烯酸聚合物，另一方面，使用通过挤出吹塑成型制备单层膜的加工温度，即，温度为约220至260℃，从而用于防止含氟聚合物的降解。

22. 发明授权

US08178179B2 PVDF-based conductive composition 有权
标题翻译：基于PVDF的导电组合物
公开(公告)号：US08178179B2
公开(公告)日：2012-05-15
申请号：US12297020
申请日：2007-03-20
申请人： Anthony Bonnet , Michael Werth , Karine Triballier
发明人： Anthony Bonnet , Michael Werth , Karine Triballier
IPC分类号： B32B1/08
CPC分类号： H01B1/24 , B32B1/02 , B32B1/08 , B32B15/08 , B32B27/06 , B32B27/08 , B32B27/18 , B32B27/304 , B32B27/322 , B32B2264/108 , B32B2307/202 , B32B2307/3065 , B32B2597/00 , C08K3/04 , C08L27/16 , C08L2205/02 , Y10T428/1352 , Y10T428/139 , Y10T428/3154 , C08L2666/04
摘要： The invention concerns a conductive composition comprising (by weight): 30 to 60 parts of a fluid PVDF; 25 to 62 parts of a viscous PVDF; 8 to 13 parts of a conductive filler; 0 to 2 parts of a fire retardant agent; 0 to 0.05 parts of a nucleating agent, based on a total of 100 parts. Preferably, it comprises by weight: 35 to 50 parts of a fluid PVDF; 45 to 55 parts of a viscous PVDF; 8 to 13 parts of a conductive filler; 0 to 2 parts of a fireproof agent; 0 to 0.05 parts of a nucleating agent, based on a total of 100 parts. Preferably, the conductive composition has a viscosity in the molten state at 230° C. of less than 106 Pa·s, preferably between 102 and 106 Pa·s. The invention also concerns multilayer structures combining the conductive composition and a thermoplastic polymer or a metal.
摘要翻译：本发明涉及一种导电组合物，其包含（重量）：30至60份的流体PVDF; 25〜62份粘性PVDF; 8〜13份导电填料; 0〜2份阻燃剂; 0〜0.05份成核剂，总共100份。优选地，其包含重量：35至50份流体PVDF; 45〜55份粘性PVDF; 8〜13份导电填料; 0〜2份防火剂; 0〜0.05份成核剂，总共100份。优选地，导电组合物在230℃的熔融状态下的粘度小于106Pa·s，优选在102和106Pa·s之间。本发明还涉及组合导电组合物和热塑性聚合物或金属的多层结构。

23. 发明授权

US08053502B2 PVDF-based extrusion-aiding agent 有权
标题翻译： PVDF型挤出助剂
公开(公告)号：US08053502B2
公开(公告)日：2011-11-08
申请号：US12295954
申请日：2007-03-20
申请人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
发明人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
IPC分类号： C08K5/51
CPC分类号： C08L23/0815 , C08F14/18 , C08K5/527 , C08L23/06 , C08L27/16 , C08F2/02 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The invention concerns to a composition comprising: at least one fluorinated polymer (A), at least one interfacing agent (B), and at least one stabilizer (C) of formula (I) wherein Ar1 and Ar2 represent an aryl group. The composition is used as an agent for extruding a thermoplastic polyolefin or resin. The invention also concerns an extruding method consisting in: (i) contacting in the solid phase a composition as defined above with a thermoplastic polyolefin or a thermoplastic resin; (ii) then extruding the mixture obtained in (i) in the form of a film, a tube, a profiled section or a hollow body.
摘要翻译：本发明涉及一种组合物，其包含：至少一种氟化聚合物（A），至少一种界面剂（B）和至少一种式（I）的稳定剂（C），其中Ar1和Ar2表示芳基。该组合物用作挤出热塑性聚烯烃或树脂的试剂。本发明还涉及挤出方法，其包括：（i）在固相中使如上定义的组合物与热塑性聚烯烃或热塑性树脂接触; （ii）然后将（i）中获得的混合物以薄膜，管，型材部分或中空体的形式挤出。

24. 发明授权

US07494740B2 Microcomposite powder based on flat graphite particles and on a fluoropolymer and objects made from same 有权
标题翻译：基于平坦石墨颗粒和含氟聚合物的微复合粉末和由其制成的物体
公开(公告)号：US07494740B2
公开(公告)日：2009-02-24
申请号：US10499847
申请日：2002-12-27
申请人： Anthony Bonnet , Jean-Felix Salas
发明人： Anthony Bonnet , Jean-Felix Salas
IPC分类号： H01M4/00
CPC分类号： H01M8/0239 , H01M8/0213 , H01M8/0221 , H01M8/0234 , H01M8/0243 , Y10T428/2998
摘要： The present invention concerns a microcomposite powder comprising: flat graphite particles GLP having sides from 50 to 1000 μm and a thickness from 5 to 50 μm, consisting of agglomerates of more elementary graphite particles joined together and superimposed so that their principal planes are mutually parallel, said particles being covered with particles of a fluoropolymer from 0.1 to 0.5 μm in size.
摘要翻译：本发明涉及一种微复合材料粉末，其包含：扁平石墨颗粒GLP，其侧面为50至1000μm，厚度为5至50μm，由更多的基本石墨颗粒的附聚物组成，并且叠加成使它们的主平面相互平行，所述颗粒被尺寸为0.1至0.5μm的含氟聚合物颗粒覆盖。

25. 发明申请

US20050069710A1 Thermoformable multilayer film based on acrylic polymer for protecting substrates and resulting objects 审中-公开
标题翻译：基于丙烯酸聚合物的可热成型多层膜，用于保护底物和产生的物体
公开(公告)号：US20050069710A1
公开(公告)日：2005-03-31
申请号：US10496922
申请日：2002-11-29
申请人： Anthony Bonnet , Marius Hert , Gilles Marot , David Silagy
发明人： Anthony Bonnet , Marius Hert , Gilles Marot , David Silagy
IPC分类号： B32B27/28 , B32B27/08 , B32B27/32 , B32B27/30
CPC分类号： B32B27/08 , Y10T428/31504
摘要： The present invention relates to a thermoformable multilayer film comprising in succession: an optional protective layer (A); a layer (B) comprising (the total being 100% by weight) 0 to 30% of a fluoropolymer (B1) and 100 to 70% of a functionalized polymer (B2) essentially consisting of alkyl (meth)acrylate units; a layer (C) based on an ethylene/alkyl (meth)acrylate/unsaturated epoxide copolymer; a polyolefin tie layer (D); the layers adhering to one another in their respective contact regions. This film is obtained by coextrusion or coating of the various layers, the layer (A) possibly being laminated using the standard technique for thermoplastics. This film is then used to cover various substrates, for example by injecting the substrate in the melt onto the multilayer film deposited in the bottom of an injection mould, the layer (B) or the optional layer (A) of the film being placed against the wall of the mould. The present invention also relates to the substrates coated with these films.
摘要翻译：本发明涉及一种可热成型的多层膜，其包括：可选的保护层（A）; 含有（总共为100重量％）0〜30％的氟聚合物（B1）和100〜70％的主要由（甲基）丙烯酸烷基酯单元组成的官能化聚合物（B2）的层（B）基于乙烯/（甲基）丙烯酸烷基酯/不饱和环氧化物共聚物的层（C）聚烯烃粘结层（D）; 这些层在各自的接触区域中彼此附着。该膜通过共挤出或各层的涂覆获得，层（A）可能使用热塑性塑料的标准技术层压。然后将该膜用于覆盖各种基材，例如通过将熔体中的基材注入沉积在注射模具底部的多层膜上，将膜（B）或膜的任选层（A）放置成抵抗模具的墙壁。本发明还涉及涂覆有这些膜的基材。

26. 发明授权

US06811859B2 Composition coextrudable with PVDF 有权
标题翻译：组合可与PVDF共挤出
公开(公告)号：US06811859B2
公开(公告)日：2004-11-02
申请号：US10619558
申请日：2003-07-16
申请人： Anthony Bonnet , Francois Beaume , Karine Loyen , Karine Triballier , David Silagy
发明人： Anthony Bonnet , Francois Beaume , Karine Loyen , Karine Triballier , David Silagy
IPC分类号： B32B2708
CPC分类号： B32B27/30 , B32B27/08 , C08L27/16 , C08L33/08 , C08L33/12 , C08L51/003 , Y10T428/24975 , Y10T428/254 , Y10T428/3154 , Y10T428/31909 , Y10T428/31928 , Y10T428/31931 , Y10T428/31935 , C08L2666/02
摘要： A composition coextrudable with PVDF comprises in parts by weight: 20 to 40 parts of PVDF; 40 to 60 parts of PMMA; 5 to 18 parts of an acrylic elastomer; 1 to 4 parts of a UV absorber; the total making 100 parts. Coextruded films comprise a layer of the above coextrudable composition directly attached to the latter; and a PVDF-based layer comprising, as main constituents, 50 to 100 parts of PVDF per 50 to 0 parts of PMMA respectively. The PVDF layer may be in the form of two layers: one placed against the coextrudable layer and comprising, as main constituents, 50 to 90 parts of PVDF per 50 to 10 parts of PMMA respectively; and the other (also called the outer layer) comprising, as main constituents, 75 to 100 parts of PVDF per 25 to 0 parts of PMMA respectively. The resultant products are generally applied to substrates, e.g. as protective films.
摘要翻译：与PVDF共挤出的组合物包含重量份数：20-40份PVDF; 40〜60份PMMA; 5〜18份丙烯酸弹性体; 1至4份UV吸收剂; 共制100部分。共挤出膜包含直接附着在其上的上述可共挤出组合物层; 和基于PVDF的层，分别包含每50至0份PMMA作为主要成分的50至100份PVDF。 PVDF层可以是两层的形式：一个放置在可共挤出的层上，分别以50至10份的PMMA为主要成分，分别为50至90份的PVDF; 和另外（也称为外层），主要成分为每25〜0份PMMA分别为75〜100份PVDF。所得产物通常施用于底物，例如作为保护膜。

27. 发明授权

US06548608B2 Polyetherimide and/or polysulphone, aromatic polyamine-modified epoxy resin and thermoplastic 失效
标题翻译：聚醚酰亚胺和/或聚砜，芳族聚胺改性环氧树脂和热塑性塑料
公开(公告)号：US06548608B2
公开(公告)日：2003-04-15
申请号：US09838264
申请日：2001-04-20
申请人： Yves Camberlin , Jacky Grenier , Jacques Vallet , Anthony Bonnet , Jean-Pierre Pascault , Mohamed Taha
发明人： Yves Camberlin , Jacky Grenier , Jacques Vallet , Anthony Bonnet , Jean-Pierre Pascault , Mohamed Taha
IPC分类号： B32B1704
CPC分类号： C08L63/00 , C08G59/5033 , Y10T428/24994 , C08L81/00 , C08L79/08
摘要： A polymer composition comprises at least one thermoplastic polymer selected from the group formed by polyetherimides and polysulphones, at least one epoxy resin modified by at least one aromatic polyamine, and at least one other thermoplastic selected from the group consisting of a polyphenylene ether, a polyphenylene sulfide and an aromatic polyether. The epoxy resin is formed from at least one polyepoxide containing at least 2 epoxy groups in its molecule and the aromatic polyamine contains at least two primary amine groups in its molecule and preferably at least one alkyl substituent containing 1 to 12 carbon atoms located alpha to one of the amino groups. The molar ratio of the polyamine to the epoxy is such that, each amino group corresponds to 1.6 to 2.6 epoxy groups. The thermoplastic polymer content is preferably about 15% to 98% by weight with respect to the total weight of the polymer composition; the amount of epoxy resin modified by at least one aromatic polyamine is about 2% to 85% by weight with respect to the total weight of the polymer composition.
摘要翻译：聚合物组合物包含至少一种选自由聚醚酰亚胺和聚砜形成的基团的热塑性聚合物，至少一种由至少一种芳族多胺改性的环氧树脂和至少一种选自聚苯醚，聚亚苯基硫化物和芳香族聚醚。环氧树脂由其分子中至少含有至少2个环氧基的聚环氧化物形成，并且芳族多胺在其分子中含有至少两个伯胺基团，优选至少一个含有1至12个碳原子的烷基取代基位于一个的氨基。多胺与环氧的摩尔比使得每个氨基相当于1.6-2.6个环氧基。相对于聚合物组合物的总重量，热塑性聚合物含量优选为约15％至98％重量; 由至少一种芳族多胺改性的环氧树脂的量相对于聚合物组合物的总重量为约2重量％至85重量％。

28. 发明申请

US20130022806A1 MULTILAYER FLUORINATED FILMS 审中-公开
标题翻译：多层氟化膜
公开(公告)号：US20130022806A1
公开(公告)日：2013-01-24
申请号：US13637398
申请日：2011-03-29
申请人： Anthony Bonnet , Nicolas Devaux , Stephane Bizet , Nadine Rivas , Frederic Godefroy
发明人： Anthony Bonnet , Nicolas Devaux , Stephane Bizet , Nadine Rivas , Frederic Godefroy
IPC分类号： B32B27/08 , A01G13/02 , A01G9/14 , B29C49/22
CPC分类号： B32B27/08 , A01G9/1438 , B32B27/28 , B32B27/304 , B32B27/322 , B32B2250/42 , B32B2307/51 , B32B2307/5825 , B32B2307/732 , B32B2410/00 , Y02A40/252 , Y10T428/3154
摘要： The present invention relates to multilayer films made of fluoro polymers, which have properties that make them suitable for use in the agricultural field, especially as greenhouse covering films. According to a first aspect, the invention relates to multilayer fluorinated films comprising at least three layers, including a layer A made of a first vinylidene fluoride copolymer with a crystallization temperature TcA, and a layer B made of a second vinylidene fluoride copolymer with a crystallization temperature TcB, TcA being greater than TcB, layers A and B being alternating, layer A being placed to the exterior and layer B between two layers A. Another subject of the invention relates to the use of the film according to the invention as an agricultural covering material, especially as a greenhouse covering.
摘要翻译：本发明涉及由氟聚合物制成的多层膜，其具有使其适合用于农业领域，特别是作为温室覆盖膜的性质。根据第一方面，本发明涉及包括至少三层的多层氟化膜，包括由结晶温度TcA的第一偏二氟乙烯共聚物制成的层A和由具有结晶的第二偏二氟乙烯共聚物制成的层B 温度TcB，TcA大于TcB，层A和B是交替的，层A被放置在两层A之间的外部和层B.本发明的另一个主题涉及根据本发明的膜作为农业覆盖材料，特别是作为温室覆盖物。

29. 发明授权

US08182912B2 Coating compositions for inorganic substrates 失效
标题翻译：无机基材涂料组合物
公开(公告)号：US08182912B2
公开(公告)日：2012-05-22
申请号：US11577567
申请日：2005-10-19
申请人： Anthony Bonnet , Michael Werth , Walter Kosar , Scott Gaboury , Ophelie Rousseau
发明人： Anthony Bonnet , Michael Werth , Walter Kosar , Scott Gaboury , Ophelie Rousseau
IPC分类号： B32B5/16
CPC分类号： C09D151/06 , C08F14/18 , C08L27/16 , C08L33/04 , C08L33/06 , C08L51/003 , C09D127/16 , Y10T428/254 , C08F2/00 , C08L2666/24 , C08L2666/02
摘要： The invention relates to a coating composition comprising a radiation grafted functionalized fluoropolymer. This coating is preferably, in the form of a powder coating. The coating can be used on inorganic substrates, especially un-primed metals. The invention also relates to the coated inorganic substrate and to the use of the coating composition to protect the inorganic substrate, especially from corrosion.
摘要翻译：本发明涉及包含辐射接枝官能化含氟聚合物的涂料组合物。该涂层优选为粉末涂层的形式。涂层可用于无机基材，特别是未涂底漆的金属。本发明还涉及涂覆的无机基材和涂料组合物用于保护无机基材，特别是防止腐蚀的用途。

30. 发明授权

US07867604B2 Composition coextrudable with PVDF and having no stress-whitening effect 失效
标题翻译：组合物可与PVDF共挤出并且不具有应激美白效果
公开(公告)号：US07867604B2
公开(公告)日：2011-01-11
申请号：US11058932
申请日：2005-02-16
申请人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
发明人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
IPC分类号： B32B7/02
CPC分类号： C08L27/16 , C08L33/12 , Y10T428/24942 , Y10T428/24975 , Y10T428/3154 , Y10T428/31928 , C08L2666/04
摘要： The present invention relates to a composition coextrudable with PVDF and comprising: 30 to 50 parts of PVDF; 70 to 50 parts of a copolymer comprising, by weight, 90 to 50% of methyl methacrylate (MMA) per 10 to 50% of an alkyl (meth)acrylate respectively, the alkyl having from 2 to 24 carbon atoms; 1 to 4 parts of a UV absorber; the total making 100 parts. The invention also relates to coextruded films consisting of this composition as the adhesive layer and a PVDF-based layer of 50 to 100 parts of PVDF per 50 to 0 parts of PMMA respectively. These films possess mechanical properties sufficient to allow them to be used as a coating transparent to visible light but opaque to UV radiation.
摘要翻译：本发明涉及一种可与PVDF共挤出的组合物，包括：30-50份PVDF; 70〜50份共聚物，其中，每10〜50％的（甲基）丙烯酸烷基酯分别含有90〜50％的甲基丙烯酸甲酯（MMA），碳原子数2〜24的烷基。 1至4份UV吸收剂; 共制100部分。本发明还涉及由该组合物作为粘合剂层组成的共挤出膜，以及每50至0份PMMA分别为50至100份PVDF的PVDF基层。这些膜具有足够的机械性能，使其能够用作对可见光透明但对UV辐射不透明的涂层。

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