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1. 发明申请

US20050187354A1 Composition Coextrudable with PVDF and having no stress-whitening effect 失效
标题翻译：成分可与PVDF共挤出，无应变增白作用
公开(公告)号：US20050187354A1
公开(公告)日：2005-08-25
申请号：US11058932
申请日：2005-02-16
申请人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
发明人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
IPC分类号： B32B27/00 , C08F259/00 , C08L27/16 , C08L33/12
CPC分类号： C08L27/16 , C08L33/12 , Y10T428/24942 , Y10T428/24975 , Y10T428/3154 , Y10T428/31928 , C08L2666/04
摘要： The present invention relates to a composition coextrudable with PVDF and comprising: 30 to 50 parts of PVDF; 70 to 50 parts of a copolymer comprising, by weight, 90 to 50% of methyl methacrylate (MMA) per 10 to 50% of an alkyl (meth)acrylate respectively, the alkyl having from 2 to 24 carbon atoms; 1 to 4 parts of a UV absorber; the total making 100 parts. The invention also relates to coextruded films consisting of this composition as the adhesive layer and a PVDF-based layer of 50 to 100 parts of PVDF per 50 to 0 parts of PMMA respectively. These films possess mechanical properties sufficient to allow them to be used as a coating transparent to visible light but opaque to UV radiation.
摘要翻译：本发明涉及一种可与PVDF共挤出的组合物，包括：30-50份PVDF; 70〜50份共聚物，其中，每10〜50％的（甲基）丙烯酸烷基酯分别含有90〜50％的甲基丙烯酸甲酯（MMA），碳原子数2〜24的烷基。 1至4份UV吸收剂; 共制100部分。本发明还涉及由该组合物作为粘合剂层组成的共挤出膜，以及每50至0份PMMA分别为50至100份PVDF的PVDF基层。这些膜具有足够的机械性能，使其能够用作对可见光透明但对UV辐射不透明的涂层。

2. 发明授权

US07867604B2 Composition coextrudable with PVDF and having no stress-whitening effect 失效
标题翻译：组合物可与PVDF共挤出并且不具有应激美白效果
公开(公告)号：US07867604B2
公开(公告)日：2011-01-11
申请号：US11058932
申请日：2005-02-16
申请人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
发明人： Anthony Bonnet , Karine Triballier , Johann Laffargue , Francois Beaume , Karine Loyen , Sandrine Duc
IPC分类号： B32B7/02
CPC分类号： C08L27/16 , C08L33/12 , Y10T428/24942 , Y10T428/24975 , Y10T428/3154 , Y10T428/31928 , C08L2666/04
摘要： The present invention relates to a composition coextrudable with PVDF and comprising: 30 to 50 parts of PVDF; 70 to 50 parts of a copolymer comprising, by weight, 90 to 50% of methyl methacrylate (MMA) per 10 to 50% of an alkyl (meth)acrylate respectively, the alkyl having from 2 to 24 carbon atoms; 1 to 4 parts of a UV absorber; the total making 100 parts. The invention also relates to coextruded films consisting of this composition as the adhesive layer and a PVDF-based layer of 50 to 100 parts of PVDF per 50 to 0 parts of PMMA respectively. These films possess mechanical properties sufficient to allow them to be used as a coating transparent to visible light but opaque to UV radiation.
摘要翻译：本发明涉及一种可与PVDF共挤出的组合物，包括：30-50份PVDF; 70〜50份共聚物，其中，每10〜50％的（甲基）丙烯酸烷基酯分别含有90〜50％的甲基丙烯酸甲酯（MMA），碳原子数2〜24的烷基。 1至4份UV吸收剂; 共制100部分。本发明还涉及由该组合物作为粘合剂层组成的共挤出膜，以及每50至0份PMMA分别为50至100份PVDF的PVDF基层。这些膜具有足够的机械性能，使其能够用作对可见光透明但对UV辐射不透明的涂层。

3. 发明授权

US08053502B2 PVDF-based extrusion-aiding agent 有权
标题翻译： PVDF型挤出助剂
公开(公告)号：US08053502B2
公开(公告)日：2011-11-08
申请号：US12295954
申请日：2007-03-20
申请人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
发明人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
IPC分类号： C08K5/51
CPC分类号： C08L23/0815 , C08F14/18 , C08K5/527 , C08L23/06 , C08L27/16 , C08F2/02 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The invention concerns to a composition comprising: at least one fluorinated polymer (A), at least one interfacing agent (B), and at least one stabilizer (C) of formula (I) wherein Ar1 and Ar2 represent an aryl group. The composition is used as an agent for extruding a thermoplastic polyolefin or resin. The invention also concerns an extruding method consisting in: (i) contacting in the solid phase a composition as defined above with a thermoplastic polyolefin or a thermoplastic resin; (ii) then extruding the mixture obtained in (i) in the form of a film, a tube, a profiled section or a hollow body.
摘要翻译：本发明涉及一种组合物，其包含：至少一种氟化聚合物（A），至少一种界面剂（B）和至少一种式（I）的稳定剂（C），其中Ar1和Ar2表示芳基。该组合物用作挤出热塑性聚烯烃或树脂的试剂。本发明还涉及挤出方法，其包括：（i）在固相中使如上定义的组合物与热塑性聚烯烃或热塑性树脂接触; （ii）然后将（i）中获得的混合物以薄膜，管，型材部分或中空体的形式挤出。

4. 发明申请

US20100204375A1 PVDF-BASED EXTRUSION-AIDING AGENT 有权
标题翻译：基于PVDF的挤出助剂
公开(公告)号：US20100204375A1
公开(公告)日：2010-08-12
申请号：US12295954
申请日：2007-03-20
申请人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
发明人： Anthony Bonnet , Johann Laffargue , Karine Triballier , Francois Beaume
IPC分类号： C08K5/52
CPC分类号： C08L23/0815 , C08F14/18 , C08K5/527 , C08L23/06 , C08L27/16 , C08F2/02 , C08L2666/04 , C08L2666/02 , C08L2666/14
摘要： The invention concerns to a composition comprising: at least one fluorinated polymer (A), at least one interfacing agent (B), and at least one stabilizer (C) of formula (I) wherein Ar1 and Ar2 represent an aryl group. The composition is used as an agent for extruding a thermoplastic polyolefin or resin. The invention also concerns an extruding method consisting in: (i) contacting in the solid phase a composition as defined above with a thermoplastic polyolefin or a thermoplastic resin; (ii) then extruding the mixture obtained in (i) in the form of a film, a tube, a profiled section or a hollow body.
摘要翻译：本发明涉及一种组合物，其包含：至少一种氟化聚合物（A），至少一种界面剂（B）和至少一种式（I）的稳定剂（C），其中Ar1和Ar2表示芳基。该组合物用作挤出热塑性聚烯烃或树脂的试剂。本发明还涉及挤出方法，其包括：（i）在固相中使如上定义的组合物与热塑性聚烯烃或热塑性树脂接触; （ii）然后将（i）中获得的混合物以薄膜，管，型材部分或中空体的形式挤出。

5. 发明申请

US20080311406A1 (Ligno) Cellulose Material Board Coated with a Pmma and Pvdf-Based film 审中-公开
标题翻译：（Ligno）纤维素材料板，涂有Pmma和Pvdf基胶片
公开(公告)号：US20080311406A1
公开(公告)日：2008-12-18
申请号：US12096089
申请日：2006-12-06
申请人： Anthony Bonnet , Johann Laffargue , Nadine Rivas , Karine Triballier , Sandrine Duc , Cyrille Mathieu , Frederic Godefroy
发明人： Anthony Bonnet , Johann Laffargue , Nadine Rivas , Karine Triballier , Sandrine Duc , Cyrille Mathieu , Frederic Godefroy
IPC分类号： B32B27/08
CPC分类号： B32B27/08 , B32B7/12 , B32B21/08 , B32B27/10 , B32B27/30 , B32B27/304 , B32B27/308 , B32B2270/00 , B32B2274/00 , B32B2307/71 , B32B2307/712 , B32B2419/00 , Y10T428/3154
摘要： The invention relates to the use of a coextruded multilayer film for protecting a (lingo)cellulose material, wherein said multilayer film consists of the following arranged to each other layers: a surface layer (I) comprising PVDF and possibly PMMA in the form of the main components, an intermediate layer (II) comprising in the form of main components 0-60 PVDF parts, 40 to 100 PMMA parts, 0-25 acrylic elastomer parts, and 0-10 UV absorber parts, the totality thereof being equal to 100 parts, and an adhesive layer (III), which comprises a functional PMMA in the form of the main component and is arranged on the side of the (ligno)cellulose material.
摘要翻译：本发明涉及共挤出多层膜用于保护（纤维素）纤维素材料的用途，其中所述多层膜由以下布置成彼此层组成：包含PVDF和可能的PMMA形式的PMMA的表面层（I）主要成分为中间层（II），主要成分为0-60 PVDF部件，40-100个PMMA部件，0-25个丙烯酸弹性体部件和0-10个紫外线吸收部件，其总数等于100 部分和粘合剂层（III），其包含主要成分形式的功能性PMMA并且布置在（木质素）纤维素材料的一侧。

6. 发明授权

US08501862B2 Extrusion agent based on a heterogeneous PVDF 有权
标题翻译：基于异质PVDF的挤出剂
公开(公告)号：US08501862B2
公开(公告)日：2013-08-06
申请号：US12160493
申请日：2007-01-05
申请人： Anthony Bonnet , Johann Laffargue , Francois Beaume
发明人： Anthony Bonnet , Johann Laffargue , Francois Beaume
IPC分类号： C08L27/16 , C08L83/06
CPC分类号： C08L27/16 , C08K5/0008 , C08K5/06 , C08K5/10 , C08K5/32 , C08L23/00 , C08L23/0815 , C08L71/02 , C08L2205/06 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The invention relates to an extrusion agent comprising: at least one heterogeneous PVDF (A), in other words a copolymer of VDF and at least one comonomer of VDF, comprising by weight at least 50%, advantageously at least 75%, of VDF which has a melting point Tm (expressed in ° C.)>172-549 m, preferably >1.1×(172-549 m), where m denotes the overall molar percentage of comonomer(s); and at least one interface agent (B), which are optionally diluted in a polyolefin (C). The heterogeneous PVDF preferably has a Tm of between 160 and 172° C. Advantageously it is also a VDF-HFP copolymer containing, by weight, from 88% to 92% of VDF and from 8% to 12% of HFP. The extrusion agent is used to reduce or eliminate the surface defects which arise during the extrusion of a thermoplastic resin (D). This resin may be a polyolefin, a styrenic resin, a polyester or a PVC. Optionally it may also be filled, i.e., may contain dispersed organic or inorganic particles.
摘要翻译：本发明涉及一种挤出剂，其包含：至少一种非均相PVDF（A），换句话说，VDF和至少一种VDF共聚单体的共聚物，包含至少50％，有利地至少75％的VDF，熔点Tm（以℃表示）>172-549μm，优选> 1.1×（172-549μm），其中m表示共聚单体的总摩尔百分比。和至少一种界面剂（B），其任选地在聚烯烃（C）中稀释。非均相PVDF优选具有160至172℃的Tm。有利地，它还是含有重量百分比为88％至92％的VDF和8％至12％的HFP的VDF-HFP共聚物。挤出剂用于减少或消除在挤出热塑性树脂（D）期间出现的表面缺陷。该树脂可以是聚烯烃，苯乙烯树脂，聚酯或PVC。任选地，它也可以被填充，即可以含有分散的有机或无机颗粒。

7. 发明申请

US20100298487A1 EXTRUSION AGENT BASED ON A HETEROGENEOUS PVDF 有权
标题翻译：基于异质PVDF的挤出剂
公开(公告)号：US20100298487A1
公开(公告)日：2010-11-25
申请号：US12160493
申请日：2007-01-05
申请人： Anthony Bonnet , Johann Laffargue , Francois Beaume
发明人： Anthony Bonnet , Johann Laffargue , Francois Beaume
IPC分类号： C08L27/16 , C08L83/06 , C08L67/00 , C08L71/00
CPC分类号： C08L27/16 , C08K5/0008 , C08K5/06 , C08K5/10 , C08K5/32 , C08L23/00 , C08L23/0815 , C08L71/02 , C08L2205/06 , C08L2666/02 , C08L2666/04 , C08L2666/14
摘要： The invention relates to an extrusion agent comprising: at least one heterogeneous PVDF (A), in other words a copolymer of VDF and at least one comonomer of VDF, comprising by weight at least 50%, advantageously at least 75%, of VDF which has a melting point Tm (expressed in ° C.)>172-549 m, preferably >1.1×(172-549 m), where m denotes the overall molar percentage of comonomer(s); and at least one interface agent (B), which are optionally diluted in a polyolefin (C). The heterogeneous PVDF preferably has a Tm of between 160 and 172° C. Advantageously it is also a VDF-HFP copolymer containing, by weight, from 88% to 92% of VDF and from 8% to 12% of HFP. The extrusion agent is used to reduce or eliminate the surface defects which arise during the extrusion of a thermoplastic resin (D). This resin may be a polyolefin, a styrenic resin, a polyester or a PVC. Optionally it may also be filled, i.e., may contain dispersed organic or inorganic particles.
摘要翻译：本发明涉及一种挤出剂，其包含：至少一种非均相PVDF（A），换句话说，VDF和至少一种VDF共聚单体的共聚物，包含至少50％，有利地至少75％的VDF，熔点Tm（以℃表示）>172-549μm，优选> 1.1×（172-549μm），其中m表示共聚单体的总摩尔百分比。和至少一种界面剂（B），其任选地在聚烯烃（C）中稀释。非均相PVDF优选具有160至172℃的Tm。有利地，它还是含有重量百分比为88％至92％的VDF和8％至12％的HFP的VDF-HFP共聚物。挤出剂用于减少或消除在挤出热塑性树脂（D）期间出现的表面缺陷。该树脂可以是聚烯烃，苯乙烯树脂，聚酯或PVC。任选地，它也可以被填充，即可以含有分散的有机或无机颗粒。

8. 发明申请

US20090275251A1 FLEXIBLE FILM BASED ON FLUORINATED POLYMER 审中-公开
标题翻译：基于氟化聚合物的柔性膜
公开(公告)号：US20090275251A1
公开(公告)日：2009-11-05
申请号：US12162144
申请日：2007-01-25
申请人： Anthony Bonnet , Sandrine Duc , Cyrille Mathieu , Johann Laffargue
发明人： Anthony Bonnet , Sandrine Duc , Cyrille Mathieu , Johann Laffargue
IPC分类号： B32B27/12 , B32B27/06 , B32B27/08 , B32B27/38 , C08L27/12
CPC分类号： B32B27/30 , B29C48/05 , B29C48/08 , B29C48/10 , B29C48/21 , B29C48/22 , B29K2027/16 , B32B7/06 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/12 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B27/36 , B32B2262/0238 , B32B2262/0269 , B32B2262/101 , B32B2264/10 , B32B2307/542 , B32B2307/71 , B32B2307/712 , B32B2457/12 , C08L27/16 , C08L33/12 , C08L71/02 , C08L2205/03 , H01L31/049 , Y02E10/50 , Y10T428/31511 , Y10T428/3154 , Y10T428/31544 , Y10T442/2607 , C08L2666/02 , C08L2666/04
摘要： The invention concerns a multilayer structure comprising: a PVDF-based film F1 affixed to a PET or PEN sheet; or a PVDF-based film F1 bonded to a PET or PEN sheet which is itself affixed to a PVDF-based film F2. The F1 and/or F2 films comprising (starting from the PET or PEN sheet): optionally a layer of composition B comprising 5 to 40 parts of at least one PVDF, 60 to 95 parts of at least one PMMA and 0 to 5 parts of at least one UV absorber, the total making 100 parts; a layer of composition A, comprising 50 to 100 parts of at least one PVDF, 0 to 50 parts of at least one PMMA, 0 to 30 parts of at least one mineral filler and 0 to 3 parts of at least one dispersant, the total making 100 parts; optionally a layer of composition C comprising 80 to 100 parts of at least one PVDF, 0 to 20 parts of at least one PMMA, 0 to 30 parts of at least one mineral filler and 0 to 3 parts of at least one dispersant, the total making 100 parts; such that an adhesive layer is interposed between the PET or PEN sheet and the F1 and/or F2 films; said adhesive layer being optional if the layer of composition B is present and not including any polyolefin functionalized by an unsaturated carboxylic acid or anhydride, or a homo- or copolymer including as monomer(s) acrylic acid, acrylates and alkyl acrylates optionally modified by an unsaturated acid or anhydride; such that the compositions A and/or B do not contain any acrylic elastomer particle nor any core-coat particle.
摘要翻译：本发明涉及一种多层结构，其包括：固定在PET或PEN薄片上的基于PVDF的薄膜F1; 或者结合到PET或PEN片上的PVDF基膜F1，其本身固定在基于PVDF的膜F2上。包括（从PET或PEN片开始）的F1和/或F2膜：任选地包含5至40份至少一种PVDF，60至95份至少一种PMMA和0至5份至少一个紫外线吸收剂，共制作100份; 组合物A的层，包含50至100份的至少一种PVDF，0至50份至少一种PMMA，0至30份至少一种矿物填料和0至3份至少一种分散剂，总计制作100份; 可选地包含80至100份至少一种PVDF，0至20份至少一种PMMA，0至30份至少一种矿物填料和0至3份至少一种分散剂的组合物C层，总计制作100份; 使得在PET或PEN片材与F1和/或F2膜之间插入粘合剂层; 如果组合物B存在并且不包括由不饱和羧酸或酸酐官能化的任何聚烯烃或包含丙烯酸，丙烯酸酯和丙烯酸烷基酯的均聚物或共聚物，任选地通过不饱和酸或酸酐; 使得组合物A和/或B不含有任何丙烯酸弹性体颗粒和任何芯涂层颗粒。

9. 发明申请

US20110232735A1 THREE-LAYER FILM FOR A PHOTOVOLTAIC CELL 有权
标题翻译：三层细胞膜三膜
公开(公告)号：US20110232735A1
公开(公告)日：2011-09-29
申请号：US12532573
申请日：2009-02-06
申请人： Stephane Bizet , Anthony Bonnet , Nicholas Devaux , Johann Laffargue , Aude Lapprand
发明人： Stephane Bizet , Anthony Bonnet , Nicholas Devaux , Johann Laffargue , Aude Lapprand
IPC分类号： H01L31/0216 , B32B27/28 , B32B27/30 , B32B5/16 , B32B5/00 , B32B7/02
CPC分类号： B32B27/28 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B2250/03 , B32B2250/40 , B32B2264/02 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/41 , B32B2307/50 , B32B2307/546 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2457/12 , C08L27/16 , C08L33/12 , H01L31/048 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y10T428/24231 , Y10T428/24975 , Y10T428/25 , Y10T428/265 , Y10T428/3154 , C08L2666/04
摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.
摘要翻译：本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％膜厚25微米。本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

10. 发明授权

US08878054B2 Three-layer film for a photovoltaic cell 有权
标题翻译：用于光伏电池的三层膜
公开(公告)号：US08878054B2
公开(公告)日：2014-11-04
申请号：US12532573
申请日：2009-02-06
申请人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
发明人： Stephane Bizet , Anthony Bonnet , Nicolas Devaux , Johann Laffargue , Aude Lapprand
IPC分类号： H01L31/00 , B32B27/28 , B32B27/08 , B32B27/30 , C08L27/16 , C08L33/12 , H01L31/048
CPC分类号： B32B27/28 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/322 , B32B2250/03 , B32B2250/40 , B32B2264/02 , B32B2307/30 , B32B2307/306 , B32B2307/308 , B32B2307/41 , B32B2307/50 , B32B2307/546 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2457/12 , C08L27/16 , C08L33/12 , H01L31/048 , H01L31/0481 , H01L31/049 , Y02E10/50 , Y10T428/24231 , Y10T428/24975 , Y10T428/25 , Y10T428/265 , Y10T428/3154 , C08L2666/04
摘要： The invention relates to a multilayer film of A/B/C structure comprising: a first layer of composition A, comprising a fluoropolymer; a second layer of composition B, comprising a filled fluoropolymer; and a third layer of composition C, comprising a fluoropolymer, characterized in that the first and third layers have a melting point above 150° C., measured by DSC, and in that the transmittance in visible light is less than 30% for a multilayer film thickness of 25 μm. The invention also relates to the use of a fluoropolymer-based film preferably for a photovoltaic cell back panel, a high-performance textile or a metal, the film adhering to the substrate by means of an adhesive layer placed between the substrate and the film.
摘要翻译：本发明涉及一种A / B / C结构的多层膜，其包括：第一层组合物A，其包含含氟聚合物; 组合物B的第二层，包含填充的含氟聚合物; 以及包含含氟聚合物的组合物C的第三层，其特征在于，通过DSC测量，第一层和第三层的熔点高于150℃，并且对于多层膜，可见光的透射率小于30％膜厚25微米。本发明还涉及优选用于光伏电池背板，高性能织物或金属的氟聚合物基膜的使用，所述膜通过设置在基板和膜之间的粘合剂层粘附到基板。

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