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    • 26. 发明授权
    • Poly(meth) acrylimides of improved color
    • 改进颜色的聚(甲基)丙烯酰亚胺
    • US5476907A
    • 1995-12-19
    • US320386
    • 1994-10-11
    • Siegmund BeseckeAndreas DeckersHarald Lauke
    • Siegmund BeseckeAndreas DeckersHarald Lauke
    • C08F8/32C08F8/48C08F20/52
    • C08F8/48C08F2800/20
    • A polymer useful for preparing moldings and comprising essentially units of the formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or methyl, andR.sup.3 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.6 -C.sub.10 -aryl-C.sub.1 -C.sub.4 -alkyl, each of which may be monosubstituted, disubstituted or trisubstituted by radicals selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and halogen, is obtainable by reacting a polymer based on C.sub.1 -C.sub.20 -alkyl esters of (meth)acrylic acid with a primary amine of the general formula IIR.sup.3 NH.sub.2 II in the presence of a compound selected from the group consisting of phosphinic acid and phosphonic acid and their alkali metal, alkaline earth metal, aluminum and ammonium salts, wherein the ammonium ion can be monosubstituted, disubstituted, trisubstituted or tetrasubstituted by C.sub.1 -C.sub.4 -alkyl and/or C.sub.5 -C.sub.8 -cycloalkyl, or mixtures thereof.
    • 一种可用于制备模制品的聚合物,其基本上包含式I的单元,其中R 1和R 2各自为氢或甲基,R 3为氢,C 1 -C 18烷基,C 5 -C 8 - 环烷基,C 6 -C 10 - 芳基 或C 6 -C 10 - 芳基-C 1 -C 4烷基,其各自可以被选自C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基和卤素的基团单取代,二取代或三取代,可通过使 基于(甲基)丙烯酸的C1-C20烷基酯与通式II R3NH2II的伯胺在选自次膦酸和膦酸及其碱金属,碱土金属的化合物存在下的聚合物 铝和铵盐,其中铵离子可以被C1-C4-烷基和/或C5-C8-环烷基单取代,二取代,四取代或四取代,或其混合物。
    • 29. 发明授权
    • Isolation and purification of oxadimethacrylics
    • 氧化二甲基丙烯酸酯的分离和纯化
    • US5393917A
    • 1995-02-28
    • US167119
    • 1993-12-16
    • Siegmund BeseckeAndreas DeckersHarald Lauke
    • Siegmund BeseckeAndreas DeckersHarald Lauke
    • C07C69/734C07C69/73
    • C07C69/734
    • A process for isolating and purifying oxadimethacrylics of the general formula ICH.sub.2 .dbd.C(A)CH.sub.2 --O--CH.sub.2 C(B).dbd.CH.sub.2 Iwhere A and B are selected from the group consisting of --COOR.sup.1, --COR.sup.1, --CONR.sup.2 R.sup.3 and --CN and R.sup.1, R.sup.2 and R.sup.3 are each defined as follows:R.sup.1 is hydrogen, alkyl, substituted or unsubstituted cycloalkyl or cycloalkylalkyl, hydroxyalkyl, aminoalkyl, N-alkylaminoalkyl, N,N-dialkylaminoalkyl, substituted or unsubstituted aryl or arylalkyl,R.sup.2 and R.sup.3 are each hydrogen, alkyl, substituted or substituted cycloalkyl or cycloalkylalkyl, substituted or unsubstituted aryl or arylalkyl,comprises precipitating or crystallizing them from their solutions that contain at least one liquid hydrocarbon compound.
    • 分离和纯化通式I CH 2 = C(A)CH 2 -O-CH 2 C(B)= CH 2 I的肟基甲基丙烯酸酯的方法,其中A和B选自-COOR 1,-COR 1,-CONR 2 R 3和-CN R 1,R 2和R 3各自定义如下:R 1是氢,烷基,取代或未取代的环烷基或环烷基烷基,羟基烷基,氨基烷基,N-烷基氨基烷基,N,N-二烷基氨基烷基,取代或未取代的芳基或芳基烷基, 氢,烷基,取代或取代的环烷基或环烷基烷基,取代或未取代的芳基或芳基烷基包括从含有至少一种液态烃化合物的溶液中沉淀或结晶它们。
    • 30. 发明授权
    • Glass fiber-reinforced styrene copolymers
    • 玻璃纤维增​​强苯乙烯共聚物
    • US5346945A
    • 1994-09-13
    • US110216
    • 1993-08-23
    • Andreas DeckersNorbert Guentherberg
    • Andreas DeckersNorbert Guentherberg
    • C08L25/12C08L33/24C08J5/08C08K3/40C08L25/04
    • C08L25/12C08L33/24
    • A thermoplastic molding material comprising (A) a copolymer composed of acrylonitrile plus styrene, a-methylstyrene or a nuclear-substituted styrene derivative or mixtures of these three monomers; (B) a graft copolymer prepared either by (B.sub.1) emulsion polymerization of a monomer mixture, based on either styreneacrylonitrile or styreneacrylonitrile-methyl methacrylate, on a latex, obtained as an emulsion, of an elastomer based on butadiene or acrylic ester as a grafting base, or by (B.sub.2) solution polymerization of a monomer mixture, based on either styreneacrylonitrile or styreneacrylonitrile-methyl methacrylate, on an elastomer, prepared in solution, based on butadiene or acrylic ester or an EPDM elastomer as grafting base; (C) a. reinforcing agent based on an inorganic glass; and (D) a copolymer composed of (D.sub.1) units of the formula I, ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or methyl and R.sup.3 is hydrogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.6 -C.sub.16 aryl or C.sub.1 -C.sub.14 aralkyl, and (D.sub.2) units derived from a copolymerizable monomer selected from styrene, .alpha.-methylstyrene, (meth)acrylonitrile or (meth)acrylic acid esters.
    • 一种热塑性模塑材料,其包含(A)由丙烯腈加苯乙烯,α-甲基苯乙烯或核取代的苯乙烯衍生物或这三种单体的混合物组成的共聚物; (B)接枝共聚物,其通过(B1)基于苯乙烯 - 丙烯腈或苯乙烯 - 丙烯腈 - 甲基丙烯酸甲酯的单体混合物在作为乳液获得的胶乳上的基于丁二烯或丙烯酸酯作为接枝的弹性体进行乳液聚合而制备 基于丁二烯或丙烯酸酯或EPDM弹性体作为接枝基的在溶液中制备的弹性体上的基于苯乙烯丙烯腈或苯乙烯 - 丙烯腈 - 甲基丙烯酸甲酯的单体混合物的(B2)溶液聚合反应; (C)a。 基于无机玻璃的增强剂; 和(D)由式I的(D1)单元组成的共聚物,甲基和R 3是氢,C 1 -C 8烷基,C 5 -C 12环烷基,C 6 -C 16芳基或C 1 -C 14芳烷基,和(D2)来自可共聚单体的单元 来自苯乙烯,α-甲基苯乙烯,(甲基)丙烯腈或(甲基)丙烯酸酯。