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11. 发明授权

US4639478A Bismorpholines, a process for their preparation and their use for protection against hydrolysis 失效
标题翻译：双蝎子，它们的制备方法及其用于防止水解的用途
公开(公告)号：US4639478A
公开(公告)日：1987-01-27
申请号：US857014
申请日：1986-04-29
申请人： Peter Haas , James M. Barnes , Wilhelm Goyert
发明人： Peter Haas , James M. Barnes , Wilhelm Goyert
IPC分类号： C07D498/04 , C08K5/35 , C08K5/15
CPC分类号： C07D498/04 , C08K5/35
摘要： The present invention relates to 2,3,2',3'-bis-morpholine derivatives corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these derivatives and to their use as hydrolysis protective agents for synthetic polymers containing ester groups and/or carbonate groups. Preferred synthetic polymers are polyurethanes.
摘要翻译：本发明涉及对应于式的2,3,2'，3'-双 - 吗啉衍生物本发明还涉及制备这些衍生物的方法及其作为合成的水解保护剂的用途含有酯基和/或碳酸酯基团的聚合物。优选的合成聚合物是聚氨酯。

12. 发明授权

US4476253A Process for the preparation of polyurethane elastomers using diols of the anhydro-tetritol series 失效
标题翻译：使用脱水四氢呋喃系列的二醇制备聚氨酯弹性体的方法
公开(公告)号：US4476253A
公开(公告)日：1984-10-09
申请号：US570045
申请日：1984-01-11
申请人： Herbert Salzburg , Holger Meyborg , Wilhelm Goyert , James M. Barnes
发明人： Herbert Salzburg , Holger Meyborg , Wilhelm Goyert , James M. Barnes
IPC分类号： C08G18/10 , C08G18/32 , C08G18/14
CPC分类号： C08G18/3218 , C08G18/10
摘要： Polyurethane elastomers are made by reacting organic polyisocyanates with compounds having at least two groups containing isocyanate-reactive hydrogen atoms and a molecular weight of from 400 to 10,000 and a 1,4-monoanhydro-tetritol in accordance with techniques known to those in the art. Known chain-lengthening agents, auxiliaries and additives may be included in the reaction mixture. The reaction mixtures employed in the process of the present invention have a longer pot life than prior art reaction mixtures. The elastomers produced by this process are shrink stable.
摘要翻译：根据本领域已知的技术，聚氨酯弹性体是通过有机多异氰酸酯与具有至少两个含异氰酸酯反应性氢原子和分子量为400至10,000的化合物和1,4-单羟基 - 氢化四醇反应制备的。已知的增链剂，助剂和添加剂可以包括在反应混合物中。在本发明方法中使用的反应混合物具有比现有技术的反应混合物更长的适用期。由该方法生产的弹性体收缩稳定。

13. 发明授权

US5210170A Process for stabilizing plastics containing ester groups 失效
标题翻译：用于稳定含有酯类的塑料的方法
公开(公告)号：US5210170A
公开(公告)日：1993-05-11
申请号：US708590
申请日：1991-05-31
申请人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
发明人： Bernd Quiring , Thomas Munzmay , Wolfgang Henning , Eduard Mayer , Walter Meckel , Wilhelm Goyert
IPC分类号： C08G63/91 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/76 , C08G18/79 , C08G18/83 , C08K5/29 , C08L67/00 , C09J175/06
CPC分类号： C09J175/06 , C08G18/10 , C08G18/42 , C08G18/60 , C08G18/7678 , C08G18/797 , C08K5/29 , C08G2101/00 , C08G2150/20
摘要： The invention relates to a process for stabilizing ester-containing plastics against degradation by heat and/or hydrolysis by the incorporation of sterically hindered isocyanate-terminated carbodiimides. The incorporable carbodiimides produce an excellent anti-aging effect and do not give rise to volatile products, even at very high temperatures.
摘要翻译：本发明涉及稳定含酯塑料的方法，以防止加入和/或水解通过加入空间位阻异氰酸酯封端的碳二亚胺的降解。可加入的碳二亚胺产生优异的抗老化作用，即使在非常高的温度下也不会产生挥发性产物。

14. 发明授权

US4617387A Bismorpholines and a process for their preparation 失效
标题翻译：双膦酰胺及其制备方法
公开(公告)号：US4617387A
公开(公告)日：1986-10-14
申请号：US640907
申请日：1984-08-15
申请人： Peter Haas , James M. Barnes , Wilhelm Goyert
发明人： Peter Haas , James M. Barnes , Wilhelm Goyert
IPC分类号： C07D498/04 , C08K5/35 , C07D265/28
CPC分类号： C07D498/04 , C08K5/35
摘要： The present invention relates to 2,3,2',3'-bis-morpholine derivatives corresponding to the formula ##STR1## The present invention also relates to a process for the preparation of these derivatives and to their use as hydrolysis protective agents for synthetic polymers containing ester groups and/or carbonate groups. Preferred synthetic polymers are polyurethanes.
摘要翻译：本发明涉及对应于式的2,3,2'，3'-双 - 吗啉衍生物本发明还涉及制备这些衍生物的方法及其作为合成的水解保护剂的用途含有酯基和/或碳酸酯基团的聚合物。优选的合成聚合物是聚氨酯。

15. 发明授权

US4521582A Thermoplastic polyurethanes having a high heat stability, based on naphthylene diisocyanate, their production and their use 失效
标题翻译：具有高热稳定性，基于亚萘基二异氰酸酯的热塑性聚氨酯，其制备及其用途
公开(公告)号：US4521582A
公开(公告)日：1985-06-04
申请号：US637242
申请日：1984-08-02
申请人： Wilhelm Goyert , Jurgen Winkler
发明人： Wilhelm Goyert , Jurgen Winkler
IPC分类号： C08G18/00 , C08G18/10 , C08G18/65 , C08G18/76 , C08G18/32
CPC分类号： C08G18/7678 , C08G18/10
摘要： This invention relates to novel, thermoplastically processible, branched polyurethanes based on naphthylene-1,5-diisocyanate which have good heat stability and are obtained by the claimed process. In the first stage of the process long-chain polyols are reacted with a first diisocyanate which is any diisocyanate other than naphthylene-1,5-diisocyanate in substoichiometric NCO quantities to produce an OH prepolymer which is then lengthened with excess napthylene-1,5-diisocyanate and with a chain lengthening mixture of short-chain diols and triols and/or polyols in specific ratios. The resulting semi-rigid, thermoplastic polyurethane elastomers are characterized by their good dimensional stability under heat, a good rebound elasticity (even at relatively high temperatures), acceptable low temperature flexibility and an outstanding resistance to wear which properties render them useful for the production of hydraulic seals, seals, rollers, buffers, tubes, bellows, plugs, cylinders, couplings and similar moldings.
摘要翻译：本发明涉及基于亚萘基-1,5-二异氰酸酯的热塑性加工性支化聚氨酯，其具有良好的热稳定性并且通过所要求的方法获得。在该方法的第一阶段中，长链多元醇与作为亚化学计量NCO量的除亚萘基-1,5-二异氰酸酯以外的任何二异氰酸酯的第一二异氰酸酯反应以产生OH预聚物，然后用过量的萘二酚-1,5 二异氰酸酯和具有特定比例的短链二醇和三醇和/或多元醇的链延长混合物。所得的半刚性热塑性聚氨酯弹性体的特征在于其在加热下具有良好的尺寸稳定性，良好的回弹弹性（即使在相对高的温度下），可接受的低温柔韧性和优异的耐磨性，这些性质使其对于生产液压密封件，密封件，辊子，缓冲器，管子，波纹管，塞子，气缸，联轴器和类似的模制品。

16. 发明授权

US3963656A Thermoplastic polyurethanes and a two-stage process for their preparation 失效
标题翻译：热塑性聚氨酯及其制备的两阶段工艺
公开(公告)号：US3963656A
公开(公告)日：1976-06-15
申请号：US546062
申请日：1975-01-31
申请人： Ernst Meisert , Wilhelm Goyert
发明人： Ernst Meisert , Wilhelm Goyert
IPC分类号： C08G18/10 , C08G18/32
CPC分类号： C08G18/10
摘要： Polyurethane elastomers suitable for coating textiles, leather, paper and similar substrate and a multi-stage process for their production. The polyurethane elastomers are obtained fromA. a polyol with an average molecular weight between 900 and 5300,B. 4,4'-diisocyanatodiphenylmethane andC. a diol with a molecular weight below 500, characterized in that the equivalent ratio ((b)/(a)+(c)) is between 0.87 and 1 and in that (a) contains at least 40% by weight of a polyurethane of the formula ##EQU1## where R is a divalent group such as can be obtained by removing the hydroxyl groups from a diol which has a molecular weight of between 700 and 1750, andQ is a divalent aliphatic, cycloaliphatic, araliphatic or aromatic group which contains 2 to 20, and preferably, 4 to 15, carbon atoms; but Q is not ##SPC1##
摘要翻译：适合涂布纺织品，皮革，纸张和类似基材的聚氨酯弹性体，以及用于生产的多阶段工艺。聚氨酯弹性体得自A.具有900和5300之间的平均分子量的多元醇，B，4,4'-二异氰酸亚氨基乙酯和C.具有以下分子量的二醇，其特征在于等同比（（B） /（A）+（C））在0.87和1之间，并且其中（A）至少包含40质量％的配方HO-ROC-NH-Q-NH-COR-OH并行性平行OO的聚氨酯，其中 R是二价基团，例如可以通过从分子量为700〜1750的二醇除去羟基而获得，Q为含有2〜20的二价脂肪族，脂环族，芳脂族或芳族基团，优选，4至15个碳原子; 但Q不是

17. 发明授权

US4889908A Polyethers and their use as mold release agents for plastics 失效
标题翻译：聚醚及其作为塑料脱模剂的用途
公开(公告)号：US4889908A
公开(公告)日：1989-12-26
申请号：US250453
申请日：1988-09-28
申请人： Joachim Franke , Wilhelm Goyert , Helmut Kipphardt
发明人： Joachim Franke , Wilhelm Goyert , Helmut Kipphardt
IPC分类号： C08G65/08 , C08G18/40 , C08G18/48 , C08G65/02 , C08G65/26 , C08G65/28
CPC分类号： C08G18/4009 , C08G18/4858 , C08G18/487 , C08G65/26 , C08G2125/00
摘要： The present invention is directed to polyethers obtained by the reaction of a substituted 1,2-epoxy-alkane bearing at least one alkyl substituent containing at least 8 carbon atoms with at least one polyol corresponding to the formulaR(OH).sub.x (1)whereinR is an organic radical andx is an integer having a value of 2 or more,2 or more moles of epoxyalkane being added onto the polyol (1).The present invention is also directed to a process for the preparation of high molecular weight polymers wherein the process is conducted in the presence of the previously described polyethers as a mold release agent.
摘要翻译：本发明涉及通过使至少一个含有至少8个碳原子的烷基取代基的取代的1,2-环氧烷烃与至少一种对应于式R（OH）x（1）的多元醇反应得到的聚醚，其中R是有机基团，x是具有2或更大值的整数，加入到多元醇（1）上的2个或更多摩尔的环氧烷烃。本发明还涉及制备高分子量聚合物的方法，其中该方法在前述聚醚作为脱模剂的存在下进行。

18. 发明授权

US4762884A Process for the production of radiation-crosslinked thermoplastic polyurethanes 失效
标题翻译：辐射交联热塑性聚氨酯生产工艺
公开(公告)号：US4762884A
公开(公告)日：1988-08-09
申请号：US40428
申请日：1987-04-20
申请人： Wilhelm Goyert , Jurgen Winkler , Hermann Perrey , Herbert Heidingsfeld
发明人： Wilhelm Goyert , Jurgen Winkler , Hermann Perrey , Herbert Heidingsfeld
IPC分类号： C08J3/28 , C08F2/46 , C08F2/54 , C08F283/00 , C08F299/06 , C08G18/00 , C08L75/00 , C08L75/04 , C08G18/40
CPC分类号： C08F299/06
摘要： The invention is directed to a process for the production of polyurethanes suitable for thermoplastic processing comprising mixingI. at least 75% by weight of preformed thermoplastic polyurethane elastomers, or of a blend of(A) substantially bifunctional, compounds(B) substantially bifunctional chain-extending agents(C) organic diisocyanates and optionally(D) lubricants or other known additivessaid blend characterized in that it contains no peroxides and polymerization initiators which decompose into radicals under the effect of actinic light and further in that the molar ratio of the sum of said (A) and said (B) to said (C) is between 0.9 to 1.1, withII. (E) from 4 to 24% by weight of a crosslinking agent andIII. (F) from 0.01 to 3% by weight of a polymerization inhibitor and/or an antioxidant,by adding said II and said III to said I at a temperature below 230.degree. C., and the cooling the mixture to below 130.degree. C. in less than 5 minutes in a continuous extruder and optionally granulating the resulting polyurethane.
摘要翻译：本发明涉及一种用于生产适用于热塑性加工的聚氨酯的方法，其包括将I.至少75重量％的预成型热塑性聚氨酯弹性体或（A）基本上双官能的化合物（B）的混合物（B）基本上是双功能链 - 扩展剂（C）有机二异氰酸酯和任选的（D）润滑剂或其它已知的添加剂，所述共混物的特征在于其不含过氧化物和聚合引发剂，其在光化光的作用下分解成自由基，并且进一步地，总和的摩尔比（A）和所述（B）至（C）之间的比例在0.9至1.1之间。（E）4至24重量％的交联剂和III。（F）0.01〜3重量％的阻聚剂和/或抗氧化剂，通过在低于230℃的温度下将所述II和所述III加入到所述I中，并将混合物冷却至130℃以下。在连续挤出机中在不到5分钟的时间内，并任选地造粒得到的聚氨酯。

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