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    • 11. 发明专利
    • Combustor for gas turbine
    • 燃气轮机
    • JPS5924122A
    • 1984-02-07
    • JP13203182
    • 1982-07-30
    • Toshiba Corp
    • FURUYA TOMIAKIHAYATA TERUNOBUYAMANAKA CHIKAUHIZUKA JIYUNJI
    • F23C13/00F23R3/40
    • F23R3/40
    • PURPOSE:To improve ignition property and reduce pressure loss by a method wherein a catalyst bearing part is constituted by three-stage structure consisting of first stage, a ceramic honeycomb structure bearing a precious meral series catalyst, second structure, a refractory honeycomb structure bearing the same catalyst and third structure, a honeycomb structure catalyst body of composite oxide. CONSTITUTION:The ceramic, constituting the first stage of ceramic honeycomb structure, is alpha-alumina, zirconia or the like while the refractory alloy, constituting the second stage of the refractory alloy honeycomb structure, is the alloy of hastelloy, inconel or the like. The precious metal series catalyst, born by the structures of the first and second stages, begins combustion reaction from a comparatively low temperature. The composite oxide honeycomb structural catalyst body, constituting the third stage, has the effect of the catalyst by itself at a high temperature and is made of titanic acid, zirconate or the like of Ba, Mn, Ni, Co, Cu, Fe, Ca or the like added with alumina of high purity or the like, and it is prepared by mixing and forming into the honeycomb shape, thereafter, calcining under a pressure.
    • 目的:通过以下方法提高点火性能和降低压力损失的方法:其中催化剂承载部分由第一阶段组成的三级结构构成,承载珍贵的矿物系列催化剂的陶瓷蜂窝结构体,第二结构,承载有 相同的催化剂和第三结构,复合氧化物的蜂窝结构催化剂体。 构成:构成陶瓷蜂窝结构的第一阶段的陶瓷是α-氧化铝,氧化锆等,构成耐火合金蜂窝结构体的第二阶段的耐火合金是哈氏合金,铬镍铁合金等的合金。 贵金属系列催化剂由第一和第二阶段的结构产生,从较低的温度开始燃烧反应。 构成第三阶段的复合氧化物蜂窝结构体催化剂体在高温下本身具有催化剂本身的作用,并且由Ba,Mn,Ni,Co,Cu,Fe,Ca等的钛酸,锆酸酯等构成 加入高纯度的氧化铝等,通过混合形成蜂窝状,然后在压力下进行煅烧而制备。
    • 12. 发明专利
    • Combustion in combustor for gas turbine
    • 燃气轮机燃烧器
    • JPS5924121A
    • 1984-02-07
    • JP13203282
    • 1982-07-30
    • Toshiba Corp
    • FURUYA TOMIAKIYAMANAKA CHIKAUHAYATA TERUNOBUHIZUKA JIYUNJI
    • F23R3/28F23D11/40F23R3/40
    • F23R3/40
    • PURPOSE:To reduce the amount of NOx and improve combustion efficiency by a method wherein a part of fuel is burnt previously by a burner with a specified air rate while the remaining fuel is injected to the flame of the precombustion or the vicinity thereof and, further, is mixed with air, thereafter, is introduced to a part filled with catalyst. CONSTITUTION:A part of the fuel 1 and air 3 are mixed previously in the upstream side of the combustor so as to obtain the air rate of 60-90% while the mixed gas is burnt by the burner. The remaining fuel 1' is injected to the flame under combustion or the vicinity thereof to effect the precombustion of the fuel itself as well as the quenching of the flame simultaneously. The mixture is further mixed with the remaining air 3'. When the air is mixed after the quenching of the flame, the temperature of the mixture is risen sufficiently to a temperature necessary for the catalytic combustion when it arrives at the part 7 filled with the catalyst while the mixture contains no NOx substantially. Accordingly, the characteristics of the catalytic combustion system is utilized effectively and the efficient combustion may be effected as the whole of the combustor.
    • 目的:为了减少NOx的量并提高燃烧效率,其中一部分燃料先由具有特定空气速率的燃烧器燃烧,同时将剩余的燃料喷射到预燃火焰或其附近, 与空气混合,然后引入填充有催化剂的部分。 构成:将燃料1和空气3的一部分预先混合在燃烧器的上游侧,以使燃烧器燃烧混合气体时的空气率为60〜90%。 剩余的燃料1'在燃烧或其附近被注入到火焰中以实现燃料本身的预燃以及火焰的同时淬火。 将混合物与剩余的空气3'进一步混合。 当空气在火焰淬火后混合时,混合物的温度升高到催化燃烧所必需的温度,当其到达填充有催化剂的部分7时,混合物基本上不含有NOx。 因此,有效地利用催化燃烧系统的特性,并且可以作为整个燃烧器实现有效的燃烧。
    • 14. 发明专利
    • UNIT AND METHOD FOR INCINERATING WASTE
    • JPH11211052A
    • 1999-08-06
    • JP1370298
    • 1998-01-27
    • TOSHIBA CORP
    • HAYATA TERUNOBUHANAKADA YOSHIOUENO CHIKARAKITA YUMIKO
    • F23G7/00F23G7/06F23G7/07F23G7/12F23J15/00
    • PROBLEM TO BE SOLVED: To prevent dioxin from being generated without requiring an organic halogen decomposition catalyst by eliminating the hydrocarbon in a high- temperature exhaust gas being discharged from an incinerator for incinerating the waste including a halogen so that the amount of the hydrocarbon becomes a specific amount or less. SOLUTION: A catalyst is set to the internal side wall of a hydrocarbon elimination tower 3, where the catalyst eliminates hydrocarbon from an exhaust gas being discharged from a compact incinerator 1 for incinerating waste including a halogen so that the amount of the hydrocarbon becomes 1 ppb level or less. In this case, the catalyst should be set to the internal side wall of the hydrocarbon elimination tower 3 while being brought into contact with a high- temperature gas from the incinerator 1 when the gas is allowed to flow from an upper stream to a lower stream inside the hydrocarbon elimination tower 3. A high-temperature gas of 400 deg.C or more that cannot easily generate dioxin being eliminated in the hydrocarbon elimination tower 3 is introduced to a chimney 4, and an exhaust gas 5 is discharged by the chimney 4, thus preventing the dioxin from being generated without requiring an organic halogen decomposition catalyst.