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    • 11. 发明专利
    • Metal glass sprayed coating, and method for forming the same
    • 金属玻璃喷涂,及其形成方法
    • JP2007084902A
    • 2007-04-05
    • JP2005277947
    • 2005-09-26
    • Akihisa InoueTopy Ind Ltdトピー工業株式会社明久 井上
    • INOUE AKIHISAKIMURA HISAMICHIOHARA MASAKIIGARASHI TAKANORISUGIYAMA MASAHARU
    • C23C4/06C23C4/12
    • PROBLEM TO BE SOLVED: To provide a method for forming a sprayed coating having excellent adhesion to a base material. SOLUTION: When metal glass is thermally sprayed, the linear expansion coefficient of the metal glass is measured by TMA (Thermomechanical Analysis), so as to obtain the inflection point thereof, and, while the temperature of the base material as the object for thermal spraying is controlled to 100°C or above, and also, to less than the above inflection point, the metal glass is thermally sprayed. A sprayed coating is formed on the surface of a base material to the thick one of ≥500 μm. Further, an amorphous metal glass sprayed coating having a porosity of ≤2%, and free from continuous pores passing through the coating is formed. The overcooled liquid temperature region ΔTx of the metal glass is suitably ≥30°C. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成对基材具有优异粘附性的喷涂涂层的方法。 解决方案:当金属玻璃被热喷涂时,通过TMA(热机械分析)测量金属玻璃的线性膨胀系数,以获得其拐点,并且在基材作为对象的温度下 对于热喷涂控制在100℃以上,并且为了小于上述拐点,金属玻璃被热喷涂。 在基材表面形成厚度≥500μm的喷涂层。 此外,形成孔隙率为≤2%,并且没有贯穿涂层的连续孔的无定形金属玻璃喷涂层。 金属玻璃的过冷液温区域ΔTx适宜≥30℃。 版权所有(C)2007,JPO&INPIT
    • 13. 发明专利
    • Composite layered product, gas separation membrane using the same, and production method thereof
    • 复合层状产品,使用其的气体分离膜及其生产方法
    • JP2006159108A
    • 2006-06-22
    • JP2004355520
    • 2004-12-08
    • Tohoku UnivTopy Ind Ltdトピー工業株式会社国立大学法人東北大学
    • SUGIYAMA MASAHARUOHARA MASAKIIGARASHI TAKANORIMOCHIZUKI ATSUOKIMURA HISAMICHIINOUE AKIHISA
    • B01D69/12B01D69/04B01D71/02B32B5/18B32B15/00C01B3/56H01M8/06
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a composite layered product comprising a porous support and a metal glass thin film and sufficiently usable as a gas separation membrane and a simple production method of the product.
      SOLUTION: The composite layered body comprises a metal glass sprayed coating free from pin holes and formed on the surface of a porous support. Metal glass is sprayed by high speed flame spraying to the surface of the porous support to firmly and directly layer the metal glass sprayed coating which is dense, free from pin holes, and has uniform amorphous phase on the surface of the porous support. If those having gas permselectivity against hydrogen or the like are used as metal glass, the composite layered product can sufficiently be used as a gas separation membrane for hydrogen or the like without requiring any particular sealing treatment. Since the sprayed coating is obtained in uniform amorphous phase, it has less hydrogen embrittleness than a crystalline metal and excellent in corrosion resistance and strength. Also, since high speed flame spraying can be carried out in atmospheric air, the production is easy.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种包含多孔载体和金属玻璃薄膜并且可充分地用作气体分离膜的复合层叠体和该产品的简单制造方法。 解决方案:复合层压体包括不具有针孔的金属玻璃喷涂层,并形成在多孔载体的表面上。 通过高速火焰喷涂将金属玻璃喷涂到多孔支撑体的表面上,以牢固且直接地层叠金属玻璃喷涂层,该涂层致密,没有针孔,并且在多孔载体的表面上具有均匀的无定形相。 如果将具有氢气选择性的那些作为金属玻璃使用,则复合层叠体可以充分地用作氢等的气体分离膜,而不需要特别的密封处理。 由于在均匀的非晶相中获得喷涂,所以它具有比结晶金属更少的氢脆性,并且具有优异的耐腐蚀性和强度。 此外,由于可以在大气中进行高速火焰喷涂,所以生产容易。 版权所有(C)2006,JPO&NCIPI
    • 14. 发明专利
    • Die molding body consisting of metallic glass laminate, and method for manufacturing the same body
    • 金属玻璃层压板的成型体模具及其制造方法
    • JP2006122918A
    • 2006-05-18
    • JP2004310862
    • 2004-10-26
    • Tohoku UnivTopy Ind Ltdトピー工業株式会社国立大学法人東北大学
    • MOTOE KATSUJIOHARA MASAKIIGARASHI TAKANORIMOCHIZUKI ATSUOKIMURA HISAMICHIINOUE AKIHISA
    • B21D37/02B21D37/20C22C45/02C22C45/04C22C45/10C23C4/06C23C4/18H01M8/02
    • Y02P70/56
    • PROBLEM TO BE SOLVED: To provide a die molding body, the surface of whose base material is laminated with a metallic glass layer, whose surface has precise rugged shapes or a mirror surface, and to provide a method for simply manufacturing the die molding body. SOLUTION: A laminate 18, which has a metallic glass layer 14 formed on the surface of a base material 12, is manufactured. A die molding body 10 having rugged shapes 16 on the surface of the metallic glass layer 14 is obtained by transferring a die shape to the surface of the metallic glass layer 14 by the press-work using a die 20 in a supercooled liquid region. A die molding body having a mirror surface may be obtained by using a die having a highly smooth surface. The laminate 18 is favorably obtained by applying high-speed flame spraying of metallic glass particles to the surface of the base material 12. A compact amorphous layer of metallic glass is easily and firmly laminated as a thick film and further can be enlarged in its surface area, by applying high-speed flame spraying of metallic particles to a base material. A die molding body having a desired size and shape and having functionality of metallic glass is easily obtained. Further, the weight is made light, and the material cost is reduced, by using a lightweight material and a general-purpose material as a base material. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供一种模具成型体,其基材的表面与金属玻璃层层叠,其表面具有精确的凹凸形状或镜面,并且提供简单制造模具的方法 成型体。 解决方案:制造在基材12的表面上形成有金属玻璃层14的层压体18。 在金属玻璃层14的表面上具有凹凸形状16的模具成型体10通过使用过冷液体区域中的模具20进行压制而将模具形状转印到金属玻璃层14的表面。 可以通过使用具有高度光滑表面的模具来获得具有镜面的模制成型体。 通过将金属玻璃颗粒高速火焰喷涂到基材12的表面上,可以有利地获得层压体18.金属玻璃的紧凑非晶层容易且牢固地层压成厚膜,并且还可以在其表面上扩大 通过将金属颗粒高速火焰喷涂到基材上。 容易获得具有所需尺寸和形状并具有金属玻璃功能的模制成型体。 此外,重量轻,通过使用轻质材料和通用材料作为基材,材料成本降低。 版权所有(C)2006,JPO&NCIPI
    • 16. 发明专利
    • Hydrogen gas sensor
    • 氢气传感器
    • JP2005164584A
    • 2005-06-23
    • JP2004327675
    • 2004-11-11
    • Akihisa InoueTopy Ind Ltdトピー工業株式会社明久 井上
    • INOUE AKIHISAKIMURA HISAMICHIYAMAURA SHINICHIOHARA MASAKIIGARASHI TAKANORIMOCHIZUKI ATSUO
    • G01N27/12
    • PROBLEM TO BE SOLVED: To provide a small-size, inexpensive, and highly reliable hydrogen gas sensor capable of selectively and easily detecting hydrogen gas.
      SOLUTION: In this hydrogen gas sensor, an amorphous alloy changing its physical value reversibly by storage/release of hydrogen is used for a sensor element. When the change of the physical value such as an electric resistance value and a circuit constant of the amorphous alloy is measured, presence/absence of hydrogen gas and/or hydrogen gas concentration are/is detected. Desirably, the sensor element is heated at least in detection of hydrogen gas. In this way, this sensor is provided with the sensor element containing hydrogen storage amorphous alloy, two or more electrodes connected to the sensor element, and a heater part for heating the sensor element.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供能够选择性且容易地检测氢气的小型,便宜且高可靠性的氢气传感器。 解决方案:在这种氢气传感器中,传感器元件使用通过氢的储存/释放可逆地改变其物理值的非晶态合金。 当测量诸如电阻值和非晶态合金的电路常数的物理值的变化时,检测是否存在氢气和/或氢气浓度。 理想地,传感器元件至少在氢气的检测中被加热。 以这种方式,该传感器设置有包含储氢非晶合金,连接到传感器元件的两个或更多个电极的传感器元件和用于加热传感器元件的加热器部件。 版权所有(C)2005,JPO&NCIPI
    • 17. 发明专利
    • Magnesium-based composite material
    • 基于镁的复合材料
    • JP2013001987A
    • 2013-01-07
    • JP2011137031
    • 2011-06-21
    • Topy Industries Ltdトピー工業株式会社
    • OHARA MASAKIENAMI KEITAROISHIDA AKIRAKODAMA TATSUO
    • C22C1/04B22F3/02B22F3/20C22C23/00
    • PROBLEM TO BE SOLVED: To provide a magnesium-based composite material which has excellent strength at room temperature to high temperature while suppressing decrease in corrosion resistance and elongation by using a smaller amount of metal particles.SOLUTION: The magnesium-based composite material uses a Ca-containing magnesium alloy as a matrix and metal particles are dispersed on the grain boundaries of the magnesium alloy. The maximum crystal grain diameter of the Ca-containing magnesium alloy is 20 μm or less, the maximum particle diameter of the metal particles is 30 μm or less, and the amount of the metal particles is 0.1-1 vol% of the composite material. This magnesium-based composite material can be obtained by mechanically comminuting a mixture of the Ca-containing magnesium alloy as the matrix and the metal powder as the metal particles in a solid phase and subjecting the comminuted mixture or a compact thereof to heating and plastic working at a temperature less than a melting point.
    • 解决的问题:提供一种在室温至高温下具有优异强度的镁基复合材料,同时通过使用较少量的金属颗粒来抑制耐腐蚀性和伸长率的降低。 解决方案:镁基复合材料使用含Ca的镁合金作为基体,金属颗粒分散在镁合金的晶界上。 含Ca的镁合金的最大晶粒直径为20μm以下,金属粒子的最大粒径为30μm以下,金属粒子的量为复合材料的0.1〜1vol%。 这种镁基复合材料可以通过将含Ca的镁合金作为基质和作为金属颗粒的金属粉末的混合物以固相机械粉碎并将粉碎的混合物或其成型体进行加热和塑性加工 在低于熔点的温度下。 版权所有(C)2013,JPO&INPIT