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11. 发明申请

US20110070374A1 POLYCARBODIIMIDES 审中-公开
标题翻译：聚碳酸酯
公开(公告)号：US20110070374A1
公开(公告)日：2011-03-24
申请号：US12938438
申请日：2010-11-03
申请人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann M. Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwenderman
发明人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann M. Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwenderman
IPC分类号： B05D3/02 , C08L79/00
CPC分类号： C08G18/025 , C08G18/0823 , C08G18/095 , C08G18/12 , C08G18/2865 , C08G18/758 , C08G18/797 , C08G2105/06 , C09D175/04 , Y10T428/249991 , Y10T442/20 , C08G18/3262
摘要： Polycarbodiimides, processes for their preparation, water-borne coating compositions and the use of the water-borne coating compositions to coat flexible substrates such as leather, artificial leather, textile fabrics, fibers and non-wovens that are used in the manufacture of athletic footwear are disclosed.
摘要翻译：聚碳化二亚胺，其制备方法，水性涂料组合物以及水性涂料组合物在制造运动鞋中所用的柔软底物如皮革，人造皮革，纺织织物，纤维和非织造布的用途被披露。

12. 发明申请

US20090246393A1 POLYCARBODIIMIDES 审中-公开
标题翻译：聚碳酸酯
公开(公告)号：US20090246393A1
公开(公告)日：2009-10-01
申请号：US12056306
申请日：2008-03-27
申请人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwendeman
发明人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwendeman
IPC分类号： C08G73/06 , B05D3/02
CPC分类号： C08G18/025 , C08G18/0823 , C08G18/095 , C08G18/12 , C08G18/2865 , C08G18/758 , C08G18/797 , C08G2105/06 , C09D175/04 , Y10T428/249991 , Y10T442/20 , C08G18/3262
摘要： Polycarbodiimides, processes for their preparation, water-borne coating compositions and the use of the water-borne coating compositions to coat flexible substrates such as leather, artificial leather, textile fabrics, fibers and non-wovens that are used in the manufacture of athletic footwear are disclosed.
摘要翻译：聚碳化二亚胺，其制备方法，水性涂料组合物以及水性涂料组合物在制造运动鞋中所用的柔软底物如皮革，人造皮革，纺织织物，纤维和非织造布的用途被披露。

13. 发明申请

US20080176061A1 SUBSTRATES AND ARTICLES OF MANUFACTURE COATED WITH A WATERBORNE 2K COATING COMPOSITION 有权
标题翻译：用2W涂料组合物制成的基材和制品
公开(公告)号：US20080176061A1
公开(公告)日：2008-07-24
申请号：US12056304
申请日：2008-03-27
申请人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann M. Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwendeman
发明人： Ronald R. Ambrose , Anthony M. Chasser , Mary Ann M. Fuhry , Hongying Zhou , Gregory J. McCollum , Irina G. Schwendeman
IPC分类号： B32B27/40 , B32B27/00 , A43B5/00
CPC分类号： C09D175/04 , A43B1/00 , A43B1/0027 , A43B23/0205 , B32B1/00 , B32B5/02 , B32B9/025 , B32B9/045 , B32B25/08 , B32B27/065 , B32B27/08 , B32B27/40 , C08F8/00 , C08G18/0823 , C08G18/095 , C08G18/12 , C08G18/4833 , C08G18/5024 , C08G18/6692 , C08G18/706 , C08G18/758 , C08G18/797 , D06N3/14 , Y10T428/1334 , Y10T428/1397 , Y10T428/249921 , Y10T428/249991 , Y10T428/31504 , Y10T428/31551 , Y10T428/31554 , Y10T428/31558 , Y10T428/31562 , Y10T428/31569 , Y10T428/31587 , Y10T442/20 , C08F20/00 , C08F22/00 , C08G18/3262 , C08L2666/20
摘要： A compressible substrate coated at least in part with a waterborne coating composition comprising at least one base neutralized active hydrogen containing film-forming resin and a water dispersible carbodiimide crosslinker capable of reacting with the film-forming resin to form a crosslinked film is disclosed. An article of manufacture having at least two different flexible substrates coated at least in part with such a coating is also disclosed.
摘要翻译：公开了至少部分涂覆有包含至少一种碱中和的含活性氢的成膜树脂和能够与成膜树脂反应形成交联膜的水分散性碳二亚胺交联剂的水性涂料组合物的可压缩基材。还公开了具有至少部分涂覆有这种涂层的至少两种不同柔性基材的制品。

14. 发明授权

US07160959B2 Polymer additives for powder coatings 失效
标题翻译：粉末涂料用聚合物添加剂
公开(公告)号：US07160959B2
公开(公告)日：2007-01-09
申请号：US10804685
申请日：2004-03-19
申请人： Michael J. Ziegler , William H. Retsch, Jr. , Anthony M. Chasser , Ronald R. Ambrose , Jackie L. Kulfan
发明人： Michael J. Ziegler , William H. Retsch, Jr. , Anthony M. Chasser , Ronald R. Ambrose , Jackie L. Kulfan
IPC分类号： C08F8/16
CPC分类号： C09D5/033 , Y10S524/904
摘要： Comb polymers prepared by reacting an acrylic polyol or a siloxane polyol with a lactone are disclosed. These comb polymers find particular application as additives for powder coating compositions, to improve various performance properties thereof. Powder coating composition comprising the described comb polymers are also disclosed.
摘要翻译：公开了通过使丙烯酸多元醇或硅氧烷多元醇与内酯反应制备的梳理聚合物。这些梳状聚合物特别用作粉末涂料组合物的添加剂，以改善其各种性能。还公开了包含所述梳状聚合物的粉末涂料组合物。

15. 发明授权

US07091286B2 Low-cure powder coatings and methods for using the same 失效
标题翻译：低固化粉末涂料及其使用方法
公开(公告)号：US07091286B2
公开(公告)日：2006-08-15
申请号：US10673313
申请日：2003-09-29
申请人： Shawn P. Duffy , Anthony M. Chasser , Ronald R. Ambrose
发明人： Shawn P. Duffy , Anthony M. Chasser , Ronald R. Ambrose
IPC分类号： C08G18/28 , C08L63/00 , C08L63/02 , C08L83/05
CPC分类号： C09D5/03 , C07C275/26 , C08G18/2865 , C08G18/3215 , C08G18/3228 , C08G18/755 , C08G18/807 , C08G59/621 , C08G59/686 , C08G2150/20 , C09D163/00 , C09D163/10 , Y10T428/31511 , Y10T428/31522 , Y10T428/31663 , Y10T428/31678 , Y10T428/31681 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31895 , C08L2666/04
摘要： Low-cure powder coating compositions are disclosed, comprising at least one epoxy-containing resin and/or at least one siloxane-containing resin, and at least one material having the structure wherein R1 is an organic radical having 6 to 25 carbon atoms; each R2 is independently a multivalent hydrocarbon group having 1 to 20 carbon atoms; Y is each R3 and R4 are independently alkyl or aryl groups having 1 to 8 carbon atoms; each Z is independently oxygen or nitrogen; R5 is absent when Z is oxygen and R5 is hydrogen, an alkyl or aryl group having 1 to 20 carbon atoms, or (Y)a —R2— when Z is nitrogen; a and b are integers; a is at least 1; b is 1 to 3; and (b) at least one epoxy-containing resin and/or at least one siloxane-containing resin. The material can optionally be reacted with an acidic hydrogen-containing compound. Some compositions are curable without using crosslinking agents or accelerators. Methods for coating a substrate using these compositions, the coated substrates, and additional catalysts useful for the same purpose are also disclosed.
摘要翻译：公开了低固化粉末涂料组合物，其包含至少一种含环氧树脂和/或至少一种含硅氧烷的树脂，以及至少一种具有以下结构的材料：其中R 1为有机基团具有6至25个碳原子; 每个R 2独立地是具有1至20个碳原子的多价烃基; Y是每个R 3和R 4独立地是具有1至8个碳原子的烷基或芳基; 每个Z独立地是氧或氮; 当Z为氧且R 5为氢时，R 5为不存在的基团，或具有1至20个碳原子的烷基或芳基，或（Y）当Z为氮时，R 2为-N 2 - a和b是整数; a至少为1; b为1〜3; 和（b）至少一种含环氧基的树脂和/或至少一种含硅氧烷的树脂。该材料可任选地与酸性含氢化合物反应。一些组合物是可固化的而不使用交联剂或促进剂。还公开了使用这些组合物涂布基材的方法，涂布的基材和用于相同目的的其它催化剂。

16. 发明授权

US06797387B2 Modified aminoplast crosslinkers and powder coating compositions containing such crosslinkers 失效
标题翻译：含有这种交联剂的改性氨基塑料交联剂和粉末涂料组合物
公开(公告)号：US06797387B2
公开(公告)日：2004-09-28
申请号：US09919094
申请日：2001-07-31
申请人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , Jackie L. Smith
发明人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , Jackie L. Smith
IPC分类号： B32B2706
CPC分类号： C08G12/30 , C08G12/20 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D5/033 , C09D161/32 , C09D167/00 , Y10S524/904 , Y10S525/934 , Y10T428/31576 , Y10T428/31794 , C08L2666/20 , C08L61/20
摘要： A crosslinking agent is provided, prepared by reacting (A) an aminoplast resin; (B) a reactive urethane group-containing adduct of a polyfunctional polymer and monoisocyanate, and (C) at least one other compound having active hydrogen groups reactive with aminoplast resin (A). Compound (C) is selected from: (i) compounds having the structure (I): wherein X is aromatic; R1, R2, and R3 each independently represents H, (cyclo)alkyl having from 1 to 12 carbon atoms, aryl, alkaryl, aralkyl, or an active hydrogen-containing group, (ii) compounds having the structure (II) or (III): where R′ and R″ each independently represents an aromatic group or an alkyl group having 1 to 12 carbon atoms; and (iii) compounds different from (i) and (ii), having a melting point of at least 80° C. Further provided are methods for preparing the crosslinking agent, curable compositions containing the crosslinking agent, and coated substrates.
摘要翻译：提供了一种通过（A）氨基塑料树脂反应制备的交联剂; （B）多官能聚合物和单异氰酸酯的反应性氨基甲酸酯基加合物，和（C）至少一种具有与氨基塑料树脂（A）反应的活性氢基团的其它化合物。化合物（C）选自：（i）具有结构（I）的化合物：其中X是芳族的; R 1，R 2和R 3各自独立地表示H 1，具有1至12个碳原子的（环）烷基，芳基，烷芳基，芳烷基或含活性氢基团，（ii）化合物具有结构（II）或（III）：其中R'和R“各自独立地表示芳族基团或具有1至12个碳原子的烷基; 和（iii）不同于（i）和（ii）的化合物，其熔点至少为80℃。进一步提供了制备交联剂的方法，含有交联剂的可固化组合物和涂覆的基材。

17. 发明授权

US06713182B2 Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效
标题翻译：含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物
公开(公告)号：US06713182B2
公开(公告)日：2004-03-30
申请号：US10206719
申请日：2002-07-25
申请人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , Jackie L. Smith
发明人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , Jackie L. Smith
IPC分类号： B32B2738
CPC分类号： C08L67/02 , C08K5/34922 , C09D167/00 , Y10S525/934 , Y10T428/31511 , Y10T428/31551 , Y10T428/31794 , Y10T428/31935 , C08L61/20
摘要： Provided is a crosslinking agent which is the ungelled reaction product of a polyester polyol and an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The polyester polyol is the reaction product of a cycloaliphatic polyol and a cyclic polycarboxylic acid or anhydride. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 10° C. Further provided is a powder coating composition including a solid particulate film-forming mixture of a polymer containing reactive functional groups and having a Tg of at least 30° C., and the crosslinking agent. Additionally provided is a multi-layer composite coating composition having a basecoat layer deposited from a basecoat film-forming composition and a topcoat over the basecoat deposited from the previously described powder coating composition. Coated substrates are also provided.
摘要翻译：提供了一种交联剂，其是聚酯多元醇和具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。聚酯多元醇是脂环族多元醇与环状多元羧酸或酸酐的反应产物。交联剂基本上不含羟基官能团并且具有至少10℃的玻璃化转变温度。还提供了一种粉末涂料组合物，其包含含有反应性官能团并且具有Tg的Tg的聚合物的固体颗粒成膜混合物至少30℃，和交联剂。另外提供了一种多层复合涂料组合物，其具有从底涂层成膜组合物沉积的底涂层和在前述粉末涂料组合物沉积的底涂层上的顶涂层。还提供涂覆的基材。

18. 发明授权

US06635724B2 Modified aminoplast crosslinkers and powder coating compositions containing such crosslinkers 失效
标题翻译：含有这种交联剂的改性氨基塑料交联剂和粉末涂料组合物
公开(公告)号：US06635724B2
公开(公告)日：2003-10-21
申请号：US09918788
申请日：2001-07-31
申请人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu
发明人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu
IPC分类号： C08G1240
CPC分类号： C08G12/42 , C08G12/428 , C08G2150/20 , C08L61/28 , C08L61/32 , C09D161/32 , Y10T428/31725
摘要： A crosslinking agent is provided which is an ungelled reaction product of (a) an aminoplast resin and (b) a compound having active hydrogen groups reactive with the aminoplast resin (a) such that the crosslinking agent is essentially free of functional groups reactive with aminoplast resin and has a glass transition temperature of at least 10° C. Also provided is a method for preparing the crosslinking agent. Further provided is a curable powder coating composition including (A) a polymer having a glass transition temperature of at least 30° C. containing reactive functional groups and (B) the previously described crosslinking agent. Additionally provided is a multilayer composite coating composition including a base coat deposited from a film-forming composition and a top coat over the base coat deposited from the previously described powder coating composition. Coated substrates are also provided.
摘要翻译：提供了一种交联剂，其是（a）氨基塑料树脂和（b）具有与氨基塑料树脂（a）反应的活性氢基团的化合物的未凝胶化反应产物，使得交联剂基本上不含与氨基塑料反应的官能团并且玻璃化转变温度至少为10℃。还提供了制备交联剂的方法。还提供了一种可固化粉末涂料组合物，其包含（A）含有反应性官能团的玻璃化转变温度至少为30℃的聚合物和（B）前述交联剂。另外提供了一种多层复合涂料组合物，其包含从成膜组合物沉积的底涂层和由前述粉末涂料组合物沉积的底涂层上的顶涂层。还提供涂覆的基材。

19. 发明授权

US06500545B1 Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效
标题翻译：含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物
公开(公告)号：US06500545B1
公开(公告)日：2002-12-31
申请号：US09666175
申请日：2000-09-21
申请人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , John R. Schneider , Jackie L. Smith
发明人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , John R. Schneider , Jackie L. Smith
IPC分类号： B32B2738
CPC分类号： C09D167/00 , C08G12/427 , C08G14/06 , C08G14/12 , C08L61/28 , C08L61/32 , C08L61/34 , C09D161/32 , C09D161/34 , C09D163/00 , C09D175/04 , Y10T428/31511 , Y10T428/31529 , Y10T428/31551 , Y10T428/31681 , Y10T428/31688 , Y10T428/31699 , Y10T428/31942 , C08L2666/16 , C08L61/20
摘要： The present invention provides a crosslinking agent having reactive benzoxazine groups which is the ungelled reaction product of (a) at least one mono-hydroxy aromatic compound and (b) at least one aminotriazine compound having one or less non-alkylated NH group present in a molar ratio of reactant (a) to reactant (b) ranging from 1.0 to 3.0: 1.0, provided that where reactant (a) is a single ring monohydroxy aromatic compound, the molar ratio of reactant (a) to reactant (b) ranges from 1.0 to 1.8:1.0 and from 2.2 to 3.0:1.0. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent. Also provided is a curable powder coating composition comprising a solid particulate, film-forming mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups, the polymer having a glass transition temperature of at least 30° C.; and (B) the previously described crosslinking agent. Multilayer composite coating compositions are also provided including a base coat deposited from a film-forming composition and a topcoat over the base coat. The topcoat is deposited from the curable powder coating composition described above. The present invention further provides coated substrates.
摘要翻译：本发明提供具有反应性苯并恶嗪基团的交联剂，其是（a）至少一种单羟基芳族化合物和（b）至少一种具有一个或多个非烷基化NH基团的氨基三嗪化合物的未凝胶化反应产物，反应物（a）与反应物（b）的摩尔比为1.0-3.0:1.0，条件是当反应物（a）为单环一羟基芳族化合物时，反应物（a）与反应物（b）的摩尔比范围为 1.0至1.8：1.0和2.2至3.0：1.0。交联剂基本上不含羟基官能团，玻璃化转变温度至少为25℃。本发明还涉及制备上述交联剂的方法。还提供了一种可固化粉末涂料组合物，其包含（A）具有与氨基三嗪和/或苯并恶嗪基反应的官能团的聚合物的固体颗粒，成膜混合物，所述聚合物具有至少30℃的玻璃化转变温度; 和（B）前述交联剂。还提供了多层复合涂料组合物，包括从成膜组合物沉积的底涂层和底涂层上的顶涂层。从上述可固化粉末涂料组合物沉积面漆。本发明还提供涂覆的基材。

20. 发明授权

US06441103B1 Aminoplast-based crosslinkers and powder coating compositions containing such crosslinkers 失效
标题翻译：含有氨基塑料的交联剂和含有这种交联剂的粉末涂料组合物
公开(公告)号：US06441103B1
公开(公告)日：2002-08-27
申请号：US09666265
申请日：2000-09-21
申请人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , John R. Schneider , Jackie L. Smith
发明人： Ronald R. Ambrose , Anthony M. Chasser , Shengkui Hu , John R. Schneider , Jackie L. Smith
IPC分类号： C08L7506
CPC分类号： C09D5/033 , C08G12/20 , C08G12/30 , C08G12/42 , C08G12/427 , C08G12/428 , C08G18/2825 , C08G18/3851 , C08G18/423 , C08G18/71 , C08G18/792 , C08G18/8064 , C08G2150/20 , C08K5/0025 , C08K5/34922 , C08L61/28 , C08L61/32 , C09D161/32 , C09D167/00 , Y10S524/904 , Y10S525/934 , C08L2666/20 , C08L61/20
摘要： Two types of aminotriazine-based crosslinking agents are provided. Crosslinking agent I includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyester polyol, and (2) a mono-isocyanate. The crosslinking agent I is essentially free of urethane NH functionality and has a glass transition temperature of at least 25° C. Crosslinking agent II includes the ungelled reaction product of (A) a reactive urethane group-containing reaction product and (B) an aminotriazine compound having one or less non-alkylated NH bond per triazine ring. The reactive urethane group-containing reaction product (A) is the reaction product of (1) a polyisocyanate and (2) a monohydric capping agent. The crosslinking agent II is essentially free of urethane N—H functionality and has a glass transition temperature of at least 10° C. Methods for preparing crosslinking agents I and II are also provided. Further provided is a curable composition of a film-forming polymer having reactive functional groups and the previously described crosslinking agent II. Also provided are powder coating compositions which each include a solid particulate mixture of a reactive group-containing polymer having a Tg of at least 30° C and the previously described crosslinking agents I or II. Multilayer composite coating compositions and coated substrates are also provided.
摘要翻译：提供了两种类型的氨基三嗪类交联剂。交联剂I包括（A）含有反应性氨基甲酸酯基的反应产物和（B）具有每个三嗪环具有一个或多个非烷基化NH键的氨基三嗪化合物的未凝胶化反应产物。反应性氨基甲酸酯基反应产物（A）是（1）聚酯多元醇和（2）单异氰酸酯的反应产物。交联剂I基本上不含氨基甲酸酯官能团，玻璃化转变温度至少为25℃。交联剂II包括（A）反应性氨基甲酸酯基反应产物和（B）氨基三嗪的未凝胶化反应产物每个三嗪环具有一个或多个非烷基化NH键的化合物。反应性氨基甲酸酯基反应产物（A）是（1）多异氰酸酯与（2）一羟基封端剂的反应产物。交联剂II基本上不含氨基甲酸酯N-H官能团，玻璃化转变温度至少为10℃。还提供了制备交联剂I和II的方法。还提供了具有反应性官能团的成膜聚合物和前述交联剂II的可固化组合物。还提供了粉末涂料组合物，其各自包含Tg至少为30℃的反应性基团聚合物和前述交联剂I或II的固体颗粒混合物。还提供了多层复合涂层组合物和涂覆的基底。

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