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    • 13. 发明授权
    • Difluorovinyl compound, liquid crystal composition and liquid crystal display
    • 二氟乙烯基化合物,液晶组合物和液晶显示
    • US06649227B2
    • 2003-11-18
    • US09899169
    • 2001-07-06
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • Takashi KatoShuichi MatsuiHiroyuki TakeuchiYasuhiro KuboEtsuo Nakagawa
    • C09K1934
    • C07C49/753C07C49/687C07C49/693C07C49/697C07D319/06C09K19/04C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10
    • Provided are liquid crystalline compounds having a wide liquid crystal phase temperature range, low viscosity, a large elastic constant ratio K33/K11 and excellent solubility at low temperature, a liquid crystal composition using the same and a liquid crystal display. Preferred compounds are difluorovinyl compounds represented by Formula (1): wherein Y1, represents H or a straight chain or branched alkyl group having 1 to 10 carbon atoms, and optional —CH2— in the above alkyl group may be replaced by —O— or —CH═CH—, but —O— is not adjacent to each other, and at least one H in Y1 may be substituted with halogen or a cyano group: A1, A2, A3 and A4 each independently represent 1,4-cyclohexylene in which optional —CH2— which is not adjacent to each other may be replaced by —O—, 1,4-phenylene in which optional H may be substituted with halogen, and a single bond, in which at least two of A1, A2, A3 and A4 have the ring structure described above, and at least one of them is 1,4-cyclohexylene in which —CH2— is replaced by —O—; Z1, Z2 and Z3 each independently represent a single bond, —(CH2)2—, —CH═CH—, —(CH2)4—, —O(CH2)3— or —(CH2)3O—; n represents 0 or an integer of 1 to 10, provided that when any of A1, A2, A3 and A4 is 1,4-phenylene, Z1, Z2 and Z3 are single bonds, and among them, when A1 is 1,3-dioxane-2,5-diyl and A2 is 1,4-phenylene and when A3 is 1,4-cyclohexylene and A4 is a single bond, Y1 is H, and n is not 0.
    • 本发明提供具有宽液晶相温度范围,低粘度,大弹性常数比K33 / K11和低温溶解度优异的液晶化合物,使用该液晶组合物的液晶组合物和液晶显示器。 优选的化合物是由式(1)表示的二氟乙烯基化合物:其中Y 1表示H或具有1至10个碳原子的直链或支链烷基,并且上述烷基中任选的-CH 2 - 可以被 - O-或-CH = CH-,但-O-不彼此相邻,并且Y 1中的至少一个H可以被卤素或氰基取代:A 1,A 2, A 3和A 4各自独立地表示1,4-亚环己基,其中不相邻的任选的-CH 2可以被-O-,1,4-亚苯基代替,其中任选的H可以被取代 具有卤素和单键,其中A 1,A 2,A 3和A 4中的至少两个具有上述环结构,并且它们中的至少一个为1,4 - 环己烯,其中-CH 2 - 被-O-取代; Z 1,Z 2和Z 3各自独立地表示单键, - (CH 2)2 - , - CH = CH - , - (CH 2)4 - , - O(CH 2)3 - (CH2)3O-; n表示0或1〜10的整数,条件是当A 1,A 2,A 3和A 4中的任何一个为1,4-亚苯基时,Z 1,Z 2 且Z 3为单键,其中A 1为1,3-二恶烷-2,5-二基,A 2为1,4-亚苯基,当A 3为1时, ,4-环亚己基和A 4为单键,Y 1为H,n为0。
    • 14. 发明授权
    • Cyclohexane derivatives, liquid crystal compositions comprising the same and liquid crystal display devices
    • 环己烷衍生物,含有它们的液晶组合物和液晶显示装置
    • US06500503B2
    • 2002-12-31
    • US09842254
    • 2001-04-26
    • Koichi ShibataShuichi MatsuiHiroyuki TekeuchiKatsuyuki KawanoYasuhiro KuboEtsuo Nakagawa
    • Koichi ShibataShuichi MatsuiHiroyuki TekeuchiKatsuyuki KawanoYasuhiro KuboEtsuo Nakagawa
    • C09K1930
    • C07D239/26C07C17/16C07C17/18C07C17/2635C07C25/18C07C25/24C07C45/29C07C45/513C07C255/50C07C255/54C07C2601/14C07D319/06C07D339/08C09K19/3001C09K19/3028C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10C07C22/08C07C49/813C07C47/24
    • Liquid crystalline compounds are disclosed which have large dielectric anisotropy and relatively low viscosity, and which are represented by formula (1) wherein R1 represents hydrogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; R2 represents hydrogen, cyano, halogen or C1-C15 alkyl in which one or more non-adjacent methylene may be replaced by oxygen, sulfur or —CH═CH— and one or more hydrogen may be replaced by halogen; L represents halogen or hydrogen; A1, A2, A4 and A5 each independently represent trans-1,4-cyclohexylene or 1,4-phenylene, one or more —CH2— in the trans-1,4-cyclohexylene may be replaced by oxygen or sulfur, one or more ═CH— in the 1,4-phenylene may be replaced by nitrogen, and one or more hydrogen in the 1,4-phenylene ring may be replaced by halogen; A3represents trans-1,4-cyclohexylene in which one or more —CH2— may be replaced by oxygen or sulfur; Z1,Z2,Z3 and Z4 each independently represent —COO—, —OCO—, —CH2CH2—, —(CH2)4—, —CH2O —, —OCH2—, —CF2O—, —OCF2— or a single bond; Q represents —CF2CH2— or —CH2CF2—; and k, l, m and n each independently represent 0 or 1 with the condition of k+l+m+n≦2. Further, liquid crystal compositions comprising at least one liquid crystalline compound of formula (1) and liquid crystal display devices composed of the compositions are disclosed.
    • 公开了具有大介电各向异性和相对低粘度的液晶化合物,其由式(1)表示,其中R 1表示氢或C 1 -C 15烷基,其中一个或多个不相邻的亚甲基可被氧,硫或 -CH = CH-,一个或多个氢可被卤素取代; R 2表示氢,氰基,卤素或C 1 -C 15烷基,其中一个或多个不相邻的亚甲基可被氧,硫或-CH = CH-代替,并且一个或多个氢可被卤素取代; L表示卤素或氢; A1,A2,A4和A5各自独立地表示反式-1,4-亚环己基或1,4-亚苯基,反式-1,4-亚环己基中的一个或多个-CH 2 - 可被氧或硫代替,一个或多个 = 1,4-亚苯基中的CH-可以被氮代替,1,4-亚苯基环中的一个或多个氢可被卤素取代; A3表示反式-1,4-亚环己基,其中一个或多个-CH 2 - 可被氧或硫取代; Z 1,Z 2,Z 3和Z 4各自独立地表示-COO - , - OCO - , - CH 2 CH 2 - , - (CH 2)4 - , - CH 2 O - , - OCH 2 - , - CF 2 O-,-OCF 2-或单键; Q表示-CF 2 CH 2 - 或-CH 2 CF 2 - ; 并且k,l,m和n各自独立地表示0或1,条件为k + 1 + m + n <= 2。 此外,公开了包含至少一种式(1)的液晶化合物和由该组合物组成的液晶显示装置的液晶组合物。
    • 19. 发明授权
    • DMA transfer device
    • DMA传输设备
    • US06557052B1
    • 2003-04-29
    • US09586042
    • 2000-06-02
    • Yasuhiro Kubo
    • Yasuhiro Kubo
    • G06F1328
    • G06F13/28
    • A DMA transfer device has stream inputting means for receiving an encoded first stream; first stream storing means for storing the first stream; a main storage unit which stores the stream of said first stream storing means; first DMA transfer executing means,for executing a first DMA transfer from said first stream storing means to said main storage unit; first DMA transfer controlling means for controlling said first DMA transfer executing means on the basis of an amount of data which are stored in said first stream storing means or a free capacity; a processing unit which produces a second stream from the first stream that is read out from said main storage unit, and which writes the second stream into said main storage unit; second stream storing means for storing the second stream of said main storage unit; second DMA transfer executing means for executing a second DMA transfer from said main storage unit to said second stream storing means; and second DMA transfer controlling means for controlling said second DMA transfer executing means on the basis of an amount of data which are stored in said second stream storing means or a free capacity.
    • DMA传送装置具有用于接收编码的第一流的流输入装置;存储第一流的第一流存储装置;存储所述第一流存储装置的流的主存储单元;第一DMA传送执行装置,用于执行第一流 DMA从所述第一流存储装置传送到所述主存储单元;第一DMA传送控制装置,用于根据存储在所述第一流存储装置中的数据量或可用容量来控制所述第一DMA传送执行装置; 处理单元,其从所述第一流产生从所述主存储单元读出的第二流,并将所述第二流写入所述主存储单元;第二流存储装置,用于存储所述主存储单元的第二流;第二DMA 用于执行从所述主存储单元到所述第二流存储装置的第二DMA传送的传送执行装置; 以及第二DMA传送控制装置,用于根据存储在所述第二流存储装置中的数据量或可用容量来控制所述第二DMA传送执行装置。
    • 20. 发明授权
    • Liquid crystal composition and liquid crystal display element
    • 液晶组成和液晶显示元件
    • US06395353B2
    • 2002-05-28
    • US09808019
    • 2001-03-15
    • Motoki YanaiYasuhiro KuboEtsuo Nakagawa
    • Motoki YanaiYasuhiro KuboEtsuo Nakagawa
    • C09K1930
    • C09K19/42C09K19/406Y10T428/10
    • The present invention provides a liquid crystal composition comprising the compounds represented by the following formulas (I) and (II) wherein each R1 independently represents an alkyl group having 1-10 carbon atoms or an alkenyl group having 2-10 carbon atoms; each R2 independently represents an alkyl or alkoxy group having 1-10 carbon atoms or an alkenyl group having 2-10 carbon atoms; Z1 and Z2 represent —CH2SiH2—, a single bond or —CH2CH2—, with the proviso that one of Z1 and Z2 represents —CH2SiH2— and the other represents a single bond or —CH2CH2—; A1, A2 and A3 each independently represent a ring including aromatic, alicyclic and heterocyclic groups; m and n are each independently 0 or 1; and Z3 and Z4 each independently represent a single bond, —CH2CH2—, —CF2O— or —OCF2—. The composition has a suitable &Dgr;n, a low viscosity, a largely negative &Dgr;&egr; and a broad nematic liquid crystal phase range while satisfying various properties required for liquid crystal compositions for AM-LCD.
    • 本发明提供一种液晶组合物,其含有下述式(I)和(II)表示的化合物,其中,各R1独立地表示碳原子数1〜10的烷基或碳原子数2〜10的烯基。 每个R 2独立地表示具有1-10个碳原子的烷基或烷氧基或具有2-10个碳原子的烯基; Z 1和Z 2表示-CH 2 SiH 2 - ,单键或-CH 2 CH 2 - ,条件是Z 1和Z 2中的一个表示-CH 2 SiH 2 - ,另一个表示单键或-CH 2 CH 2 - ; A1,A2和A3各自独立地表示包括芳族,脂环族和杂环基团的环; m和n各自独立地为0或1; Z 3和Z 4各自独立地表示单键,-CH 2 CH 2 - , - CF 2 O-或-OCF 2 - 。 该组合物具有适合的DELTAn,低粘度,大量负DELTAepsi和宽向列型液晶相范围,同时满足AM-LCD液晶组合物所需的各种性能。