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    • 14. 发明授权
    • Silicon carbide light emitting diode and a method for the same
    • 硅碳化硅发光二极管及其相关方法
    • US5243204A
    • 1993-09-07
    • US702819
    • 1991-05-17
    • Akira SuzukiKatsuki FurukawaYoshihisa Fujii
    • Akira SuzukiKatsuki FurukawaYoshihisa Fujii
    • H01L33/00H01L33/34
    • H01L33/34H01L33/0054
    • There are provided silicon carbide light emitting diodes having a p-n junction which is constituted by a p-type silicon carbide single-crystal layer and an n-type silicon carbide single-crystal layer formed thereon. In cases where light emission caused by recombination of free excitons is substantially utilized, at least a part of the n-type silicon carbide layer adjacent to the interface of the p-n junction is doped with a donor impurity at a concentration of 5.times.10.sup.16 cm.sup.-3 or lower. In cases where light emission caused by acceptor-associated recombination is substantially utilized, the p-type silicon carbide layer is doped with an acceptor impurity and at least a part of the n-type silicon carbide layer adjacent to the interface of the p-n junction is doped with a donor impurity at a concentration of 1.times.10.sup.18 cm.sup.-3 or higher. Also provided are a method for producing such silicon carbide light emitting diodes and a method for producting another silicon carbide light emitting diode.
    • 提供了由在其上形成的p型碳化硅单晶层和n型碳化硅单晶层构成的具有p-n结的碳化硅发光二极管。 在实质上利用游离激子的重组引起的发光的情况下,与pn结的界面相邻的n型碳化硅层的至少一部分掺杂有浓度为5×10 16 cm -3的施主杂质或 降低。 在基本上利用由受体相关复合引起的发光的情况下,p型碳化硅层掺杂有受主杂质,并且与pn结的界面相邻的n型碳化硅层的至少一部分为 掺杂浓度为1×10 18 cm -3或更高的施主杂质。 还提供了这种碳化硅发光二极管的制造方法和制造另一种碳化硅发光二极管的方法。
    • 19. 发明授权
    • Method of producing silicon-carbide single crystals by sublimation
recrystallization process using a seed crystal
    • 使用晶种的升华重结晶法生产碳化硅单晶的方法
    • US5433167A
    • 1995-07-18
    • US156472
    • 1993-11-23
    • Katsuki FurukawaYoshimitsu TajimaAkira Suzuki
    • Katsuki FurukawaYoshimitsu TajimaAkira Suzuki
    • C30B23/02C30B29/36
    • C30B23/02C30B23/002C30B29/36
    • There is provided a method of producing a high-quality n-type, 6H silicon carbide single crystal with good reproducibility. A silicon carbide single crystal substrate having a growth orientation of , as a seed crystal, is mounted to an inner surface of a cover of a graphite crucible. A source material includes a high-purity silicon carbide powder having an impurity proportion of not more than 1 ppm and an aluminum powder of 50 ppm relative to the silicon carbide powder. The source material is loaded into the graphite crucible. The graphite crucible is closed with a seed crystal-mounted cover placed in a double quartz tube. Ar gas and N.sub.2 gas are caused to flow in the double quartz tube. Temperature of the silicon carbide powder and aluminum powder is controlled to 2300.degree. C., and temperature of the silicon carbide single crystal substrate to 2200.degree. C.; and interior of the double quartz tube is controlled to 30 torr. Silicon carbide single crystal growth is effected on the seed crystal under these conditions. A high-quality n-type, 6H silicon carbide single crystal is thus obtained which has a uniform crystal structure with little defect, if any, throughout its structure, from the substrate surface to the outermost grown surface, and has a specific resistance of 0.5 .OMEGA.cm.
    • 提供了一种制造高品质的n型,6H碳化硅单晶,具有良好的再现性的方法。 具有生长方向<0001>的碳化硅单晶衬底作为晶种安装在石墨坩埚的盖的内表面上。 源材料包括杂质比例不大于1ppm的高纯度碳化硅粉末和相对于碳化硅粉末为50ppm的铝粉末。 将原料装入石墨坩埚中。 石墨坩埚用放置在双重石英管中的晶种安装的盖封闭。 使Ar气和N2气在双重石英管中流动。 将碳化硅粉末和铝粉末的温度控制在2300℃,将碳化硅单晶基板的温度控制在2200℃。 并将双重石英管的内部控制在30乇。 在这些条件下,对晶种进行碳化硅单晶生长。 因此获得了高质量的n型6H碳化硅单晶,其具有从基材表面到最外面的生长表面的整个结构中几乎没有缺陷(如果有的话)的均匀晶体结构,并且具有0.5的电阻率 欧米茄厘米