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11. 发明授权

US5556884A Substituted oxime ethers, their preparation and their use for controlling pests and fungi 失效
标题翻译：取代的肟醚，它们的制备及其用于防治害虫和真菌的用途
公开(公告)号：US5556884A
公开(公告)日：1996-09-17
申请号：US449223
申请日：1995-05-24
申请人： Klaus Oberdorf , Hubert Sauter , Wassilios Grammenos , Reinhard Kirstgen , Volker Harries , Gisela Lorenz , Eberhard Ammermann , Randall E. Gold , Wolfgang Siegel , Albrecht Harreus
发明人： Klaus Oberdorf , Hubert Sauter , Wassilios Grammenos , Reinhard Kirstgen , Volker Harries , Gisela Lorenz , Eberhard Ammermann , Randall E. Gold , Wolfgang Siegel , Albrecht Harreus
IPC分类号： A01N37/18 , A01N37/34 , A01N37/36 , A01N37/38 , A01N37/50 , C07C251/40 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C255/32 , C07C255/62 , C07D213/63 , C07D333/32 , C07D521/00
CPC分类号： C07C251/52 , A01N37/38 , A01N37/50 , C07C251/48 , C07C251/54 , C07C251/60 , C07C255/62 , C07C2101/02 , C07C2101/08 , C07C2101/14
摘要： Substituted oxime ethers of the general formula I ##STR1## where R.sup.1 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxyalkyl, cycloalkyl, cycloalkylalkyl, cyanoalkyl, alkoxycarbonylalkyl, arylalkyl, heteroarylalkyl, arylalkenyl or aryloxyalkyl, the aromatic or heteroaromatic ring being substituted or unsubstituted,R.sup.2 and R.sup.3 are hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano or nitro,R.sup.4 is hydrogen, alkyl, cycloalkyl, haloalkyl or aryl, the aromatic ring being substituted or unsubstituted, andR.sup.5 and R.sup.6 are identical or different and each is hydrogen or alkyl, andX is CH or N, and fungicides and pesticides containing these compounds.
摘要翻译：取代的通式I的肟醚，其中R 1是烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基烷基，环烷基，环烷基烷基，氰基烷基，烷氧基羰基烷基，芳基烷基，杂芳基烷基，芳基烯基或芳氧基烷基，芳族或杂芳环被取代或未取代的，R2和R3是氢，烷基，卤代烷基，烷氧基，卤代烷氧基，卤素，氰基或硝基，R4是氢，烷基，环烷基，卤代烷基或芳基，芳环是取代或未取代的，R5和R6是相同的或不同的是氢或烷基，X是CH或N，以及含有这些化合物的杀真菌剂和杀虫剂。

12. 发明授权

US5254717A Imino-substituted phenyl derivatives, the preparation thereof and fungicides containing these 失效
标题翻译：亚氨基取代的苯基衍生物，其制备方法和含有它们的杀真菌剂
公开(公告)号：US5254717A
公开(公告)日：1993-10-19
申请号：US825378
申请日：1992-01-24
申请人： Wassilios Grammenos , Albrecht Harreus , Hubert Sauter , Beate Hellendahl , Reinhard Doetzer , Eberhard Ammermann , Gisela Lorenz
发明人： Wassilios Grammenos , Albrecht Harreus , Hubert Sauter , Beate Hellendahl , Reinhard Doetzer , Eberhard Ammermann , Gisela Lorenz
IPC分类号： A01N37/50 , A01N43/54 , A01N43/58 , A01N43/76 , A01N43/836 , C07C69/65 , C07C69/653 , C07C69/734 , C07C69/738 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/56 , C07C251/58 , C07C251/60 , C07C251/86 , C07C255/15 , C07C255/57 , C07C255/58 , C07C255/62 , C07D213/77 , C07D239/42 , C07D241/20 , C07D263/32 , C07D333/28 , C07C229/34 , C07C37/50
CPC分类号： C07D213/77 , A01N37/50 , A01N43/54 , A01N43/58 , A01N43/76 , C07C251/48 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C251/86 , C07C255/15 , C07C255/57 , C07C255/58 , C07C255/62 , C07C69/65 , C07C69/734 , C07C69/738 , C07D239/42 , C07D241/20 , C07D263/32 , C07D333/28 , C07C2101/02 , C07C2101/14 , C07C2103/24
摘要： Compound of the formula I ##STR1## where R is hydrogen or alkyl,R.sup.1 is hydrogen, alkyl, haloalkyl or aryl,Z.sup.1 and Z.sup.2 are hydrogen, halogen, alkoxy, alkenyloxy, cyano, nitro, haloalkyl, haloalkenyloxy, alkenyl, haloalkoxy, alkyl or alkynyl,Y is O or NR.sup.3, where R.sup.3 is hydrogen or alkyl,R.sup.2 is H, alkyl, cycloalkyl, alkenyl, aryl, alkynyl, cycloalkenyl, arylalkyl, aryloxyalkyl, hetaryl, hetarylalkyl, hetaryloxyalkyl, acyl, arylalkenyl, hetarylalkenyl, heterocyclyl, arylcarbonyl, hetarylcarbonyl or alkoxycarbonylalkyl,Y and R.sup.2 may form a ring, andX is CH.sub.2, CH-alkyl, CH-alkoxy, CH-alkylthio, N-alkoxy or NOH,and fungicides containing these compounds.
摘要翻译：式I化合物其中R是氢或烷基，R 1是氢，烷基，卤代烷基或芳基，Z 1和Z 2是氢，卤素，烷氧基，烯氧基，氰基，硝基，卤代烷基，卤代烯氧基，烯基，卤代烷氧基，烷基或炔基，Y是O或NR 3，其中R 3是氢或烷基，R 2是H，烷基，环烷基，烯基，芳基，炔基，环烯基，芳基烷基，芳氧基烷基，杂芳基，杂芳基烷基，环氧基烷基，酰基，芳基烯基，杂芳基烯基，杂环基，芳基羰基，杂芳基羰基或烷氧基羰基烷基，Y和R2可以形成环，X是CH 2，CH-烷基，CH-烷氧基，CH-烷硫基，N-烷氧基或NOH，以及含有这些化合物的杀真菌剂。

13. 发明授权

US06316459B1 O-benzyloxime ethers and crop protection agents containing these compounds 失效
标题翻译： O-苄氧基肟醚和含有这些化合物的作物保护剂
公开(公告)号：US06316459B1
公开(公告)日：2001-11-13
申请号：US08328516
申请日：1994-10-25
申请人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
发明人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
IPC分类号： A01N4348
CPC分类号： C07D209/48 , A01N37/36 , A01N37/38 , A01N37/50 , A01N43/16 , C07C251/60 , C07C255/64 , C07C257/06 , C07C323/47 , C07C323/56 , C07C323/60 , C07C327/22 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D309/04 , C07D309/12
摘要： O-Benzyloxime ethers of the formula I where X is substituted or unsubstituted CH2, NOalkyl Y is O, S, NR5 R1, R2, R5 are H, alkyl Z1, Z2 are H, halogen, methyl, methoxy, cyano R3, R4 are hydrogen, cyano, substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, alkynyl, alkoxy, haloalkoxy, alkylthio, benzylthio, alkylcarbonyl, substituted or unsubstituted phenylcarbonyl, substituted or unsubstituted benzylcarbonyl, alkoxycarbonyl, substituted or unsubstituted phenoxycarbonyl, substituted or unsubstituted benzyloxycarbonyl, N(R6)2, where R6 is H, alkyl, substituted or unsubstituted phenyl, —CO—N(R7)2, where R7 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted arylthio, substituted or unsubstituted hetaryl, substituted or unsubstituted hetaryloxy, substituted or unsubstituted hetarylthio, substituted or unsubstituted heterocyclyl, substituted or unsubstituted heterocyclyloxy, R3 and R4 together may form a carbocyclic or heterocyclic ring which is substituted or unsubstituted, and R3 or R4 may be halogen, or may be where n is an integer from 1 to 4, and R8 is, or, when n>1, the R8's are identical or different and are each, H, halogen, cyano, nitro or substituted or unsubstituted C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, aryl, aryloxy, benzyloxy, hetaryl or hetaryloxy. and crop protection agents containing these compounds.
摘要翻译：式I的O-苄氧基肟醚是取代或未取代的CH 2，N 2烷基Y是O，S，NR 5 R 1，R 2，R 5是H，烷基Z 1，Z 2是H，卤素，甲基，甲氧基，氰基R 3，R 4是氢，氰基，未取代的烷基，烯基，环烷基，环烯基，炔基，烷氧基，卤代烷氧基，烷硫基，苄硫基，烷基羰基，取代或未取代的苯基羰基，取代或未取代的苄基羰基，烷氧基羰基，取代或未取代的苯氧基羰基，取代或未取代的苄氧羰基，N（R6） R6是H，烷基，取代或未取代的苯基，-CO-N（R7）2，其中R7是H，取代或未取代的烷基，取代或未取代的芳基，取代或未取代的芳氧基，取代或未取代的芳硫基，取代或未取代的杂芳基，取代或未取代的杂芳氧基，取代或未取代的杂芳硫基，取代或未取代的杂环基，取代或未取代的杂环氧基，R3和R4至可以形成被取代或未取代的碳环或杂环，R 3或R 4可以是卤素，或者可以是1〜4的整数，R 8是，或者当n> 1时，R 8相同或不同， C 1 -C 4烷氧基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，芳基，芳氧基，苄氧基，杂芳基或杂环氧基和作物含有这些化合物的保护剂。

14. 发明授权

US5889059A Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them 失效
标题翻译：苯乙酸衍生物，其制备方法及其中间体，以及含有它们的组合物
公开(公告)号：US5889059A
公开(公告)日：1999-03-30
申请号：US687480
申请日：1996-08-05
申请人： Herbert Bayer , Hubert Sauter , Ruth Muller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Rohl , Eberhard Ammermann , Gisela Lorenz
发明人： Herbert Bayer , Hubert Sauter , Ruth Muller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Rohl , Eberhard Ammermann , Gisela Lorenz
IPC分类号： C07D249/08 , A01N37/50 , A01N37/52 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/80 , A01N43/82 , A01N43/824 , A01P3/00 , A01P7/04 , C07C251/38 , C07C251/40 , C07C251/48 , C07C251/54 , C07C251/56 , C07C251/58 , C07C255/11 , C07C327/44 , C07C327/48 , C07C327/58 , C07D207/32 , C07D207/333 , C07D207/36 , C07D213/30 , C07D213/53 , C07D213/62 , C07D213/64 , C07D213/79 , C07D233/64 , C07D237/14 , C07D239/34 , C07D239/46 , C07D241/18 , C07D261/08 , C07D261/10 , C07D263/32 , C07D263/34 , C07D271/06 , C07D271/10 , C07D277/24 , C07D307/42 , C07D333/32 , C07D521/00 , A01N37/18 , C07C233/05
CPC分类号： C07D207/333 , A01N37/50 , A01N37/52 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/80 , A01N43/82 , C07C251/58 , C07C255/11 , C07C327/48 , C07C327/58 , C07D213/53 , C07D213/64 , C07D239/34 , C07D261/08 , C07D263/32 , C07D271/06 , C07D277/24 , C07D307/42
摘要： Phenylacetic acid derivatives of the formula I ##STR1## where the substituents and the index have the following meanings: X is oxygen or sulfur;R is hydrogen or alkyl;R.sup.1 is hydrogen or alkyl;R.sup.2 is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy;m is 0, 1 or 2, it being possible for the R.sup.2 radicals to be different if m is 2;R.sup.3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino or dialkylamino;R.sub.4 is hydrogen, cyano, nitro, hydroxyl, amino, halogen,unsubstituted or substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkynyl, alkynyloxy, alkynylthio, alkynylamino, N-alkynyl-N-alkylamino;unsubstituted or substituted cycloalkyl, cycloalkoxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxcy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, N-hetaryl-N-alkylamino;R.sup.5 is hydrogen,unsubstituted or substituted alkyl, cycloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl or alkylsulfonyl;unsubstituted or substituted aryl, arylcarbonyl, arylsulfonyl, hetaryl, hetarylcarbonyl or hetarylsulfonyl,and their salts, processes and intermediates for their preparation, and their use are described.
摘要翻译： PCT No.PCT / EP95 / 00007 Sec。 371日期：1996年8月5日 102（e）日期1996年8月5日PCT提交1995年1月3日PCT公布。公开号WO95 / 21154 日期：1995年8月10日下式的苯乙酸衍生物具有以下含义：X为氧或硫; R是氢或烷基; R1是氢或烷基; R2是氰基，硝基，三氟甲基，卤素，烷基或烷氧基; m为0,1或2，如果m为2，则R2基团可能不同; R3是氢，氰基，硝基，羟基，氨基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基; R4是氢，氰基，硝基，羟基，氨基，卤素，未取代或取代的烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，烯基，烯氧基，烯硫基，烯基氨基，N-烯基-N-烷基氨基，炔基，炔氧基，炔硫基，炔基氨基，N-炔基-N-烷基氨基; 未取代或取代的环烷基，环烷氧基，环烷硫基，环烷基氨基，N-环烷基-N-烷基氨基，环烯基，环烯基氧基，环烯基硫基，环烯基氨基，N-环烯基-N-烷基氨基，杂环基，杂环基，杂环硫基，杂环基氨基，N-杂环基-N-烷基氨基，芳基，芳氧基，芳硫基，芳基氨基，N-芳基-N-烷基氨基，杂芳基，杂芳氧基，杂芳硫基，杂芳基氨基，N-芳基-N-烷基氨基; R5是氢，未取代或取代的烷基，环烷基，烯基，炔基，烷基羰基，烯基羰基，炔基羰基或烷基磺酰基; 未取代或取代的芳基，芳基羰基，芳基磺酰基，杂芳基，杂芳基羰基或杂芳基磺酰基及其盐，其制备方法和中间体及其用途。

15. 发明授权

US06326399B1 O-benzyloxime ethers and crop protection agents containing these compounds 失效
标题翻译： O-苄氧基肟醚和含有这些化合物的作物保护剂
公开(公告)号：US06326399B1
公开(公告)日：2001-12-04
申请号：US08630091
申请日：1996-04-09
申请人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
发明人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
IPC分类号： A01N4740
CPC分类号： C07D209/48 , A01N37/36 , A01N37/38 , A01N37/50 , A01N43/16 , C07C251/60 , C07C255/64 , C07C257/06 , C07C323/47 , C07C323/56 , C07C323/60 , C07C327/22 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D309/04 , C07D309/12
摘要： O-Benzyloxime ethers of the formula I where X is substituted or unsubstituted CH2, NOalkyl Y is O, S, NR5 R1, R2, R5 are H, alkyl Z1, Z2 are H, halogen, methyl, methoxy, cyano and crop protection agents containing these compounds.
摘要翻译：式I的O-苄氧基肟醚是取代或未取代的CH 2，N 2烷基Y是O，S，NR 5 R 1，R 2，R 5是H，烷基Z 1，Z 2是含有这些化合物的H，卤素，甲基，甲氧基，氰基和作物保护剂。

16. 发明授权

US5990339A Phenylacetic acid derivatives, and use as fungicides 失效
标题翻译：苯乙酸衍生物，用作杀真菌剂
公开(公告)号：US5990339A
公开(公告)日：1999-11-23
申请号：US97862
申请日：1998-06-16
申请人： Herbert Bayer , Hubert Sauter , Ruth Muller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Rohl , Eberhard Ammermann , Gisela Lorenz
发明人： Herbert Bayer , Hubert Sauter , Ruth Muller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Rohl , Eberhard Ammermann , Gisela Lorenz
IPC分类号： C07D249/08 , A01N20060101 , A01N37/00 , A01N37/36 , A01N37/44 , A01N37/50 , A01N41/10 , A01N43/00 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/54 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/66 , A01N43/707 , A01N43/72 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/824 , A01N43/836 , A01N43/88 , A01N47/02 , A01P3/00 , A01P7/04 , C07C20060101 , C07C205/04 , C07C249/08 , C07C251/34 , C07C251/36 , C07C251/38 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/56 , C07C251/60 , C07C255/07 , C07C255/12 , C07C255/62 , C07C255/64 , C07C259/06 , C07C259/14 , C07C309/04 , C07C309/28 , C07C317/18 , C07C317/22 , C07C317/26 , C07C317/44 , C07C323/12 , C07C323/19 , C07C323/23 , C07C325/00 , C07C327/38 , C07C327/42 , C07C327/48 , C07C327/58 , C07D207/32 , C07D207/323 , C07D207/333 , C07D207/36 , C07D211/72 , C07D211/88 , C07D213/30 , C07D213/50 , C07D213/53 , C07D213/61 , C07D213/64 , C07D213/65 , C07D213/68 , C07D213/71 , C07D213/79 , C07D213/80 , C07D215/20 , C07D215/22 , C07D231/12 , C07D231/20 , C07D231/22 , C07D233/61 , C07D233/64 , C07D237/08 , C07D237/12 , C07D237/14 , C07D239/26 , C07D239/28 , C07D239/30 , C07D239/34 , C07D239/36 , C07D239/38 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/18 , C07D241/44 , C07D251/16 , C07D251/26 , C07D251/30 , C07D261/06 , C07D261/08 , C07D261/10 , C07D261/12 , C07D263/32 , C07D263/34 , C07D263/46 , C07D271/06 , C07D271/10 , C07D275/02 , C07D277/20 , C07D277/24 , C07D277/28 , C07D277/32 , C07D277/34 , C07D277/36 , C07D285/08 , C07D285/12 , C07D307/12 , C07D307/36 , C07D307/42 , C07D307/52 , C07D307/56 , C07D307/58 , C07D333/16 , C07D333/22 , C07D333/28 , C07D333/32 , C07C251/10
CPC分类号： C07D207/333 , A01N37/36 , A01N37/50 , A01N43/08 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/88 , C07C249/08 , C07C251/38 , C07C251/48 , C07C251/60 , C07C327/58 , C07D213/53 , C07D213/64 , C07D239/34 , C07D239/36 , C07D261/08 , C07D261/10 , C07D263/32 , C07D271/06 , C07D277/24 , C07D307/12 , C07C2101/02 , C07C2101/04 , C07C2101/08 , C07C2101/14
摘要： The present invention relates to phenylacetic acid derivatives of the formula I ##STR1## where the substituents and the index have the following meanings: X is NOCH.sub.3, CHOCH.sub.3, CHCH.sub.3 and [sic] CHCH.sub.2 CH.sub.3 ;R.sup.1 is hydrogen and [sic] C.sub.1 -C.sub.4 -alkyl;R.sup.2 is cyano, nitro, trifluoromethyl, halogen, C.sub.1 -C.sub.4 -alkyl and [sic] C.sub.1 -C.sub.4 -alkoxy;m is 0, 1 or 2, it being possible for the R.sup.2 radicals to be different if m is 2;R.sup.3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, C.sub.1 -C.sub.1 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylamino or di-C.sub.1 -C.sub.4 -alkylamino;R.sup.4 is hydrogen, cyano, nitro, hydroxyl, amino, halogen,R.sup.5 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.10 -alkenyl, C.sub.2 -C.sub.10 -alkynyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.2 -C.sub.10 -alkenylcarbonyl, C.sub.3 -C.sub.10 -alkynylcarbonyl or C.sub.1 -C.sub.10 -alkylsulfonyl, it being possible for these radicals to be partly or completely halogenated or to carry one to three of the following groups: cyano, nitro, hydroxyl, mercapto, amino, carboxyl, aminocarbonyl, aminothiocarbonyl,
摘要翻译：本发明涉及式I的苯乙酸衍生物，其中取代基和指数具有以下含义：X为NOCH 3，CHOCH 3，CHCH 3和[sic] CHCH 2 CH 3; R 1是氢和[C 1-6] C 1 -C 4 - 烷基; R2是氰基，硝基，三氟甲基，卤素，C 1 -C 4 - 烷基和[C 1] C 1 -C 4 - 烷氧基; m为0,1或2，如果m为2，则R2基团可能不同; R3是氢，氰基，硝基，羟基，氨基，卤素，C1-C1烷基，C1-C4卤代烷基，C1-C4-烷氧基，C1-C4-卤代烷氧基，C1-C4-烷硫基，C1-C4烷基氨基或二-C 1 -C 4烷基氨基; R4是氢，氰基，硝基，羟基，氨基，卤素，R5是氢，C1-C10-烷基，C3-C6-环烷基，C2-C10-烯基，C2-C10-炔基，C1-C10-烷基羰基，C2- C 1 -C 10 - 烯基羰基，C 3 -C 10 - 炔基羰基或C 1 -C 10 - 烷基磺酰基，这些基团可能被部分或完全卤化或携带一至三个以下基团：氰基，硝基，羟基，巯基，氨基，羧基，氨基羰基，氨基硫代羰基，

17. 发明授权

US5358968A Substituted oxime ethers, their preparation and their use for controlling pests and fungi 失效
标题翻译：取代的肟醚，它们的制备及其用于防治害虫和真菌的用途
公开(公告)号：US5358968A
公开(公告)日：1994-10-25
申请号：US91254
申请日：1993-07-15
申请人： Klaus Oberdorf , Hubert Sauter , Wassilios Grammenos , Reinhard Kirstgen , Volker Harries , Gisela Lorenz , Eberhard Ammermann , Randall E. Gold , Wolfgang Siegel , Albrecht Harreus
发明人： Klaus Oberdorf , Hubert Sauter , Wassilios Grammenos , Reinhard Kirstgen , Volker Harries , Gisela Lorenz , Eberhard Ammermann , Randall E. Gold , Wolfgang Siegel , Albrecht Harreus
IPC分类号： A01N37/18 , A01N37/34 , A01N37/36 , A01N37/38 , A01N37/50 , C07C251/40 , C07C251/48 , C07C251/50 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C255/32 , C07C255/62 , C07D213/63 , C07D333/32 , C07D521/00 , A61K31/165 , C07C251/38
CPC分类号： C07C251/52 , A01N37/38 , A01N37/50 , C07C251/48 , C07C251/54 , C07C251/60 , C07C255/62 , C07C2101/02 , C07C2101/08 , C07C2101/14
摘要： Substituted oxime ethers of the general formula I ##STR1## where R.sup.1 is alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, alkoxyalkyl, cycloalkyl, cycloalkylalkyl, cyanoalkyl, alkoxycarbonylalkyl, arylalkyl, heteroarylalkyl, arylalkenyl or aryloxyalkyl, the aromatic or heteroaromatic ring being substituted or unsubstituted,R.sup.2 and R.sup.3 are hydrogen, alkyl, haloalkyl, alkoxy, haloalkoxy, halogen, cyano or nitro,R.sup.4 is hydrogen, alkyl, cycloalkyl, haloalkyl or aryl, the aromatic ring being substituted or unsubstituted, andR.sup.5 and R.sup.6 are identical or different and each is hydrogen or alkyl, andX is CH or N, and fungicides and pesticides containing these compounds.
摘要翻译：取代的通式I的肟醚，其中R 1是烷基，烯基，炔基，卤代烷基，卤代烯基，烷氧基烷基，环烷基，环烷基烷基，氰基烷基，烷氧基羰基烷基，芳基烷基，杂芳基烷基，芳基烯基或芳氧基烷基，芳族或杂芳环被取代或未取代的，R2和R3是氢，烷基，卤代烷基，烷氧基，卤代烷氧基，卤素，氰基或硝基，R4是氢，烷基，环烷基，卤代烷基或芳基，芳环是取代或未取代的，R5和R6是相同的或不同的是氢或烷基，X是CH或N，以及含有这些化合物的杀真菌剂和杀虫剂。

18. 再颁专利

USRE37873E1 Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them 失效
标题翻译：苯乙酸衍生物，其制备方法及其中间体，以及含有它们的组合物
公开(公告)号：USRE37873E1
公开(公告)日：2002-10-08
申请号：US09834711
申请日：2001-04-16
申请人： Herbert Bayer , Hubert Sauter , Ruth Müller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Röhl , Eberhard Ammermann , Gisela Lorenz
发明人： Herbert Bayer , Hubert Sauter , Ruth Müller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Röhl , Eberhard Ammermann , Gisela Lorenz
IPC分类号： A01N3718
CPC分类号： C07D207/333 , A01N37/50 , A01N37/52 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/80 , A01N43/82 , C07C251/58 , C07C255/11 , C07C327/48 , C07C327/58 , C07D213/53 , C07D213/64 , C07D239/34 , C07D261/08 , C07D263/32 , C07D271/06 , C07D277/24 , C07D307/42
摘要： Phenylacetic acid derivatives of the formula I
摘要翻译：式I的苯乙酸衍生物

19. 再颁专利

USRE37839E1 O-benzyloxime ethers and crop protection agents containing these compounds 失效
标题翻译： O-苄氧基肟醚和含有这些化合物的作物保护剂
公开(公告)号：USRE37839E1
公开(公告)日：2002-09-10
申请号：US08627377
申请日：1996-04-05
申请人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
发明人： Siegbert Brand , Uwe Kardorff , Reinhard Kirstgen , Bernd Mueller , Klaus Oberdorf , Hubert Sauter , Gisela Lorenz , Eberhard Ammermann , Christoph Kuenast , Albrecht Harreus
IPC分类号： A61K3116
CPC分类号： C07D209/48 , A01N37/36 , A01N37/38 , A01N37/50 , A01N43/16 , C07C251/60 , C07C255/64 , C07C257/06 , C07C323/47 , C07C323/56 , C07C323/60 , C07C327/22 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D309/04 , C07D309/12
摘要： O-Benzyloxime ethers of the formula I wherein 5 x is substituted or unsubstituted CH2, NOalkyl Y is O, S, NR5 R1, R2, R5 are H, alkyl Z1, Z2 are H, halogen, methyl, methoxy, cyano R3, R4 are hydrogen, cyano, substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, alkynyl, alkoxy, haloalkoxy, alkylthio, benzylthio, alkylcarbonyl, substituted or unsubstituted benzylcarbonyl, alkoxycarbonyl, substituted or unsubstituted phenoxycarbonyl substituted or unsubstituted benzyloxycarbonyl, N(R6)2, where R6 is H, alkyl, substituted or unsubstituted phenyl, —CO—N(R7)2, where R7 is H, substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted arylthio, substituted or unsubstituted hetaryl, substituted or unsubstituted hetaryloxy, substituted or unsubstituted hetarylthio, substituted or unsubstituted heterocyclyl, substituted or unsubstituted heterocyclyloxy, R3 and R4 together may form a carbocyclic or heterocyclic ring which is substituted or unsubstituted, and R3 or R4 may be halogen, or may be where n is an integer from 1 to 4, and R8 is, or, when n>1, the R8's are identical or different and are each, H, halogen, cyano, nitro or substituted or unsubstituted C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-haloalkoxy, aryl, aryloxy, benzyloxy, hetaryl or hetaryloxy, and crop protection agents containing these compounds.
摘要翻译：式I的O-苄氧基醚，其中5是取代或未取代的CH 2，N 2，R 3，R 5，取代或未取代的苯氧基羰基取代或未取代的苄氧基羰基，N（R6）2，其中R6是H，烷基，环烷基，炔基，烷氧基，卤代烷氧基，取代或未取代的苯基，-CO-N（R7）2，其中R7是H，取代或未取代的烷基，取代或未取代的芳基，取代或未取代的芳氧基，取代或未取代的芳硫基，取代或未取代的杂芳基，取代或未取代的杂芳氧基，取代或未取代的杂芳硫基，取代或未取代的杂环基，取代或未取代的杂环氧基，R3和R4一起可以形成碳环或杂环取代或未取代的环，R 3或R 4可以是卤素，或者可以是1至4的整数，R 8是或当n> 1时，R 8相同或不同，各自为H，卤素，氰基，硝基或取代或未取代的C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4卤代烷基，C 1 -C 4 - 卤代烷氧基，芳基，芳氧基，苄氧基，杂芳基或苯氧基，以及含有这些化合物的作物保护剂。

20. 发明授权

US06187812B1 Phenylacetic acid derivatives, preparation thereof and intermediates therefor, and compositions containing them 失效
标题翻译：苯乙酸衍生物，其制备方法及其中间体，以及含有它们的组合物
公开(公告)号：US06187812B1
公开(公告)日：2001-02-13
申请号：US09497152
申请日：2000-02-03
申请人： Herbert Bayer , Hubert Sauter , Ruth Müller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Röhl , Eberhard Ammermann , Gisela Lorenz
发明人： Herbert Bayer , Hubert Sauter , Ruth Müller , Wassilios Grammenos , Albrecht Harreus , Reinhard Kirstgen , Franz Röhl , Eberhard Ammermann , Gisela Lorenz
IPC分类号： A01N3718
CPC分类号： C07D207/333 , A01N37/50 , A01N37/52 , A01N43/06 , A01N43/36 , A01N43/40 , A01N43/54 , A01N43/80 , A01N43/82 , C07C251/58 , C07C255/11 , C07C327/48 , C07C327/58 , C07D213/53 , C07D213/64 , C07D239/34 , C07D261/08 , C07D263/32 , C07D271/06 , C07D277/24 , C07D307/42
摘要： Phenylacetic acid derivatives of the formula I where the substituents and the index have the following meanings: X is oxygen or sulfur; R is hydrogen or alkyl; R1 is hydrogen or alkyl; R2 is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; m is 0, 1 or 2, it being possible for the R2 radicals to be different if m is 2; R3 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, alkylthio, alkylamino or dialkylamino; R4 is hydrogen, cyano, nitro, hydroxyl, amino, halogen, unsubstituted or substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkynyl, alkynyloxy, alkynylthio, alkynylamino, N-alkynyl-N-alkylamino; unsubstituted or substituted cycloalkyl, cycloalkoxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino, aryl, aryloxy, arylthio, arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetaryl amino, N-hetaryl-N-alkylamino; R5 is hydrogen, unsubstituted or substituted alkyl, cycloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl or alkylsulfonyl; unsubstituted or substituted aryl, arylcarbonyl, arylsulfonyl; hetaryl, hetarylcarbonyl or hetarylsulfonyl, and their salts, processes and intermediates for their preparation, and their use are described.
摘要翻译：式I的苯乙酸衍生物，其中取代基和指数具有以下含义：X是氧或硫; R是氢或烷基; R 1是氢或烷基; R 2是氰基，硝基，三氟甲基，卤素，烷基或烷氧基; m 如果m是2，则R2基团可能不同; R3是氢，氰基，硝基，羟基，氨基，卤素，烷基，卤代烷基，烷氧基，卤代烷氧基，烷硫基，烷基氨基或二烷基氨基; R4是氢，氰基，硝基，羟基，氨基，卤素，未取代或取代的烷基，烷氧基，烷硫基，烷基氨基，二烷基氨基，烯基，烯氧基，烯硫基，烯基氨基，N-烯基-N-烷基氨基，炔基，炔氧基，炔硫基，炔基氨基，N-炔基-N-烷基氨基，未取代或取代的环烷基，环烷氧基，环烷硫基，环烷基氨基，N-环烷基-N-烷基氨基，环烯基，环烯基氧基，环烯基硫基，环烯基氨基，N-环烯基-N-烷基氨基，杂环基，杂环氧基，杂环基硫基，杂种 N-烷基氨基，N-杂环基-N-烷基氨基，芳基，芳氧基，芳硫基，芳基氨基，N-芳基-N-烷基氨基，杂芳基，杂芳氧基，杂芳硫基，杂芳基氨基，N-芳基-N-烷基氨基; R 5为氢，未取代或取代烷基，环烷基，烯基，炔基，烷基羰基，烯基羰基，炔基羰基或烷基磺酰基;未取代或取代的芳基，芳基羰基，芳基磺酰基; 杂芳基，杂芳基羰基或杂芳基磺酰基及其盐，其制备方法和中间体及其用途。

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