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11. 发明授权

US06333145B1 Method for preparing a conductive polythiophene layer at low temperature 有权
标题翻译：在低温下制备导电聚噻吩层的方法
公开(公告)号：US06333145B1
公开(公告)日：2001-12-25
申请号：US09433971
申请日：1999-11-04
申请人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
发明人： Tom Cloots , Johan Loccufier , Frank Louwet , Hieronymus Andriessen
IPC分类号： G03C185
CPC分类号： H01B1/127 , H01G9/028 , H01G11/48 , H01G11/56 , H01L51/5203 , Y02E60/13
摘要： A method for producing a polymeric conductive layer on an object comprising the steps of: providing an aqueous composition containing a polythiophene, a polyanion compound and an aprotic compound with a dielectric constant, &egr;, ≧15, applying said composition to said object forming a layer and drying said layer to form a conductive polymeric layer on said object, characterised in that during said production said object and said layer are kept at a temperature below 100° C. and said conductive polymeric layer has a resistivity of at most 2 k&OHgr;/square.
摘要翻译：一种用于在物体上制备聚合物导电层的方法，包括以下步骤：提供含有聚噻吩，聚阴离子化合物和介质常数εi= 15的非质子化合物的水性组合物，将所述组合物施加到所述物体上形成层和干燥所述层以在所述物体上形成导电聚合物层，其特征在于，在所述生产期间，所述物体和所述层保持在低于100℃的温度，并且所述导电聚合物层具有至多2kOMEGA /平方的电阻率。

12. 发明授权

US5593817A Developing solution and method for developing an exposed silver halide photographic material 失效
公开(公告)号：US5593817A
公开(公告)日：1997-01-14
申请号：US594144
申请日：1996-01-31
申请人： Freddy Henderickx , Ann Verbeeck , Pascal Meeus , Hieronymus Andriessen
发明人： Freddy Henderickx , Ann Verbeeck , Pascal Meeus , Hieronymus Andriessen
IPC分类号： G03C5/29 , G03C5/30 , G03C5/305 , G03C5/31 , G03C5/38 , G03C8/36
CPC分类号： G03C8/365 , G03C5/30 , G03C5/305 , G03C5/31 , G03C5/383
摘要： A photographic developing solution and a method of developing silver halide materials in the said developing solution is disclosed, the said developing solution comprising hydroquinone in an amount from 0 to 30 g per litre, an auxiliary developer, and silver halide complexing agents in an amount from 0 to 50 g per litre, characterized in that said developer further comprisesin amounts from 0.1 to 5 g per litre a compound corresponding to the formula (I), accompanied by charge compensating anions,Z'N.sup.+ --R--N.sup.+ Z" (I)wherein at least divalent group R contains at least one oxyethylene group and wherein Z' and Z", being the same or different, are composed of enough atoms to form a heterocyclic aromatic 5- or 6-ring;andat least 1 g of a compound corresponding to the formula (II), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein each of A, B and D independently represents an oxygen atom or NR.sup.1 ;X represents an oxygen atom, a sulphur atom, NR.sup.2 ; CR.sup.3 R.sup.4 ;C=O; C=NR.sup.5 or C=S;Y represents an oxygen atom, a sulphur atom, NR.sup.'2 ; CR.sup.'3 R.sup.'4 ; C=O, C=NR.sup.'5 or C=S;Z represents an oxygen atom, a sulphur atom, NR.sup."2 ; CR.sup."3 R.sup."4 ; C=O; C=NR.sup."5 or C=S;n equals 0, 1 or 2;each of R.sup.1 to R.sup.5, R.sup.'1 to R.sup.'5 and R.sup."1 to R.sup."5 independently represents hydrogen, alkyl, aralkyl, hydroxyalkyl, carboxyalkyl; alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl or heterocyclyl;and whereinR.sup.3 and R.sup.4, R.sup.'3 and R.sup.'4, R.sup."3 and R.sup."4, may further form together a ring; andwherein in the case that X=CR.sup.3 R.sup.4 and Y=CR.sup.'3 R.sup.'4, R.sup.3 and R.sup.'3 and/or R.sup.4 and R.sup.'4 may form a ring and wherein in the case that Y=CR.sup.'3 R.sup.'4 and Z=CR.sup."3 R.sup."4 with n=1 or 2, R.sup.'3 and R.sup."3 and/or R.sup.'4 and R.sup."4 may form a ring.

13. 发明授权

US08216769B2 Negative working, heat sensitive lithographic printing plate precursor 有权
标题翻译：负工作，热敏平版印刷版前体
公开(公告)号：US08216769B2
公开(公告)日：2012-07-10
申请号：US12300805
申请日：2007-05-22
申请人： Hieronymus Andriessen , Steven Lezy , Hubertus Van Aert , Joan Vermeersch
发明人： Hieronymus Andriessen , Steven Lezy , Hubertus Van Aert , Joan Vermeersch
IPC分类号： G03F7/09 , G03F7/26 , B41N1/08
CPC分类号： B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24 , Y10S430/145
摘要： A heat-sensitive negative-working lithographic printing plate precursor includes a support having a hydrophilic surface or which is provided with a hydrophilic layer and a coating provided thereon, the coating including an image-recording layer which includes hydrophobic thermoplastic polymer particles, a binder, and an infrared absorbing dye; wherein the hydrophobic thermoplastic polymer particles have an average particle diameter, measured by Photon Correlation Spectroscopy, of more than 10 nm and less than 40 nm; the amount of the IR-dye, without taking into account an optional counter ion, is more than 0.80 mg per m2 of the total surface of the thermoplastic polymer particles, measured by Hydrodynamic Fractionation; and the amount of hydrophobic thermoplastic polymer particles relative to the total weight of the ingredients of the imaging layer is at least 60%.
摘要翻译：热敏负性平版印刷版原版包括具有亲水性表面的或具有亲水层的涂层及其上设置的涂层，所述涂层包括图像记录层，该图像记录层包括疏水性热塑性聚合物颗粒，粘合剂，和红外吸收染料; 其中所述疏水热塑性聚合物颗粒具有通过光子相关光谱测量的平均粒径大于10nm且小于40nm; 通过流体力学分级测量，不考虑任选的抗衡离子的IR染料的量大于0.80mg / m 2热塑性聚合物颗粒的总表面; 并且疏水性热塑性聚合物颗粒相对于成像层的成分的总重量的量为至少60％。

14. 发明申请

US20100050895A1 PROCESSLESS LITHOGRAPHIC PRINTING PLATE 审中-公开
标题翻译：无过程印刷版
公开(公告)号：US20100050895A1
公开(公告)日：2010-03-04
申请号：US12439804
申请日：2007-09-06
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： B41N3/00 , B41F1/18 , G03F7/004
CPC分类号： B41C1/1041 , B41N1/006
摘要： According to the present invention a non-ablative, negative-working, heat-sensitive printing plate precursor is disclosed capable of switching from a hydrophilic state into a hydrophobic state upon exposure to heat and/or infrared light. The printing plate precursor is obtainable by the method comprising the step of providing on a support a titanium oxide layer by reactive physical vacuum deposition of titanium, characterised in that said vacuum deposition is carried out under a partial oxygen pressure of 10% or more and less than 25%.
摘要翻译：根据本发明，公开了一种非烧蚀，负性工作的热敏印刷版前体，其能够在暴露于热和/或红外光时从亲水状态转变成疏水状态。通过包括以下步骤的方法可获得印版前体：通过钛的反应物理真空沉积在载体上提供氧化钛层的方法，其特征在于，所述真空沉积在10％或更多或更低的部分氧气压力下进行超过25％。

15. 发明申请

US20100037791A1 METHOD OF MAKING A LITHOGRAPHIC PRINTING PLATE 审中-公开
标题翻译：制作平版印刷版的方法
公开(公告)号：US20100037791A1
公开(公告)日：2010-02-18
申请号：US12530656
申请日：2008-03-06
申请人： Hieronymus Andriessen , Guido Hauquier
发明人： Hieronymus Andriessen , Guido Hauquier
IPC分类号： B41F1/18 , G03F7/00 , B41N3/00
CPC分类号： B41C1/1025 , B41C2201/02 , B41C2201/14 , B41C2210/04 , B41C2210/08 , B41C2210/22 , B41C2210/24
摘要： A method for making a lithographic printing plate including the steps of providing a lithographic printing plate precursor including a heat sensitive image-recording layer, the image-recording layer including hydrophobic thermoplastic particles; image-wise exposing the precursor to infrared radiation having an energy density of 190 mJ/cm2 or less; mounting the exposed precursor on a printing press; developing the mounted precursor by supplying ink and/or fountain; and baking the plate by keeping the plate at a temperature above the glass transition temperature of the thermoplastic particles during a period between 5 seconds and 2 minutes.
摘要翻译：一种制备平版印刷版的方法，包括以下步骤：提供包括热敏图像记录层的平版印刷版原版，所述图像记录层包括疏水性热塑性颗粒; 将前体成像地曝光到能量密度为190mJ / cm 2以下的红外辐射; 将暴露的前体安装在印刷机上; 通过供应墨水和/或喷泉来显影所安装的前体; 并且在5秒至2分钟之间的时间内将板保持在高于热塑性颗粒的玻璃化转变温度的温度下烘烤该板。

16. 发明申请

US20080295720A1 Method For Making A Lithographic Printing Plate 审中-公开
标题翻译：制作平版印刷版的方法
公开(公告)号：US20080295720A1
公开(公告)日：2008-12-04
申请号：US12158084
申请日：2006-12-05
申请人： Emiel Verdonck , Hieronymus Andriessen
发明人： Emiel Verdonck , Hieronymus Andriessen
IPC分类号： B41N3/00
CPC分类号： B41C1/1066
摘要： A method for making a lithographic printing plate includes the steps of a) providing an aqueous fluid containing at least 2 weight % of a fluorosurfactant based on the total weight of the aqueous fluid wherein the fluorosurfactant has a phosphorous containing group capable of reacting with the surface of a lithographic printing plate precursor; and b) jetting the aqueous fluid on the surface of a lithographic printing plate precursor.
摘要翻译：制备平版印刷版的方法包括以下步骤：a）基于水性流体的总重量提供含有至少2重量％的含氟表面活性剂的含水流体，其中含氟表面活性剂具有能够与表面反应的含磷基团的平版印刷版前体; 和b）将水性流体喷射在平版印刷版原版的表面上。

17. 发明授权

US07297462B2 Heat-sensitive lithographic printing plate precursor 有权
标题翻译：热敏平版印刷版前体
公开(公告)号：US07297462B2
公开(公告)日：2007-11-20
申请号：US10987928
申请日：2004-11-12
申请人： Huub Van Aert , Bert Groenendaal , Hieronymus Andriessen , Martin Moeller , Uwe Beginn , Ahmed Mourran
发明人： Huub Van Aert , Bert Groenendaal , Hieronymus Andriessen , Martin Moeller , Uwe Beginn , Ahmed Mourran
IPC分类号： G03F7/00 , G03F7/004
CPC分类号： B41C1/1041 , Y10S430/145 , Y10S430/146
摘要： A heat sensitive lithographic printing plate precursor is disclosed comprising on a support having a hydrophilic surface or which is provided with a hydrophilic layer, a coating comprising an infrared light absorbing agent and a copolymer which comprises a plurality of recurring units X having a hydrophilic polymeric pendant group and a plurality of recurring units Y having a hydrophobic polymeric pendant group. Said coating is capable of switching from a hydrophilic state into a hydrophobic state after exposure to heat and/or infrared light.
摘要翻译：公开了一种热敏平版印刷版原版，其包含在具有亲水性表面的支持体上，或者设置有亲水层，包含红外光吸收剂的涂层和包含多个具有亲水性聚合物侧基的重复单元X的共聚物基团和多个具有疏水性聚合物侧基的重复单元Y。所述涂层能够在暴露于热和/或红外光之后从亲水状态转变成疏水状态。

18. 发明申请

US20050269616A1 Nano-porous metal oxide semiconductor spectrally sensitized with metal oxide chalcogenide nano-particles 审中-公开
标题翻译：用金属氧化物硫族化物纳米粒子光谱增感的纳米多孔金属氧化物半导体
公开(公告)号：US20050269616A1
公开(公告)日：2005-12-08
申请号：US11186440
申请日：2005-07-21
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： B32B9/00 , H01G9/20 , H01L31/00 , H01L31/0352 , H01L31/119
CPC分类号： H01G9/2031 , H01L31/0352 , Y02E10/542
摘要： A nano-porous metal oxide semiconductor with a band-gap of greater than 2.9 eV in-situ spectrally sensitized on its internal and external surface with metal chalcogenide nano-particles with a band-gap of less than 2.9 eV containing at least one metal chalcogenide, wherein the nano-porous metal oxide further contains a phosphoric acid or a phosphate; and a process for in-situ spectral sensitization of nano-porous metal oxide semiconductor with a band-gap of greater than 2.9 eV on its internal and external surface with metal chalcogenide nano-particles with a band-gap of less than 2.9 eV, containing at least one metal chalcogenide, comprising a metal chalcogenide-forming cycle comprising the steps of: contacting nano-porous metal oxide with a solution of metal ions; contacting nano-porous metal oxide with a solution of chalcogenide ions; and subsequent to metal chalcogenide formation rinsing the nano-porous metal oxide with an aqueous solution containing a phosphoric acid or a phosphate.
摘要翻译：具有大于2.9eV的带隙大于2.9eV的纳米多孔金属氧化物半导体在其内部和外部表面上原位光致敏化，其中金属硫族化物纳米颗粒具有小于2.9eV的带隙，其含有至少一种金属硫族化物其中所述纳米多孔金属氧化物还含有磷酸或磷酸盐; 以及具有小于2.9eV的带隙的金属硫属元素化物纳米粒子在其内表面和外表面上具有大于2.9eV的带隙的纳米多孔金属氧化物半导体的现场光谱增感的方法，其包含至少一种金属硫族化物，其包含金属硫族化物形成循环，包括以下步骤：使纳米多孔金属氧化物与金属离子溶液接触; 使纳米多孔金属氧化物与硫属元素离子的溶液接触; 并且在金属硫族化物形成之后，用含磷酸或磷酸盐的水溶液冲洗纳米多孔金属氧化物。

19. 发明申请

US20050042556A1 Process for preparing a substantially transparent conductive layer configuration 失效
标题翻译：制备基本上透明的导电层构型的方法
公开(公告)号：US20050042556A1
公开(公告)日：2005-02-24
申请号：US10645160
申请日：2003-08-21
申请人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
发明人： Frank Louwet , Tom Cloots , Hieronymus Andriessen
IPC分类号： H01B1/12 , H01B1/22 , H01L51/00 , H01L51/30 , H01L51/52 , H05K3/10 , G03C1/46
CPC分类号： H05K3/106 , H01B1/127 , H01B1/22 , H01L51/0021 , H01L51/0037 , H01L51/445 , H01L51/5203 , H05K2201/0329 , Y02E10/549
摘要： A process for preparing a substantially transparent conductive layer configuration on a support, the layer configuration comprising in any order at least a first layer containing an intrinsically conductive polymer optionally containing structural units represented by formula (I): wherein n is larger than 1 and each of R1 and R2 independently represents hydrogen or an optionally substituted C1-4 alkyl group or together represent an optionally substituted C1-4 alkylene group or an optionally substituted cycloalkylene group, preferably an ethylene group, an optionally alkyl-substituted methylene group, an optionally C1-12 alkyl- or phenyl-substituted ethylene group, a 1,3-propylene group or a 1,2-cyclohexylene group; and a second layer consisting of a non-continuous layer of conductive silver, the process comprising the step of: preparing the second layer by a photographic process; and light emitting diodes, photovoltaic devices, transistors and electroluminescent devices comprising a layer configuration prepared according to this process.
摘要翻译：一种用于在载体上制备基本上透明的导电层构型的方法，所述层构型至少包含含有本发明的导电聚合物的第一层，所述固有导电聚合物任选含有由式（I）表示的结构单元：其中n大于1， R 1和R 2独立地表示氢或任选取代的C 1-4烷基或一起表示任选取代的C 1-4亚烷基或任选取代的亚环烷基，优选亚乙基，任选烷基取代的亚甲基，任选的C 1-12烷基或苯基取代的亚乙基，1,3-亚丙基或1,2-亚环己基; 以及由不连续的导电银层组成的第二层，该方法包括以下步骤：通过摄影法制备第二层; 以及发光二极管，光电器件，晶体管和电致发光器件，其包括根据该工艺制备的层构型。

20. 发明授权

US06724141B2 Particular type of a thin layer inorganic light emitting device 失效
标题翻译：特定类型的薄层无机发光器件
公开(公告)号：US06724141B2
公开(公告)日：2004-04-20
申请号：US10264201
申请日：2002-10-03
申请人： Hieronymus Andriessen
发明人： Hieronymus Andriessen
IPC分类号： H01J162
CPC分类号： H05B33/14 , C09K11/025 , C09K11/565 , H01L33/08 , H01L33/18 , H01L33/28 , H05B33/26
摘要： A Thin Layer Inorganic Light Emitting device is disclosed comprising a substrate, a first electrode, a coated layer comprising substantially undoped zinc sulfide nanoparticles, and a second electrode. On applying a voltage between the two electrodes the device emits light with an emission maximum of electroluminescence at a wavelength above 450 nm.
摘要翻译：公开了薄层无机发光器件，其包括基底，第一电极，包含基本上未掺杂的硫化锌纳米颗粒的涂层和第二电极。在两个电极之间施加电压时，该装置发射具有在450nm以上波长处的电致发光的发射最大值。

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