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11. 发明授权

US4732903A Certain cyclopropyl dicarboxylates having pesticidal and insecticidal activity 失效
标题翻译：某些具有杀虫活性和杀虫活性的环丙基二羧酸酯
公开(公告)号：US4732903A
公开(公告)日：1988-03-22
申请号：US756396
申请日：1985-07-17
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： A01N53/00 , A23K1/16 , A61K31/22 , C07D209/48 , C07D213/64 , C07D213/647 , C07D233/72 , C07D307/20 , C07D307/45 , C07D309/12 , C07D213/55 , A01N43/40 , C07C69/743 , C07C121/75
CPC分类号： C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A23K20/132 , A61K31/22 , C07D209/48 , C07D233/72 , C07D307/20 , C07D307/42 , C07D309/12
摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of wherein B is selected from the group consisting of --CH.sub.2 --, ##STR2## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3,--C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer from 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR3## wherein R.sub.13 is selected from the group consisting of hydrogen and ##STR4## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position, ##STR5## wherein R.sub.14 is selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR6## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3, 3,4-methylenedioxy, chlorine, bromine and fluorine B' is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.
摘要翻译：环丙烷羧酸衍生物与式（I）所示的3-不饱和侧链的新颖异构体及其混合物，其中A'选自由下列组成的组：其中B选自： -CH 2 - ， -O-和-S-，R 4选自氢，-CH 3，-C 3BOND N CONH 2，-CSNH 2和-C 3 CH 3，n是0的整数，（3）其中R 13选自氢和（4）其中R 13具有上述基团，其中R 13选自氢和（14）其中R 14选自氢，甲基，乙炔基和-CN，R 15和R 16分别选自氢，，溴和氟，并且其中R 14具有上述定义，p为0,1或2，每个R 17选自1至4个碳原子的烷基 1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基磺酰基，-CF 3，3,4-亚甲二氧基，氯，溴和氟B'选自： -O-和-S-，并且R选自被一个或多个任选不同的官能团取代的1至18个碳原子的烷基，任选被一个或多个任选不同的官能团取代的6至14个碳原子的芳基组，具有Z或E几何形状的双键具有杀虫和杀线虫活性以及植物和动物杀螨活性及其制备。

12. 发明授权

US4658043A Ethers of pantolactone 失效
标题翻译：泛酸内酯醚
公开(公告)号：US4658043A
公开(公告)日：1987-04-14
申请号：US745653
申请日：1985-06-17
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： B01J31/02 , C07B31/00 , C07B57/00 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/88 , C07C37/86 , C07C41/18 , C07C43/295 , C07C45/57 , C07C51/487 , C07C62/02 , C07C62/04 , C07C67/00 , C07D307/33 , C07D307/88 , C07D307/93 , C07D315/00
CPC分类号： C07D307/33 , C07C29/10 , C07C41/26 , C07C43/295 , C07C45/57 , C07D307/93 , C07D315/00 , C07B2200/07 , C07C2101/14
摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and a substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.
摘要翻译：含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以呈现手性，这是由于整个分子的不对称空间结构和Z 选自至少含有不对称碳原子的伯醇，仲醇或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和取代的醇或苯酚部分具有由于不对称空间构型引起的手性整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，它们可用于共沉淀式II或ZOH III的化合物，其中A和Z具有上述定义，X选自氢和1至4个碳原子的烷基。

13. 发明授权

US4356187A Novel esters of 2-methyl-3-allyl-4-substituted-cyclopent-2-ene-1-yl 失效
公开(公告)号：US4356187A
公开(公告)日：1982-10-26
申请号：US141201
申请日：1980-04-17
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07C69/013 , A01N37/10 , A01N37/18 , A01N37/34 , A01N53/00 , A01N53/02 , A01N53/10 , A23K1/16 , C07C29/09 , C07C29/32 , C07C45/66 , C07C45/72 , C07C49/24 , C07C61/35 , C07C62/38 , C07C67/00 , C07C231/00 , C07C231/02 , C07C231/12 , C07C235/30 , C07C235/34 , C07C253/00 , C07C255/31 , C07C313/00 , C07C323/62 , C07D307/58 , C07D333/32 , C07F9/54 , C07C121/48 , A01N37/08 , C07C69/743 , C07C121/66
CPC分类号： C07D333/32 , A01N53/00 , C07C29/095 , C07C29/32 , C07C45/66 , C07C45/72 , C07C49/24 , C07C61/35 , C07C62/38 , C07D307/58 , C07F9/5407 , C07B2200/07 , C07B2200/09 , C07C2101/10
摘要： Novel esters of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of carbamoyl and R.sub.1 ' and R.sub.2 ', R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, aralkyl of 7 to 13 carbon atoms, alkoxycarbonyl of 2 to 5 carbon atoms and --CN, R.sub.3 and R.sub.3 ' are individually selected from the group consisting of hydrogen, halogen, alkenyl of 2 to 3 carbon atoms and alkyl of 1 to 3 carbon atoms, Y' is selected from the group consisting of ##STR2## R.sub.4 ' and R.sub.5 ' are individually selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms, fluorine, bromine, chlorine and R.sub.4 ' and R.sub.5 ' together with the carbon atom to which they are attached form an optionally unsaturated hydrocarbon ring or heterocycle of 3 to 7 chain members and a heterocycle of the formula X is selected from the group consisting of sulfur and oxygen or R.sub.4 ' is cyano and R.sub.5 ' is phenyl or R.sub.4 ' is hydrogen and R.sub.5 ' is selected from the group consisting of cyano, ##STR3## AlK is alkyl of 1 to 4 carbon atoms, the double bond in the 1- position of the vinyl side chain of formula (A) having (E) or (Z) configuration, R.sub.6 is selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms and alkoxycarbonyl of 2 to 5 carbon atoms, the substituents on the cyclopropane ring of formula (A) and (C) have the cis or trans, racemic or optically active configuration, Z.sub.1 is alkyl of 1 to 4 carbon atoms, Z.sub.2, Z.sub.3 and Z.sub.4 are individually selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms and halogen and the asymetric carbon of formula (D) may be (S) or (R) configuration or a racemic mixture thereof and the carbon atom in the 1- position of the alcohol moiety may have (R), (S) or racemic configuration having insecticidal properties and their preparations.

14. 发明授权

US4350637A Substituted lactones of amino acids 失效
标题翻译：取代的氨基酸内酯
公开(公告)号：US4350637A
公开(公告)日：1982-09-21
申请号：US212569
申请日：1980-12-03
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07D307/33 , C07D207/16 , C07D307/93 , C07D307/77 , C07D307/32 , C07D309/30
CPC分类号： C07D207/16
摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of: ##STR2## wherein Z is the organic remainder of an amino acid of the formula: ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y-OH and B is the remainder of a heterocycle amino acid of 3 to 6 carbon atoms of the formula: ##STR4## and their preparation and their use for the resolution of amino acids.
摘要翻译：新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自其中Z是下式的氨基酸的有机剩余物：III1Y衍生自式Y-OH的伯，仲或叔醇，B是杂环氨基酸的剩余部分 3至6个碳原子的结构式：它们的制备及其用于分解氨基酸的用途。

15. 发明授权

US4833163A Novel cyclopropane carboxylic acid derivatives 失效
标题翻译：新型环丙烷羧酸衍生物
公开(公告)号：US4833163A
公开(公告)日：1989-05-23
申请号：US120869
申请日：1987-11-16
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： A01N53/00 , A01N53/06 , C07C43/295 , C07C45/00 , C07C49/84 , C07D209/08 , C07D213/64 , C07D213/647 , C07D213/68 , C07D261/08 , C07F3/02 , C07F5/06
CPC分类号： C07D213/647 , A01N53/00 , C07C43/295 , C07C45/004 , C07C49/84 , C07D209/08 , C07D213/68 , C07D261/08 , C07F3/02 , C07F5/069
摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of Z geometry of the formula ##STR1## wherein A' is ##STR2## wherein R.sub.13 is selected from the group consisting of hydrogen and CN and R is an optionally unsaturated alkyl of 1 to 18 carbon atoms having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.
摘要翻译：环丙烷羧酸衍生物与式III'的三维不饱和侧链的新颖异构体及其混合物，其中A'为其中R 13选自氢和CN，R为具有1至18个碳原子的任选不饱和的烷基具有杀虫和杀线虫活性以及植物和动物杀螨活性及其制备。

16. 发明授权

US4542142A Insecticidal cyclopropane carboxylic acid derivatives with 3-unsaturated-side chain 失效
标题翻译：具有3-不饱和侧链的杀虫环丙烷羧酸衍生物
公开(公告)号：US4542142A
公开(公告)日：1985-09-17
申请号：US550081
申请日：1983-11-08
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： A01N53/00 , A23K1/16 , A61K31/22 , C07D209/48 , C07D213/64 , C07D213/647 , C07D233/72 , C07D307/20 , C07D307/45 , C07D309/12 , C07D213/55 , A01N43/40 , C07C121/75
CPC分类号： C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A23K20/132 , A61K31/22 , C07D209/48 , C07D233/72 , C07D307/20 , C07D307/42 , C07D309/12
摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## The double bond having Z or E geometry and having insecticidal and nematocidal activity as well as plant and animal acaricidal activity.
摘要翻译：环丙烷羧酸衍生物与式III的不饱和侧链的新异构体及其混合物具有Z或E几何形状并具有杀虫和杀线虫活性以及植物和动物杀螨活性的双键。

17. 发明授权

US4489093A Insecticidal esters 失效
标题翻译：杀虫剂
公开(公告)号：US4489093A
公开(公告)日：1984-12-18
申请号：US495481
申请日：1983-05-17
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： A01N53/00 , A01N53/02 , A23K1/16 , A61K31/22 , A61K31/225 , C07D213/64 , C07D213/647 , C07D233/74 , C07F9/40 , C07C69/743 , C07C121/75
CPC分类号： C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A61K31/22 , A61K31/225 , C07D233/74 , C07F9/4006
摘要： Novel esters in all possible isomeric forms of the formula ##STR1## wherein R is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkyl-alkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, ##STR2## aryl optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, ##STR3## R' is alkyl of 1 to 8 carbon atoms, R" and R"' are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substituent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, B is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms and the remainder of an alcohol used in synthesis of pyrethrinoid esters, X is halogen and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal acaricidal and nematocidal activity.
摘要翻译：式（Ⅰ）的所有可能异构体形式的新型酯，其中R选自（a）1-8个碳原子的任选不饱和烷基和任选不饱和的环烷基或3-8个碳原子的环烷基 - 烷基，被至少一个由以下组成的组中的至少一个取代：卤素，任选被至少一个由以下组成的组中的一个基团取代：-OH，含有1-8个碳原子的烷氧基， 1至8个碳原子，卤素，R'是1至8个碳原子的烷基，R“和R”'分别选自氢和1至8个碳原子的烷基，AlK1， AlK 2和AlK 3分别是1至18个碳原子的烷基（b）任选被至少一个选自-OH，1至8个碳原子的烷氧基，1至8个碳原子的烷基取代的6至14个碳原子的芳基， 8个碳原子，卤素，-OCF 3，-CF 3和-SCF 3和（c）任选的杂环由至少一个由-OH组成的基团，1至8个碳原子的烷氧基，1至8个碳原子的烷基，卤素，-CF 3，-OCF 3和-SCF 3，B选自任选的具有1至18个碳原子的不饱和烷基，3至18个碳原子的任选不饱和环烷基和用于合成除虫菊酯的醇的其余部分，X是卤素，烯键双键可具有具有寄生活性的Z或E几何形状，特别是杀虫杀螨和杀线虫活性。

18. 发明授权

US4434294A Preparation of .alpha.-cyano-phenoxy-benzyl esters 失效
标题翻译： α-氰基 - 苯氧基 - 苄基酯的制备
公开(公告)号：US4434294A
公开(公告)日：1984-02-28
申请号：US307690
申请日：1981-10-01
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07C255/39 , A01N53/00 , C07C67/00 , C07C213/00 , C07C253/00 , C07D333/32 , C07C121/75 , C07D307/20
CPC分类号： A01N53/00
摘要： Novel imino derivatives of esters of 3-formyl-cyclopropane-1-carboxylic acids in their various isomeric forms and mixtures thereof of the formula ##STR1## wherein Z is an organic residue of a primary amine of the formula Z--NH.sub.2 and the acid moiety may have the cis or trans configuration and the alcohol moiety may have the R,S or RS configuration, novel intermediates therefore and a process for the preparation of the corresponding 3-substituted vinyl esters having insecticidal activity.
摘要翻译： 3-甲酰基 - 环丙烷-1-羧酸酯的各种异构体形式的新颖的亚氨基衍生物及其混合物，其中Z是式Z-NH 2的伯胺和酸的有机残基部分可以具有顺式或反式构型，并且醇部分可以具有R，S或RS构型，因此是新的中间体，以及制备相应的具有杀虫活性的3-取代乙烯基酯的方法。

19. 发明授权

US4304733A Novel allethrolone derivatives 失效
标题翻译：新型氢溴酸衍生物
公开(公告)号：US4304733A
公开(公告)日：1981-12-08
申请号：US141200
申请日：1980-04-17
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07C69/732 , A01N31/06 , A01N37/18 , A01N37/34 , A01N37/36 , A01N53/00 , C07C27/00 , C07C29/09 , C07C29/10 , C07C29/12 , C07C29/32 , C07C35/06 , C07C35/21 , C07C35/48 , C07C67/00 , C07C235/30 , C07C235/34 , C07C253/00 , C07C255/31 , C07C121/48 , A01N37/08 , C07C69/74
CPC分类号： C07C35/21 , A01N53/00 , C07C29/095 , C07C29/32 , C07C35/06 , C07C35/48 , C07B2200/07 , C07B2200/09 , C07C2101/10
摘要： Novel alcohols of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of carbamoyl and R.sub.1 ' and R.sub.2 ', R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, arylalkyl of 7 to 13 carbon atoms, alkoxycarbonyl of 2 to 5 carbon atoms and --CN and R.sub.3 and R.sub.3 ' are individually selected from the group consisting of hydrogen, alkyl of 1 to 3 carbon atoms and alkenyl of 2 to 3 carbon atoms in the S form, R form or racemic mixtures thereof whose esters with cyclopropane carboxylic acids have an elevated insecticidal activity and their preparation.
摘要翻译：式（Ⅰ）的新型醇，其中R1和R2分别选自氨基甲酰基和R1'，R2'，R1'和R2'分别选自氢，卤素，1〜 6个碳原子的芳基，6至10个碳原子的芳基，7至13个碳原子的芳烷基，2至5个碳原子的烷氧基羰基和-CN，R3和R3'分别选自氢，1至3的烷基碳原子和2至3个碳原子的链烯基，R形式或其外消旋混合物，其酯与环丙烷羧酸具有提高的杀虫活性及其制备。

20. 发明授权

US4303585A 3-Oxa-bicyclo (3,1,0)-hexan-2-one intermediates 失效
标题翻译： 3-氧杂双环（3,1,0） - 己烷-2-酮中间体
公开(公告)号：US4303585A
公开(公告)日：1981-12-01
申请号：US232118
申请日：1981-02-06
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N37/34 , A01N37/10 , A01N37/38 , A01N53/08 , A01P7/04 , C07B57/00 , C07C57/58 , C07C67/00 , C07C253/00 , C07C253/30 , C07C253/34 , C07C255/33 , C07C255/36 , C07C255/37 , C07C255/39 , C07C255/53 , C07D307/93
CPC分类号： C07D307/93 , A01N37/38 , C07C255/00 , C07C255/53 , C07C57/58
摘要： (S) .alpha.-cyano-3-phenoxy-benzyl alcohol having the formula ##STR1## and a novel process for its preparation and novel intermediates.
摘要翻译：（S）具有式“IMAGE”I的α-氰基-3-苯氧基 - 苄醇和其制备新颖的方法和新型中间体。

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