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11. 发明授权

US4024172A Preparation of prostanoic acid derivatives 失效
标题翻译：前列腺酸衍生物的制备
公开(公告)号：US4024172A
公开(公告)日：1977-05-17
申请号：US176234
申请日：1971-08-30
申请人： Jacques Martel , Jean Buendia , Edmond Toromanoff
发明人： Jacques Martel , Jean Buendia , Edmond Toromanoff
IPC分类号： C07C61/06 , C07C69/74 , C07C405/00 , C07D303/42 , C07D309/12 , C07D521/00 , C07C177/00
CPC分类号： C07D231/12 , C07C405/00 , C07D233/56 , C07D249/08 , C07D303/42 , C07D309/12
摘要： A novel process for the preparation of derivatives of prostanoic acids of the prostaglandin A.sub.2 (PGA.sub.2) group of the formula ##STR1## wherein R is selected from the group consisting of hydrogen and lower alkyl, n is a whole number of 2, 3 or 4 and m is a whole number of 3, 4 or 5 and to novel intermediates produced in the said process.
摘要翻译：用于制备式IMA的前列腺素A2（PGA2）组的前列腺酸衍生物的新方法，其中R选自氢和低级烷基，n是整数2,3或 4和m是3,4或5的整数，以及在所述方法中生产的新型中间体。

12. 发明授权

US5136050A Process for resolving amino acids using substituted lactones 失效
标题翻译：使用取代的内酯拆分氨基酸的方法
公开(公告)号：US5136050A
公开(公告)日：1992-08-04
申请号：US154799
申请日：1988-02-11
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07D207/16
CPC分类号： C07D207/16
摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y-OH and B is the remainder of a heterocycle amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.
摘要翻译：新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自其中Z是下式的氨基酸的有机剩余部分III1衍生自式Y-OH的伯，仲或叔醇，B是其余的具有式（III）III2的3至6个碳原子的杂环氨基酸及其制备及其在分解氨基酸中的用途。

13. 发明授权

US4883806A Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity 失效
公开(公告)号：US4883806A
公开(公告)日：1989-11-28
申请号：US100284
申请日：1987-09-23
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： A01N53/00 , A23K1/16 , A61K31/22 , C07D209/48 , C07D213/64 , C07D213/647 , C07D233/72 , C07D307/20 , C07D307/45 , C07D309/12
CPC分类号： C07D213/647 , A01N53/00 , A23K20/105 , A23K20/111 , A23K20/132 , A61K31/22 , C07D209/48 , C07D233/72 , C07D307/20 , C07D307/42 , C07D309/12
摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of (1) alkyl of 1 to 18 carbon atoms, (2) benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy or halogen, ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen and methyl and R.sub.2 is selected from the group consisting of --CH.sub.2 --C.tbd.CH and monocyclic aryl, ##STR3## wherein a is selected from the group consisting of hydrogen and methyl and R.sub.3 is an aliphatic group of 2 to 6 carbon atoms containing at least one carbon-carbon unsaturation ##STR4## wherein a and and R.sub.3 have the above definition and R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, cyano and alkoxy carbonyl of 2 to 5 carbon atoms, (6) ##STR5## wherein B is selected from the group consisting of ##STR6## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3, --C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer form 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR7## wherein R.sub.6, R.sub.7 , R.sub.8 and R.sub.9 are selected from the group consisting of hydrogen, chlorine and methyl and S/I symbolizes an aromatic ring or dihydro or tetrahydro ring, ##STR8## wherein R.sub.10 is selected from the group consisting of hydrogen and --CN, R.sub.12 is selected from the group consisting of --CH.sub.2 -- and --O-- and R.sub.11 is selected from the group consisting of thiazolyl and thiadiazolyl with the bond the bond to ##STR9## being in anyone of the positions, R.sub.12 being bonded to R.sub.11 by the carbon atom included between a sulfur atom and a nitrogen atom, ##STR10## wherein R.sub.13 is selected from the group consisting of hydrogen and --CN ##STR11## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position; ##STR12## wherein R.sub.14 is; selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR13## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3 3,4-methylenedioxy, chlorine, bromine and fluorine, B is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.

14. 发明授权

US4556732A Pentenoic acid and its preparation 失效
标题翻译：戊烯酸及其制备方法
公开(公告)号：US4556732A
公开(公告)日：1985-12-03
申请号：US153338
申请日：1980-05-27
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/73 , A01N43/08 , C07C51/00 , C07C51/09 , C07C59/74 , C07C67/00 , C07D307/33 , C07D307/93 , C07F9/655
CPC分类号： C07D307/33 , C07C59/74 , C07D307/93
摘要： Novel 3-formyl-4-methyl-pent-3-ene-1-oic acid of the formula ##STR1## and a process for its preparation and intermediates and a process for the preparation of compounds of the formula ##STR2## wherein W is selected from the group consisting of hydrogen and R.sub.1 of an optionally chiral alcohol R.sub.1 OH, useful as an intermediate for the production of numerous esters having elevated insecticidal activity.
摘要翻译：具有下式的新颖的3-甲酰基-4-甲基 - 戊-3-烯-1-酸及其制备方法和中间体以及制备式（VI）的化合物的方法其中 W选自氢和任选的手性醇R 1 OH的R 1，其可用作生产具有高杀虫活性的许多酯的中间体。

15. 发明授权

US4540797A Process for resolution of chiral alcohols or phenols or chiral lactonic compounds 失效
标题翻译：手性醇或酚或手性内酯化合物的拆分方法
公开(公告)号：US4540797A
公开(公告)日：1985-09-10
申请号：US447442
申请日：1982-12-06
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： B01J31/02 , C07B31/00 , C07B57/00 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/88 , C07C37/86 , C07C41/18 , C07C43/295 , C07C45/57 , C07C51/487 , C07C62/02 , C07C62/04 , C07C67/00 , C07D307/33 , C07D307/88 , C07D307/93 , C07D315/00 , C07D307/77
CPC分类号： C07D307/33 , C07C29/10 , C07C41/26 , C07C43/295 , C07C45/57 , C07D307/93 , C07D315/00 , C07B2200/07 , C07C2101/14
摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymmetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymmetric carbon atom, a phenol moiety substituted comprising at least one asymmetric carbon atom and a substituted alcohol or phenol moiety with a chirality due to the dissymmetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.
摘要翻译：含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以由于整个分子和Z的不对称空间构型而呈现手性选自含有至少不对称碳原子的伯，仲或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和具有由于不对称空间构型引起的手性的取代的醇或苯酚部分整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，它们对分辨率o有用 f化合物，其中A和Z具有上述定义，X选自氢和1至4个碳原子的烷基。

16. 发明授权

US4501704A Aromatic sulfonyl alkanoates and alkylnitriles 失效
标题翻译：芳族磺酰基链烷酸酯和烷基腈
公开(公告)号：US4501704A
公开(公告)日：1985-02-26
申请号：US479163
申请日：1983-03-28
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/74 , C07C51/00 , C07C61/04 , C07C61/125 , C07C67/00 , C07C253/00 , C07C255/46 , C07C313/00 , C07C315/04 , C07C317/44 , C07C121/66 , C07C147/107
CPC分类号： C07C317/44
摘要： A process for the preparation of tetrasubstituted novel compounds of the formula ##STR1## wherein Y' is selected from the group consisting of --CN and --COOR, R is alkyl of 1 to 6 carbon atoms and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are individually selected from alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 together with the carbon atoms to which they are attached form a carbon homocycle of 3 to 6 carbon atoms with the 2 substituents not forming the ring being alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 on the one hand and R.sub.3 and R.sub.4 on the other together with the carbon atom to which they are attached form a carbon homocycle of 3 to 6 carbon atoms and Z is an aromatic group which are useful intermediates for the preparation of insecticidal esters.
摘要翻译：制备式“IMAGE”的四取代新化合物的方法，其中Y'选自-CN和-COOR，R为1至6个碳原子的烷基，R 1，R 2，R 3和R 4分别为选自1至4个碳原子的烷基或R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成3至6个碳原子的碳均碳原子，2个取代基不形成环，为1至 4个碳原子，一方面是R 1和R 2，另一方面是R 3和R 4与它们所连接的碳原子一起形成3至6个碳原子的碳原子，Z是芳族基团，它们是杀虫剂的制备。

17. 发明授权

US4443617A Process for the preparation of derivatives of 6,6-dimethyl-4-hydroxy-3-oxabicyclo-[3,1,0]-hexan-2-one 失效
标题翻译：制备6,6-二甲基-4-羟基-3-氧杂双环 - [3,1,0] - 己烷-2-酮的衍生物的方法
公开(公告)号：US4443617A
公开(公告)日：1984-04-17
申请号：US394457
申请日：1982-07-01
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/73 , A01N43/08 , C07C51/00 , C07C51/09 , C07C59/74 , C07C67/00 , C07D307/33 , C07D307/93 , C07F9/655
CPC分类号： C07D307/33 , C07C59/74 , C07D307/93
摘要： Novel 3-formyl-4-methyl-pent-3-ene-1-oic acid of the formula ##STR1## and a process for its preparation and intermediates and a process for the preparation of compounds of the formula ##STR2## wherein W is selected from the group consisting of hydrogen and R.sub.1 of an optionally chiral alcohol R.sub.1 OH, useful as an intermediate for the producton of numerous ester having elevated insecticidal activity.
摘要翻译：具有下式的新颖的3-甲酰基-4-甲基 - 戊-3-烯-1-酸及其制备方法和中间体以及制备式（VI）的化合物的方法其中 W选自氢和任选的手性醇R 1 R的R 1，其可用作具有高杀虫活性的多种酯的产物的中间体。

18. 发明授权

US4412069A Process for preparing cyclopropane carboxylic acid derivatives 失效
标题翻译：制备环丙烷羧酸衍生物的方法
公开(公告)号：US4412069A
公开(公告)日：1983-10-25
申请号：US58273
申请日：1979-07-17
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07D305/12 , C07D307/58 , C07D309/32 , C07D331/04 , C07D333/32 , C07D335/02 , C09B23/00
CPC分类号： C07D305/12 , C07D307/58 , C07D309/32 , C07D331/04 , C07D333/32 , C07D335/02
摘要： A novel process for the preparation of a compound of the formula ##STR1## wherein X is selected from the group consisting of oxygen and sulfur and n is 1,2 or 3 comprising reacting in an organic solvent in the presence of a strong base the lactone of cis 2,2-dimethyl-3S-(dihydroxymethyl)-cyclopropane-1R-carboxylic acid with a compound of the formula ##STR2## to obtain a compound of the formula ##STR3## reacting the latter with an acid agent in an apolar organic solvent to obtain a compound of the formula ##STR4## and reacting the latter with a basic agent in an apolar organic solvent to obtain a compound of formula I useful for the preparation of insecticidal esters and the novel compounds of formula I wherein n is 1 or 3.
摘要翻译：一种制备式I化合物的新方法，其中X选自氧和硫，n为1,2或3，包括在强碱存在下在有机溶剂中反应，顺式2,2-二甲基-3S-（二羟甲基） - 环丙烷-1R-羧酸的内酯与式III的化合物反应，得到下式的化合物，其中IV与式非极性有机溶剂，以获得下式化合物，并使其与非极性有机溶剂中的碱性试剂反应，得到可用于制备杀虫剂的式I化合物和式I的新化合物，其中n 是1或3。

19. 发明授权

US4402972A Cyclopropane carboxylic acid derivatives 失效
标题翻译：环丙烷羧酸衍生物
公开(公告)号：US4402972A
公开(公告)日：1983-09-06
申请号：US254537
申请日：1981-04-15
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： C07C253/00 , A01N53/00 , A01N53/06 , A01N53/08 , A23K1/16 , A61K31/275 , A61P17/00 , A61P33/00 , C07C51/377 , C07C67/00 , C07C67/08 , C07C69/00 , C07C69/608 , C07C69/74 , C07C69/743 , C07C253/30 , C07C255/39 , C07C255/40 , C07C121/66
CPC分类号： A01N53/00 , A23K20/111
摘要： Novel cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein A is selected from the group consisting of --O--, --CH.sub.2 -- and ##STR2## R is selected from the group consisting of alkyl of 1 to 8 carbon atoms, alkenyl and alkynyl of 2 to 8 carbon atoms and optionally unsaturated cycloalkyl and cycloalkylalkyl of 3 to 8 carbon atoms optionally substituted with at least one alkyl group and the double bond in the 3-side chain has the Z geometry in all possible stereoisomeric forms and mixtures of stereoisomers having insecticidal, nematocidal and animal and vegetable acaricidal activities and their preparation.
摘要翻译：式（Ⅰ）的新型环丙烷羧酸衍生物，其中A选自-O + 13，-CH 2 - 和R 3选自1至8个碳原子的烷基，烯基 2至8个碳原子的炔基和任选被至少一个烷基取代的3至8个碳原子的不饱和环烷基和环烷基烷基，并且3侧链中的双键具有所有可能的立体异构形式的Z几何形式和具有杀虫，杀线虫和动植物杀螨活性的立体异构体及其制备。

20. 发明授权

US4283727A Separable microwave coupling and antenna using same 失效
标题翻译：可分离的微波耦合和天线使用相同
公开(公告)号：US4283727A
公开(公告)日：1981-08-11
申请号：US4985
申请日：1979-01-19
申请人： Jacques Martel , Roger Famin
发明人： Jacques Martel , Roger Famin
IPC分类号： H01P1/06 , H01Q1/34
CPC分类号： H01P1/061
摘要： A transmission path between a source of microwaves, such as a radar transceiver, and a load rectilinearly movable with reference thereto, such as an aerial mounted on a retractable mast of a submarine periscope, comprises two relatively movable parallel waveguides respectively connected to a pair of coaxial ancillary guide portions with mating extremities which are separated from each other in one relative position and are interfitted in another relative position of the source and the load. The male guide portion is externally grooved to form microwave chokes whose effect is enhanced by a peripheral layer of energy-absorbent coating disposed beyond these chokes as seen from the female guide portion. The main waveguides may be coaxial with the interfitting guide portions or may extend parallel thereto and be connected to them by respective elbows.
摘要翻译：诸如雷达收发器之类的微波源之间的传输路径以及可参照其直线运动的负载，诸如安装在海底潜望镜的可伸缩桅杆上的天线，包括两个相对移动的平行波导，分别连接到一对同轴辅助引导部分具有配合的四肢，它们在一个相对位置上彼此分离，并且与源极和负载的另一个相对位置相互配合。阳引导部分是外槽形成微波扼流圈，其效果通过设置在这些扼流圈之外的能量吸收涂层的外围层增强，从阴引导部分看。主波导可以与相互配合的引导部分同轴，或者可以与其平行延伸并且通过相应的弯头连接到它们。

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